Surface Effects of Flame Spreading over Igniting Composite Solid Propellants Constituents
Flame spreading over surface of igniting composite solid propellant constituents
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Flame spreading over surface of igniting composite solid propellant constituents
The effect of low-speed mixed convection (forced plus buoyant) on concurrent flow flame spread over a thin solid is examined. Computations are carried out using an existing model. Results indicate that seemingly small levels of gravity can significantly alter flame spread rates. Starting with a purely forced flow condition, as gravity is added, the entrainment due to buoyancy lengthens the flame and increases the spread rate significantly. Buoyancy has an influence on the extinction limits. At low speed, the presence of a small gravity level widens the flammability limit.
A theoretical model for the downward spread of a flame in the gas over a semi-infinitely thick fuel bed is presented. Gas-phase chemistry is assumed to proceed at an infinite rate while the fuel bed is taken to pyrolyze at the surface in an Arrhenius fashion. Spread rates and flame shapes are computed for two different ambient oxygen concentrations for gravitational accelerations both below and above that of the earth. Predicted spread rates decrease and actual flame size increases with decreasing gravity. Results agree favorably with available, experimental results and expected results from reduced gravity experimentation.
In the inhabited quarters of orbiting spacecraft, fire is a greatly feared hazard. Thus, the fire safety strategy in a spacecraft is (1) to keep any fire as small as possible, (2) to detect any fire as early as possible, and (3) to extinguish any fire as quickly as possible. This suggests that a material which undergoes a momentary ignition might be tolerable but a material which permits a transition from a localized ignition to flame spread would significantly increase the fire hazard in a spacecraft. If the transition does not take place, fire growth does not occur. Therefore, it is critical to understand what process controls the transition. Many previous works have studied ignition and flame spread separately or were limited to a two-dimensional configuration. In this study, time-dependent phenomena of the transition over a thermally thin sample is studied experimentally and theoretically in two- and three-dimensional (2D,3D) configurations. Furthermore, localized ignition can be initiated at the center portion of thermally thin paper sample instead of at one end of the sample. Thus, the transition to flame spread could occur either toward upstream or downstream or both directions simultaneously with an external flow. In this presentation, the difference in the transition between the 3D and 2D configurations is explained with the numerically calculated data. For sufficiently narrow samples edge effects exist. Some results on this issue are presented. New analysis of the surface smoldering experiments conducted in the space shuttle STS-75 flight is also described.
Localized ignition is initiated by an external radiant source at the middle of a thin solid sheet under external slow flow, simulating fire initiation in a spacecraft with a slow ventilation flow. Ignition behavior, subsequent transition simultaneously to upstream and downstream flame spread, and flame growth behavior are studied theoretically and experimentally. There are two transition stages in this study; one is the first transition from the onset of the ignition to form an initial anchored flame close to the sample surface, near the ignited area. The second transition is the flame growth stage from the anchored flame to a steady fire spread state (i.e. no change in flame size or in heat release rate) or a quasi-steady state, if either exists. Observations of experimental spot ignition characteristics and of the second transition over a thermally thin paper were made to determine the effects of external flow velocity. Both transitions have been studied theoretically to determine the effects of the confinement by a relatively small test chamber, of the ignition configuration (ignition across the sample width vs spot ignition), and of the external flow velocity on the two transitions over a thermally thin paper. This study is currently extending to two new areas; one is to include a thermoplastic sample such poly(methymethacrylate), PMMA, and the other is to determine the effects of sample thickness on the transitions. The recent results of these new studies on the first transition are briefly reported.
