Heavy‐ion dominance near Cluster perigees
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The rate coefficients for the first and second steps in the clustering sequence of H2CN(+) ions with HCN, H2CN(+) + HCN + M - H2CN(+) (HCN) + M and H2CN(+) (HCN) + HCN + M - H2CN(+) (HCN)2 + M, have been measured at temperatures from 189 to 296 K for M = He. The three-body association rate coefficients for both reactions are least-squares fitted for a power dependence on gas temperature. The temperature dependences of the three-body association reaction rate coefficients fitted in the range 200 to 300 K are given. The absolute values and temperature dependences are rather similar.
Construction and method of arranging plurality of ion engines to form cluster thereby increasing efficiency and control by decreasing heat radiated to space
To monitor the descriptive parameters of the lower ionosphere and construct a model which predicts their temporal and spatial variations is a particularly difficult task. In a given situation simultaneous measurements should be conducted of ionization sources, the altitude distribution of all neutral atmospheric constituents, the identification, number density, and altitude distribution of different species of positive and negative ions and electrons. These results are compared with theoretical predictions to serve as boundary conditions and guides to modification of the theory. It has not been possible to realize this goal in lower ionosphere research because of the large number of parameters and since certain parameters, such as positive ion species distribution and nitric oxide, can only be measured with the aid of sounding rockets. To illustrate the difficulty, recent positive ion composition measurements are compared with predictions utilizing clustering of ions and neutrals to form hydrated ions.
The cluster spacecraft are instrumented with ion emitters for charge neutralization. The emitters produce indium ions at 6 keV. The ion current is adjusted in a feedback loop with instruments measuring the spacecraft potential. The system is based on the evaporation of indium in the apex field of a needle. The design of the active spacecraft potential control instruments, and the ion emitters is presented.
During geomagnetic quiet times, in-situ measurements of ring current energetic ions (few to few tens of keVs) from THEMIS spacecraft often exhibit multiple ion populations at discrete energies that extend from the inner magnetosphere to the magnetopause at dayside or plasma sheet at nightside. During geomagnetic storm times, the levels of fluxes as well as the mean energies of these ions elevated dramatically and the more smooth distributions in energies and distances during quiet times are disrupted into clusters of ion populations with more confined spatial extends. This reveals local plasma heating processes that might have come into play. Several processes have been proposed. Magnetotail dipolarization, sudden enhancement of field-aligned current, local current disruptions, and plasma waves are possible mechanisms to heat the ions locally as well as strong convections of energetic ions directly from the magnetotail due to reconnections. We will examine two geomagnetic storms on October 11, 2008 and July 22, 2009 to reveal possible heating mechanisms. We will analyze in-situ plasma and magnetic field measurements from THEMIS, GOES, and DMSP for the events to study the ion pitch angle distributions and magnetic field perturbations in the auroral ionosphere and inner magnetosphere where the plasma heating processes occur.
Report describes experimental and computer-simulation study of multiple-bit errors caused by impingement of single energetic ions on 256-Kb dynamic random-access memory (DRAM) integrated circuit. Studies illustrate effects of different mechanisms for transport of charge from ion tracks to various elements of integrated circuits. Shows multiple-bit errors occur in two different types of clusters about ion tracks causing them.
Two of the many sounding rockets launched as part of the MAC/Epsilon campaign are particularly suited to test the validity or quality of D region models. The measurements covered atomic oxygen, neutral temperatures and fluxes of charged particles. With these parameters as inputs, one is thus in the position to assess their relevance for the measured parameters, i.e., ion composition, transition heights of clusters and negative ions and total plasma density. The two IOMAS payloads are believed to be the only night flights with associated measurements of atomic oxygen extending below the ledge at about 80 km.
