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At least 955 records · Page 53

Zeeman spectroscopy as a method for determining the magnetic field distribution in self-magnetic-pinch diodes (invited)

In the self-magnetic-pinch diode, the electron beam, produced through explosive field emission, focuses on the anode surface due to its own magnetic field. This process results in dense plasma formation on the anode surface, consisting primarily of hydrocarbons. Direct measurements of the beam’s current profile are necessary in order to understand the pinch dynamics and to determine x-ray source sizes, which should be minimized in radiographic applications. In this paper, the analysis of the C IV doublet (580.1 and 581.2 nm) line shapes will be discussed. The technique yields estimates of the electron density and electron temperature profiles, and the method can be highly beneficial in providing the current density distribution in such diodes.

Patel, S. G.↗

AAM Project: High Density Vertiplex (HDV) Research and Capabilities

NASA is currently engaged in dedicated research into vertiports through its Advanced Air Mobility Project, housed within the Airspace Operations Safety Program (AOSP), through a Sub-Project referred to as High Density Vertiplex, or simply HDV. This effort’s mission is to develop a reference automation architecture for vertiports that will enable operations to scale to the density levels envisioned for future environments. Through the development of the HDV Concept of Operations and accompanying architecture documents a research roadmap was developed as part of the effort's formulation process that laid the foundations for the work and schedule to be completed as part of the HDV scope and technical challenge. This presentation provides the background of the HDV Sub-Project and outlines the concept and capabilities as it has developed to date. Summaries of the completed work package and status of current work package will be provided with details on specific capabilities and supporting integration developments.

vertiport↗

Lower hybrid wave edge power loss quantification on the Alcator C-Mod tokamak

For the first time, the power deposition of lower hybrid RF waves into the edge plasma of a diverted tokamak has been systematically quantified. Edge deposition represents a parasitic loss of power that can greatly impact the use and efficiency of Lower Hybrid Current Drive (LHCD) at reactor-relevant densities. Through the use of a unique set of fast time resolution edge diagnostics, including innovative fast-thermocouples, an extensive set of Langmuir probes, and a Lyα ionization camera, the toroidal, poloidal, and radial structure of the power deposition has been simultaneously determined. Power modulation was used to directly isolate the RF effects due to the prompt (t<τ E ) response of the scrape-off-layer (SOL) plasma to Lower Hybrid Radiofrequency (LHRF) power. LHRF power was found to absorb more strongly in the edge at higher densities. It is found that a majority of this edge-deposited power is promptly conducted to the divertor. This correlates with the loss of current drive efficiency at high density previously observed on Alcator C-Mod, and displaying characteristics that contrast with the local RF edge absorption seen on other tokamaks. Measurements of ionization in the active divertor show dramatic changes due to LHRF power, implying that divertor region can be a key for the LHRF edge power deposition physics. These observations support the existence of a loss mechanism near the edge for LHRF at high density (n e >1.0×10 20 (m -3 )). Results will be shown addressing the distribution of power within the SOL, including the toroidal symmetry and radial distribution. Finally, these characteristics are important for deducing the cause of the reduced LHCD efficiency at high density and motivate the tailoring of wave propagation to minimize SOL interaction, for example, through the use of high-field-side launch.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Lower hybrid wave edge power loss quantification on the Alcator C-Mod tokamak

