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At least 91 records · Page 5

Correlated Anion Disorder in Heteroanionic Cubic TiOF 2

Resolving anion configurations in heteroanionic materials is crucial for understanding and controlling their properties. For anion-disordered oxyfluorides, conventional Bragg diffraction cannot fully resolve the anionic structure, necessitating alternative structure determination methods. We have investigated the anionic structure of anion-disordered cubic (ReO 3 -type) TiOF 2 using X-ray pair distribution function (PDF), 19 F MAS NMR analysis, density functional theory (DFT), cluster expansion modeling, and genetic-algorithm structure prediction. Our computational data predict short-range anion ordering in TiOF 2 , characterized by predominant cis-[O 2 F 4 ] titanium coordination, resulting in correlated anion disorder at longer ranges. To validate our predictions, we generated partially disordered supercells using genetic-algorithm structure prediction and computed simulated X-ray PDF data and 19 F MAS NMR spectra, which we compared directly to experimental data. To construct our simulated 19 F NMR spectra, we derived new transformation functions for mapping calculated magnetic shieldings to predicted magnetic chemical shifts in titanium (oxy)fluorides, obtained by fitting DFT-calculated magnetic shieldings to previously published experimental chemical shift data for TiF 4 . We find good agreement between our simulated and experimental data, which supports our computationally predicted structural model and demonstrates the effectiveness of complementary experimental and computational techniques in resolving anionic structure in anion-disordered oxyfluorides. From additional DFT calculations, we predict that increasing anion disorder makes lithium intercalation more favorable by, on average, up to 2 eV, highlighting the significant effect of variations in short-range order on the intercalation properties of anion-disordered materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Variation in Ion Acceleration Characteristics of the HERMeS Hall Thruster During Magnetic Optimization

To reduce design risks for future magnetically shielded Hall thrusters, a test was performed on the HERMeS to obtain data for optimizing the effect of magnetic shielding. As a part of this test, laser-induced fluorescence velocimetry was used to characterize the variations in the ion acceleration with different magnetic configurations. Four magnetic configurations representing varying amounts of magnetic shielding between the high-energy discharge plasma and the discharge channel walls were tested. The ion velocity data points to the possibility that different plasma-wall interaction physics applies to a magnetically shielded thruster than a non-shielded thruster. The transition point is very prominent and can potentially be used to test whether a thruster is fully magnetically shielded.

Hall thrusters↗

Variation in Ion Acceleration Characteristics of the HERMeS Hall Thruster During Magnetic Optimization

To reduce design risks for future magnetically shielded Hall thrusters, a test was performed on the HERMeS to obtain data for optimizing the effect of magnetic shielding. As a part of this test, laser-induced fluorescence velocimetry was used to characterize the variations in the ion acceleration with different magnetic configurations. Four magnetic configurations representing varying amounts of magnetic shielding between the high-energy discharge plasma and the discharge channel walls were tested. The ion velocity data points to the possibility that different plasma-wall interaction physics applies to a magnetically shielded thruster than a non-shielded thruster. The transition point is very prominent and can potentially be used to test whether a thruster is fully magnetically shielded.

HERMeS↗

Evaluation of a method to shield a welding electron beam from magnetic interference

It is known that electron beams are easily deflected by magnetic and electrostatic fields. Therefore, to prevent weld defects, stray electromagnetic fields are avoided in electron beam welding chambers if at all possible. The successful results of tests conducted at MSFC to evaluate a simple magnetic shield made from steel tubing are reported. Tests indicate that this shield was up to 85 percent effective in reducing magnetic effects on the electron beam of a welding machine. In addition, residual magnetic fields within the shield were so nearly uniform that the net effect on the beam alignment was negligible. It is concluded that the shield, with the addition of a tungsten liner, could be used in production welding.

