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At least 91 records · Page 5

Reconnaissance geologic mapping in the Dry Valleys of Antarctica using the Earth Resources Technology Satellite

The author has identified the following significant results. Reconnaissance geologic mapping can be done with 60-70% accuracy in the Dry Valleys of Antarctica using ERTS-1 imagery. Bedrock geology can be mapped much better than unconsolidated deposits of Quaternary age. Mapping of bedrock geology is facilitated by lack of vegetation, whereas mapping of Quaternary deposits is hindered by lack of vegetation. Antarctic images show remarkable clarity and under certain conditions (moderate relief, selection of the optimum band for specific rock types, stereo-viewing) irregular contacts can be mapped in local areas that are amazing like those mapped at a scale of 1:25,000, but, of course, lack details due to resolution limitations. ERTS-1 images should be a valuable aid to Antarctic geologists who have some limited ground truth and wish to extend boundaries of geologic mapping from known areas.

Houston, R. S.↗

Photoemission from cesium-oxide-activated InGaAsP.

Zinc-doped InGaAsP quaternary III-V material of the proper composition range shows superior photoemission properties to either InGaAs or InAsP ternary material. The minority-carrier diffusion length in the quaternary material is at least as long as that in InAsP and much longer than observed in InGaAs. The barrier height at the InGaAsP-Cs2O interface is lowered by cooling, giving increased electron escape probability and new highs in quantum efficiency over a wide wavelength range. For example, a 1.06-micron quantum efficiency of 7.5%/incident photon was observed at -90 C.

James, L. W.↗

The effect of yttrium and thorium on the oxidation behavior of Ni-Cr-Al alloys

The effect of quaternary additions of 0.5% Y, 0.5 and 1.0% Th to a base alloy of Ni-10CR-5Al on the oxidation behavior and mechanism was studied during oxidation in air over the range of 1000 to 1200 C. The presence of yttrium decreased the oxidation kinetics slightly, whereas, the addition of thorium caused a slight increase. Oxide scale adherence was markedly improved by the addition of the quaternary elements. Although a number of oxides formed on yttrium containing alloys, quantitative X-ray diffraction clearly showed that the rate-controlling step was the diffusion of aluminum through short circuit paths in a thin layer of alumina that formed parabolically with time. Although the scale adherence of the yttrium containing alloy was considerably better than the base alloys, spalling did occur that was attributed to the formation of the voluminous YAG particles which grew in a mushroom-like manner, lifting the protective scale off the subrate locally. The YAG particles formed primarily at grain boundaries in the substrate in which the yttrium originally existed as YNi9.

Kumar, A.↗

Extracting lignins from mill wastes

Addition of quaternary ammonium compound and activated charcoal to pulp and mill wastes precipitates lignins in sludge mixture. Methanol dissolves lignins for separation from resulting slurry. Mineral acid reprecipitates lignins in filtered solution. Quaternary ammonium compound, activated charcoal, as well as water may be recovered and recycled from this process.

Humphrey, M. F.↗

Mossbauer effect studies in iron containing nonmagnetic impurities

Mossbauer parameters of dilute quaternary (Fe-XYZ) alloys where X, Y, Z, are Al, Ge, and La, respectively were studied. A comparison between the computed and the observed values indicates that changes in effective hyperfine field, outer peak widths and the isomer shift predicted on the basis of binary alloys of the individual impurities are equal, within experimental errors, to those obtained in quaternary (Fe-XYZ) alloys. The effects of simultaneously present dilute impurities are shown to be additive, independent of their respective electronic configurations.

Singh, J. J.↗

Nuclear alkylated pyridine aldehyde polymers and conductive compositions thereof

A thermally stable, relatively conductive polymer was disclosed. The polymer was synthesized by condensing in the presence of catalyst a 2, 4, or 6 nuclear alklylated 2, 3, or 4 pyridine aldehyde or quaternary derivatives thereof to form a polymer. The pyridine groups were liked by olefinic groups between 2-4, 2-6, 2-3, 3-4, 3-6 or 4-6 positions. Conductive compositions were prepared by dissolving the quaternary polymer and an organic charge transfer complexing agent such as TCNQ in a mutual solvent such as methanol.