The Radiative Ignition and Transition to Spread Investigation (RITSI) is a shuttle middeck Glovebox combustion experiment developed by the NASA Lewis Research Center, the National Institute for Standards and Technology (NIST), and Aerospace Design and Fabrication (ADF). It is scheduled to fly on the third United States Microgravity Payload (USMP-3) mission in February 1996. The objective of RITSI is to experimentally study radiative ignition and the subsequent transition to flame spread in low gravity in the presence of very low speed air flows in two- and three-dimensional configurations. Toward this objective, a unique collaboration between NASA, NIST, and the University of Hokkaido was established to conduct 15 science and engineering tests in Japan's 10-sec drop shaft. For these tests, the RITSI engineering hardware was mounted in a sealed chamber with a variable oxygen atmosphere. Ashless filter paper was ignited during each drop by a tungsten-halogen heat lamp focused on a small spot in the center of the paper. The flame spread outward from that point. Data recorded included fan voltage (a measure of air flow), radiant heater voltage (a measure of radiative ignition energy), and surface temperatures (measured by up to three surface thermocouples) during ignition and flame spread.
The recently developed numerical model of concurrent-flow flame spread over thin solids has been used as a simulation tool to help the designs of a space experiment. The two-dimensional and three-dimensional, steady form of the compressible Navier-Stokes equations with chemical reactions are solved. With the coupled multi-dimensional solver of the radiative heat transfer, the model is capable of answering a number of questions regarding the experiment concept and the hardware designs. In this paper, the capabilities of the numerical model are demonstrated by providing the guidance for several experimental designing issues. The test matrix and operating conditions of the experiment are estimated through the modeling results. The three-dimensional calculations are made to simulate the flame-spreading experiment with realistic hardware configuration. The computed detailed flame structures provide the insight to the data collection. In addition, the heating load and the requirements of the product exhaust cleanup for the flow tunnel are estimated with the model. We anticipate that using this simulation tool will enable a more efficient and successful space experiment to be conducted.
An infrared (IR) camera provides a way of examining temperature trends associated with simulated microgravity flame spread in the Narrow Channel Apparatus (NCA). The IR camera measures the surface temperature of solid poly methyl methacrylate (PMMA) fuel. These tests examine the forward conduction of heat ahead of the flame front in the non-thermally thin fuel.The NCA is a combustion wind tunnel that simulates a microgravity flame spread environment by employing a narrow gap between the fuel and ceiling of the device, limiting the effects of buoyancy. Test conditions of a 5 mm gap, mean opposed flow velocity of 15 cm/s, and fuel thickness of 3 mm are used.PMMA is selected as the fuel due to repeatability of test results, ease of computational modeling, and known combustion mechanics. Using specific lens and bandpass filter combinations the PMMA can be imaged as effectively opaque. The spectral emissivity for PMMA was calculated and incorporated into the calibration of the camera.Surface temperatures from the IR camera are compared to results from thermocouples embedded in the surface of the fuel. The IR camera results show that nontrivial forward conduction occurs during tests, and therefore must be included in computational models of the process.
The characteristics of flame propagation along the interface between a solid fuel and a gaseous oxidizer are considered. It is found that difficulties in a study of this problem are related to the eigenvalue character of the relative velocity of the flame with respect to the oxidizer flow. In the proposed model of flame spreading the difficulties are overcome by retaining the ellipticity of the governing equations and by taking the surface pyrolysis into account. The solution procedure makes use of a sink-source approach and the Fourier-transform method. Flame propagation velocity data computed on the basis of the described approach are compared with experimental results.
The objective of this work is to determine the effect of varying imposed radiation levels on the flame spread and burning characteristics of PMMA in low gravity. The NASA Learjet is used for these experiments; it provides an environment of 10(exp -2) g's for approximately 20 seconds. Flame spread rates are found to increase non-linearly with increased external radiant flux over the range studied. This range of imposed flux values is believed to be sufficient to compensate for the radiative loss from the flame and the surface.
Experiments were conducted in which the burning of cylindrical materials in a flowing oxidant stream was studied. Plexiglas, Nylon, and Teflon fuel specimens were oriented such that the flames spread along the surface in a direction opposed to flowing gas. Correlations of flame spread rate were obtained that were power law relations in terms of pressure, oxygen concentration, and gas velocity.
