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At least 91 records · Page 5

A Surface Science Paradigm for a Post-Huygens Titan Mission

With the Cassini-Huygens atmospheric probe drop-off mission fast approaching, it is essential that scientists and engineers start scoping potential follow-on surface science missions. This paper provides a summary of the first year of a two year design study which examines in detail the desired surface science measurements and resolution, potential instrument suite, and complete payload delivery system. Also provided are design concepts for both an aerial inflatable mobility platform and deployable instrument sonde. The tethered deployable sonde provides the capability to sample near surface atmosphere, sub-surface liquid (if it exists), and surface solid material. Actual laboratory tests of the amphibious sonde prototype are also presented.

Zimmerman, Wayne F.↗

Contextualizing Ancestral Pueblo Turkey (Meleagris gallopavo spp.) Management

Abstract Penning turkeys ( Meleagris gallopavo spp.) in the Ancestral Pueblo American Southwest/Mexican Northwest (SW/NW) involved the creation or use of a variety of spaces and contexts throughout AD 1–1600 and into the post-contact era. Turkey pens, or captivity, occur through simple tethering, reuse of abandoned pit houses or surface rooms, or creation of pens within villages, plazas, and elsewhere. Turkey dung, droppings, and eggshells are fundamental for determining the presence or absence of pens at archaeological sites. In this paper, I review the archaeological record for turkey pens and focus on three main questions: (1) how are turkey pens identified in the SW/NW, (2) if turkey pen construction or evidence for turkey captivity shifts through time, and (3) what the record of turkey penning informs us regarding the long-term human management of these birds and global perspectives on human–bird/human–animal management. Ancestral Pueblo peoples created an adaptive and flexible strategy for turkey penning, which successfully integrated these birds into ceremonial and socioeconomic processes for approximately 1600 years.

59 BASIC BIOLOGICAL SCIENCES↗

High-Energy Hybridized States Enable Long-Lived Hot Electrons in Cobaloxime-Silicon Nanocrystal System

Strong electronic coupling is achieved between the molecular catalyst cobaloxime ([Co]) and silicon nanocrystals (Si NCs) bridged by an ethylenepyridine group derived from vinylpyridine (vpy) covalently bound to the Si NC surface (Si-vpy-[Co]). The ethylenepyridine tether in Si-vpy-[Co] is key to dramatic changes to the system’s physical properties which are not observed in the corresponding formylpyridine (fpy) system (Si-fpy-[Co]) consistent with strong electronic coupling previously observed only in dark electrochemical systems. UV−vis absorption spectroscopy reveals new [Co]-centered electronic states in Si-vpy-[Co], and transient absorption spectroscopy finds a strong absorption feature appearing within 250 fs and persisting for at least 5 ns. Astoundingly, spectroelectrochemical measurements reveal that this absorption feature is consistent with both the singly reduced [Co] − and doubly reduced [Co] 2− complexes, leading to the conclusion that these long-lived charges are derived from high-energy “hot” electrons residing in [Co]-centered states. Detailed analysis using cyclic voltammetry, spectroelectrochemistry, electron paramagnetic resonance spectroscopy, and density functional theory (DFT) calculations provides insight into the unique electronic structure created in Si-vpy-[Co]. DFT reveals that the new electronic states arise from hybridization between deep Si NC band states and high-energy molecular orbitals of the ethylenepyridine tether and the [Co] catalyst and are facilitated by σ-bonding character at the ethylenepyridine linkage. This study demonstrates that strong electronic coupling achieved through precise molecular chemistry can change the paradigm of otherwise fixed energy levels in hybrid photoelectrochemical systems for artificial photosynthesis and related applications.

14 SOLAR ENERGY↗

Tethers and asteroids for artificial gravity assist in the solar system

Analytical models are defined for gravity-assist trajectory changes for spacecraft passing massive compact bodies. The models are applied in an examination of the benefits of lowering a tether to an asteroid during a flyby in order to gain a trajectory change equivalent to that from a massive body (planet). Direct flybys yield velocity gains while retrograde flybys shed velocity. The magnitude of the effects are a function of the proximity to the body during flyby. This inherently limits the gravity assist technique used around planets, which usually have atmospheres and can have intense radiation fields. If a spacecraft could extend a tether (such as to be tested on the Orbiter) to snag on an asteroid surface, the potential trajectory/velocity change of the spacecraft would be limited mainly by the tether strength. The encounter physics are treated as a soft collision. Possible applications of the asteroid tether technique are outer planet, Mars and main belt asteroid exploration missions.

