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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

The Effects of Polyolefin Structure and Source on Pyrolysis-Derived Plastic Oil Composition

Seven types of plastics were pyrolyzed in a fluidized bed reactor: post-consumer recycled (PCR) high-density polyethylene (HDPE), PCR polypropylene (PP), virgin resins of varying molecular weights of HDPE, virgin resins of low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and (PP). Pyrolysis produced non-condensable gases (C1-C3), liquid phase products (C4-C40), and solids (C40+ and chars), with alkane, alkene, alkadiene, aromatic, and multi-cycloaromatics as the predominant compounds. Polymer structure had the greatest impact on product distribution, with minimal influence from molecular weight. Branches in polyethylene (PE) acted as thermal defects initiating degradation. Higher branch density in PE led to increased concentrations of aromatics, branched alkanes, and internal alkenes. PP and PE exhibited distinct degradation mechanisms, with PP requiring less energy for decomposition and yielding more oil. Here, pyrolysis oil from PCR HDPE and PCR PP contained a higher proportion of branched compounds. Additives in PCR plastics may promote isomerization during pyrolysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Decoupling the capacity fade contributions in polymer electrolyte-based high-voltage solid-state batteries

Polymer electrolyte (PE)-based solid-state batteries (PE-SSBs) made with high-voltage cathodes are known to suffer from severe capacity fade, stemming primarily from the poor oxidative stability of most PEs under high-voltage cycling conditions. PEs also suffer from greater ion-transport limitations compared to liquid or solid electrolytes. However, often, these limitations are collectively stated to be responsible for the observed capacity fade, and it is challenging to decouple the contributions of different factors. Herein, a tunable cell fabrication platform was developed to systematically investigate and decouple the two primary capacity fade drivers (cell impedance growth and kinetic limitations), while keeping the other cell parameters constant. Three PE types with distinct transport characteristics were compared. By utilizing a voltage profile analysis method, the contribution of the cell's internal impedance growth was quantitatively decoupled from the kinetic limitations stemming from the high concentration gradient in the polymer catholyte and slow charge transfer reactions. We demonstrate that the high interfacial impedance did not necessarily correlate with the high capacity fade rate. Kinetic limitations that are not reflected by impedance measurements can play a dominant role in causing cumulative capacity decay.

Ock, Ji-young [Oak Ridge National Laboratory (ORNL↗
DOE OSTI2025

Enhancing Thermal Transport in Polymeric Composites Via Engineered Noncovalent Filler–Polymer Interactions

Understanding thermal transport mechanisms in polymeric composites allows us to expand the boundaries of thermal conductivity in them, either increasing it for more efficient heat dissipation or decreasing it for better thermal insulation. But, these mechanisms are not fully understood. Systematic experimental investigations remain limited. Practical strategies to tune the interfacial thermal resistance (ITR) between fillers and polymers and the thermal conductivity of composites remain elusive. Here, we studied the thermal transport in representative polymer composites, using polyethylene (PE) or polyaniline (PANI) as matrices and graphite as fillers. PANI, with aromatic rings in its backbone, interacts with graphite through strong noncovalent π–π stacking interactions, whereas PE lacks such interactions. We can then quantify how π–π stacking interactions between graphite and polymers enhance thermal transport in composites. PE/graphite and PANI/graphite composites with the same 1.5% filler volume fractions show a ∼22.82% and ∼34.85% enhancement in thermal conductivity compared to pure polymers, respectively. Calculated ITRs in PE/graphite and PANI/graphite are ~6 x 10 -8 m 2 KW -1 and ~1 x 10 -8 m 2 KW -1 , respectively, highlighting how π–π stacking interactions reduce ITR. Molecular dynamics (MD) simulations suggest that π–π stacking interactions between PANI chains and graphite surfaces enhance alignment of PANI's aromatic rings with graphite surfaces. This allows more carbon atoms from PANI chains to interact with graphite surfaces at a shorter distance compared to PE chains. Finally, our work indicates that tuning the π–π stacking interactions between polymers and fillers is an effective approach to reduce the ITR and enhance the thermal conductivity of composites.