This paper provides an overview of NASA s activities in the area of electric propulsion with an emphasis on project directions, recent progress, and a view of future project directions. The goals of the electric propulsion programs are to develop key technologies to enable new and ambitious science missions and to transfer these technologies to industry. Activities include the development of gridded ion thruster technology, Hall thruster technology, pulsed plasma thruster technology, and very high power electric propulsion technology, as well as systems technology that supports practical implementation of these advanced concepts. The performance of clusters of ion and Hall thrusters is being revisited. Mission analyses, based on science requirements and preliminary mission specifications, guide the technology projects and introduce mission planners to new capabilities. Significant in-house activity, with strong industrial/academia participation via contracts and grants, is maintained to address these development efforts. NASA has initiated a program covering nuclear powered spacecraft that includes both reactor and radioisotope power sources. This has provided an impetus to investigate higher power and higher specific impulse thruster systems. NASA continues to work closely with both supplier and user communities to maximize the understanding and acceptance of new technology in a timely and cost-effective manner. NASA s electric propulsion efforts are closely coordinated with Department of Defense and other national programs to assure the most effective use of available resources. Several NASA Centers are actively involved in these electric propulsion activities, including, the Glenn Research Center, Jet Propulsion Laboratory, Johnson Space Center, and Marshall Space Flight Center.
The bullfrog saccule, a sensor of gravity and substrate-borne vibration, is a model system for hair cell transduction. Saccular hair cells also increase in number throughout adult life and rapidly recover after hair cell damage, making this organ an ideal system for studying hair cell development, repair, and regeneration. We have used of hair cell and supporting cell immunocytochemical markers to identify damaged hair cells and hair cell precursors in organotypic cultures of the bullfrog saccule. We then used an innovative combination of confocal, electron, and time-lapse microscopy to study the fate of damaged hair cells and the origin of new hair cells after gentamicin ototoxicity in normal and mitotically blocked saccular cultures. These studies have shown that gentamicin ototoxicity produces both lethal and sublethal hair cell damage. They have also shown that hair cell recovery in this organ takes place by both the repair of sublethally damaged hair cells and by the replacement of lost hair cells by mitotic regeneration. In parallel studies, we have used biophysical and molecular biological techniques to study the differentiation and innervation of developing, repairing, and regenerating hair cells. More specifically, we have used RT-PCR to obtain the bullfrog homologues of L-type voltage- gated calcium (L-VGCC) and large-conductance Ca(2+)-activated potassium (BK) channel genes. We have then obtained probes for these genes and, using in situ hybridization, begun to examine their expression in the bullfrog saccule and amphibian papilla. We have also used fluorescent-labeled channel toxins and channel toxin derivatives to determine the time of appearance of L-type voltage-gated calcium (L-VGCC) and Ca(2+)-activated potassium (BK) channels and to study dynamic changes in the number, distribution, and co-localization of these proteins in developing, repairing, and regenerating hair cells. Using time-lapse microscopy, we are also studying the dynamic relationship between ion channel clustering and synaptic formation in hair cells and afferent neurons. In future studies, we will determine when hair cell precursors acquire electrical tuning, and, using whole-cell patch-clamp techniques, identify and characterize their L-VGCC and BK currents. We will also use biophysical techniques to determine the number of L-VGCC and BK channels and the size and gating kinetics of their underlying L-VGCC and BK conductances, correlating these variables with the amplitude and frequency of membrane oscillations produced by intracellular current steps. We expect these studies to determine how hair cells regulate ion channel expression to achieve specific physiological responses.
Superfluidity and nucleation concepts demonstrated by superfluid helium in finite geometries which can be tested in spaceborne experiments are discussed. Three specific problems are addressed: the liquid vapor interface, films and droplets, and ion induced clusterings.