Penzo, P. A.↗

Analysis of a rotating advanced-technology space station for the year 2025

An analysis is made of several aspects of an advanced-technology rotating space station configuration generated under a previous study. The analysis includes examination of several modifications of the configuration, interface with proposed launch systems, effects of low-gravity environment on human subjects, and the space station assembly sequence. Consideration was given also to some aspects of space station rotational dynamics, surface charging, and the possible application of tethers.

Queijo, M. J.↗

Organic nanoparticles with tunable size and rigidity by hyperbranching and cross-linking using microemulsion ATRP

Unlike inorganic nanoparticles, organic nanoparticles (oNPs) offer the advantage of “interior tailorability,” thereby enabling the controlled variation of physicochemical characteristics and functionalities, for example, by incorporation of diverse functional small molecules. In this study, a unique inimer-based microemulsion approach is presented to realize oNPs with enhanced control of chemical and mechanical properties by deliberate variation of the degree of hyperbranching or cross-linking. The use of anionic cosurfactants led to oNPs with superior uniformity. Benefitting from the high initiator concentration from inimer and preserved chain-end functionality during atom transfer radical polymerization (ATRP), the capability of oNPs as a multifunctional macroinitiator for the subsequent surface-initiated ATRP was demonstrated. This facilitated the synthesis of densely tethered poly(methyl methacrylate) brush oNPs. Detailed analysis revealed that exceptionally high grafting densities (~1 nm −2 ) were attributable to multilayer surface grafting from oNPs due to the hyperbranched macromolecular architecture. The ability to control functional attributes along with elastic properties renders this “bottom-up” synthetic strategy of macroinitiator-type oNPs a unique platform for realizing functional materials with a broad spectrum of applications.

ATRP↗

Modifying Silicates for Better Dispersion in Nanocomposites

An improved chemical modification has been developed to enhance the dispersion of layered silicate particles in the formulation of a polymer/silicate nanocomposite material. The modification involves, among other things, the co-exchange of an alkyl ammonium ion and a monoprotonated diamine with interlayer cations of the silicate. The net overall effects of the improved chemical modification are to improve processability of the nanocomposite and maximize the benefits of dispersing the silicate particles into the polymer. Some background discussion is necessary to give meaning to a description of this development. Polymer/silicate nanocomposites are also denoted polymer/clay composites because the silicate particles in them are typically derived from clay particles. Particles of clay comprise layers of silicate platelets separated by gaps called "galleries." The platelet thickness is 1 nm. The length varies from 30 nm to 1 m, depending on the silicate. In order to fully realize the benefits of polymer/silicate nanocomposites, it is necessary to ensure that the platelets become dispersed in the polymer matrices. Proper dispersion can impart physical and chemical properties that make nanocomposites attractive for a variety of applications. In order to achieve nanometer-level dispersion of a layered silicate into a polymer matrix, it is typically necessary to modify the interlayer silicate surfaces by attaching organic functional groups. This modification can be achieved easily by ion exchange between the interlayer metal cations found naturally in the silicate and protonated organic cations - typically protonated amines. Long-chain alkyl ammonium ions are commonly chosen as the ion-exchange materials because they effectively lower the surface energies of the silicates and ease the incorporation of organic monomers or polymers into the silicate galleries. This completes the background discussion. In the present improved modification of the interlayer silicate surfaces, the co-ion exchange strengthens the polymer/silicate interface and ensures irreversible separation of the silicate layers. One way in which it does this is to essentially tether one amine of each diamine molecule to a silicate surface, leaving the second amine free for reaction with monomers during the synthesis of a polymer. In addition, the incorporation of alkyl ammonium ions into the galleries at low concentration helps to keep low the melt viscosity of the oligomer formed during synthesis of the polymer and associated processing - a consideration that is particularly important in the case of a highly cross-linked, thermosetting polymer. Because of the chemical bonding between the surface-modifying amines and the monomers, even when the alkyl ammonium ions become degraded at high processing temperature, the silicate layers do not aggregate and, hence, nanometer-level dispersion is maintained.

