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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Cyclic Topology Enhancing Structural Ordering and Stability of Comb-Shaped Polypeptoid Thin Films against Melt-Induced Dewetting

We investigated the effect of cyclic chain topology on the molecular ordering and thermal stability of comb-shaped polypeptoid thin films on silicon (Si) substrates. Cyclic and linear poly(N-decylglycine) (PNDG) bearing long n-decyl side chains were synthesized by ring-opening polymerization of N-decylglycine-derived N-carboxyanhydrides. When the spin-coated thin films were subjected to thermal annealing at temperatures above the melting temperature (T > T m ), the cyclic PNDG films exhibited significantly enhanced stability against melt-induced dewetting than the linear counterparts (l-PNDG). When recrystallized at temperatures below the crystallization temperature (T < T c ), the homogeneous c-PNDG films exhibit enhanced crystalline ordering relative to the macroscopically dewetted l-PNDG films. Both cyclic and linear PNDG molecules adopt cis-amide conformations in the crystalline film, which transition into trans-amide conformations upon melting. A top-down solvent leaching treatment of both l/c-PNDG films revealed the formation of an irreversibly physisorbed monolayer with similar thickness (ca. 3 nm) on the Si substrate. The physisorbed monolayers are more disordered relative to the respective thicker crystalline films for both cyclic and linear PNDGs. Upon heating above T m , the adsorbed c-PNDG chains adopt trans-amide backbone conformation identical with the free c-PNDG molecules in the molten film. By contrast, the backbone conformations of l-PNDG chains in the adsorbed layers are notably different from those of the free chains in the molten film. We postulate that the conformational disparity between the chains in the physically adsorbed layers versus the free chains in the molten film is an important factor to account for the difference in the thermal stability of PNDG thin films. These findings highlight the use of cyclic chain topology to suppress the melt-induced dewetting in polymer thin films.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Coronal closed structures. IV - Hydrodynamical stability and response to heating perturbations

The response of magnetically confined atmospheres to perturbations in the temperature and density distribution, and the local heating rate by means of a one-dimensional time-dependent hydrodynamical code, which incorporates the full energy, momentum and mass conservation equations is studied. These studies extend the linear instability analysis of Habbal and Rosner (1979) into the finite-amplitude regime, and generalize the confined atmosphere models of Serio et al., to the time-dependent domain. The results show that closed coronal atmospheres are stable against finite-amplitude perturbations if the chromospheric response is taken into account; and observed correlated increases in coronal density and temperature can only be achieved under quiescent conditions by increasing the heat deposition rate relatively more in the chromosphere than in the corona.

Peres, G.↗
NASA NTRS1985

Vibrational Stabilization of Flexible Structures

It has been demonstrated that a high frequency excitation (HFE) field significantly changes the fundamental properties of mechanical systems. The most important contribution of HFE is the stiffening effect of an elastic continuum in the direction of the wave vector. This effect allows control of stiffness in any selected direction by the corresponding changes in the intensity of HFE. This new approach can be effective for large flexible space structures. Such an approach may prove to be very practical in the sense that large structures need to be made as flimsy as possible for low cost under ordinary situations. However, for certain operations such as development, orbital transfer, docking, and other circumstances, it would be vital to have a means of temporarily stiffening certain structural members. If the structure was designed to meet these occasional loads without temporary stiffening, it would be considerably more massive and more expensive.

Zak, M.↗