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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

SNL CSP Library Archive Project (FY19 Report)

Sandia National Laboratories (SNL) National Solar Thermal Test Facility (NSTTF) and Tech Library have been collaborating over the course of the FY19 period to establish and maintain the first and only digital collection in the world of Concentrating Solar Power (CSP) related historical documents, dating back to the CSP program inception here at Sandia in the 1970's thru to the present. The unclassified, unrestricted (UUR) collection, comprised of internally generated Sandia documents as well as a significant number of external reports will be searchable via both the Sandia website and OSTI, DOE's document repository. DOE is currently championing efforts to get the collection launched, where international partners, which include Australia and Germany, plan to forward related documents to be included in the CSP archive. Advancing this transformative project will make the CSP collection accessible to the Sandia and global communities.

14 SOLAR ENERGY↗

DET Kaizen Summary [Slides]

In October while the process was down for other reasons DET-1 conducted several Kaizens to identify our wastes and show our workforce specific examples of what wastes we struggle with. Our biggest identified wastes were transportation (up to a quarter mile an hour of walking by techs) and inventory (unused equipment).

99 GENERAL AND MISCELLANEOUS↗

A Magnetized Electron Source For Ion Beam Cooling

A number of electron-ion collider facilities for nuclear physics research are under consid- eration in the United States. At Brookhaven National Lab (BNL), the eRHIC (electron Relativistic Heavy Ion Collider) facility would augment the existing ion/proton facility with an electron accelerator. Thomas Jefferson National Accelerator Facility (JLab) plans to use the existing CEBAF machine and add an ion/proton accelerator, as part of the Jefferson Lab Electron-Ion Collider (JLEIC). All such facilities require cooling of the ion beams in order to reach the luminosity goals. Different methods of cooling the ions using an electron beam are envisaged. BNL is pursuing coherent electron cooling and non-magnetized, bunched-beam cooling, while JLab is considering magnetized cooling. In addition to electron cooling, magnetized beams are of interest for other applica- tions, such as flat beam klystrons and novel means for producing bright beams for micro- undulators and compact X-ray sources. For example, flat beams generated from a mag- netized injector, in conjunction with low emittance, enable RF sources with frequencies above 100 GHz. While the market for high-performance injectors for electron cooling is limited, the market for high-frequency RF sources and compact X-ray systems is con- siderable. Thus, the design methodologies developed in this project have a wide range of applicability. In Phase I of this SBIR project, Xelera Research LLC performed simulations and calcu- lations to develop a prototype design for a magnetized electron injector that can be used as a source for cooling an ion beam. We developed general design methodologies and tech- niques that are applicable not only to specific machine designs but to other applications requiring magnetized injectors as well. In this Phase II SBIR project, Xelera Research LLC, in collaboration with a team at JLab, designed, built, and tested a thermionic elec- tron source for driving a magnetized electron cooler in a future electron-ion collider project. This device was delivered to JLab in July 2019 and achieved first beam in December 2019.

43 PARTICLE ACCELERATORS↗

Mesoscale Design of Magnetoelectric Heterostructures and Nanocomposites

Multiferroic materials have a coexistence of at least two ferroic orders. The coupling interaction between the different order parameters can produce new phenomena, such as the magnetoelectric (ME) effect. The ME response is the appearance of an electric polarization P upon applying a magnetic field H, and/or vice versa. Magnetoelectricity has been observed as an intrinsic effect in some natural materials at low temperature; however, such single phase materials suffer from extremely weak ME exchange. Better alternatives are two-phase composites consisting of magnetostrictive and piezoelectric phases, which have been shown to have large ME coefficients. Said composites exploit a unique product ME tensor property that depends upon the individual strictions of the piezoelectric and magnetostrictive phases, the elastic stiffness and integrity of the interphase interfaces, the phase distribution and the dimensionality of its connectivity, and any elastic constraint; amongst other things. This research program between D. Viehland PI and S.Priya at Virginia Tech investigated the mesoscale physics and chemistry of such two-phase ME heterostructures. The results of the proposed research are relevant to new generations of multifunctional materials involving heterogeneous components. How the product ME property be optimized? The answers lies with the interphase-interfaces, where the atomic layers coordinate stress transfer from one phase to another. It was the primary goal of this research program to discover such fundamental relationship for two phase ME heterostructures and nanocomposites. This research program integrated all the components required to fully investigate the ME phenomenon: starting from synthesis of nanomaterials with diversified interfacial characteristics; to full electrical, magnetic, and structural characterizations.