The term plasma process diagnostics (PPD) refers to a spectroscopic technique and sensing hardware that have been proposed for monitoring plasma processes used to fabricate electronic devices that feature sizes as small as several nanometers. Nanometer dimensions are characteristic of the quantum level of miniaturization, where single impurity atoms or molecules can drastically change the local properties of the nanostructures. Such changes may be purposely used in nanoscale design but may also be extremely damaging or cause improper operation of the fabricated devices. Determination of temperature and densities of reactants near the developing features is important, since the structural synthesis is affected by characteristics of the local microenvironment. Consequently, sensors capable of nonintrusive monitoring with high sensitivity and high resolution are essential for real-time atomistic control of reaction kinetics and minimizing trace contamination in plasma processes used to fabricate electronic nanodevices. Such process-monitoring sensors are required to be compact, multiparametric, and immune to the harsh environments of processing plasmas. PPD is intended to satisfy these requirements. The specific technique used to implement plasma diagnostics with a PPD sensor would be an advanced version of continuous-wave cavity-ringdown spectroscopy (CW-CRDS) capable of profiling spectral line broadenings in order to derive both Doppler and Stark components. CRDS is based on measurements of the rate of absorption of laser light in an optical resonator. The ultimate sensitivity results from a very long absorption path length within the cavity and immunity to variations in incident laser intensity. The proposed version of this technique would involve the use of multiplexing tunable laser diodes and an actively modulated high-reflectivity optical resonator, thus offering a synergistic combination of simplicity, compactness, high sensitivity, and high resolution. The multiplexing capabilities of diode lasers could be utilized to make the PPD sensor a single, simple, compact, and inexpensive tool for the acquisition of multiparametric data. A PPD sensor would be capable of continuous measurement of such physical parameters as gas temperature, gas velocity, electron number density, and absolute densities of reacting chemical species. A laser beam can be easily adjusted to analyze the immediate vicinity of the growing nanostructures (or features etched down) in real time. The absorption enhancement in an optical cavity would afford the sensitivity needed for measurement of the temperature and densities of species at concentrations significantly lower than measurable by other nonintrusive techniques. It is anticipated that fully developed PPD sensors would enable simultaneous measurement of local temperature and determination of plasma species responsible for the synthesis and functionalization of nanodevices. These sensors would also enable tracking the pathways and origins of damaging contaminants, thereby providing feedback for adjustment of processes to optimize them and reduce contamination. The PPD sensors should also be useful for optimization of conventional microelectronics manufacturing plasma processes. Going beyond plasma processes for fabrication of electronic devices, PPD sensors could be used for monitoring of atoms, molecules, ions, radicals, clusters, and particles in a variety of other settings, including outer space. Because of their high sensitivity, such sensors could also prove useful for detecting traces of illegal drugs and explosives.
Diffusion results from random motion of particles and entities. Diffusion in melts and magmas is due to thermally excited random motion of atoms, ions, and clusters, and plays a critical role in magmatic and volcanic processes. In melts and magmas, diffusion is one of the two mechanisms of mass transfer; the other being bulk flow (referred to as convection or advection). When both are present, diffusion refers to the dispersive motion relative to the mean bulk flow in a given reference frame (Richter et al. 1998). Diffusion plays critical roles in controlling magma mixing (Watson 1982; Koyaguchi 1985, 1989; Lesher 1994; Huber et al. 2009; Guo and Zhang 2020), mineral growth and dissolution rates in magmas (e.g., Watson 1982; Harrison and Watson 1983; Zhang et al. 1989; Newcombe et al. 2014; Macris et al. 2018), bubble growth and dissolution rate in magmas (Sparks 1978; Proussevitch and Sahagian 1998; Liu and Zhang 2000; Zhang 2013), and elemental and isotope fractionation during mineral 2 growth and dissolution (Jambon 1980; Richter et al. 1999, 2003; Watson and Muller 2009; Chopra et al. 2012; Watkins et al. 2014, 2017; Holycross et al. 2016, 2018). As a result, diffusion also plays an essential role in explosive volcanic eruptions and magma crystallization. Furthermore, diffusion has important applications in geospeedometry (Lasaga 1983, 1998; Zhang 1994, 2008; Trail et al. 2016; Zhang and Xu 2016). Experimental investigation of diffusion in geologically relevant silicate melts began to flourish in the 1970’s when micro-analytical measurements of diffusion profiles became available. In addition to the vast number of papers published since then, numerous books and reviews are