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At least 937 records · Page 52

Structural basis of 7SK RNA 5'-γ-phosphate methylation and retention by MePCE

Among RNA 5'-cap structures, γ-phosphate monomethylation is unique to a small subset of noncoding RNAs, 7SK and U6 in humans. 7SK is capped by methylphosphate capping enzyme (MePCE), which has a second nonenzymatic role as a core component of the 7SK ribonuclear protein (RNP), an essential regulator of RNA transcription. We report 2.0- and 2.1-Å X-ray crystal structures of the human MePCE methyltransferase domain bound to S-adenosylhomocysteine (SAH) and uncapped or capped 7SK substrates, respectively. 7SK recognition is achieved by protein contacts to a 5'-hairpin-single-stranded RNA region, thus explaining MePCE’s specificity for 7SK and U6. The structures reveal SAH and product RNA in a near-transition-state geometry. Unexpectedly, binding experiments showed that MePCE has higher affinity for capped versus uncapped 7SK, and kinetic data support a model of slow product release. Overall, this work reveals the molecular mechanism of methyl transfer and 7SK retention by MePCE for subsequent assembly of 7SK RNP.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Infiltration Data Package for the E-Area Low-Level Waste Facility Performance Assessment

The infiltration data package contains the input parameters, the cap design and material properties assumptions, and the modeling results for the Hydrologic Evaluation of Landfill Performance (HELP) infiltration model simulations performed in support of the E-Area Low-Level Waste Facility Performance Assessment (PA). The infiltration estimates establish the upper boundary condition for the PORFLOW vadose-zone model and GoldSim model simulations for the following E-Area disposal unit types: Slit and Engineered Trenches, Low-Activity Waste Vault (LAWV), Intermediate-Level Vault (ILV), Componentin- Grout (CIG) special waste form trench segments, and the Naval Reactor Component Disposal Areas (NRCDAs). The infiltration data package builds upon relevant, foundational PA technical reports and memoranda from the past 15 years and is supported by three important components: the HELP model input parameter datasheets, HELP model input and output filenames and directory structure, and infiltration rates as a function of time for each scenario for each disposal unit type. For Slit and Engineered Trenches, a single best-estimate Bahia-grass case of two-percent slope and 585- foot slope length represents an upper bound on intact closure-cap infiltration rates over a 10,000-year period. Building upon the single, bounding, and intact case, two different approaches were considered for incorporating the effect of localized cap subsidence on infiltration rates in the PORFLOW flow and transport model simulations. In the first approach, a Monte Carlo probabilistic model was developed to calculate infiltration rates for 0.54%, 2%, 3.6%, and 4.9% subsidence scenariosa reflecting historical and future non-crushable content for the Slit and Engineered Trenches. The resulting blended (spatially and slope-length averaged) infiltration rates become an inflow upper boundary condition for the PORFLOW vadose zone model simulations. In the second and preferred approach, a Monte Carlo rectangle packing algorithm (Danielson, 2019) and a simplified equation for the total mass flux of water draining into a subsided compartment (Equation 1) will be employed to implement a weighted blending of radionuclide fluxes to the water table using the results of deterministic PORFLOW vadose zone simulations representative of specific subsidence cases. Finally, HELP-model results from sensitivity studies of the intact infiltration case were fit to a log-logistic function to generate infiltration profiles over a 10,000-year period for most-optimistic, more-optimistic, best-estimate, more-pessimistic, and most-pessimistic cases, for both the intact and four subsidence scenarios. For the LAWV and IL vaults, infiltration rate profiles for a 10,000-year period were developed for both an on-vault (above the concrete/metal vault roof) and an off-vault (10-foot soil zone adjacent to vault walls) scenario. The purpose of the off-vault simulations was to confirm that subsurface runoff from the concrete vault roof will adequately drain through the lowermost backfill layers adjacent to the vault walls. The LAWV and ILV infiltration profiles assume collapse of the concrete roof at relative Years 2,905 and 7,100, respectively. The identical Bahia-grass case with two-percent slope and 585-foot slope length assumed for the Slit and Engineered Trenches will represent an upper bound on intact infiltration rates for the NRCDAs and CIG special waste form as well. While the NRCDA casks are assumed to remain structurally intact (i.e., non-assumed to collapse 300 years after the end of operations. Because both rows of the existing CIG trench segments in ST23 (formerly CIG01) extend across the planned cap crest, the subsided CIG trench segments are treated conservatively in the HELP model as a 100%-subsidence case with zero subsurface run-on. The CIG special waste form trench segment infiltration profile, therefore, consists of an intact-cap period from relative Year 100 to Year 300, followed by a 100%-subsidence period from relative Year 300 to Year 10,100.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Effect of Silica Particle Size of Nuclear Waste-to-Glass Conversion - 17319