36 MATERIALS SCIENCE↗

Annual LDRD Report (FY2019)

The performance of Nuclear Deterrence (ND) systems could be improved by adopting advanced commercial CMOS technologies. However, the radiation hardness of these ND systems must be assured. This project quantified dose rate upset thresholds, allowing us to evaluate whether advanced commercial technologies can be used in rad hard applications. This project also evaluated the susceptibility of advanced commercial technologies to neutron displacement damage and single event effects, and developed hardness assurance methods. As a result of this work, Sandia is now collaborating more closely with DoD agencies and their contractors to understand and improve the radiation hardness of advanced commercial technologies. Sandia Capabilities (SPHINX, lon Beam Lab, FPGA test capabilities) were developed and are being utilized by other programs. Staff were trained to do radiation survivability testing and developed proposals that were funded. Internal and external collaborations and partnerships were developed, including with Georgia Tech. This project received the Best Paper award at the 2019 Hardened Electronics And Radiation Technology (HEART) Conference.

36 MATERIALS SCIENCE↗

UNITY: Unified Memory and Storage Space

UNITY is a 36-month project focused on providing design and evaluate a new distributed storage paradigm that unifies the traditionally distinct application views of memory- and file-based data storage into a single scalable and resilient environment. The project is a collaboration among Oak Ridge National Laboratory (ORNL, Lead institution), Los Alamos National Labs (LANL), and Georgia Tech (GT). The main contributions of the GT team have been around development of low level systems software for best leveraging the capabilities of new types of persistent memory technologies, and for development of methods for intelligent data management across memory/storage substrates with heterogeneous components. GT contributed the Phoenix library for optimized checkpoint/restart for HPC I/O for systems with non-volatile memory (NVM), the NVStream library for NVM-specialized streaming I/O for HPC workflows, the CoMerge, Mnemo and Kleio solutions for intelligent data management on NVM-based systems. These contributions result in significant improvements in both application performance and system efficiency.

97 MATHEMATICS AND COMPUTING↗

APS Science 2019 (V.1): Research and Engineering Highlights from the Advanced Photon Source at Argonne National Laboratory

The Advanced Photon Source Facility at Argonne National Laboratory The APS, a national synchrotron radiation research facility operated by UChicago Argonne, LLC, and Argonne National Laboratory for the U.S. Department of Energy (DOE) Office of Science-Basic Energy Sciences, Scientific User Facilities Division, provides this nation’s brightest high-energy x-ray beams for science. Research by APS users extends from the center of the Earth to outer space, from new information on batteries, combustion engines and microcircuits, to new and improved pharmaceuticals, and nanotechnologies whose scale is measured in billionths of a meter. The APS helps researchers illuminate answers to the challenges of our high-tech world, from developing new forms of energy to sustaining our nation’s technological and economic competitiveness to pushing back against the ravages of disease. Research at the APS promises to have far-reaching impact on our technology, our economy, our health, and fundamental knowledge of the materials that make up our world.