Wall, W. A.↗

Analytical-HZETRN Model for Rapid Assessment of Active Magnetic Radiation Shielding

The use of active radiation shielding designs has the potential to reduce the radiation exposure received by astronauts on deep-space missions at a significantly lower mass penalty than designs utilizing only passive shielding. Unfortunately, the determination of the radiation exposure inside these shielded environments often involves lengthy and computationally intensive Monte Carlo analysis. In order to evaluate the large trade space of design parameters associated with a magnetic radiation shield design, an analytical model was developed for the determination of flux inside a solenoid magnetic field due to the Galactic Cosmic Radiation (GCR) radiation environment. This analytical model was then coupled with NASA's radiation transport code, HZETRN, to account for the effects of passive/structural shielding mass. The resulting model can rapidly obtain results for a given configuration and can therefore be used to analyze an entire trade space of potential variables in less time than is required for even a single Monte Carlo run. Analyzing this trade space for a solenoid magnetic shield design indicates that active shield bending powers greater than 15 Tm and passive/structural shielding thicknesses greater than 40 g/cm2 have a limited impact on reducing dose equivalent values. Also, it is shown that higher magnetic field strengths are more effective than thicker magnetic fields at reducing dose equivalent.

Washburn, S. A.↗

Final Design of the Production SSR1 Cryomodule for PIP-II Project at Fermilab

This contribution reports the design of the production Single Spoke Resonator Type 1 Cryomodule (SSR1 CM) for the PIP-II project at Fermilab. The innovative design is based on a structure, the strongback, which supports the coldmass from the bottom, stays at room temperature during operations, and can slide longitudinally with respect to the vacuum vessel. The Fermilab style cryomodule developed for the prototype Single Spoke Resonator Type 1 (pSSR1), the prototype High Beta 650 MHz (pHB650), and preproduction Single Spoke Resonator Type 2 (ppSSR2) cryomodules is the baseline of the present design. The focus of this contribution is on the results of calculations and finite element analyses performed to optimize the critical components of the cryomodule: vacuum vessel, strongback, thermal shield, and magnetic shield.

43 PARTICLE ACCELERATORS↗

Final Design Of The Pre-production SSR2 Cryomodule For PIP-II Project At Fermilab

The present contribution reports the design of the pre-production Single Spoke Resonator Type 2 Cryomodule (ppSSR2 CM), developed in the framework of the PIP-II project at Fermilab. The innovative design is based on a structure, the strongback, which supports the coldmass from the bottom, stays at room temperature during operations, and can slide longitudinally with respect to the vacuum vessel. The Fermilab style cryomodule developed for the prototype Single Spoke Resonator Type 1 (pSSR1) and the prototype High Beta 650 MHz (pHB650) cryomodules is the baseline of the current design, which paves the way for production SSR1 and SSR2 cryomodules for the PIP-II linac. The focus of this contribution is on the results of calculations and finite element analysis performed to optimize the critical components of the cryomodule: vacuum vessel, strongback, thermal shield, and magnetic shield.

43 PARTICLE ACCELERATORS↗

Near-Surface Plasma Characterization of the 12.5-kW NASA TDU1 Hall Thruster

To advance the state-of-the-art in Hall thruster technology, NASA is developing a 12.5-kW, high-specific-impulse, high-throughput thruster for the Solar Electric Propulsion Technology Demonstration Mission. In order to meet the demanding lifetime requirements of potential missions such as the Asteroid Redirect Robotic Mission, magnetic shielding was incorporated into the thruster design. Two units of the resulting thruster, called the Hall Effect Rocket with Magnetic Shielding (HERMeS), were fabricated and are presently being characterized. The first of these units, designated the Technology Development Unit 1 (TDU1), has undergone extensive performance and thermal characterization at NASA Glenn Research Center. A preliminary lifetime assessment was conducted by characterizing the degree of magnetic shielding within the thruster. This characterization was accomplished by placing eight flush-mounted Langmuir probes within each discharge channel wall and measuring the local plasma potential and electron temperature at various axial locations. Measured properties indicate a high degree of magnetic shielding across the throttle table, with plasma potential variations along each channel wall being less than or equal to 5 eV and electron temperatures being maintained at less than or equal to 5 eV, even at 800 V discharge voltage near the thruster exit plane. These properties indicate that ion impact energies within the HERMeS will not exceed 26 eV, which is below the expected sputtering threshold energy for boron nitride. Parametric studies that varied the facility backpressure and magnetic field strength at 300 V, 9.4 kW, illustrate that the plasma potential and electron temperature are insensitive to these parameters, with shielding being maintained at facility pressures 3X higher and magnetic field strengths 2.5X higher than nominal conditions. Overall, the preliminary lifetime assessment indicates a high degree of shielding within the HERMeS TDU1, effectively mitigating discharge channel erosion as a life-limiting mechanism.