The process for converting nuclear waste-to-glass in an electric melter occurs in the cold cap, a crust of reacting solids floating on the glass pool. As the melter feed (a mixture of the nuclear waste and glass forming and modifying additives) heats up in the cold cap, glass-forming reactions ensue, causing the feed matrix to connect, trapping reaction gases to create a foam layer. The foam layer reduces the rate of melting by separating the reacting feed from the melt pool. The size of the silica particle additives in the melter feed affects melt viscosity and, hence, foam stability. To investigate this effect, seven nuclear waste simulant feeds of a high-level waste were batched as slurries and prepared with dissimilar ranges of silica particle size. Each slurry feed was charged into a laboratory-scale melter (LSM) to produce a cold cap and the propensity of feeds to foam was determined by pressing dried feeds into pellets and monitoring the change of pellet volume in response to heating. Two of these slurries were designed to have dissimilar glass viscosities at 1150°C. In the low temperature region of the cold cap, before the melter feed connects, the feeds without fine silica particles behaved similar to the high viscosity feed as their volume contracted while the feed with silica particles no larger than 5 µm reacted like the low viscosity feed. However, the feed volume similarities reversed as the feed connected and expanded through the foam region of the cold cap.

Cold Cap↗

Plasma-induced inactivation of Staphylococcus aureus biofilms: The role of atomic oxygen and comparison with disinfectants and antibiotics

Microbial biofilms are of critical concern because of their recalcitrance to antimicrobials. Cold atmospheric plasmas (CAP) represent a promising biofilm remediation strategy as they generate reactive oxygen and nitrogen species (RONS), but mechanisms underpinning CAP-biofilm interactions remain unknown. We assess the impact of treatment modality on biofilm inactivation and show that CAP killing of Staphylococcus aureus biofilms is dependent on treatment conditions, including solution chemistry. In dry treatments, biofilms are locally ablated due to plasma-produced O flux. For saline-submerged biofilms, while we show that ClO – is generated at high concentrations in larger treatment volumes, CAP inactivation at low ClO – concentrations implicates other reaction pathways. Finally, we demonstrate CAP efficacy over conventional antimicrobials, underscoring its promise as a biofilm treatment approach.

60 APPLIED LIFE SCIENCES↗

Elucidating the impact of stress states on grain boundary passivation in Ni-5Cr using the Rhines pack method

The oxidation behavior of a Ni–5Cr (at.%) alloy was evaluated at 420 ° C using the Rhines pack method and simultaneous tensile and compressive stress states via a miniature four-point bending fixture. At this moderate temperature, grain boundaries dominate mass transport and the resulting oxidation response. Oxidation produced approximately 1μ⁢m-wide protective Cr 2 O 3 films capping some grain boundaries and penetrative, intergranular Cr-rich oxides at other grain boundaries. Externally applied tensile and compressive stress during oxidation increased the prevalence of Cr 2 O 3 cap formation compared to no applied stress, with tensile stress resulting in more Cr 2 O 3 caps than compressive stress. The observed oxide cap morphology was similar across all test conditions. Regions under compressive stress showed an order of magnitude greater Cr depletion depth along the grain boundary. Chromium nitrides (CrN), likely from N contamination of the Rhines pack cell, were observed both at the oxide–metal interface and intergranularly within the alloy. Collectively these results demonstrate that applied stress promotes localized protective oxide cap formation over grain boundaries, with compressive stress additionally promoting deeper Cr depletion. Furthermore the experimental approach helped separate out the effects of stress on local oxide formation and grain boundary passivation.

