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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

High-frequency thermal-electrical cycles for pyroelectric energy conversion

We report thermal to electrical energy conversion from a 150 nm thick BaTiO{sub 3} film using pyroelectric cycles at 1 kHz. A microfabricated platform enables temperature and electric field control with temporal resolution near 1 μs. The rapid electric field changes as high as 11 × 10{sup 5 }kV/cm-s, and temperature change rates as high as 6 × 10{sup 5 }K/s allow exploration of pyroelectric cycles in a previously unexplored operating regime. We investigated the effect of phase difference between electric field and temperature cycles, and electric field and temperature change rates on the electrical energy generated from thermal-electrical cycles based on the pyroelectric Ericsson cycle. Complete thermodynamic cycles are possible up to the highest cycle rates tested here, and the energy density varies significantly with phase shifts between temperature and electric field waveforms. This work could facilitate the design and operation of pyroelectric cycles at high cycle rates, and aid in the design of new pyroelectric systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The CMS Barrel Calorimeter Processor demonstrator (BCPv1) board evaluation

For the CERN LHC phase 2, the barrel region of the CMS electromagnetic (ECAL EB) and hadronic calorimeters (HCAL HB) require new back-end electronics for their readout. To this purpose, a first version of the ATCA-based blade, the Barrel Calorimeter Processor (BCPv1), has been developed. The performance of the optical links as well as clock distribution are also presented here. Here, the BCPv1 has been tested together with front-end and trigger boards, as well as with the new DAQ and TCDS Hub (DTH) [1], to demonstrate that the BCPv1 meets the required specifications.

47 OTHER INSTRUMENTATION↗

Antibiotic tigecycline inhibits cell proliferation, migration and invasion via down‐regulating CCNE2 in pancreatic ductal adenocarcinoma

Abstract Recently, many researches have reported that antibiotic tigecycline has significant effect on cancer treatment. However, biomedical functions and molecular mechanisms of tigecycline in human pancreatic ductal adenocarcinoma (PDAC) remain unclear. In the current study, we tried to assess the effect of tigecycline in PDAC cells. AsPC‐1 and HPAC cells were treated with indicated concentrations of tigecycline for indicated time, and then, MTT, BrdU and soft agar assay were used to test cell proliferation. The effect of tigecycline on cell cycle and cellular apoptosis was tested by cytometry. Migration and invasion were detected by wound healing assay and transwell migration/invasion assay. Expressions of cell cycle‐related and migration/invasion‐related protein were determined by using Western blot. The results revealed that tigecycline observably suppressed cell proliferation by inducing cell cycle arrest at G0/G1 phase and blocked cell migration/invasion via holding back the epithelial‐mesenchymal transition (EMT) process in PDAC. In addition, tigecycline also remarkably blocked tumorigenecity in vivo. Furthermore, the effects of tigecycline alone or combined with gemcitabine in vitro or on PDAC xenografts were also performed. The results showed that tigecycline enhanced the chemosensitivity of PDAC cells to gemcitabine. Interestingly, we found CCNE2 expression was declined distinctly after tigecycline treatment. Then, CCNE2 was overexpressed to rescue tigecycline‐induced effect. The results showed that CCNE2 overexpression significantly rescued tigecycline‐inhibited cell proliferation and migration/invasion. Collectively, we showed that tigecycline inhibits cell proliferation, migration and invasion via down‐regulating CCNE2, and tigecycline might be used as a potential drug for PDAC treatment alone or combined with gemcitabine.