Rembaum, A.↗

Application of multispectral radar and LANDSAT imagery to geologic mapping in death valley

Side-Looking Airborne Radar (SLAR) images, acquired by JPL and Strategic Air Command Systems, and visible and near-infrared LANDSAT imagery were applied to studies of the Quaternary alluvial and evaporite deposits in Death Valley, California. Unprocessed radar imagery revealed considerable variation in microwave backscatter, generally correlated with surface roughness. For Death Valley, LANDSAT imagery is of limited value in discriminating the Quaternary units except for alluvial units distinguishable by presence or absence of desert varnish or evaporite units whose extremely rough surfaces are strongly shadowed. In contrast, radar returns are most strongly dependent on surface roughness, a property more strongly correlated with surficial geology than is surface chemistry.

Daily, M.↗

Discrimination of geologic units in Death Valley using dual frequency and polarization imaging radar data

A simultaneous analysis of dual-frequency and dual-polarization radar imagery of an area located in the central part of Death Valley, Calif., is discussed. The radar imagery analyzed consists of like-polarized L-band, cross-polarized L-band, and like-polarized X-band imagery digitally combined and ratioed to enhance the variation in the backscatter cross section of different geologic units. It is shown that simultaneous analysis of such radar imagery leads to a synergism effect which, in the case of the area studied in Death Valley, allows nearly complete discrimination of surficial geologic units. Radar backscatter is found generally to increase with roughness from smooth Quaternary sand facies to rough and extremely rough Quaternary silty rock salt.

Daily, M.↗

Modified Fabrication for InGaAsP Strip Laser

Improved fabrication of InGaAsP stripe lasers involves replacement of oxide stripe in quaternary laser by an n-type layer of InP grown on top of quaternary cap layer. Process allows use of stop etch that selectively removes InP and does not etch InGaAsP, making fabrication especially convenient.

Ladany, I.↗

A study of tectonic activity in the Basin-Range Province and on the San Andreas Fault. No. 1: Kinematics of Basin-Range intraplate extension

Strain rates assessed from brittle fracture and total brittle-ductile deformation measured from geodetic data were compared to estimates of paleo-strain from Quaternary geology for the intraplate Great Basin part of the Basin-Range, western United States. These data provide an assessment of the kinematics and mode of lithospheric extension that the western U.S. Cordillera has experienced from the past few million years to the present. Strain and deformation rates were determined by the seismic moment tensor method using historic seismicity and fault plane solutions for sub-regions of homogeneous strain. Contemporary deformation in the Great Basin occurs principally along the active seismic zones. The integrated opening rate across the entire Great Basin is accommodated by E-E extension at 8 to 10 mm/a in the north that diminishes to NW-SE extension of 3.5 mm/a in the south. Zones of maximum lithospheric extension correspond to belts of thin crust, high heat flow, and Quaternary basaltic volcanism, suggesting that these parameters are related through mechanism of extension such as a stress relaxation, allowing bouyant uplift and ascension of magmas.

Eddington, P. K.↗

A study of tectonic activity in the Basin-Range Province and on the San Andreas Fault. No. 3: Kinematics of Great Basin intraplate extension from earthquake, geodetic and geologic information

Strain rates assessed from brittle fracture, associated with earthquakes, and total brittle-ductile deformation measured from geodetic data were compared to paleostrain from Quaternary geology for the intraplate Great Basin of the western United States. These data provide an assessment of the kinematics and mode of lithospheric extension that the western U.S. Cordillera has experienced in the last 5 to 10 million years. Strain and deformation rates were determined by the seismic moment tensor method using historic seismicity and fault plane solutions. Contemporary deformation of the Great Basin occurs principally along the active seismic zones. The earthquake related strain shows that the Great Basin is characterized by regional E-W extension at 8.4 mm/a in the north that diminishes to NW-SE extension of 3.5 mm/a in the south. Zones of maximum extension correspond to belts of shallow crust, high heat flow, and Quaternary basaltic volcanism, suggesting that these parameters are related through an effect such as a stress relaxation allowing bouyant uplift and ascension of magmas.