Lifetime↗

Langmuir Probe Measurements Within the Discharge Channel of the 20-kW NASA-300M and NASA-300MS Hall Thrusters

NASA is presently developing a high-power, high-efficiency, long-lifetime Hall thruster for the Solar Electric Propulsion Technology Demonstration Mission. In support of this task, studies have been performed on the 20-kW NASA-300M Hall thruster to aid in the overall design process. The ability to incorporate magnetic shielding into a high-power Hall thruster was also investigated with the NASA- 300MS, a modified version of the NASA-300M. The inclusion of magnetic shielding would allow the thruster to push existing state-of-the-art technology in regards to service lifetime, one of the goals of the Technology Demonstration Mission. Langmuir probe measurements were taken within the discharge channels of both thrusters in order to characterize differences at higher power levels, as well as validate ongoing modeling efforts using the axisymmetric code Hall2De. Flush-mounted Langmuir probes were also used within the channel of the NASA-300MS to verify that magnetic shielding was successfully applied. Measurements taken from 300 V, 10 kW to 600 V, 20 kW have shown plasma potentials near anode potential and electron temperatures of 4 to 12 eV at the walls near the thruster exit plane of the NASA-300MS, verifying magnetic shielding and validating the design process at this power level. Channel centerline measurements on the NASA-300M from 300 V, 10 kW to 500 V, 20 kW show the electron temperature peak at approximately 0.1 to 0.2 channel lengths upstream of the exit plane, with magnitudes increasing with discharge voltage. The acceleration profiles appear to be centered about the exit plane with a width of approximately 0.3 to 0.4 channel lengths. Channel centerline measurements on the NASA-300MS were found to be more challenging due to additional probe heating. Ionization and acceleration zones appeared to move downstream on the NASA-300MS compared to the NASA-300M, as expected based on the shift in peak radial magnetic field. Additional measurements or alternative diagnostics will be needed to verify peak electron temperatures in the NASA-300MS and compare them with model predictions.

Hall thruster↗

Shielding system for wireless power transfer

A shield construction for transfer of wireless power is provided. The shield construction may be a magnetic shield having a plurality of layers and provided for a wireless transmitter or a wireless receiver, or both. The magnetic shield may include a first layer and a second layer, where the first layer may be nearer to a core than the second layer, and where the second layer may include a second layer area that is larger than a first layer area of the first layer. The wireless transmitter and the wireless receiver may be configured to multi-phase wireless power transfer.

Mohammad, Mostak↗

Performance and Thermal Characterization of the NASA-300MS 20 kW Hall Effect Thruster

NASA's Space Technology Mission Directorate is sponsoring the development of a high fidelity 15 kW-class long-life high performance Hall thruster for candidate NASA technology demonstration missions. An essential element of the development process is demonstration that incorporation of magnetic shielding on a 20 kW-class Hall thruster will yield significant improvements in the throughput capability of the thruster without any significant reduction in thruster performance. As such, NASA Glenn Research Center and the Jet Propulsion Laboratory collaborated on modifying the NASA-300M 20 kW Hall thruster to improve its propellant throughput capability. JPL and NASA Glenn researchers performed plasma numerical simulations with JPL's Hall2De and a commercially available magnetic modeling code that indicated significant enhancement in the throughput capability of the NASA-300M can be attained by modifying the thruster's magnetic circuit. This led to modifying the NASA-300M magnetic topology to a magnetically shielded topology. This paper presents performance evaluation results of the two NASA-300M magnetically shielded thruster configurations, designated 300MS and 300MS-2. The 300MS and 300MS-2 were operated at power levels between 2.5 and 20 kW at discharge voltages between 200 and 700 V. Discharge channel deposition from back-sputtered facility wall flux, and plasma potential and electron temperature measurements made on the inner and outer discharge channel surfaces confirmed that magnetic shielding was achieved. Peak total thrust efficiency of 64% and total specific impulse of 3,050 sec were demonstrated with the 300MS-2 at 20 kW. Thermal characterization results indicate that the boron nitride discharge chamber walls temperatures are approximately 100 C lower for the 300MS when compared to the NASA- 300M at the same thruster operating discharge power.