Yang, Jie↗

Comprehensive compilations of computation results and validations for neutronics start-up tests at China Experimental Fast Reactor

This paper compiles and analyzes refined results of the coordinated research project (CRP) on Neutronics Benchmark of China Experimental Fast Reactor (CEFR) Start-Up Tests conducted by the International Atomic Energy Agency (IAEA) since 2018. Twenty-eight research organizations participated with various code systems. The China Institute of Atomic Energy (CIAE) provided the benchmark specifications and participants conducted the benchmark through blind and refined phases. This paper presents the benchmark results on six experimental measurements, criticality, control rod worth, temperature reactivity coefficients, sodium void worth, assembly swap reactivities, and foil activations. Except for a few outlier results, the simulation results show good agreement with the measured data within 1-σ experiment uncertainties. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Metals and Quantum Materials with Spin-orbit Interactions by Quantum Monte Carlo methods

The key goals of this project were as follows: 1) Analysis and benchmarks of electron correlation effects recovered in the fixed-node approximation that is inherent to quantum Monte Carlo (QMC) method as applied to metallic states; 2) development of new algorithms for electron spin-degrees of freedom to be treated as explicit quantum variables; 3) designing electronic structure QMC algorithm for efficient evaluation of spin-orbit effects in systems with heavy atoms; 4) adapting the algorithm to complex wave functions and developing corresponding fixed-phase approximation; 5) design and testing of algorithm for valence-only non-local spin-orbit operators; 6) analysis of fixed-node vs fixed-phase errors and their comparisons. The key accomplishments: i) We carried out a systematic study of Li systems by the fixed-node diffusion Monte Carlo method. This involved Li atom, molecule, cluster and solid calculated by the full range of QMC methods including fixed-node QMC.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Stochastic Optimization for Grid Resilience. FY18 Final Technical Report

The optimal restoration problem lies at the foundation of the evaluation and improvement of resilience in power systems. In this report we present a scalable decomposition algorithm for solving this problem for realistic power systems. The algorithm has been developed in three major research threads, corresponding to the chapters in the present report. Chapter 1 studies mixed-integer programming (MIP) formulations for the requirement that each electrical island that appears after a recon guration must have at least one energized generator. We provide three alternative MIP formulations for this restriction, show their equivalence, and prove that two of them are stronger in terms of their linear programming relaxation than the formulation most commonly used in the power systems literature. Since the time to solve MIPs can vary signi cantly between equivalent formulations, we also present computational experiments on IEEE test systems for the Intentional Controlled Islanding (ICI) and the Black Start Allocation (BSA) problems. We observe that a polynomially separable, exponential in size, strong formulation yields the best performance for the BSA problem and exhibits a comparable performance to a linear in size, weak formulation for the ICI problem. Chapter 2 presents a methodology to generate mixed-integer linear approximations of the AC power ow equations governing lines, transformers (including tap regulators and phase shifters), shunt and series compensators, and consumption responsive to voltage. Our approximations are capable of capturing limitations for power grids under abnormal or uncommon operating conditions where common assumptions used in power ow relaxations may not hold. Particularly, the approximation captures overvoltages under almost no load, which is a major concern when energizing lines after a blackout. The method constructs piecewise linear approximations of the non-linear power ow equations by minimizing the squared approximation error over a subset of the feasible domain. We test the method using a realistic database for the Chilean system (1548 buses, 1114 lines, 564 transformers). The resulting approximations yield root mean square errors in the order of 0.05pu and are successfully applied to solve a transmission switching instance for the Chilean system. Chapter 3 presents our algorithm for optimal restoration. The algorithm works by partitioning the problem into a master problem and a slave problem. The master problem optimizes over energization sequences of generators, buses and branches, for the entire restoration horizon, while respecting the energization requiments studied in Chapter 1. The slave problem veri es that there exist power ow solutions supporting the energization sequences proposed by the master problem, adding cuts to the master if an infeasible sequence is detected.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Anion-redox nanolithia cathodes for Li-ion batteries

The development of lithium-air batteries is plagued by a high potential gap (>1.2 V) between charge and discharge, and poor cyclability due to the drastic phase change of O-2 (gas) and Ox- (condensed phase) at the cathode during battery operations. Here we report a cathode consisting of nanoscale amorphous lithia (nanolithia) confined in a cobalt oxide, enabling charge/discharge between solid Li2O/Li2O2/LiO2 without any gas evolution. The cathode has a theoretical capacity of 1,341 Ah kg(-1), a mass density exceeding 2.2 g cm(-3), and a practical discharge capacity of 587 Ah kg(-1) at 2.55V versus Li/Li+. It also displays stable cycling performance (only 1.8% loss after 130 cycles in lithium-matched full-cell tests against Li4Ti5O12 anode), as well as a round-trip overpotential of only 0.24V. Interestingly, the cathode is automatically protected from O-2 gas release and overcharging through the shuttling of self-generated radical species soluble in the carbonate electrolyte.