Eddington, P. K.↗

Stress patterns in an interplate shear zone - An effective anisotropic model and implications for the Transverse Ranges, California

The pervasive Quaternary strike-slip (or wrench) structure that occurs in southern California is analyzed by solving a series of planar, linear elastic boundary value problems of tractional type that assume pure shear forces at infinity. It is concluded that the cross-cutting tectonic fabric of the Transverse Ranges in southern California causes the Ranges to act as a stress concentrator. In addition, it is found that rigid rotation of the Transverse Ranges is mechanically supported by an asymmetric distribution of stress and elastic strain encircling it. It is noted that for Quaternary tectonic orientation, a clockwise sense to this rotation is expected.

Ivins, E. R.↗

The mid-quarternary climatic transition as the free response of a three-variable dynamical model

A simplified version of a previously described dynamical model governing global ice mass, atmospheric carbon dioxide, and mean ocean temperature is shown to possess solutions, in a realistic parameter range, that can replicate the main features of the climatic variations implied by the full, two million years, Quaternary delta-O-18 record. These variations include a major 'transition' between a low-ice delta-O-18, low variance mode before roughly 900 kyr BP to a high-ice, high (near 100 kyr period) variance mode after that time to the present. The model contains only three free parameters in this simplified form. No external earth-orbital forcing is prescribed; i.e., the model represents only internal dynamics. From the previous studies it seems clear that additional variance representing such features as the 'rapid' deglaciation and the phase of the major Quaternary oscillation can be largely explained with no more than four additional parameters representing an internal asymmetry and the external perodic forcing. The present results, therefore, constitute a first-order account for the existence of the 'ice age' fluctuations over the last two million years, including the concomitant variations of atmospheric CO2.

Saltzman, Barry↗

Phase compatibilities of YBa2Cu3O(9-delta) type structure in quintenary systems Y-Ba-Cu-O-X (impurity)

Electrical transport properties of the oxidic high T(sub c) superconductors are significantly affected by the presence of minor amounts of various elements adventing as impurities, e.g., from the chemical environment during manufacturing. YBa2Cu3O(9-delta) is prone to an extinction of the superconductivity on (partial) substitution of all four elemental components. E.g., Pr (for Y), La (for Ba), Zn (for Cu) or peroxygroup (for O) substituents will alter some of the superconductivity preconditions, like mixed valence state in Cu3O7/O(9-delta) network or structural distortion of the network. Although various pseudoternary chemical equilibrium phase diagrams of the Y(O)-Ba(O)-Cu(O) system now are available, no consensus is generally shown, however, this is partly due to lack of compatible definitions of the equilibrium conditions. Less information is available about the phase compatibilities in the appropriate quaternary phase diagram (including oxygen) and virtually no information exists about any pentenary phase diagrams (including one impurity). Unfortunately, complexity of such systems, stemming both from number of quaternary or pentenary compounds and from visualizing the five-component phase system, limits this presentation to more or less close surroundings of the YBa2Cu3O(9-delta) type phase in appropriate pseudoquaternary or pseudopseudoternary diagrams, involving Y-Ba-Cu and O, O-CO2, alkaline metals, Mg and alkaline earths, and Sc and most of the 3-d and 4-f elements. The systems were investigated by means of x ray diffraction, neutron diffraction and chemical analytical methods on samples prepared by sol-gel technique from citrates. The superconductivity was characterized by measuring the diamagnetic susceptibility by SQUID.

Karen, P.↗

Thematic Mapper and field investigations at the intersection of the Death Valley and Garlock fault zones, California

Analysis of processed images and detailed field investigations have provided significant information concerning the late-Pliocene and Quaternary evolution of the intersection of the Garlock and Death Valley fault zones. The imagery was used to determine patterns of sedimentation and age relationships on alluvial fans and to determine the geometry, styles of deformation, and relative ages of movements on major and minor faults in the study area. The field investigation often confirmed the inferences drawn from the images and provided additional tectonic and geomorphologic data about the Quaternary deformation of the region. All the data gathered in the course of this project support the contention that the Garlock fault zone terminates in the Avawatz Mountains and that the Death Valley fault zone continues south of the intersection for at least 50 km, forming the eastern boundary of the Mojave province.