4 point bend↗

Time-domain Brillouin scattering theory for probe light and acoustic beams propagating at an angle and acousto-optic interaction at material interfaces

A theory has been developed to interpret time-domain Brillouin scattering (TDBS) experiments involving coherent acoustic pulse (CAP) and light pulse beams propagating at an angle to each other. It predicts the influence of the directivity pattern of their acousto-optic interaction on TDBS signals when heterodyne detection of acoustically scattered light is in backward direction to incident light. The theory reveals relationships between the carrier frequency, amplitude and duration of acoustically induced ”wave packets” in light transient reflectivity signals, and factors such as CAP duration, widths of light and sound beams, and their interaction angle. It describes the transient dynamics of these wave packets when the light and CAP encounter material interfaces, and how the light scattering by the incident CAP transforms into scattering by the reflected and transmitted CAPs. The theory suggests that single-point TDBS experiments can determine not only depth positions of buried interfaces but also their local inclinations/orientations.

42 ENGINEERING↗

CD44 collaborates with ERBB2 mediate radiation resistance via p38 phosphorylation and DNA homologous recombination pathway in prostate cancer

Highlights: • CD44/ERBB2 mediates radioresistance in prostate cancer. • CD44 enhances the stabilization of proteins. • P38 and DNA HR pathways are involved in CD44/ERBB2 mediating radioresistance. CD44, a glycoprotein, has been reported to have relationship with resistance to radiation in prostate cancer (Cap) cells. However, its molecular mechanism remains unknown. In this study, we demonstrated that inhibited CD44 enhanced the radiosentivity in Cap cells. It has been hypothesized that CD44 combine with ERBB2 and activate downstream phosphated protein to mediate DNA damage repair. Therefore, we conducted a detailed analysis of effects of radiation by clonogenic assay and immunofluorescence stain for p-H2AX foci. The downstream of CD44/ERBB2 and DNA damage repair proteins was detected by western blot. The results reveal that CD44 interacted with ERBB2, the downstream of CD44/ERBB2 was p-p38 when Cap cells were irradiated. Among the pathways, homologous recombination (HR) related proteins Mre11 and Rad50 were involved in CD44/ERBB2/p-p38 mediated radioresistance in Cap. In conclusion, CD44 could stabilize ERBB2 and co-activate p-p38 expression then promote the DNA damage repair by HR pathway, which finally contribute to the radioresistance of CaP.

60 APPLIED LIFE SCIENCES↗

Organic-to-Aqueous Phase Transfer of Cadmium Chalcogenide Quantum Dots Using a Sulfur-Free Ligand for Enhanced Photoluminescence and Oxidative Stability

This article describes a procedure for transferring colloidal CdS and CdSe quantum dots (QDs) from organic solvents to water by exchanging their native hydrophobic ligands for phosphonopropionic acid (PPA) ligands, which bind to the QD surface through the phosphonate group. This method, which uses dimethylformamide as an intermediate transfer solvent, was developed in order to produce high-quality water soluble QDs with neither a sulfur-containing ligand nor a polymer encapsulation layer, both of which have disadvantages in applications of QDs to photocatalysis and biological imaging. CdS (CdSe) QDs were transferred to water with a 43% (48%) yield using PPA. The photoluminescence (PL) quantum yield for PPA-capped CdSe QDs is larger than that for QDs capped with the analogous sulfur-containing ligand, mercaptopropionic acid (MPA), by a factor of four at pH 7, and by up to a factor of 100 under basic conditions. The MPA ligands within MPA-capped QDs oxidize at E ox ~ +1.7 V vs. SCE, whereas cyclic voltammograms of PPA-capped QDs show no discerible oxidation peaks at applied potentials up to +2.5 V vs. SCE. The PPA-capped QDs are chemically and colloidally stable for at least five days in the dark, even in the presence of O 2 , and are stable when continuously illuminated for five days, when oxygen is excluded and a sacrificial reductant is present to capture photogenerated holes.