Campbell, Sandi↗

Tethered oxygen turns methane into methanol

Precise control of the oxidant — that is, preventing overoxidation — is the missing link in low-temperature methane upgrading. Now, the electro-splitting of carbonate on rutile IrO 2 is shown to cover the surface with on-top oxygen adatoms that act as tethered, single-step hydrogen abstractors. One subset can pull the hydrogen from methane to form a methoxy intermediate, while the neighbouring site can protonate this intermediate to form methanol. Together, this mechanism delivers a room-temperature conversion of methane to methanol with >90% selectivity.

climate-change mitigation↗

Tethers as Debris: Simulating Impacts of Tether Fragments on Shuttle Tiles

The SPHC hydrodynamic code was used to simulate impacts of Kevlar and aluminum projectiles on a model of the LI-900 type insulating tiles used on Space Shuffle Orbiters The intent was to examine likely damage that such tiles might experience if impacted by orbital debris consisting of tether fragments. Projectile speeds ranged from 300 meters per second to 10 kilometers per second. Damage is characterized by penetration depth, tile surface-hole diameter, tile body-cavity diameter, coating fracture diameter, tether and cavity wall material phases, and deformation of the aluminum backwall.

Evans, Steven W.↗

Tethered Lunar Subsatellites for Multipoint and Low Altitude Measurements

The difficulty in making global measurements in orbit close to planetary bodies (and in particular the Moon) seriously constrains our ability to collect crucial, high-resolution data. We describe a unique and groundbreaking approach using tethered subsatellites to make measurements arbitrarily close to planetary surfaces, particularly those with no atmosphere, and to determine altitude profiles of geophysical parameters. The approach is feasible with current technology, and the subsatellite could be as small as a CubeSat. The initial results of a feasibility study and mission design for a tethered lunar CubeSat indicate that it is achievable.

Airless bodies↗

Surface Operations: Two Case Studies of Simulated Lunar Operations

In September 2007, a team of scientists and engineers from several NASA centers participated in a field exercise at Meteor Crater, Arizona. The tests in this field exercise utilized recently developed robots of varying scales and capabilities and humans in pressurized space suits. Two examples of operations performed in the field are presented: a surface operations scenario involving suited crew supported by a number of mobile robots and setup operations for accessing a crater. The surface operations scenario simulated the end of a crew sortie and involved the following agents: 1) Suit subjects from Johnson Space Center s (JSC) advanced spacesuit laboratory 2) JSC's unpressurized crewed rover testbed, SCOUT 3) The Jet Propulsion Laboratory s (JPL) rough terrain, payload carrying robot, ATHLETE 4) JSC's Astronaut assist robot, Robonaut 5) Ames Research Center's (ARC) inspection robot, K-10. Operations began with ATHLETE positioning a pressurized rover compartment (PRC) as two crew members drove the SCOUT unpressurized rover from the field. The crew dismounted SCOUT, walked to the PRC for recharging. Robonaut then removed a sample box from the SCOUT equipment tray. K-10 then performed a drive around inspection of SCOUT, assembling a mosaic image. Lastly, the SCOUT vehicle was remotely driven to the next site. The setup operations for crater access scenario involved ATHLETE and Robonaut. This scenario began with Robonaut approaching ATHLETE and extracting a tether line. ATHLETE then extracted a drill and drilled an anchor into the surface. Robonaut then reconnected the tether to the anchor and backed away. ATHLETE is then ready to descend into the crater. This descending into the crater step is currently in the planning phase.

Bluethmann, William J.↗

Tethered Balloon System Merged Data (TBSMERGED) Value-Added Product Report

The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Tethered Balloon System Merged Data (TBSMERGED) Value-Added Product (VAP) integrates data from instruments flown on ARM’s tethered balloon system missions that collect in situ measurements of temperature, humidity, wind speed, wind direction, and aerosol properties with estimates of cloud base and boundary-layer height from a surface-based ceilometer to improve the ease of use of tethered balloon system (TBS) data sets. The TBSMERGEDINCLOUD VAP, a variation of TBSMERGED, includes supercooled liquid water content (tbsslwc) measurements collected within the cloud.

