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At least 91 records · Page 5

Development of a Technique to Relate Aeolian Roughness to Radar Backscatter using Multiparameter SIR-C Data

Progress and future plans for the following objectives are presented: (1) To develop a technique to obtain values of aeolian roughness for geologic surfaces from values of surface roughness determined from calibrated L- and C-band, like- and cross-polarized, multiple incidence angle radar data from SIR-C; (2) To define the optimal combination of radar parameters from which aeolian roughness can be derived; and (3) To gain an understanding of the physical processes behind the empirical relationship.

Greeley, Ronald↗

Energy- and Structure-Related Properties for the (100) Surface of Beta-SiC

Calculations were carried out to investigate energy- and structure-related properties for the (100) surfaces of beta-SiC. Investigations for both C- and Si-terminated planes include (1 x 1), (2 x 1) and c(2 x 2) surface phases. All calculations were performed employing the empirical Tersoff function developed for SiC systems. This function has been used on several occasions, with varying sets of parameters to calculate properties for systems containing Si and C atoms. Here a comparative study was conducted. Results obtained from different sets of parameters were compared with respect to each other and also with values from the literature. Suitabilities and limitations of each parameter set were delineated.

Halicioglu, Timur↗

Multilayer Relaxation Features on (100) and (111) Surfaces of Beta-SiC

Multilayer relaxation features were investigated for beta-SiC surfaces. Calculations include (1 x 1), (2 x 1) and c(2 x 2) phases of the (100) surface, and the (1 x 1) structure of the (111) surface. For both C- and Si-terminated surfaces, variations in the top three interlayer spacings were calculated. The largest vertical displacement was calculated for the top interlayer spacing of the (111) surface. In general, it was found that top interlayer spacings contract, while the second interlayer spacings expand moderately. The third interlayer spacings, on the other hand, were found to exhibit very small amounts of contractions. Dimerization energies and bond distances were also calculated for reconstructed phases of the (100) surface. Calculated results were compared with data from the literature.

Halicioglu, Timur↗

Laboratory Studies in UV and EUV Solar Physics

The Ion Beam Experiment at the Center for Astrophysics is dedicated to the study of ion-electron collision processes of importance in solar physics. The analysis of measurements of Electron Impact Excitation (EIE) from the 3s3p(exp 3)P(exp o) metastable state to the 3s3p(exp 1)P state of Si(2+) was completed during the past year and a paper describing the results is available as a preprint. Our current program is directed at measuring absolute cross sections for dielectronic recombination (DR) and EIE in Si(3+), one of the primary ions used for probing the solar transition region. Our study of DR is particularly concerned with the effects of electric and magnetic fields on the recombination rates. Measurements of silicon ions with charge greater than n=2 have necessitated upgrading the experiment with a new ion source. The new source is also suitable for producing C(2+) beams to be used for measurements of EIE and DR for that system. The source is expected to be capable of producing beams of more highly charged systems as well.

Parkinson, W. H.↗

Aerothermal Effects of Cavities and Protuberances for High-Speed Sample Return Capsules

Extraterrestrial sample return is a growing component of solar system exploration. Currently, four missions, Stardust, 1 Muses-C, 2 Genesis, and Mars Sample Return, are under development that employ sample return as a prime component of the mission architecture. Respectively, these missions will return samples from the tail of a comet, an asteroid, the solar wind, and, Mars. An important component of these missions and the focus of this paper is the design of the sample return capsule (SRC). The purpose of the SRC is to safely return to Earth any gathered samples for terrestrial analysis. The two major design constraints for any SRC are as follows: 1) it must be able to survive a high-speed Earth entry (11 km/s to as a high as 15 km/s), 2) the mass of the SRC must be as small as possible. Because the SRC mass is carried from Earth to the sample sight and back, the SRC mass is a strong driver in the mission mass budget. Further, for the Mars Sample Return Capsule, planetary protection is another constraint. For this capsule, the probability of planetary contamination at Earth due to an SRC failure at entry must be minimal. For an SRC, a possible failure mechanism is severe local heating as a result of cavities and or protuberances in the SRC forebody heatshield. For example, the Apollo Command Module had a number of cavities and protuberances as part of the baseline designs Wind-tunnel tests of models containing small cavities and protuberances showed severe local heating augmentations in the vicinity of these surface discontinuities.4-5 As another example, the Genesis SRC forebody heat-shield contains penetrations (cavities) to mount the vehicle to the carrier bus. It is expected that these penetrations will also experience a severe local heating environment. A concern is that the large thermal gradients may produce sufficient thermal stress to cause local mechanical failure of the heatshield. Penetrations to the forebody heat-shield can also result from damage at vehicle integration, during launch, or during transportation of the sample return capsule from earth to the sample site and back. For example, the Starting SRC was damaged near the shoulder during the heatshield integration process producing a local surface discontinuity. Also, the Starting SRC traverses through the tail of a comet and is in space for 7 years. Thus, damage to the heatshield as a result of micrometeroid impact is a concern. Finally, it is difficult to characterize the effects of these potential heatshield singularities with ground-test facilities. Either detailed simulation or a dedicated flight test is required.