Experimental data for flame spread down thin fuel samples in an opposing, mixed-convection, boundary-layer flow are analyzed to determine the gas-phase velocity that characterizes how the flame reacts as it spreads toward the leading edge of the fuel sample into a thinning boundary layer. In the forced-flow limit where the cube of the Reynolds number divided by the Grashof number, Re exp 3/Gr, is large, L(q)/L(e), where L(q) is a theoretical flame standoff distance at extinction and L(e) is the measured distance from the leading edge of the sample where extinction occurs, is found to be proportional to Re exp n with n = -0.874 and Re based on L(e). The value of n is established by the character of the flow field near the leading edge of the flame. The Re dependence is used, along with a correction for the mixed-convection situation where Re exp 3/Gr is not large, to construct a Damkohler number with which the measured spread rates correlate for all values of Re exp 3/Gr.
Flame spreading over surface of condensed phase material in quiescent gas environment with reacting component
Experiments show that buoyancy influences the downward spread rate of flames consuming thermally thin fuel beds. For index cards (0.0098 cm half-thickness) and adding-machine tape (0.0043 cm half-thickness), an increase in the buoyancy level causes the spread rate to drop until no flame propagation is possible. A dimensionless spread rate is found to correlate with a Damkoehler number. As the Damkoehler number increases with decreasing buoyancy level brought about by an increase in pressure or a decrease in gravity, the dimensionless spread rate approaches unity. It is also found that a small change in orientation with respect to the vertical is equivalent to a change in the magnitude of gravity in the direction of spread, and power-law relations between the dimensional spread rate and pressure are only valid over a small pressure range.
Solid fuel combustion experiments aboard the ISS examine the effects of confinement on a concurrent, purely-forced-flow flame spread in microgravity environment. The results for a thin, cotton-fiberglass-blended textile fabric fuel are presented. Flat baffles of differing materials are used to alter the radiative boundary conditions with transparent polycarbonate, black anodized aluminum (reflectance ~ 0), and highly polished aluminum (reflectance ~ 1). The baffles are parallel to the fuel sheet and placed symmetrically on each side. The inter-baffle distance is varied to change the boundary conditions for the flow. In all tests, samples are ignited at the upstream leading edge and allowed to burn to completion. Results show that the flame reaches a steady length and spread rate at low flow speeds (< 15 cm/s) for all tested inter-baffle distances. As the distance decreases, the flame length and spread rate first increase then decrease showing an optimal inter-baffle distance. For all baffle types, the flame either fails to ignite or extinguishes before reaching the end of the sample when the inter-baffle distance is too small (~ 1 cm). This is attributed to the reduction of oxygen supply to the flame zone and heat loss to the baffles. The results also show at the same inter-baffle distance, flame length and spread rate are highest for polished aluminum baffles, and lowest for transparent polycarbonate baffles. The differences are most prominent at intermediate tested baffle distances. While the radiative heat feedback from the baffles is expected to increase when the baffle distance decreases, the combustion is limited by the reduced oxygen supply. Near this limit, flame lengths and spread rates are similar for all baffle types.
Flame spread over surface of solid-fuel bed in oxygen-inert environment
Chemical and fluid dynamic parameters effecting the flame spreading process downstream from a bluff-body flame holder
Weight, size, and power constraints severely limit the ability of researchers to fully characterize temperature and species distributions in microgravity combustion experiments. A powerful diagnostic technique, infrared imaging spectrometry, has the potential to address the need for temperature and species distribution measurements in microgravity experiments. An infrared spectrum imaged along a line-of-sight contains information on the temperature and species distribution in the imaged path. With multiple lines-of-sight and approximate knowledge of the geometry of the combustion flowfield, a three-dimensional distribution of temperature and species can be obtained from one hyperspectral image of a flame. While infrared imaging spectrometers exist for collecting hyperspectral imagery, the remaining challenge is retrieving the temperature and species information from this data. An initial version of an infrared analysis software package, called CAMEO (Combustion Analysis Model et Optimizer), has been developed for retrieving temperature and species distributions from hyperspectral imaging data of combustion flowfields. CAMEO has been applied to the analysis of multispectral imaging data of flame spread over a PMMA surface in microgravity that was acquired in the DARTFire program. In the next section of this paper, a description of CAMEO and its operation is presented, followed by the results of the analysis of microgravity flame spread data.