54 ENVIRONMENTAL SCIENCES↗

Factor VIII moiety of recombinant Factor VIII Fc fusion protein impacts Fc effector function and CD16 + NK cell activation

Recombinant Factor VIII-Fc fusion protein (rFVIIIFc) is an enhanced half-life therapeutic protein product used for the management of hemophilia A. Recent studies have demonstrated that rFVIIIFc interacts with Fc gamma receptors (FcγR) resulting in the activation or inhibition of various FcγR-expressing immune cells. We previously demonstrated that rFVIIIFc, unlike recombinant Factor IX-Fc (rFIXFc), activates natural killer (NK) cells via Fc-mediated interactions with FcγRIIIA (CD16). Additionally, we showed that rFVIIIFc activated CD16 + NK cells to lyse a FVIII-specific B cell clone. Here, we used human NK cell lines and primary NK cells enriched from peripheral blood leukocytes to study the role of the FVIII moiety in rFVIIIFc-mediated NK cell activation. Following overnight incubation of NK cells with rFVIIIFc, cellular activation was assessed by measuring secretion of the inflammatory cytokine IFNγ by ELISA or by cellular degranulation. We show that anti-FVIII, anti-Fc, and anti-CD16 all inhibited indicating that these molecules were involved in rFVIIIFc-mediated NK cell activation. To define which domains of FVIII were involved, we used antibodies that are FVIII domain-specific and demonstrated that blocking FVIII C1 or C2 domain-mediated membrane binding potently inhibited rFVIIIFc-mediated CD16 + NK cell activation, while targeting the FVIII heavy chain domains did not. We also show that rFVIIIFc binds CD16 with about five-fold higher affinity than rFIXFc. Based on our results we propose that FVIII light chain-mediated membrane binding results in tethering of the fusion protein to the cell surface, and this, together with increased binding affinity for CD16, allows for Fc-CD16 interactions to proceed, resulting in NK cellular activation. Our working model may explain our previous results where we observed that rFVIIIFc activated NK cells via CD16, whereas rFIXFc did not despite having identical IgG1 Fc domains.

59 BASIC BIOLOGICAL SCIENCES↗

Comet nucleus and asteroid sample return missions

During the 1991-92 academic year, the Pennsylvania State University has developed three sample return missions: one to the nucleus of comet Wild 2, one to the asteroid Eros, and one to three asteroids located in the Main Belt. The primary objective of the comet nucleus sample return mission is to rendezvous with a short period comet and acquire a 10 kg sample for return to Earth. Upon rendezvous with the comet, a tethered coring and sampler drill will contact the surface and extract a two-meter core sample from the target site. Before the spacecraft returns to Earth, a monitoring penetrator containing scientific instruments will be deployed for gathering long-term data about the comet. A single asteroid sample return mission to the asteroid 433 Eros (chosen for proximity and launch opportunities) will extract a sample from the asteroid surface for return to Earth. To limit overall mission cost, most of the mission design uses current technologies, except the sampler drill design. The multiple asteroid sample return mission could best be characterized through its use of future technology including an optical communications system, a nuclear power reactor, and a low-thrust propulsion system. A low-thrust trajectory optimization code (QuickTop 2) obtained from the NASA LeRC helped in planning the size of major subsystem components, as well as the trajectory between targets.

Melton, Robert G.↗

Navigation on the Line: Traversability Analysis and Path Planning for Extreme-Terrain Rappelling Rovers

Many areas of scientific interest in planetaryexploration, such as lunar pits, icy-moon crevasses, and Martiancraters, are inaccessible to current wheeled rovers. Rappellingrovers can safely traverse these steep surfaces, but requiretechniques to navigate their complex terrain. This dynamicnavigation is inherently time-critical and communication constraints(e.g. delays and small communication windows) willrequire planetary systems to have some autonomy.Autonomous navigation for Martian rovers is well studiedon moderately sloped and locally planar surfaces, but thesemethods do not readily transfer to tethered systems in nonplanar3D environments. Rappelling rovers in these situationshave additional challenges, including terrain-tether interactionand its effects on rover stability, path planning and control.This paper presents novel traversability analysis and pathplanning algorithms for rappelling rovers operating on steepterrains that account for terrain-tether interaction and theunique stability and reachability constraints of a rapellingsystem. The system is evaluated with a series of simulations andan analogue mission. In simulation, the planner was shown toreliably find safe paths down a 55 degree slope when a stabletether-terrain configuration exists and never recommended anunsafe path when one did not. In a planetary analogue mission,elements of the system were used to autonomously navigateAxel, a JPL rappelling rover, down a 30 degree slope with95% autonomy by distance travelled over 46 meters.