36 MATERIALS SCIENCE↗

Calorimetric Energies and Chemical Potentials of Metal Atoms in Catalytic Nanoparticles on Oxide and Carbon Supports: Improved Size Dependencies and Adhesion Energies

The chemical potential of metal atoms, μM, in supported metal nanoparticles is an important descriptor related to both the catalytic activity and the stability of the nanoparticles. Here, we derive an expression relating μM to the radius of the particle’s contact area with the support and the adhesion energy at the metal/support interface (E adh ) that assumes the particles have the shape of spherical caps but of arbitrary contact angle with the support (θ c ) and includes an empirical correction for the increase in metal surface energy and adhesion energy with decreasing radius of curvature. We then show that, at any assumed contact angle, we can simultaneously fit previously reported measurements of both calorimetric μ M (from heats of metal vapor adsorption during nanoparticle growth by vapor deposition) versus metal coverage data and the He + low-energy ion scattering (LEIS) intensities for the metal and/or support versus metal coverage (using our recently developed spherical cap model for quantitative LEIS intensities), to determine the particle size versus coverage and E adh . Only one choice of contact angle gives a pair of values for contact angle and E adh , which is consistent with the Young–Dupré equation for the equilibrium shape of a spherical particle. At this equilibrium shape, we then applied this spherical cap model (SCM) to reanalyze microcalorimetric metal chemical potentials and LEIS signals versus coverage data for nine metal/support combinations that were previously analyzed by assuming that the particles had the shape of hemispherical caps, i.e., with a contact angle of 90°. We show that this revised approach gives close agreement with the calorimetric and LEIS data; the best-fit contact angles vary from 64 to 84°, correcting the earlier assumption of 90°. Furthermore, these results provide significant accuracy improvements in particle size versus coverage, metal chemical potential versus size and coverage, metal/support adhesion energies and contact angles for Cu, Ag and Au on CeO 2 (111), Ni on MgO(100), Ag on Fe 3 O 4 (111) and TiO 2 (100), and Ag, Ni and Pd on Ni-supported graphene. This revised approach is much more broadly applicable than the earlier hemispherical cap model (HCM).

99 GENERAL AND MISCELLANEOUS↗

Engineering Calcium-Bearing Mineral/Hydrogel Composites for Effective Phosphate Recovery

Effectively recovering phosphate from wastewater streams and reutilizing it as a nutrient will critically support sustainability. Here, to capture aqueous phosphate, we developed novel mineral-hydrogel composites composed of calcium alginate, calcium phosphate (CaP), and calcium silicate (CSH) (CaP + CSH/Ca-Alg). The CaP + CSH/Ca-Alg composites were synthesized by dripping a sodium alginate (Na-Alg) solution with ionic precursors into a calcium chloride bath. To change the mineral seed’s properties, we varied the calcium bath concentrations and the ionic precursor (sodium dibasic phosphate (NaH 2 PO 4 ) and/or sodium silicate (Na 2 SiO 3 )) amounts and their ratios. The added CSH in the mineral-hydrogel composites resulted in the release of calcium and silicate ions in phosphate-rich solutions, increasing the saturation ratio with respect to calcium phosphate within the mineral-hydrogel composites. The CSH addition to the mineral-hydrogel composites doubled the phosphate removal rate while requiring lesser initial amounts of Ca and P materials for synthesis. Furthermore, by incorporating both CSH and CaP mineral seeds in composites, we achieved a final concentration of 0.25 mg-P/L from an initial 6.20 mg-P/L. Moreover, the mineral-hydrogel composites can remove phosphate even under CaP undersaturated conditions. This suggests their potential to be a widely applicable and environmentally-sustainable treatment and recovery method for nutrient-rich wastewater.

42 ENGINEERING↗

Implications of an emission trading scheme for India’s net-zero strategy: a modelling-based assessment