Zhu, Zhi↗

Magnetron R&D toward the Amplitude Modulation Control for SRF Accelerator

The scheme of using a high efficiency magnetron to drive a superconducting radio frequency (SRF) accelerator cavity needs not only the injection phase locking but also the amplitude modulation to compensate the cavity's microphomics caused cavity voltage change and the beam loading variation. To be able to do a fast and efficient modulation, the magnetron's magnetic field has to be trimmed by an external coil to compensate the frequency pushing effect due to the anode current change [1]. A low eddy current magnetron body has been designed and built [2]. This paper will present the analytical prediction, simulation and experimental results on the 2.45 GHz magnetron test stand with the modulation frequency up to 1 kHz. In addition, the progresses on the injection lock to a copper cavity, new 1497 MHz magnetron prototype, 13 kW high power magnetron test stand development and newly built low level RF (LLRF) controller for the amplitude modulation will be reported.

Rimmer, Robert A.↗

Sockeye: A 1-D Heat Pipe Modeling Tool

Sockeye is a 1-D MOOSE-based application for modeling heat pipes. Sockeye is aimed at modeling heat pipes with annular wick and contains two-phase fluid property packages for sodium and potassium working fluids. Sockeye adapts the two-phase flow model from RELAP-7 to the simulation of heat pipes, by accounting for the capillary pressure in pressure relaxation terms. Additionally, a simple, aggregate heat transfer model exists for transitioning from temperatures below the melting temperature of the working fluid. Results are presented for an example test problem, and some future work is discussed.

42 ENGINEERING↗

Effect of helical micro-fins on two-phase flow behavior of R410A evaporating in horizontal round tubes obtained through visualization

This paper presents a new approach in visualization of the evaporation mechanism and the two phase flow. The visualization test section is a transparent micro-fin tube made by 3D printing. The 3D printing technology helps reproduce the real geometry in commercial metal micro-fin tubes. Even though the wall material is different from the real metal, this new method provides a more complete understanding of the mechanisms of flow boiling and the heat transfer enhancement due to micro-fin geometry. To investigate the effect of micro-fin geometries on two-phase flow behavior, R410A flow boiling experiments are conducted at 1°C saturation temperature and visualized through a clear smooth tube and micro-fin tubes of 0°, 10° and 18° helix angles. The results showed that the annular flow pattern in the helical micro-fin tube occurred at a lower vapor quality than the smooth and axial micro-fin tubes. Helix angle affects the transition boundary of stratified wavy flow to wavy annular flow, which shifts downward (to lower mass flux and vapor quality conditions) as the helix angle increases. Other transitions are not significantly affected by the helix angle. Helical micro-fin tubes with different groove directions were made to understand the flow behavior on the upward side and downward side of the tube.

3D printing↗

Facile synthesis and temperature-dependent luminescence of single-phase dual-emitting CdTe@NaNO{sub 3} composite

Graphical abstract: Single-phase dual-emitting CdTe@NaNO{sub 3} composite was prepared by a facile and efficient aqueous ethanol phase assisted coprecipitation method. Its use in self-referencing luminescent thermometry was tested, by exploiting the temperature-dependence of fluorescence intensity ratio (green/red) in range of 273–473 K. - Highlights: • Single-phase green and red dual-emitting CdTe@NaNO{sub 3} composite was prepared. • CdTe QDs embedded in NaNO{sub 3} matrices exhibit photoluminescence quantum yields of 35%. • Temperature-dependent luminescent properties of CdTe@NaNO{sub 3} composite were studied. • It could be a good candidate for ratiometric temperature sensing with a high relative sensitivity. - Abstract: Single-phase dual-emitting CdTe@NaNO{sub 3} composite was prepared by a facile and efficient aqueous ethanol phase assisted coprecipitation method, providing a new type of solid-state luminescent material with processability, robustness and high luminescence. Cubic-shape Green + Red (G + R) CdTe@NaNO{sub 3} composite particles display single-excitation, dual-emission with two well-resolved, intensity-comparable fluorescence peaks. Its application potential in ratiometric luminescent thermometry was tested, by exploiting the temperature-dependence of fluorescence intensity ratio (green/red) in range of 273–473 K, and the maximum sensitivity is found to be 0.6183% K{sup −1} at 473 K. The results indicate that dual-emitting G + R CdTe@NaNO{sub 3} composite could be considered as potential candidates for ratiometric temperature sensing.