High power↗

Improved high-gradient performance for medium-velocity superconducting half-wave resonators: Surface preparation and trapped flux mitigation

A development effort to improve the performance of superconducting radio-frequency half-wave resonators (SRF HWRs) is underway at the Facility for Rare Isotope Beams (FRIB), where 220 such resonators are in operation. Our goal was to achieve an intrinsic quality factor (𝑄 0 ) of ≥ 2 × 10 10 at an accelerating gradient (𝐸 acc ) of 12 MV/m. FRIB production resonators were prepared with buffered chemical polishing. First trials of electropolishing (EP) and post-EP low-temperature baking of FRIB HWRs allowed us to reach higher gradient (15 MV/m, limited by quench) with a higher quality factor at high gradient, but 𝑄 0 was still below our goal. Trapped magnetic flux during the Dewar test was found to be a source of 𝑄 0 reduction. Three strategies were used to reduce the trapped flux: (i) adding a local magnetic shield (LMGS) to supplement the “global” magnetic shield around the Dewar for reduction of the ambient magnetic field; (ii) performing a “uniform cooldown” (UC) to reduce the thermoelectric currents; and (iii) using a compensation coil to further reduce the ambient field with active field cancellation (AFC). The LMGS improved the 𝑄 0 , but not enough to reach our goal. With UC and AFC, we exceeded our goal, reaching 𝑄 0 = 2.8 ×10 10 at 𝐸 acc = 12 MV/m.

Cryogenics & vacuum technology↗

Complete the development and construction of a spaceborne hydrogen maser clock

The objective, to complete the development of an engineering model of a spaceborne hydrogen maser, was successfully achieved. A layout of the maser and detail drawings of the physics package was completed during the first 7 months of the contract. A computer model was made for the maser's thermal design. Using numerical computations, heater resistances were established for 7 temperature controlled zones. The physics package includes: a vacuum manifold that houses four sorption pumps capable of scavenging hydrogen for 4 years, a titanium vacuum tank housing the cavity, metallic seals for all vacuum joints, an RF dissociator within the vacuum envelope, a two-layer printed circuit solenoid and four layers of moly-permalloy magnetic shields. Problems were encountered and overcome in the procurements of the PC solenoid and the magnetic shields. After completion of the fabrication of the maser's components, the maser was assembled using these parts and other components made available by SAO, NRL, and NASA from earlier development work. In March, 1990, the vacuum system was assembled, and by May the maser assembly was completed. The magnetic shielding was poor and the shields were removed, reannealed by a local vendor, and the maser was reassembled. The maser began tests in early June and has been oscillating since that time. The test results of the maser are very good and a life test of the maser is being conducted. It is anticipated that the development and construction of a maser to be tested in space under a new contract from NASA's Marshall Space Flight Center will continue.

Vessot, Robert F. C.↗

Environmental Testing of the HERMeS TDU-2 Hall Thruster

The Hall Effect Rocket with Magnetic Shielding (HERMeS) is a 12.5 kW magnetically shielded Hall thruster presently under development for deep-space missions. A development model HERMeS thruster, TDU-2, with borosilicate channel walls, has successfully undergone proto-qualification testing including random vibration and thermal-vacuum, demonstrating the thruster can survive critical launch and operational environmental requirements. The three-axis random vibrational tests were performed with the thruster body mounted directly to the shaker table using a modified loading schedule to compensate for the vibration isolation dampers under design for the flight thruster. Initial random vibration testing revealed issues with fragmentation of magnetic coil potting material and thruster spool mount fabrication weaknesses that were addressed with an alternate potting material and fabrication revisions that were then successfully retested with an additional round of random vibration tests. Thermal-vacuum testing involved three cycles of full-power 600 V 12.5 kW thruster operation from -121°C to +373°C which included eight hours at peak temperature as well as a hot restart. A thermal model of the test configuration was developed and validated with the experiment results within an average difference of 5°C. Before and after the random vibrational and thermal-vacuum tests, the thruster performance, plasma plume, thrust vector angle, discharge characteristics, and magnetic field profile were measured. The thruster performance, magnetic field, and most other parameters remained invariant throughout the environmental testing campaign. During the thermal testing, an increase in the discharge oscillation amplitude of 11% was observed as well as subtle thrust vector changes of ±0.2° as the thruster warmed from -121°C to +373°C.