Nesnas, Issa↗

Progress in Development of the Axel Rovers

Progress has been made in the development of a family of robotic land vehicles having modular and minimalist design features chosen to impart a combination of robustness, reliability, and versatility. These vehicles at earlier stages of development were described in two previous NASA Tech Briefs articles: "Reconfigurable Exploratory Robotic Vehicles" (NPO-20944), Vol. 25, No. 7 (July 2001), page 56; and "More About Reconfigurable Exploratory Robotic Vehicles" (NPO-30890), Vol. 33, No. 8 (August 2009), page 40. Conceived for use in exploration of the surfaces of Mars and other remote planets, these vehicles could also be adapted to terrestrial applications, including exploration of volcanic craters or other hostile terrain, military reconnaissance, inspection of hazardous sites, and searching for victims of earthquakes, landslides, avalanches, or mining accidents. In addition, simplified versions of these vehicles might be marketable as toys. The most basic module in this family of reconfigurable robots is the Axel rover, which has a cylindrical body with two main wheels and a trailing link. Inside its body are three motors and associated mechanisms for driving the two wheels and for rotating the link 360 around its symmetrical body. The actuated link serves several purposes: It is used as a lever arm to react to the wheels thrust to move Axel in multiple directions. It is used to rotate the Axel housing in order to tilt, to the desired angle, any sensors and instruments mounted on or in the Axel housing. It provides an alternative mobility mode, which is primarily used in its tethered configuration. Turn ing the link into the ground in lieu of driving the wheels causes the Axel housing and wheels to roll as a unit and thereby leads to a tumbling motion along the ground. With a tether mounted around Axel s cylindrical body, the link serves as a winch mechanism to reel and unreel the tether raising and lowering Axel over steep and vertical surfaces (Figure 1). Sensors, computation, and communication modules are also housed inside Axel s body. A pair of stereo vision cameras provides three-dimensional view for autonomous navigation and avoiding obstacles. Inertial sensors determine the tilt of the robot and are used for estimating its motion. In a fully developed version, power would be supplied by rechargeable batteries aboard Axel; at the time of reporting the information for this article, power was supplied from an external source via a cable. In and of itself, the Axel rover is fully capable of traversing and sampling terrains on planetary surfaces. By use of only the two main wheel actuators and the caster link actuator, Axel can be made to follow an arbitrary path, turn in place, and operate upside- down or right-side-up. If operated in a tethered configuration, as shown in Figure 1, it can be made to move down and up a steep crater wall, descend from an overhang to a cave, and ascend from the cave back to the overhang, all by use of the same three actuators. Such tethered operation could be useful in searching for accident victims or missing persons in mines, caves, and rubble piles. Running the tether through the caster link enhances the stability of Axel and provides a restoring force that keeps the link off the ground for the most part during operation on a steep slope. In its extended configuration, two Axel modules can dock to either side of a payload module to form the four wheeled Axel2 rover (Figure 2). Additional payload and Axel modules can dock to either side of the Axel2 to form the Axel3 rover, extending its payload capacity and its mobility capabilities.

Nesnas, Issa A.↗

Applications of tethers for planetary missions

Ideas of deep space exploration are considered. The role of tethers in deep space is of most concern. A proposal of a tethered instrument package in orbit about the Moon is explored. The idea of a sling on the surface of the Moon which would take solar energy and build up momentum of the sling is studied. The NASA idea of a Mars Aeronomy Orbiter which would use a tether to enhance the planned Mars Orbiter is reviewed. It is also proposed that a tether can be attached to an asteroid during a spacecraft flyby. The possibility of using tethers to provide a transportation system for payloads which are coming to the surface from escape, and which are leaving Mars and escaping from Mars itself is also studied. A proposal from the Jet Propulsion Lab. on collecting comet or asteroid samples and returning them to Earth is reviewed. A tethered penetrator which could collect core samples is the proposed way. Also considered is the area of electrodynamic tethers at Jupiter.

Penzo, P.↗

A Surface Science Paradigm for a Post-Huygens Titan Mission

With the Cassini-Huygens atmospheric probe drop-off mission fast approaching, it is essential that scientists and engineers start scoping potential follow-on surface science missions. This paper provides a summary of the first year of a two year design study which examines in detail the desired surface science measurements and resolution, potential instrument suite, and complete payload delivery system. Also provided are design concepts for both an aerial inflatable mobility platform and deployable instrument sonde. The tethered deployable sonde provides the capability to sample nearsurface atmosphere, sub-surface liquid (if it exists), and surface solid material. Actual laboratory tests of the amphibious sonde prototype are also presented.

Cassini-Huygen↗