36 MATERIALS SCIENCE↗

Microstructural evolution of Q12{sup TM} alloy irradiated in PWRs and comparison with other Zr base alloys - 2016-0061

Based on the M5{sup R}* alloy metallurgy, the Q12{sup TM} alloy (Zr-1Nb-0.5Sn-0.1Fe) was developed by AREVA NP for structural components, with ultra-low tin addition and slightly increased iron content. The behavior of this alloy was tested under irradiation in a pressurized water reactor (PWR) and has shown improvement in irradiation creep strength and similar free growth compared with M5. This paper provides results on dimensional stability and details the microstructural evolution of the Q12 alloy under neutron irradiation in PWRs. The Q12 microstructural evolution under irradiation was studied for fast neutron fluences up to 13 X 10{sup 25} n/m{sup 2} (E>1 MeV) with analytical transmission electron microscopy observations. We focused on radiation-enhanced needle-like particles, Laves phases, and the linear density of -component loops. These results are compared with other quaternary zirconium-niobium-tin-iron alloys and with M5. All these results allow a general discussion about microstructural evolution and behavior under irradiation of quaternary-type alloys compared to M5 alloy. This study, in agreement with previous works on Zr-1Nb and quaternary alloys, seems to show that increasing the iron content with the presence of niobium and tin will decrease the -component loop linear density and delay the growth breakaway. (authors)

36 MATERIALS SCIENCE↗

Properties of Noise Cross-Correlation Functions Obtained from a Distributed Acoustic Sensing Array at Garner Valley, California

A field test that was conducted at Garner Valley, California, on 11 and 12 September 2013 using distributed acoustic sensing (DAS) to sense ground vibrations provided a continuous overnight record of ambient noise. Furthermore, the energy of ambient noise was concentrated between 5 and 25 Hz, which falls into the typical traffic noise frequency band. A standard procedure (Bensen et al., 2007) was adopted to calculate noise cross-correlation functions (NCFs) for 1-min intervals. The 1-min-long NCFs were stacked using the time–frequency domain phase-weighted-stacking method, which significantly improves signal quality. The obtained NCFs were asymmetrical, which was a result of the nonuniform distributed noise sources. A precursor appeared on NCFs along one segment, which was traced to a strong localized noise source or a scatterer at a nearby road intersection. NCF for the radial component of two surface accelerometers along a DAS profile gave similar results to those from DAS channels. Here, we calculated the phase velocity dispersion from DAS NCFs using the multichannel analysis of surface waves technique, and the result agrees with active-source results. We then conclude that ambient noise sources and the high spatial sampling of DAS can provide the same subsurface information as traditional active-source methods.

58 GEOSCIENCES↗

An Improved Refractive Focusing Optic

A diamond optic that can both dissipate the heat load while reducing phase profile errors of the beam will allow a more full realization of the benefits of the previous investments in light sources by allowing experiments that depend on high resolution imaging or spacial resolution. Reducing the x-ray spot size on samples will improve the quality of this information leading to better understanding of materials properties. During Phase I, we explored techniques for characterizing and improving the accuracy of the shape of diamond lenses, particularly in the apex of the parabolic curve, in order to make an optic whose optical performance exceeds what is currently available. We made efforts to reduce the lens surface roughness through a variety of dry etching methods. Additional work sought to make compound lenses with shorter focal lengths and to mount the lenses on copper supports by a variety of methods. Lastly, lenses were made and tested on the 1-BM beamline at APS.