atoms↗
DOE OSTI2025

Pigment removal from reverse-printed laminated flexible films by solvent-targeted recovery and precipitation

The solvent-targeted recovery and precipitation (STRAP) process separates and recovers the constituent resins in multilayer plastic packaging films by selective polymer dissolution. In this work, the cause of coloring in the STRAP-recycled polyethylene (PE) resins from postindustrial printed films was identified as decomposed diarylide pigments. Two different approaches are needed to completely remove the dissolved colorants during the STRAP process including (i) adding an activated carbon (AC) adsorbent to the solvent after polymer dissolution and (ii) proper mechanical filtration of the polymer-solvent cake to remove as much solvent from the cake as possible. Colorless recycled PE can be produced by a combination of the proposed approaches (choosing the proper solvent, adding an AC adsorbent, and doing proper mechanical filtration) with minimal accumulation of colorants in the recycled STRAP solvents. This study demonstrated that high-quality STRAP low-density PE can be obtained from printed plastic films, enhancing the potential circularity of these packaging materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Generation of fast photoelectrons in strong-field emission from metal nanoparticles

We investigated the generation and control of fast photoelectrons (PEs) by exposing plasmonic nanoparticles (NPs) to short infrared (IR) laser pulses with peak intensities between 10 12 and 3 × 10 13 W/cm 2 . Our measured and numerically simulated PE momentum distributions demonstrate the extent to which PE yields and cutoff energies are controlled by the NP size, material, and laser peak intensity. For strong-field photoemission from spherical silver, gold, and platinum NPs with diameters between 10 and 100 nm our results confirm and surpass extremely high PEs cutoff energies, up to several hundred times the incident laser-pulse ponderomotive energy, found recently for gold nanospheres [Saydanzad et al., Nanophotonics 12, 1931 (2023)]. As reported previously for dielectric NPs [Rupp et al., J. Mod. Opt. 64, 995 (2017)], at higher intensities the cutoff energies we deduce from measured and simulated PE spectra tend to converge to a metal-independent limit. We expect these characteristics of light-induced electron emission from prototypical plasmonic metallic nanospheres to promote the understanding of the electronic dynamics in more complex plasmonic nanostructures and the design of nanoscale light-controlled plasmonic electron sources for photoelectronic devices of applied interest.

electron source↗
DOE OSTI2024

ARC-SAFE: Accelerated Response semiconducting Contactors and Surge Attenuation For DC Electrical systems (Final Scientific/Technical Report)

The landscape of power transmission and distribution is quickly evolving as more power conversion is done through power electronics and transmitted or distributed at medium voltage direct current (MVDC). As power electronics tend to store less energy and be less resilient to faults than conventional power transformers, a reliable and fast protection against faults is critical to protect power electronics (PE) based infrastructure, especially for medium- and high-voltage applications. This motivates the development of PE based protection circuits to replace slower contemporary electromechanical breakers. In this project a novel PE based MVDC circuit breaker is developed; the new design is comprised of 1) a normally-on leg made of commercially-available, cascaded SiC junction field effect transistors (JFETs) with a passive balancing network, and 2) a normally-off leg based on an optically-triggered gallium nitride (GaN) photoconductive semiconductor switch (PCSS). The normally-off leg was designed to be quickly turned on, to divert current to an auxiliary dissipative circuit, as the normally-on leg is turned off. This approach, using solid-state devices, was selected for a high-performance, fast-switching operation for the DC circuit breaker as compared to approaches that use slower mechanical switches. To be practical, the circuit breaker must have low conduction loss (low Ron) in the normally-on leg and fast coordinated triggering of the normally-off leg to avoid damage from inductive flyback, which could be considerable for long lengths of cable.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1984

A simple expression for kilometric radiation growth rates and analytical applications