To help meet its near-term NDC goals and long-term net-zero 2070 target, the Government of India has planned to establish a Carbon Credit Trading Scheme (CCTS), i.e. a domestic emission trading scheme (ETS). An ETS is an inherently cost-effective policy instrument for emission reduction, providing the greatest flexibility to reduce emissions from within and across sectors. An effective ETS requires design features that consider country-specific challenges and reflect its role within the larger policy package to achieve long-term emission reduction. Within the Indian context and in this study we therefore investigate—(i) what might be the role of the ETS in achieving India’s long-term mitigation targets? (ii) How might the various sectors interact under an emissions cap? (iii) How might the ETS interact with existing energy and climate policies? We do this analysis by running four main scenarios using the integrated assessment model GCAM (v6.0), adapted to India-specific assumptions and expectations. These scenarios are—(i) NZ (net-zero), (ii) NZ + ETS, (iii) NZ + CC (command and control), and (iv) NZ + RPO (renewables purchase obligations) + ETS. The NZ scenario assumes India’s near-term and long-term climate commitments of net zero by 2070. Scenarios with ETS (ii) and (iv) apply an emissions cap on four sectors—electricity, iron and steel, cement, and fertilizer. The scenario with CC applies a homogenous emission cap on each of the chosen sectors but does not allow cross-sectoral trading. The last scenario includes renewables purchase obligations (RPOs along with an ETS. We show that under a specific ETS emissions cap: (i) the electricity sector emerges as the largest source of cost-effective greenhouse gas (GHG) reduction options; (ii) ETS with trading across sectors is around 24% more cost-effective than ETS with trading only within sectors, (iii) RPOs can be complementary to an ETS although the impact of RPOs on GHG reductions in the electricity sector would need to be considered when setting the level of the ETS cap (or emissions intensity targets) or the RPO targets to avoid low carbon prices, and (iv) the direction and volume of financial transfers across sectors depends on allocation targets set by the government. Based on these results we provide design recommendations for India’s ETS.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

High-resolution analogue of time-domain phonon spectroscopy in the transmission electron microscope

Femtosecond photoexcitation of semiconducting materials leads to the generation of coherent acoustic phonons (CAPs), the behaviours of which are linked to intrinsic and engineered electronic, optical and structural properties. While often studied with pump-probe spectroscopic techniques, the influence of nanoscale structure and morphology on CAP dynamics can be challenging to resolve with these all-optical methods. Here, we used ultrafast electron microscopy (UEM) to resolve variations in CAP dynamics caused by differences in the degree of crystallinity in as-prepared and annealed GaAs lamellae. Following in situ femtosecond photoexcitation, we directly imaged the generation and propagation dynamics of hypersonic CAPs in a mostly amorphous and, following an in situ photothermal anneal, a mostly crystalline lamella. Subtle differences in both the initial hypersonic velocities and the asymptotic relaxation behaviours were resolved via construction of space-time contour plots from phonon wavefronts. Comparison to bulk sound velocities in crystalline and amorphous GaAs reveals the influence of the mixed amorphous-crystalline morphology on CAP dispersion behaviours. Further, an increase in the asymptotic velocity following annealing establishes the sensitivity of quantitative UEM imaging to both structural and compositional variations through differences in bonding and elasticity. Lastly, implications of extending the methods and results reported here to elucidating correlated electronic, optical and structural behaviours in semiconducting materials are discussed.

42 ENGINEERING↗

Determination of heat conductivity of waste glass feed and its applicability for modeling the batch-to-glass conversion

The heat conductivity of reacting melter feed affects the heat transfer and conversion process in the cold cap (the reacting feed floating on molten glass). To investigate it, we simulated the feed conditions and morphology in the cold-cap by preparing “fast-dried slurry blocks”, formed by rapidly evaporating water from feed slurry poured onto a 200°C surface. A heat conductivity meter was used to measure heat conductivity of samples cut from the fast-dried slurry blocks, samples of a cold cap retrieved from a laboratory-scale melter, and loose dry powder feed samples. Our study indicates that the heat conductivity of the feed in the cold cap is significantly higher than that of loose dry powder feed, resulting from the feed solidification during the water evaporation from the feed slurry. To assess the heat transfer at higher temperatures when feed turns into foam, we developed a theoretical model that predicts the foam heat conductivity based on morphology data from in-situ X-ray computed tomography. The implications for the mathematical modeling of the cold cap are discussed.