42 ENGINEERING↗

Helical kink instability in a confined solar eruption

A model for strongly writhing confined solar eruptions suggests an origin in the helical kink instability of a coronal flux rope that remains stable against the torus instability. This model is tested against the well observed filament eruption on 2002 May 27 in a parametric MHD simulation study that comprises all phases of the event. Good agreement with the essential observed properties is obtained. These include the confinement, terminal height, writhing, distortion, and dissolution of the filament, and the flare loops. The agreement is robust against variations in a representative range of parameter space. Careful comparisons with the observation data constrain the ratio of the external toroidal and poloidal field components to B{sub et}/B{sub ep}≈1 and the initial flux rope twist to Φ≈4π. Different from ejective eruptions, two distinct phases of strong magnetic reconnection can occur. First, the erupting flux is cut by reconnection with overlying flux in the helical current sheet formed by the instability. If the resulting flux bundles are linked as a consequence of the erupting rope’s strong writhing, they subsequently reconnect in the vertical current sheet between them. This reforms the overlying flux and a far less twisted flux rope, offering a pathway to homologous eruptions.

79 ASTRONOMY AND ASTROPHYSICS↗

Muon Campus at Fermilab

The Muon Campus at Fermilab provides world class accelerator infrastructure supporting the next generation intensity frontier experiments. The anti-proton source from the Tevatron era was converted to the present day Muon Campus at the end of the collider program in 2011. Currently, the Muon Campus delivers highly polarized muon beams to the Muon g-2 experiment and in a few years, it will provide muon beams to the Mu2e experiment. The Muon g-2 experiment is a high precision test of the standard model; it is precise enough to measure QED, Weak, and QCD Standard Model contributions.The Muon g-2 experiment looks for a significant deviation from the Standard Model whereas the Mu2e experiment looks for rare processes using high intensity muon beams. The Muon g-2 experiment has measured the anomalous magnetic moment of muons to an unprecedented 460 ppb precision with Run 1 data. The experiment has completed 5 runs, accumulating 19$\times$ Brookhaven E821 data set. The Mu2e experiment has completed the construction phase and first beam to the Diagnostic Absorber was run on April 14, 2022. Installation and commissioning of the Mu2e experiment will begin in 2023 and beam commissioning and physics run is currently planned for 2026.

43 PARTICLE ACCELERATORS↗

GM Light Duty Fuel Cell Electric Vehicle Validation Data

General Motors LLC (GM) completed a multi-phase project with the Department of Energy to validate light-duty fuel cell electric vehicle (FCEV) performance and durability using dynamometer fuel cell system and real-world vehicle performance data. This project began with GM’s Gen 0 Fuel Cell Fleet vehicles with Technology Insertion operating strategies and materials, and extended to GM’s Gen 1 and early Gen 2 commercial-design intent Fuel Cell stacks and Fuel Cell Systems. The intent of this project was to understand how fuel cell materials, system architectures, and operating strategies impact fuel cell stack durability under fully dynamic operating conditions such as those seen in a light duty vehicle application. More than 87,000 hours of system run time were accumulated under this project simulating several vehicle lifetimes under aggressive driver usage conditions. Lessons learned from this demonstration project have helped expedite the development of a commercially viable, zero-petroleum, zero-emission, Fuel Cell propulsion system. Durability test results have enabled a substantial reduction in the precious metal content in the Fuel Cell Stack with each successive generation of stack design. Stack lifetimes between the first and current design iterations have increased nearly tenfold, while the overall precious metal content has been reduced by approximately 85%. The Gen 2 system power density (kW/gPt) is over five times that of the Gen 0 system. In addition, run time voltage degradation as a function of total platinum was reduced by more than an order of magnitude between the first and last phase of this project. GM is proceeding with a low volume production program aided by the results of the durability testing performed under this cooperative agreement.

08 HYDROGEN↗