14 SOLAR ENERGY↗

Partnership and Pipeline Office Overview [Slides]

Partnerships ensure a strong Laboratory and support our missions. Partnerships are critical to our success as a Laboratory: community relations, colleges and universities and technical communities, regional and national economic development through industrial partners, DOE Laboratories, and other federal agencies. The Laboratory has many tools to build and enhance partnerships. The Community Programs Office in our Northern New Mexico Region has K-12 educational programs, supports teacher professional development and retention in regional elementary, middle and high schools, and provides community college engagement. The Partnerships and Pipeline Office works with the National Security Education Center (NSEC) which has broad university engagement including New Mexico universities. The Feynman Center for Innovation is involved in 'tech transfer' to innovation asset stewardship. The External Assignments Office shares LANL's technical expertise. The Student and Postdoc Program Offices build our workforce of the future.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

The energetics and dynamics of confinement in flexible frameworks and molecular confinement

This project is part of an ongoing and long-term collaboration among Alexandra Navrotsky (who moved recently from UC Davis to Arizona State University), Nancy Ross at Virginia Tech, and Brian Woodfield at Brigham Young University (BYU) on the thermodynamics and lattice dynamics of nanophase and porous materials. Navrotsky emphasizes energetics of formation and guest molecule sorption by ambient and high temperature calorimetry, Woodfield contributes cryogenic heat capacity measurements, and Ross uses inelastic neutron scattering, X-ray and neutron diffraction, and high pressure studies to probe lattice dynamics and phase transitions. Porous frameworks form the chemical and structural basis for critical technologies in separations, catalysis, nuclear waste containment and biomedical applications. Hundreds of zeolites and metal organic frameworks (MOFs) have been synthesized, and their ability to separate and store hydrogen, methane and carbon dioxide has been investigated both experimentally and theoretically. Nevertheless, a fundamental and systematic molecular-level understanding of the thermodynamic and structural factors governing the stability and guest-host interactions in these materials lags behind focused studies of specific systems. Because the guest molecules interact with each other and with the host framework, molecular confinement is a finely balanced and complex phenomenon. The ability of the guest molecules to bind and diffuse through the pores is determined by the nature of the host framework which, in turn, responds to the nature and concentration of guest molecules and to pressure and temperature. The work explores how framework flexibility, tailored by structure, composition, temperature and pressure, is a general phenomenon, similar in nature but variable in extent, in both zeolites and MOFs and is part of a free energy landscape in which framework-guest interactions, pressure, and temperature result in changes in framework geometry and, in some cases, phase transitions. These subtle and/or pronounced changes in lattice geometry, energetics, and dynamics can play a decisive role in confinement and in differentiating the binding of molecules of similar size.

36 MATERIALS SCIENCE↗

HEX 2-piece ID Absorber: Steady and Transient Thermal FEA

Radiation fans from Insertion Devices and Bending Magnets are “trimmed” by various water-cooled absorbers located strategically downstream of those sources. Mostly, the absorber surfaces onto which power is deposited are constructed from Glidcop Al-15 (rarely OFHC copper). On the basis of Tech Note 327 a re-design for improved thermal performance has evolved to a two-piece ID Absorber configuration; one between dipole chamber and quadrupole, another after the sextupole, each with reduced incident angle. The ring’s Active Interlock (AI) system protects against overheating by disabling mis-steered beam within an allotted time. SRP (Synchrotron Radiation Protection) protocol has a limiting maximum allowable temperature of 100*C at any point when subject to mis-steered beam for a fixed period before AI activation. After 0.2 msec, radiation exceeding +/- 0.5mm offset and +/- 0.25 mrad angular error from the HEX SCW will trip in fault. AI specification allows 1.0 msec to fully dump the electron beam.

36 MATERIALS SCIENCE↗

Next Generation Three-Way Catalysts for Future, Highly Efficient Gasoline Engines (Final Report)