Olynick, David↗

Long-chain carboxylic acids in pyrolysates of Green River kerogen

Long-chain fatty acids (C10-C32), as well as C14-C21 isoprenoid acids (except for C18), have been identified in anhydrous and hydrous pyrolyses products of Green River kerogen (200-400 degrees C, 2-1000 hr). These kerogen-released fatty acids are characterized by a strong even/odd predominance (CPI: 4.8-10.2) with a maximum at C16 followed by lesser amounts of C18 and C22 acids. This distribution is different from that of unbound and bound geolipids extracted from Green River shale. The unbound fatty acids show a weak even/odd predominance (CPI: 1.64) with a maximum at C14, and bound fatty acids display an even/odd predominance (CPI: 2.8) with maxima at C18 and C30. These results suggest that fatty acids were incorporated into kerogen during sedimentation and early diagenesis and were protected from microbial and chemical changes over geological periods of time. Total quantities of fatty acids produced during heating of the kerogen ranged from 0.71 to 3.2 mg/g kerogen. Highest concentrations were obtained when kerogen was heated with water for 100 hr at 300 degrees C. Generally, their amounts did not decrease under hydrous conditions with increase in temperature or heating time, suggesting that significant decarboxylation did not occur under the pyrolysis conditions used, although hydrocarbons were extensively generated.

Non-NASA Center↗

Dissolved gases in perennially ice-covered lakes of the McMurdo Dry Valleys, Antarctica

Measurements of dissolved N2, O2, Ar, CO2, and CH4 were made in perennially ice-covered Lake Hoare. Results confirm previous reports that O2 concentrations in the upper water column exceed atmospheric equilibrium and that N2 and Ar are supersaturated throughout the water column. The mean supersaturation of N2 was found to be 2.0 (+/- 0.37) and Ar was 3.8 (+/- 1.1). The ratios of N2/Ar (20.3 +/- 13.8), and O2/Ar (22.5 +/- 4.0) at the ice-water interface are consistent with those previously measured, suggesting that bubble formation is the main process for removing gas from the lake. However, the saturations of N2 and Ar greatly exceed those previously predicted for degassing by bubble formation only at the ice-water interface. The data support the hypothesis that removal of gas by bubbles occurs in the water column to a depth of 11 m in Lake Hoare. CO2 concentration increases from near zero at the ice-water interface to 80-100 times saturation at and below the chemocline at c. 28 m. There is considerable variability in the gas concentrations throughout the water column; samples separated in depth by one metre may vary by more than 50% in gas content. It is likely that this phenomenon results from the lack of turbulent mixing in the water column. Methane (c. 2 micrograms l-1) was detected below the chemocline and immediately above the sediment/water interface at a depth of 30 m. Samples from lakes Vanda, Joyce, and Miers, also show supersaturations of O2, N2, and Ar at levels similar to levels found in Lake Hoare.