Hujova, Miroslava↗

Solar Photovoltaic (PV) Manufacturing Expansions in the United States, 2017-2019: Motives, Challenges, Opportunities, and Policy Context

This report analyzes U.S. PV manufacturing announcements from 2017 through July-2019 and explores the potential impact of tariffs on the competitiveness of U.S. PV module manufacturing. First, the fraction of announcements that resulted in established facilities in the time frame specified is analyzed, as well as firm nationality and the existence of any other U.S. facilities for the firm. The prevalence of different PV product types among the announcements was also analyzed, as well as the type of facilities selected for development (greenfield, existing PV factories, or repurposed buildings). The cost to build these facilities was also analyzed in the context of their capacity, the value of incentives received by state and local governments, and the number of jobs created. Case studies of Auxin Solar, First Solar, Hanwha Q Cells, JinkoSolar, LG, Silfab, Solaria, and SunPower were conducted and highlight five factors influencing firms’ decisions to expand their U.S. PV production capacity. These included: 1) proximity to demand, including supply contracts and demand for domestic content 2) tariffs and other incentives. The Section 201 tariffs on PV module imports were often described helpful but tariffs on cell imports (Section 201) or materials (Section 301, Section 232) were often described as counterproductive since U.S. supply chains do not exist for many necessary goods. The corporate tax decrease and local incentives were often mentioned as helpful. 3) the ability to move quickly in order to maximize the benefit of the Section 201 tariffs. This affected decisions to select localities with faster permitting or moving into existing buildings. 4) competition with scale, where competing with Asian PV imports or avoiding imports of material from China was challenging due to the larger scale of Asian manufacturers. Additionally, smaller firms expressed concerns that larger firms may not need their U.S. facilities to profitable. 5) access to capital, which was a particular challenge for smaller firms. Several U.S. tariffs affect the economics of PV cells, modules, and balance-of-module (BOM) materials, some of which are applicable to a long list of countries and others applicable only to China or Taiwan. We analyze how the tariffs interact to affect the prices of c-Si modules sourced under various assumptions about domestic and imported components and assembly. We estimate module prices under a range of baseline scenarios featuring U.S.-assembled modules with Southeast Asian cells (not from China or Taiwan). When all BOM components are sourced from the United States, baseline module prices are $0.37/W (below the 2.5-GW Section 201 cell cap) to $0.42/W (above the 2.5-GW cell cap). If all BOM components are sourced from China, the module price in this baseline U.S.-assembly scenario can reach up to $0.60/W. Imported module prices are lower than or within the range of the U.S.-assembled baseline prices under some conditions. Importing bifacial modules from Southeast Asia is the lowest-priced alternative, at $0.35/W, because bifacial modules are excluded from the Section 201 tariffs. Importing Southeast Asia modules that contain U.S. cells results in a price of $0.38/W, also owing to a Section 201 exclusion. Importing Southeast Asian modules that have Southeast Asian cells yields a price of $0.44/W, and importing Chinese modules that have U.S. cells yields a price of $0.58/W. These results suggest that U.S. tariff policy in 2019 may encourage U.S. assembly of mono-facial c-Si modules if the 2.5-GW cell import cap is not reached and Chinese BOM imports are negligible. However, some imported module options may offer the lowest prices if the 2.5-GW cell import cap is reached and/or U.S. module manufacturers must rely on significant Chinese BOM content. The analysis shows the 2.5-GW cell cap may be exceeded in 2019 and following years. It is also likely that U.S. module manufacturers will need to use at least some Chinese BOM content, since U.S. module manufacturers have stated that U.S. supply chains do not exist (or do not exist at a sufficient scale) for most BOM components, which makes them at least partially reliant on Chinese BOM and thus subject to Section 301 tariffs.

14 SOLAR ENERGY↗

Dependence of wind-farm-induced gravity waves and wind farm performance on non-dimensional atmospheric parameters and simulation configuration