A simple expression is derived for the linear growth rate of R-X mode, auroral kilometric radiation under the assumptions of cold plasma wave dispersion and (omega sub pe)-squared is much less than (Omega sub e)-squared, where omega sub pe and Omega sub e are the electron plasma frequency and gyrofrequency, respectively. The result is valid for all wave normal angles and all frequencies above the right-hand cutoff frequency. With this expression, it is not necessary to evaluate the full dispersion tensor, and variations of the growth rate with plasma parameters are easily obtained. Applying the new expression, it is found that kilometric radiation growth rates are strongly dependent upon the magnitude of the magnetic field-aligned potential difference, and that significant growth of radiation at harmonics of the fundamental is unlikely in regions where (omega sub pe)-squared is much less than (Omega sub e)-squared.

Lyons, L. R.↗
NASA NTRS1984

The effect of surface contamination on thermocapillary flow in a two-dimensional slot

In an analysis of the effect of insoluble surfactants on the steady capillary flow in a shallow slot, the problem is formulated as a two-dimensional channel heated differentially from the side, with a free surface on which an insoluble surface species is adsorbed. The vertical boundaries are considered to be isothermal and impenetrable and the lower horizontal boundary to be insulated and impenetrable. Lubrication theory and matched asymptotic expansions are used to reduce the problem to a single nonlinear integral-algebraic equation. For small elasticity E, the surface velocity is nearly constant, with the result that, for small Pe, the surface concentration is nearly uniform while, for large Pe, it develops a boundary layer near the stagnation point at the cold wall, resulting in high local surface concentrations. Condensed surfactant layers will form only with E much less than one and Pe much greater than one.

Homsy, G. M.↗
NASA NTRS1984

A simulation study of the loss cone driven cyclotron maser applied to auroral kilometric radiation

The linear growth and nonlinear saturation of electromagnetic radiation amplified by a hot (5-20 keV) population of electrons possessing a loss cone velocity distribution in the presence of a cold (20-500 eV) electron population are studied. A relativistic electromagnetic simulation code is used to study the emission process. Three cases are presented in detail to illustrate the generation process of auroral kilometric radiation. The first case, which has an electron plasma frequency omega(pe) = 0.2 omega(ce) (electron cyclotron frequency) and possesses a double loss cone distribution, exhibits a strong narrow peak of the fast extraordinary mode (X mode) radiation just above the X mode cutoff frequency. The second case with omega(pe) = 0.2 omega(ce) and a single loss cone distribution shows a preferred direction of propagation for the amplified radiation. The third case with omega(pe) = 0.5 omega(ce) shows a peak in the ordinary mode (O mode) radiation. In all cases, the radiation saturates by turbulent scattering of resonant particles into the loss cone.

Wagner, J. S.↗
NASA NTRS1984

Generation of broadband electrostatic noise by ion beam instabilities in the magnetotail

Particle data from ISEE 1 sampled in the earth's magnetotail show the presence of energetic ion beams in the boundary layer of the plasma sheet. A theory of instabilities driven by the beams is developed and compared with wave data sampled simultaneously to the particle data. It is concluded that the ion beams generate broadband electrostatic bursts of noise. The electrostatic noise correlates well with the occurrence of the beams, and the spectrum is consistent with that predicted from a negative energy beam instability under magnetotail conditions. The theory predicts that a spectrum of growing waves can be driven for frequencies from 0.001 omega(pe) up to omega(pe), the electron plasma frequency, with a spectral peak typically near 0.01 omega(pe) or lower, in agreement with the wave data. Furthermore, as one moves away from the source region perpendicular to the magnetic field, the high frequency components of the observed wave spectra are predicted to disappear gradually, leaving the low frequency part of the spectrum, also as is observed. Evidence is given for significant pitch angle scattering of the beams by the broadband electrostatic noise, leading to more isotropic ion distributions.

Grabbe, C. L.↗
NASA NTRS1985

A study of the adequacy of quasi-geostrophic dynamics for modeling the effect of frontal cyclones on the larger scale flow

The validity of quasi-geostrophic (QG) dynamics were tested on compared to primitive equation (PE) dynamics, for modeling the effect of cyclone waves on the larger scale flow. The formation of frontal cyclones and the dynamics of occluded frontogenesis were studied. Surface friction runs with the PE model and the wavelength of maximum instability is described. Also fine resolution PE simulation of a polar low is described.