Brady, Roland H., III↗

Classification of the LCVF AVIRIS test site with a Kohonen artificial neural network

We present a classification of an AVIRIS spectral image of the Lunar Crater Volcanic Field (LCVF). Geologic mapping from such data is made possible by distinctive mineral signatures: absorption features and the shape of the spectral continuum. The subtle spectral shape differences between some of the geological units in this scene along with the high dimensionality of the spectral presents a challenging pattern recognition task. We found an artificial neural network powerful in separating 13 geological units based on the full spectral resolution. The LCVF, in northern Nye County, Nevada, was the primary focus of the NASA-sponsored Geologic Remote Sensing Field Experiment in the summer of 1989. It consists of over 100 square miles of Quaternary basaltic pyroclastic and flow deposits. These deposits lie atop ignimbrites and silicic lava flows of Tertiary age and in turn are overlain by Quaternary alluvial and playa deposits. This AVIRIS image was collected on September 29, 1989 at 11:44 at 11:44 PDT. The 256-by-256 pixel subsection in this study contains oxidized basaltic cinder deposits, the southern half of the Lunar Lake playa, and outcrops of the Rhyollite of Big Sand Spring Valley. Vegetation in LCVF is sparse, but locally abundant within washes and near springs.

Merenyi, Erzsebet↗

Climatic, eustatic, and tectnoic controls on Quarternary deposits and landforms, Red Sea coast, Egypt

The degree to which local climatic variations, eustatic sea level fluctuations, and tectonic uplift have influenced the development of Quaternary marine and fluvial landforms and deposits along the Red Sea coast, Eastern Desert, was investigated using a combination of remote sensing and field data, age determinations of corals, and numerical simulations. False color composites generated from Landsat Thematic Mapper and SPOT image data, digital elevation models derived from sterophotogrammetric analysis of SPOT data, and field observations document that a approximately 10-km wide swath inland from the coast is covered in many places with coalescing alluvial fans of Quaternary age. Wadis cutting through the fans exhibit several pairs of fluvial terraces, and wadi walls expose alluvium interbedded with corraline limestone deposits Further, three distinct coral terraces are evident along the coatline. Climatic, eustatic, and tectonic uplift controls on the overall system were simulated using a cellular automata algorithm with the following characteristics: (1) uplift as a function of position and time, as defined by the elevations and ages of corals; (2) climatic variations driven by insolation changes associated with Milankovitch cycles; (3) sea level fluctuations based on U/Th ages of coral terraces and eustatic data; and (4) parametrized fluvial erosion and deposition. Results imply that the fans and coralline limestones were generated in a setting in which the tectonic uplift rate decreased over the Quarternary to negligible values at present. Coralline limestones formed furing eustatic highstands when alluvium was trapped uspstream and wadis filled with debris. During lowstands, wadis cut into sedimentary deposits; coupled with continuing uplift, fans were dissected, leaving remnant surfaces, and wadi-related terraces were generated by down cutting. Only landforms from the past three to four eustatic sea level cycles (i.e., approximately 300 to 400 kyr) are likely to have survived erosion and deposition associated with fluvial processes.

Arvidson, Raymond↗

InGaAsSb/GaSb thermophotovoltaic cells

AstroPower is developing InGaAsSb thermophotovoltaic (TPV) devices. This photovoltaic cell is a two-layer epitaxial InGaAsSb structure formed by liquid-phase epitaxy on a GaSb substrate. The (direct) bandgap of the In(1 - x)Ga(x)As(1 -y)Sb(y) alloy is 0.50 to 0.55 eV, depending on its exact alloy composition (x, y); and is closely lattice-matched to the GaSb substrate The use of the quaternary alloy, as opposed to a ternary alloy - such as, for example, InGaAs/InP - permits low bandgap devices optimized for 1000 to 1500 C thermal sources with, with at the time, near-exact lattice matching to the GaSb substrate. Lattice-matching is important since even a small degree of lattice mismatch degrades device performance and reliability and increases processing complexity. For bandgaps of 0.52 eV,Fo internal quantum efficiencies as high as 95% have been measured at a wavelength of 2 microns. At 1 micron wavelengths, internal quantum efficiencies of 55% have been observed. The open-circuit voltage at currents of 0.3 A/sq cm is 0.220 volts and 0.260 V for current densities of 2 A/sq cm. Fill factors of 56% have also been measured. These preliminary results lead to the conclusion that the GaSb-based quaternary compounds provide a viable and high performance energy conversion solution for thermophotovoltaic systems operating with 1000 to 1500 C source temperatures.

Mauk, M. G.↗