Sorenson, Ryan↗

Fairfield Plume Measurement and Analysis on the NASA-300M and NASA-300MS

NASA is developing a 10- to 15-kW Hall thruster system to support future NASA missions. This activity is funded under the Space Technology Mission Directorate Solar Electric Propulsion Technology Demonstration Mission project. As a part of the development process, the NASA-300M, a 20-kW Hall thruster, was modified to incorporate the magnetic shielding concept and named the NASA-300MS. This activity was undertaken to assess the viability of using the magnetic shielding concept on a high-power Hall thruster to greatly reduce discharge channel erosion. This paper reports on the study to characterize the far-field plumes of the NASA-300M and NASA-300MS. Diagnostics deployed included a polarlyswept Faraday probe, a Wien filter (ExB probe), a retarding potential analyzer, and a Langmuir probe. During the study, a new, more accurate, integration method for analyzing Wien filter probe data was implemented and effect of secondary electron emission on the Faraday probe data was treated. Comparison of the diagnostic results from the two thrusters showed that the magnetically shielded version performed with ~2 percent higher voltage utilization efficiency, ~2 percent lower plume divergence efficiency, and ~2 percent lower mass utilization efficiency compared to the baseline version. The net change in efficiency is within the aggregate measurement uncertainty so the overall performance is roughly equal for the two versions of the thruster. Anode efficiency calculated from thrust stand measurement corroborates this finding.

Hall thruster↗

Conducting Wall Hall Thrusters

A unique configuration of the magnetic field near the wall of Hall thrusters, called Magnetic Shielding, has recently demonstrated the ability to significantly reduce the erosion of the boron nitride (BN) walls and extend the life of Hall thrusters by orders of magnitude. The ability of magnetic shielding to minimize interactions between the plasma and the discharge chamber walls has for the first time enabled the replacement of insulating walls with conducting materials without loss in thruster performance. The boron nitride rings in the 6 kW H6 Hall thruster were replaced with graphite that self-biased to near the anode potential. The thruster efficiency remained over 60% (within two percent of the baseline BN configuration) with a small decrease in thrust and increase in Isp typical of magnetically shielded Hall thrusters. The graphite wall temperatures decreased significantly compared to both shielded and unshielded BN configurations, leading to the potential for higher power operation. Eliminating ceramic walls makes it simpler and less expensive to fabricate a thruster to survive launch loads, and the graphite discharge chamber radiates more efficiently which increases the power capability of the thruster compared to conventional Hall thruster designs.

electric propulsion (EP)↗

Progress Towards Microcalorimeter Gamma Spectroscopy Analysis for Nuclear Fuel Separations

The High Efficiency and Resolution Microcalorimeter Spectrometer, 400 pixels (HERMES-400) is an ultra-high resolution gamma-ray spectrometer at Idaho National Laboratory’s Materials and Fuels Complex. HERMES-400 is intended to enable precise nondestructive analysis of advanced fuel cycle materials. Key upgrades and repairs of the instrument were performed this year to improve performance. First, the fourth and final microcalorimeter detector module was installed, meeting the milestone for its integration into the system. Operation with all four modules enables higher detector efficiency than any previous microcalorimeter gamma-ray system. Second, a thinner magnetic shield was installed. This shields the sensitive microcalorimeter pixels from stray magnetic fields while allowing transmission of lower-energy gamma rays, which are important to isotopic analysis. Finally, the cryostat, which provides cooling of the modules to their operating temperature, was found to have a helium coolant leak, which was repaired. HERMES-400 is in a stable state to perform repeated, long-term gamma-ray measurements with good detector efficiency and energy resolution. In FY25, irradiated TRISO fuel and salts from advanced electrochemical recycling techniques are candidates for microcalorimeter measurements. A final upgrade of the magnetic shielding and vibration damping of the system is also planned to maximize the system performance.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