Ford Motor Company, Oak Ridge National Laboratory, and the University of Michigan completed a 3.25 year project on exhaust catalysts for gasoline vehicles that exhibit higher activity at lower temperatures down to 150°C. Ford has successfully used catalysts on cars and trucks to control emissions for over forty years. Changes in gasoline engine technology have allowed the use of “high tech” three-way catalysts (TWCs) to simultaneously control HC (hydrocarbons), CO (carbon monoxide), and NOx (nitrogen oxides) at nearly 100% efficiency. Excess fueling is used upon engine start to heat the catalyst up to its full operating temperature of greater than 350°C, lowering fuel economy and creating particulate matter. It was desirable to develop new catalysts for lower operating temperatures that may occur with future, more efficient gasoline powered vehicles, while still being durable to 150,000 mi with peak temperatures of 960°C. The work included laboratory preparation, aging, and poisoning of catalyst materials, activity tests, and chemical analyses. The objective of this project was to demonstrate progress toward the USDRIVE goal of achieving durable 90% conversion (T90) of hydrocarbons (HC), carbon monoxide (CO), and oxides of nitrogen (NOx) at 150°C. The project partners focused on several supported metal catalyst structures to promote lower light-off temperatures, enhance metal-support interaction, and improve durability. The raw materials (oxides of aluminum, cerium, silicon, titanium, and zirconium) were not new, but were used in novel ways. Palladium (Pd) or rhodium (Rh) were supported either on layered metal oxide supports, on nanoparticles, or used in various core@shell configurations. Catalyst materials were aged hydrothermally to a simulated high mileage. The catalyst formulation with the lowest durable light-off was 0.5 wt% Rh supported on alumina with an overlayer of either Ti or Zr. The temperatures for 90% conversion were up to 128°C lower than those of a commercial Pd three-way catalyst that had > 3x metal loading of the new Rh catalyst. An additional material made of Pd supported on nanoparticles of ceria-zirconia (CZO) was also considered; the aged T90s were up to 40°C lower than the commercial catalyst, at similar metal loading. Further understanding of the catalyst architecture provided additional confidence to move forward with scale-up of 0.5 wt% Rh/Ti/Al 2 O 3 to coated monolith laboratory cores for further evaluation. The team worked with Johnson Matthey to accomplish this, in addition to exploring manufacturability and potential costs. The overall benefit was estimated to be 10-15% lower NMOG and NOx tailpipe emissions on a cold start certification cycle.

02 PETROLEUM↗

HIGH EFFICIENCY HIGH DENSITY GAN BASED 6.6KW BI-DIRECTIONAL ON-BOARD CHARGER FOR PEVS

Executive Summary: In the 4th quarter of 2014, a program was formally initiated at Delta Products to develop and commercialize a lightweight, compact and high efficiency bi-directional on-board Charger (OBC) for plug-in electric vehicle use. The project was funded in part by the U.S. Department of Energy (DOE), under award DE- EE0006834. Delta products was the prime contractor to DOE during the three-year duration of the project. In addition to Delta Products, several additional supplier-partners were engaged in this research and development (R&D) program, including Transphorm, Inc., The Center for Power Electronics Systems (CPES) at Virginia Tech, and Fiat Chrysler Automobiles. The OBC uses novel control schemes enabled by Gallium Nitride (GaN) switches to obtain charger efficiency of 95% and reduce volume and mass by 50% of the existing state-of-the-art silicon (Si) based chargers and inverters. A Si-based bidirectional OBC is typically implemented with two separate modules: a charger and an inverter. A GaN-based bidirectional OBC can integrate both functions into a single module. It will result in substantial reductions in size, weight and cost. This enables the introduction of WBG devices in automotive production programs. The inverter function integrated with PHEV can act as emergency power source in case of power interruption. This increases the power security when the electric infrastructure is damaged by extreme weather conditions. This report summarizes the program and describes the key research outcomes of the program. A technical history of the project activities is provided, which describes the key steps taken in the research and the findings made at successive stages in the multi-stage work. The evolution of OBC prototypes is described in detail. After the program history is reviewed, the key attributes of the resulting OBC are described in terms of functionality, performance, and cost. The results clearly demonstrate the ability of this OBC to meet or exceed DOE's targets for this program, including: • Construction of a working product-intent prototype of a bi-directional on-board Charger (OBC); • Peak efficiency of 95% and volume reduction of 50% compared to a recent production modules of similar ratings. • Bi-directional operation at 120Vac and 240Vac in vehicle. In addition to meeting all the program goals, the program was completed within the original budget and timeline established at the time of the award. The summary program budget and timeline, comparing plan versus actual values, is provided for reference, along with several supporting explanatory notes. Technical information relating to the product design and test results are contained in the appendices to this report.