This large-eddy simulation (LES) study examines how wind-farm-induced atmospheric gravity waves (AGWs) and wind farm performance depend on non-dimensional atmospheric parameters and simulation configuration. A hypothetical aligned wind farm of actuator disks is simulated under neutral surface conditions, with a stable capping inversion and a mildly stable free atmosphere, to assess the effects of stratification beyond the atmospheric boundary layer (ABL) on ABL flow. Simulation set-ups fully resolving AGWs are validated to minimize spurious wave generation and reflection from the domain boundaries. The validated set-up is then used to analyze AGW types and characteristics, as well as stratification impacts under conventionally neutral boundary layer (CNBL) conditions. These conditions are governed by four non-dimensional parameters: the Froude numbers of the free atmosphere and capping inversion (Fr, Fr i ), and the aspect ratios of the ABL and wind farm (H̃ i , S h ). Simulation configurations that fully resolve AGWs – capturing at least one wavelength both horizontally and vertically – yield the most realistic stratification effects on ABL flow, whereas partial or unresolved configurations produce non-physical, channel-like behavior. A coherent description of the AGW phenomena is provided, highlighting the central role of capping inversion displacement in linking ABL fluctuations with AGWs. Trapped waves are confined within the capping inversion, while interfacial and internal waves aloft are identified as the AGW types most relevant to wind farm performance. The wavy inversion, analogous to an interfacial wave, forms converging and diverging zones that drive power fluctuations across the farm. The interfacial wavelength, measured over the wind farm, corresponds to one diverging, one converging, and one mildly diverging zone. As the interfacial wavelength decreases with Fr i , multiple convergence–divergence zones develop under sub-critical conditions (Fr i <1.0), while for super-critical conditions (Fr i > 1.0), the wavelength approaches the farm length. Wave amplitude increases with decreasing H̃ i (i.e., shallower capping inversions). Wind farm performance is most sensitive to H̃ i : shallow boundary layers increase blockage and reduce efficiency, while deeper layers enhance efficiency. Increasing Fr and Fr i mitigates blockage, and increasing S h mainly improves wake recovery. Although local power fluctuations arise from AGWs, overall wind farm efficiency remains nearly constant with Fr and Fr i , improving primarily with larger H̃ i and S h .

17 WIND ENERGY↗

Topography of the polar layered deposits of Mars

Synthesis of polar topographic data derived from the Mariner 9 radio occultation, ultraviolet spectrometer, and television imaging experiments provides new information on the behavior of polar volatiles and the topographic configuration of the Martian polar layered deposits. Gentle slopes in the vicinity of the south pole may serve to shift the point of minimum annual solar insolation from the pole to a site within the perimeter of the offset residual frost cap. Localized defrosting which gives rise to the dark-banded appearance of both residual caps correlates with a series of outward-facing slopes descending from central topographic highs. Stability of the volatile involved apparently is largely insolation controlled. The south polar residual cap lies entirely higher (at lower pressure) than the northern cap, implying that the south residual cap is an unlikely site for any permanent surface deposit of solid carbon dioxide.

Dzurisin, D.↗

Molded composite pyrogen igniter for rocket motors

A lightweight pyrogen igniter assembly including an elongated molded plastic tube adapted to contain a pyrogen charge was designed for insertion into a rocket motor casing for ignition of the rocket motor charge. A molded plastic closure cap provided for the elongated tube includes an ignition charge for igniting the pyrogen charge and an electrically actuated ignition squib for igniting the ignition charge. The ignition charge is contained within a portion of the closure cap, and it is retained therein by a noncorrosive ignition pellet retainer or screen which is adapted to rest on a shoulder of the elongated tube when the closure cap and tube are assembled together. A circumferentially disposed metal ring is provided along the external circumference of the closure cap and is molded or captured within the plastic cap in the molding process to provide, along with O-ring seals, a leakproof rotary joint.

Heier, W. C.↗

Mobile sampler for use in acquiring samples of terrestrial atmospheric gases

Samples of terrestrial atmospheric gasses from a free body of such gasses using a device characterized by a plurality of tubular bodies adapted to be mounted in side by side relation on a motorized highway vehicle in mutual parallelism with the axis of the normal path of travel for the vehicles. Each of the bodies is of a cylindrical configuration and has an axial opening at each of its opposite ends through which a linear flow path is defined. A pair of pivotally supported, spring-biased sealing caps is mounted adjacent to the ends of the body and continuously urged into a hermetic sealing relationship. A restraint for securing the caps against spring-urged pivotal displacement, includes a separable, normally tensioned line interconnecting the caps and an operable release mechanism for simultaneously releasing the caps for spring-urged displacement. A hot wire cutter is included for separating the line, whereby samples of air are trapped in the body as the caps are spring-driven to assume an hermetically sealed relation with the openings defined in each of the opposite ends of the body.

Tucker, C. E.↗