Mudrick, S.↗
NASA NTRS1984

Relativistic dispersion, the cyclotron maser instability, and auroral kilometric radiation

It is demonstrated that relativistic effects can significantly modify the wave dispersion in auroral kilometric radiation (AKR), even for only mildly relativistic electrons, when the ratio of the square of the electron plasma frequeny omega(pe) to the square of the electron cyclotron frequency Omega(e) is much less than one, which is frequently the case in the AKR source region. The k-parallel dispersion relation for waves in a relativistic Maxwellian plasma is considered for the case of omega(pe) much less than Omega(e). The results of Shkarovsky (1966) are used to evaluate the relativistic corrections to the R-X mode cutoff. The general relativistic dispersion tensor is applied to evaluate the dispersion relation for a delta function ring distribution in p-perpendicular, again assuming omega(pe) much less than Omega(e). The effect of finite velocity spread is studied by analyzing the Dory-Guest-Harris distribution in the semirelativistic approximation. The results of computer simulations for ring and shell distributions are presented.

Pritchett, P. L.↗
NASA NTRS1987

Estimating the arrival times of photon-limited laser pulses in the presence of shot and speckle noise

Maximum-likelihood (ML) receivers are frequently used to optimize the timing performance of laser-ranging and laser-altimetry systems in the presence of shot and speckle noise. Monte Carlo method was used to examine ML-receiver performance with return signals in the 10-5000-photoelectron (pe) range. The simulations were performed for shot noise only and for shot and speckle noise. The results agree with previous theory for signal strengths greater than about 100 pe's but show that the theory can significantly underestimate timing errors for weaker received signals. Sharp high-bandwidth features in the detected signals are shown to improve timing performance only if their signal levels are greater than 4-5 pe's.

Abshire, James B.↗
NASA NTRS1990

A bit-serial VLSI array processing chip for image processing

An array processing chip integrating 128 bit-serial processing elements (PEs) on a single die is discussed. Each PE has a 16-function logic unit, a single-bit adder, a 32-b variable-length shift register, and 1 kb of local RAM. Logic in each PE provides the capability to mask PEs individually. A modified grid interconnection scheme allows each PE to communicate with each of its eight nearest neighbors. A 32-b bus is used to transfer data to and from the array in a single cycle. Instruction execution is pipelined, enabling all instructions to be executed in a single cycle. The 1-micron CMOS design contains over 1.1 x 10 to the 6th transistors on an 11.0 x 11.7-mm die.

Heaton, Robert↗
NASA NTRS1991

Polymer blends for LDB applications

A series of LCP/PE blends have been studied to determine the potential of such systems to produce a high modulus balloon film material which retains the balloon fabrication and low temperature flight advantages of the current PE films. Blown films of blends of 5 and 15 percent LCP in PE have been produced which show a 28 percent enhancement in modulus over the neat PE matrix. These results are substantially lower than anticipated and are explained in terms of the LCP reinforcement aspect ratio and fibril diameter.

Lichkus, Andrew M.↗
NASA NTRS1987

In vivo synthesis of phosphatidylcholine in rat brain via the phospholipid methylation pathway