30 DIRECT ENERGY CONVERSION↗

UNESE Data Analysis - Disko Elm Gas Transport Characteristics (NA-22 Quarterly Report)

Two research papers describing gas transport studies in subsurface containment environments appropriate for underground nuclear explosions were revised and accepted for publication in the peer-reviewed journals, Nature – Scientific Reports and Journal of Geophysical Research. The Nature – Scientific Reports paper is a primary deliverable and describes the gas-transport experiment performed in P Tunnel (NNSS) and 1) subsequent analysis of field data as part of the UNESE program. The Journal of Geophysical Research paper describes an experiment, supported mainly by DARPA and led by researchers at Weston Geophysical and New Mexico Tech., with 2) analyses supported by this project to evaluate the ability of SF6 gas tracer to track xenon gas migration under conditions related to a previous UNESE experiment. Two new tasks consider 3) evaluation of detonation heating and multiphase flow on arrival of xenon at the surface and 4) the impact of surface or Langmuir adsorption of gases being transported through pores and along fractures.

58 GEOSCIENCES↗

Materials response under hypersonic flow conditions probed by multi-modal diagnostics in a benchtop wind tunnel

In this LDRD “Materials response under hypersonic flow conditions probed by multi-modal diagnostics in a benchtop wind tunnel” a peer-reviewed lab-scale hypersonic wind tunnel (WT) was planned to be assembled in-house, along with time and space resolved and related flow and materials diagnostics to derive high quality measurements and the science that is able to inform the development of our modeling and simulation codes for the hypersonic regime. The baseline capability to achieve Mach 3 flow was scheduled to be completed in Q4 2020, in the first year of the LDRD. However due to the COVID-19 delays and travel restrictions starting in March, 2020 this task could not be completed to carry out the materials response studies in-house, or those planned with external partners that were engaged during this LDRD (NASA Langley, NASA Ames, Texas A&M university, and Virginia Tech). Still, using our hypersonic computational fluid simulation codes, many of the hypersonic components have been designed (for Mach 3, 5, and 7) and procured (or in procurement phase), and a new dedicated hypersonic laboratory was facilitized, 2 WT test sections have been manufactured, and a Mach 3 nozzle was 3D printed for prototyping. In parallel, unique materials diagnostics have been tested under static conditions and fully specified and awaiting validation in our partner facilities. Due to the new hypersonic initiative announced in January, 2020 we proposed a related scope increase in hypersonics research requiring energy interactions and new diagnostics well beyond what could be supported by an LDRD ER. A decision was made to end the current LDRD ER and formally propose a new LDRD SI that leverages the current effort, which will be starting in FY21. As a result of the uniqueness of this LDRD work, our early efforts have been encouraged and well received in the hypersonic research community, and is now part of multiple unsolicited internal and external project proposals expected to be funded in the coming years, which is encouraging to make LLNL a leader in experimentally probing extreme physics of local energetics critical to hypersonics.