NASA Discipline Exobiology↗

Affinity of guanosine derivatives for polycytidylate revisited

Evidence is presented for complexation of guanosine 5'-monophosphate 2-methylimidazolide (2-MeImpG) with polycytidylate (poly(C)) at pH 8.0 and 23 degrees C in the presence of 1.0 M NaCl2 and 0.2 M MgCl2 in water. The association of 2-MeImpG with poly(C) was investigated using UV-vis spectroscopy as well as by monitoring the kinetics of the nucleophilic substitution reaction of the imidazole moiety by amines. The results of both methods are consistent with moderately strong poly(C) 2-MeImpG complexation and the spectrophotometric measurements allowed the construction of a binding isotherm with a concentration of 2-MeImpG equal to 5.55 +/- 0.15 mM at half occupancy. UV spectroscopy was employed to establish the binding of other guanosine derivatives on poly(C). These derivatives are guanosine 5'-monophosphate (5'GMP), guanosine 5'-monophosphate imidazolide (ImpG), and guanosine 5'-monophosphate morpholidate (morpG). Within experimental error these guanosine derivatives exhibit the same affinity for poly(C) as 2-MeImpG.

Non-NASA Center↗

Nitric oxide inhibits calpain-mediated proteolysis of talin in skeletal muscle cells

We tested the hypothesis that nitric oxide can inhibit cytoskeletal breakdown in skeletal muscle cells by inhibiting calpain cleavage of talin. The nitric oxide donor sodium nitroprusside prevented many of the effects of calcium ionophore on C(2)C(12) muscle cells, including preventing talin proteolysis and release into the cytosol and reducing loss of vinculin, cell detachment, and loss of cellular protein. These results indicate that nitric oxide inhibition of calpain protected the cells from ionophore-induced proteolysis. Calpain inhibitor I and a cell-permeable calpastatin peptide also protected the cells from proteolysis, confirming that ionophore-induced proteolysis was primarily calpain mediated. The activity of m-calpain in a casein zymogram was inhibited by sodium nitroprusside, and this inhibition was reversed by dithiothreitol. Previous incubation with the active site-targeted calpain inhibitor I prevented most of the sodium nitroprusside-induced inhibition of m-calpain activity. These data suggest that nitric oxide inhibited m-calpain activity via S-nitrosylation of the active site cysteine. The results of this study indicate that nitric oxide produced endogenously by skeletal muscle and other cell types has the potential to inhibit m-calpain activity and cytoskeletal proteolysis.

NASA Discipline Musculoskeletal↗

Catecholaminergic effects of prolonged head-down bed rest

Prolonged head-down bed rest (HDBR) provides a model for examining responses to chronic weightlessness in humans. Eight healthy volunteers underwent HDBR for 2 wk. Antecubital venous blood was sampled for plasma levels of catechols [norepinephrine (NE), epinephrine, dopamine, dihydroxyphenylalanine, dihydroxyphenylglycol, and dihydroxyphenylacetic acid] after supine rest on a control (C) day and after 4 h and 7 and 14 days of HDBR. Urine was collected after 2 h of supine rest during day C, 2 h before HDBR, and during the intervals 1-4, 4-24, 144-168 (day 7), and 312-336 h (day 14) of HDBR. All subjects had decreased plasma and blood volumes (mean 16%), atriopeptin levels (31%), and peripheral venous pressure (26%) after HDBR. NE excretion on day 14 of HDBR was decreased by 35% from that on day C, without further trends as HDBR continued, whereas plasma levels were only variably and nonsignificantly decreased. Excretion rates of dihydroxyphenylglycol and dihydroxyphenylalanine decreased slightly during HDBR; excretion rates of epinephrine, dopamine, and dihydroxyphenylacetic acid and plasma levels of catechols were unchanged. The results suggest that HDBR produces sustained inhibition of sympathoneural release, turnover, and synthesis of NE without affecting adrenomedullary secretion or renal dopamine production. Concurrent hypovolemia probably interferes with detection of sympathoinhibition by plasma levels of NE and other catechols in this setting. Sympathoinhibition, despite decreased blood volume, may help to explain orthostatic intolerance in astronauts returning from spaceflights.

Non-NASA Center↗

Person to Person Biological Heat Bypass During EVA Emergencies

During EVA and other extreme environments, mutual human support is sometimes the last way to survive when there is a failure of the life support equipment. The possibility to transfer a coolant to remove heat or a warming fluid to increase heat from one individual to another to support the thermal balance of the individual with system failure was assessed. The following scenarios were considered: 1. one participant has a cooling system that is not working well and already has a body heat deficit equal to 100-120 kcal and a finger temperature decline to 25 C; 2. one participant has the same status of overcooling and the other mild overheating. Preliminary findings showed promise in using such sharing tactics to extend the time duration of survival in extreme situations when there is a high metabolic rate in the donor.