available for diffusion in silicate melts. Hofmann et al. (1974) edited a book titled “Geochemical Transport and Kinetics” published by Carnegie Institution of Washington. This was the first landmark book summarizing the field. Lasaga and Kirkpatrick (1981) edited a book “Kinetics of Geochemical Processes” as volume 8 of the Reviews in Mineralogy (later becoming Reviews in Mineralogy and Geochemistry) series. Zhang and Cherniak (2010) edited “Diffusion in Minerals and Melts” as volume 72 of Reviews of Mineralogy and Geochemistry series, in which one chapter focused on diffusion theory, five chapters on diffusion in silicate melts (Behrens 2010; Lesher 2010; Liang 2010; Zhang and Ni 2010; Zhang et al. 2010), and other chapters were on experimental, analytical, and computational methods, and diffusion in minerals. Several textbooks covered the principles and applications of diffusion theories (Kirkaldy and Young 1987; Shewmon 1989; Cussler 1997; Lasaga 1998; Zhang 2008; Vrentas and Vrentas 2016), and two classic books covered the mathematics of diffusion (Carslaw and Jaeger 1959; Crank 1975). In preparing for this review chapter, we thought carefully about what to cover for this vast field, and decided to briefly go through the fundamentals of diffusion (more complete review can be found in Chakraborty 1995; Zhang 2008, 2010) and solutions to often-encountered 3 diffusion problems, and then focus on post-2010 diffusion studies on silicate melts and magmas. Here, melts refer to (mostly natural) silicate liquid, and magmas refer to crystal-bearing and/or bubble-bearing melts in which the continuous phase is the melt. There is a large body of work on diffusion in glasses, especially in the materials science literature, which is not covered in this review.
Integrating a clustered, four engine ion propulsion system to the Mariner Mark II spacecraft is shown to reduce total trip time for the five proposed Mariner Mark II missions by fifteen years. In addition, this advanced Solar Electric Propulsion (SEP) system enables rendezvous encounters with five main belt asteroids rather than one. A precursor Advanced Capability Explorer (ACE) technology demonstration vehicle is proposed to investigate SEP spacecraft interaction and control requirements in support of these future mission opportunities. It is shown that the ACE spacecraft could be assembled from existing residual hardware, protoflight equipment and commercially available flight tested components. The ion propulsion system requirements to support ambitious Nuclear Electric Propulsion (NEP) missions are also examined and specific technology development objectives presented.
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With an improved model, accelerated high-field tests can be used to predict gate-oxide breakdown in metal-oxide-semi-conductor (MOS) structures. Principal mechanism in MOS breakdown is mobile-ion emission from metal/oxide interface, which occurs during application of positive gate-bias field. Breakdown is related to clustering of emitted ions at localized defect sites in oxide/silicon interface. Using new model to interpret data, tests that normally take several weeks at low fields to accumulate sufficient statistics can be completed in only a few hours at high fields.
Spatial derivatives of the electron moments can be estimated using data from the four Cluster spacecraft. Using spatial derivatives of the velocity we have computed the vorticity in the plasmasheet for several crossings. What we have found is that vorticity appears to be a common feature in the inner plasmasheet. We will show a number of examples. In at least some of the observations the vorticity is well correlated with the passage of Cluster through the ion diffusion region of known reconnection events. That most of the vorticity events observed are reconnection related cannot be dismissed and in fact observations of vorticity may provide a means to locate times when the Cluster spacecraft are magnetically connected to regions where reconnection is taking place. Understanding the role and source of the vorticity should advance our understanding of the dissipation of the turbulence associated with reconnection. In the course of the presentation we will also touch on the methods used to estimate the spatial derivatives as well as the limitations and assumptions involved.
Trace gases evolved from a polyimide film during its thermal curing stages have been studied using ion-induced nucleation mass spectrometry. The technique involved exposing the test gas sample to a low energy beta source and recording the masses of the ion-induced molecular clusters formed in the reaction chamber. On the basis of the experimentally observed molecular cluster spectra, it has been concluded that the dominant trace component had a molecular weight of 87 atomic mass units. This component has been identified as a molecule of dimethylacetamide (DMAC) which had been used as a solvent in the preparation of the test polyimide specimen. This identification has been further confirmed by comparing the spectra of the test gas sample and the DMAC calibration sample obtained with a conventional mass spectrometer. The advantages of the ion-induced nucleation mass spectrometer versus the conventional mass spectrometer are discussed.