The in vivo synthesis of brain phosphatidylcholine (PC) by the methylation of phosphatidylethanolamine (PE) was examined. (H-3)methyl)methionine was infused i.c.v., by indwelling cannula, and brain samples were taken 0.5-18 h thereafter and assayed for (H-3)PC, as well as for its biosynthetic intermediates (H-3)phosphatidyl monomethylethanolamine ((H-3)PMME) and (H-3)phosphatidyl dimethylethanolamine ((H-3)PDME), and for (H-3)lysophosphatidylcholine ((H-3)LPC) and S-(H-3)adenosylmethionine ((H-3)SAM). Most of the (H-3)PC (79-94 percent) was present ipsilateral to the infusion site; indicating that the radioactivity in the (H-3)PC was primarily of intracerebral origin, and not taken up from the blood. Moreover, only very low levels of (H-3)PC were attained in brains of animals receiving (H-3)methionine i.p. and these levels were symmetrically distributed. (H-3)PMME and (H-3)PDME turned over with apparent half-lives of 2.2 h and 2.4 h. In contrast, the accumulation of brain (H-3)PC was biphasic, suggesting the existence of two pools, the more labile of which turned over rapidly (t(sub 1/2) = 5 h) and was formed for as long as (H-3)PMME and (H-3)PDME are present in the brain, and another, which was distinguishable only at 18 h after the (H-3)methionine infusion. (The latter pool may have been synthesized from (H-3)choline that was released via the hydrolysis of some of the brain (H-3)PC previously formed by the methylation of PE.) Subcellular fractionation of brain tissue obtained after in vivo labelling with (H-3)methionine revealed that mitochondrial PC had the highest specific radioactivity (dpm per micromol total lipid phosphorus), and myelin the least. These observations affirm that rat brain does synthesize PC in vivo by methylating PE, and the technique provides an experimental system which may be useful for examining the physiological regulation of this process.

Lakher, Michael↗
NASA NTRS1994

Langmuir turbulence in the auroral ionosphere 1: Linear theory

Intense bursts of Langmuir waves with electric fields of 50 to 500 mV / m have been frequently observed at altitudes greater than 500 km in the auroral ionosphere. These bursts are driven by 20 eV to 4 keV field-aligned electrons, which are embedded in an approximately isotropic nonthermal tail of scattered electrons. The Langmuir bursts are often observed at altitudes where the ionosphere is moderately magnetized (OMEGA (sub e) approximately equals omega (sub pe)). Both the moderate magnetization and the scattered electrons have a major influence on the linear dispersion and damping of Langmuir waves. In particular, the linear dispersion is topologically different depending on whether the magnetic field is subcritical (OMEGA (sub e) less than omega (sub pe)) or supercritical (OMEGA (sub e) greater than omega (sub pe)). The correct dispersion and damping can account for the observed polarization of the Langmuir waves, which is very nearly parallel to the geomagnetic field. Inferred properties of the linear instability driven by the field-aligned electrons are discussed. The linear dispersion and damping derived here provide the basis for a nonlinear turbulence study described in a companion paper (Newman et al., this issue).

Newman, D. L.↗
NASA NTRS1994

The determination of interplanetary magnetic field polarities around sector boundaries using E greater than 2 keV electrons

The determination of the polarities of interplanetary magnetic fields (whether the field direction is outward from or inward toward the sun) has been based on a comparison of observed field directions with the nominal Parker spiral angle. These polarities can be mapped back to the solar source field polarities. This technique fails when field directions deviate substantially from the Parker angle or when fields are substantially kinked. We introduce a simple new technique to determine the polarities of interplanetary fields using E greater than 2 keV interplanetary electrons which stream along field lines away from the sun. Those electrons usually show distinct unidirectional pitch-angle anisotropies either parallel or anti-parallel to the field. Since the electron flow direction is known to be outward from the sun, the anisotropies parallel to the field indicate outward-pointing, positive-polarity fields, and those anti-parallel indicate inward-pointing, negative-polarity fields. We use data from the UC Berkeley electron experiment on the International Sun Earth Explorer 3 (ISSE-3) spacecraft to compare the field polarities deduced from the electron data, Pe (outward or inward), with the polarities inferred from field directions, Pd, around two sector boundaries in 1979. We show examples of large (greater than 100 deg) changes in azimuthal field direction Phi over short (less than 1 hr) time scales, some with and some without reversals in Pe. The latter cases indicate that such large directional changes can occur in unipolar structures. On the other hand, we found an example of a change in Pe during which the rotation in Phi was less than 30 deg, indicating polarity changes in nearly unidirectional structures. The field directions are poor guides to the polarities in these cases.

Kahler, S.↗