Koscheyev, Victor S.↗

Lightweight Carbon-Carbon High-Temperature Space Radiator

A document summarizes the development of a carbon-carbon composite radiator for dissipating waste heat from a spacecraft nuclear reactor. The radiator is to be bonded to metal heat pipes and to operate in conjunction with them at a temperature approximately between 500 and 1,000 K. A goal of this development is to reduce the average areal mass density of a radiator to about 2 kg/m(exp 2) from the current value of approximately 10 kg/m(exp 2) characteristic of spacecraft radiators made largely of metals. Accomplishments thus far include: (1) bonding of metal tubes to carbon-carbon material by a carbonization process that includes heating to a temperature of 620 C; (2) verification of the thermal and mechanical integrity of the bonds through pressure-cycling, axial-shear, and bending tests; and (3) construction and testing of two prototype heat-pipe/carbon-carbon-radiator units having different radiator areas, numbers of heat pipes, and areal mass densities. On the basis of the results achieved thus far, it is estimated that optimization of design could yield an areal mass density of 2.2 kg/m (exp 2) close to the goal of 2 kg/m(exp 2).

Miller, W.O.↗

The Formation of Filament Threads in a Sheared Magnetic Field

This slide presentation reviews the mechanism that form the filament threads in the sheared magnetic field of the solar photosphere. There are observations of the filaments, a chart showing the magnetic field configuration for the filaments, and charts that show the thermal instability, and thermal conduction. Discussion of the question "How is it possible for a magnetic field to inhibit heat flow in a coronal plasma without simultaneously restricting the mass flow required for the growth of density condensations?" is reviewed. Equations that are used in the model are given. The characteristics of dynamic condensations are reviewed. There are charts that show the density perturbations for principal dynamic condensation mode and 1st harmonic. The characteristics of the kinematic condensations are also discussed. The types of perturbations that were studied are: (1) Generic perturbation with T(sub 0) < T(sub c) (2) Generic perturbation with T(sub 0) = T(sub c) (3) Random perturbation with T(sub 0)< T(sub c).

condensational instability↗

Development and Progress in Enabling the Photocatalyst Ti02 Visible-Light-Active

Photocatalytic oxidation (PCO) of organic contaminants is a promising air and water quality management approach which offers energy and cost savings compared to thermal catalytic oxidation (TCO). The most widely used photocatalyst, anatase TiO2, has a wide band gap (3.2 eV) and is activated by UV photons. Since solar radiation consists of less than 4% UV, but contains 45% visible light, catalysts capable of utilizing these visible photons need to be developed to make peo approaches more efficient, economical, and safe. Researchers have attempted various approaches to enable TiO2 to be visible-light-active with varied degrees of success'. Strategies attempted thus far fall into three categories based on their electrochemical' mechanisms: 1) narrowing the band gap of TiO2 by implantation of transition metal elements or nonmetal elements such as N, S, and C, 2) modifying electron-transfer processes during PCO by adsorbing sensitizing dyes, and 3) employing light-induced interfacial electron transfer in the heteronanojunction systems consisting of narrow band gap semiconductors represented by metal sulfides and TiO2. There are diverse technical approaches to implement each of these strategies. This paper presents a review of these approaches and results of the photocatalytic activity and photonic efficiency of the end .products under visible light. Although resulting visible-light-active (VLA) photocatalysts show promise, there is often no comparison with unmodified TiO2 under UV. In a limited number of studies where such comparison was provided, the UV-induced catalytic activity of bare TiO2 is much greater than the visible-light-induced catalytic activity of the VLA catalyst. Furthermore, VLA-catalysts have much lower quantum efficiency compared to the approx.50% quantum efficiency of UV-catalysts. This stresses the need for continuing research in this area.

Levine, Lanfang H.↗

High Temperature Antenna Measurement System with GSG or GS Contact Probing Capability

Applications that require data transmission at high temperatures are becoming more common due to growing commercial and military needs. Antennas are an indispensable part of these systems and the ability to characterize them at elevated temperatures is quite complicated with little or no information being reported on the subject [1]. This paper describes a measurement system that can characterize planar antennas up 600 C with ground-signal-ground (GSG) or ground-signal (GS) probe contacts. The return loss and radiation patterns of a folded slot antenna (FSA), designed to operate at 5 GHz (no ground plane on back side) and fabricated on an alumina substrate, are presented at room temperature (RT) and 250 C [2]. All measurements were made with Agilent's Precision Network Analyzer (PNA) E8361. The return loss and radiation patterns were also measured on a Styrofoam chuck to illustrate the effect the high temperature measurement system has on the patterns.