36 MATERIALS SCIENCE↗

Development and Validation of a Two-Phase Thermal-Hydraulic CFD Code NEK-2P

A project is underway to develop, verify and validate an advanced two-phase flow modeling capability for the highly-scalable, high-performance Computational Fluid Dynamics (CFD) code NEK5000. The goal of this work is to verify and validate the two-phase version of the NEK5000 code, named NEK-2P, to simulate the two-phase flow and heat transfer phenomena that occur in a Boiling Water Reactor (BWR) fuel bundle under various operating conditions. The NEK-2P two-phase flow models follow the approach used for the Extended Boiling Framework (EBF) previously developed at Argonne but include more fundamental physical models of boiling phenomena and advanced numerical algorithms for improved computational accuracy, robustness, and computational speed. The development of the NEK-2P two-phase solver and the implementation of the Extended Boiling Framework two-phase models were initially supported by Argonne National Laboratory (Argonne) through a Laboratory Directed Research and Development (LDRD) project during FY2014-2016. The development and validation of the two-phase models through analyses of selected two-phase boiling flow experiments was supported by the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program in FY2017-2020. This report focuses on verification and validation of the water-steam boiling model NEK-2P Two-Phase, CFD code. The NEK-2P was validated with Nuclear Power Engineering Corporation (NUPEC) Pressurized Water Reactor (PWR) Sub-channel and Bundle Test (PSBT) void distribution benchmark. Three different simulations were performed and analyzed for various operating conditions such as wall-heat flux and sub-cooled inlet temperatures. Reasonably good agreement with measured data was obtained in predicting the measured void distributions. Simulations were performed for Virginia Tech. (VT) 3x3 rod bundle geometry with and without spacers. The preliminary results were presented for Simplified Spacer Grid (SSG). In addition, the implementation of interface reconstruction model was tested with one of the Becker benchmark Critical Heat Flux (CHF) experiments.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Drone Video Platform—Collision Avoidance, Situational Awareness, and Communications

Small unmanned aerial systems are ideal for delivering sensors into areas that are inaccessible or too dangerous for human entry or manned aircraft over-flights. The systems can fly low and slow for enhanced sensitivity and in tight spaces where ordinary aircraft could never fit. We have configured and flown sensor payloads for radiation, chemical, and optical detection on small fixed-wing and rotary-wing aircraft. All the sensor packages provide telemetry, GPS coordinates, LIDAR distance ranging, and absolute time of day to microsecond accuracy. Payload weights range from less than 1 kg up to 5.5 kg. Currently, communications are over 2.4 GHz and 915 MHz radios, as well as over 4G LTE cellular data links. Real-time data feeds from the sensor payloads to web browser clients anywhere in the world are possible via a virtual EC2 server on the Amazon AWS cloud. In FY 2019, the Nevada National Security Site teamed with Virginia Tech, H3D Corp., and Unmanned Systems, Inc. to accomplish the four flight missions described in this report. A large part of this year’s mission goals were to demonstrate the ability to fly beyond visual line of sight (BVLOS).

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

PSL-AC-CP-1102-004-03: Electrostatic Discharge Simulator Kit Model 930D and Associated Current-Viewing Resistor (V.04)

This document provides instructions for calibrating the Electro-Tech (ETS) electrostatic discharge (ESD) simulator, Model 930D. The calibration shall meet the ± 5% specification for resistance and capacitance as specified in MIL-STD-331C 2009 newer. A series of direct measurements of the Device Under Test (DUT) output at 25 kV using a calibrated LeCroy HDO 6104 oscilloscope (or equivalent 1 MΩ) input impedance storage oscilloscope) are recorded through the 500-pF capacitor, 500-Ω resistor, and a 1-Ω Current Viewing Resistor (CVR). The certified value of the DUT's 25 kV output is calculated using Ohms Law and the certified system resistance and capacitance described in this procedure. Read this document in its entirety before proceeding with the calibration.

42 ENGINEERING↗

Asynchronous Iterative Solvers for Extreme-Scale Computing

The Asynchronous Iterative Solvers for Extreme-Scale Computing (AsyncIS) project aims to explore more efficient numerical algorithms by decreasing their overhead. AsyncIS does this by replacing the outer Krylov subspace solver with an asynchronous optimized Schwarz method, thereby removing the global synchronization and bulk synchronous operations typically used in numerical codes. AsyncIS—a U.S. Department of Energy (DOE)-funded collaboration between Georgia Tech, the University of Tennessee, Knoxville, Temple University, and Sandia National Laboratories—also focuses on the development and optimization of asynchronous preconditioners (i.e., preconditioners that are generated and/or applied in an asynchronous fashion). The novel preconditioning algorithms that provide fine-grained parallelism enable preconditioned Krylov solvers to run efficiently on large-scale distributed systems and manycore accelerators like GPUs.

97 MATHEMATICS AND COMPUTING↗