Jordan, Jennifer L.↗

Electrolytes for Use in High Energy Lithium-Ion Batteries with Wide Operating Temperature Range

Objectives of this work are: (1) Develop advanced Li -ion electrolytes that enable cell operation over a wide temperature range (i.e., -30 to +60C). (2) Improve the high temperature stability and lifetime characteristics of wide operating temperature electrolytes. (3) Improve the high voltage stability of these candidate electrolytes systems to enable operation up to 5V with high specific energy cathode materials. (4) Define the performance limitations at low and high temperature extremes, as well as, life limiting processes. (5) Demonstrate the performance of advanced electrolytes in large capacity prototype cells.

voltage stability↗

Analysis of Proposed 2007-2008 Revisions to the Lightning Launch Commit Criteria for United States Space Launches

Ascending space vehicles are vulnerable to both natural and triggered lightning. Launches under the jurisdiction of the United States are generally subject to a set of rules called the Lightning Launch Commit Criteria (LLCC) (Krider etal., 1999; Krider etal., 2006). The LLCC protect both the vehicle and the public by assuring that the launch does not take place in conditions posing a significant risk of a lightning strike to the ascending vehicle. Such a strike could destroy the vehicle and its payload, thus causing failure of the mission while releasing both toxic materials and debris. To assure safety, the LLCC are conservative and sometimes they may seriously limit the ability of the launch operator to fly as scheduled even when conditions are benign. In order to safely reduce the number of launch scrubs and delays attributable to the LLCC, the Airborne Field Mill (ABFM II) program was undertaken in 2000 - 2001. The effort was directed to collecting detailed high-quality data on the electrical, microphysical, radar and meteorological properties of thunderstorm-associated clouds. Details may be found in Dye et al., 2007. The expectation was that this additional knowledge would provide a better physical basis for the LLCC and allow them to be revised to be less restrictive while remaining at least as safe. That expectation was fulfilled, leading to significant revisions to the LLCC in 2003 and 2005. The 2005 revisions included the application of a new radar-derived quantity called the Volume Averaged Height Integrated Radar Reflectivity (VAHIRR) in the rules governing flight through anvil clouds. VAHIRR is the product of the volume averaged radar reflectivity times the radardetermined cloud thickness. The reflectivity average extends horizontally 5 km west, east, south and north of a point along the flight track and vertically from the 0 C isotherm to the top of the radar cloud. This region is defined as the "Specified Volume". See Dye et al., 2006 and Merceret et al., 2006 for a more thorough description of VAHIRR. The units are dBZ km (not dBZ per kilometer) and the threshold is 10 dBZ km. It is safe to fly through an anvil cloud for which VAHIRR is below this threshold everywhere along the flight track as long as (1) the entire cloud within 5 nmi. (9.26 km) of the flight track is colder than 0 C, (2) the points at which VAHIRR must be evaluated are at least 20 km from any active convective cores and recent lightning, and (3) the radar return is not being attenuated within the Specified Volume around those points.

Dye, James E.↗

Factors Affecting the Ductility and Strength of NaCl Single Crystals Tested in Flexure

An experimental investigation has revealed that the initial deformation of NaCl single crystals is anelastic rather than Hookean. This anelastic deformation is manifested by a low slope foot in the load‐deflection curve. The magnitude of the foot is dictated by the pretreatment given the specimen. Treatments which increase or decrease the fresh dislocation density respectively increase or decrease the length of the initial anelastic foot. The order of increasing ductility and strength with specimen pretreatment was found to be (1) heated at 135 C, (2) as cleaved, (3) coated with silver, (4) heated at 135 C and then water polished, (5) water polished and then coated with silver, (6) water polished, (7) water polished and then heated at 135 C, (8) annealed at 700 C, and (9) annealed at 700 C and then water polished. The experimental results have been discussed in terms of the role played in deformation and fracture by surface cracks, grown‐in dislocations, and fresh dislocations.

Stearns, C. A.↗