For the first time, the power deposition of Lower Hybrid RF waves into the edge plasma of a diverted tokamak has been systematically quantified. Edge deposition represents a parasitic loss of power that can greatly impact the use and efficiency of Lower Hybrid Current Drive (LHCD) at reactor-relevant densities. Through the use of a unique set of fast time resolution edge diagnostics, including innovative fast-thermocouples, an extensive set of Langmuir probes, and a Ly? ionization camera, the toroidal, poloidal and radial structure of the power deposition has been simultaneously determined. Power modulation was used to directly isolate the RF effects due to the prompt (t < ?E ) response of the scrape-off-layer (SOL) plasma to LHRF power. LHRF power was found to absorb more strongly in the edge at higher densities. It is found that a majority of this edge-deposited power is promptly conducted to the divertor. This correlates with the loss of current drive efficiency at high density previously observed on Alcator C-Mod, and displaying characteristics that contrast with the local RF edge absorption seen on other tokamaks. Measurements of ionization in the active divertor show dramatic changes due to LHRF power, implying that divertor region can be key for the LHRF edge power deposition physics. These observations support the existence of a loss mechanism near the edge for LHRF at high density (ne > 1.0 1020 [m?3]). Results will be shown addressing the distribution of power within the SOL, including the toroidal symmetry and radial distribution. These characteristics are important for deducing the cause of the reduced LHCD efficiency at high density and motivates the tailoring of wave propagation to minimize SOL interaction, for example, through the use of high-field-side launch.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Analysis of the Switching Characteristics of MRAM Cells Based on Materials with Uniaxial Anisotropy

Magnetoresistive random access memory (MRAM) has some advantages over other types of memory. However, MRAM has one substantial drawback: the current density and magnetic field that must be applied to switch the spin-valve free layer inside an MRAM cell are too high. The dependence of the current density and switching magnetic field on the magnetic parameters of the material from which the ferromagnetic layers of a spin valve are fabricated is therefore analyzed. A comparison of the critical characteristics of a spin valve with longitudinal anisotropy shows that cobalt, iron, and alloys of them; cobalt ferroborates; and alloys of cobalt with gadolinium, are promising materials for fabricating spin valves. Bifurcation diagrams of equations that describe the valve switching process are presented and analyzed. The four optimum switching modes of a valve are selected, based on an investigation of the dynamics of the magnetization vector. The magnitudes of the external magnetic field and controlling injection current that correspond to stable MRAM cell switching are compared for a variety of materials. The switching time of an MRAM cell is estimated numerically, and the conditions for its optimum speed are determined. It is established that the most promising materials for spin-valve fabrication are Fe{sub 40}Co{sub 40}B{sub 20} and Co{sub 80}Gd{sub 20}, annealed at 300 and 200°C, respectively.

36 MATERIALS SCIENCE↗

Lifetime Energy Savings Via Advanced Manufacturing of Low Density Steels for Transportation Applications

The purpose of this “Low Density Steels for Transportation Applications” project was to develop an alloy composition and processing parameters that would result in a material suitable for use in automotive structural components at a reduced density over the current advanced high strength steel (AHSS) materials used. The project work successfully developed a robust alloy capable of exceeding project mechanical property targets at each stage of development, with an 8% density reduction over benchmark AHSS materials (7.8 g/cm3). The developed alloy has the potential to offer significant vehicle lightweighting and improved fuel economy, without sacrificing the increased passenger safety of more traditional AHSS. Through the three tasks of the project, (1) Alloy design and small-scale laboratory evaluation, (2) Laboratory development of hot rolled material and (3) Laboratory development of a cold rolled material, the laboratory work utilized advanced characterization and analytical methods on novel alloy compositions subjected to both conventional and non-conventional processing operations.

36 MATERIALS SCIENCE↗

Near-infrared absorbing acceptor with suppressed triplet exciton generation enabling high performance tandem organic solar cells

Reducing the energy loss of sub-cells is critical for high performance tandem organic solar cells, while it is limited by the severe non-radiative voltage loss via the formation of non-emissive triplet excitons. Herein, we develop an ultra-narrow bandgap acceptor BTPSeV-4F through replacement of terminal thiophene by selenophene in the central fused ring of BTPSV-4F, for constructing efficient tandem organic solar cells. The selenophene substitution further decrease the optical bandgap of BTPSV-4F to 1.17 eV and suppress the formation of triplet exciton in the BTPSV-4F-based devices. The organic solar cells with BTPSeV-4F as acceptor demonstrate a higher power conversion efficiency of 14.2% with a record high short-circuit current density of 30.1 mA cm –2 and low energy loss of 0.55 eV benefitted from the low non-radiative energy loss due to the suppression of triplet exciton formation. We also develop a high-performance medium bandgap acceptor O1-Br for front cells. By integrating the PM6:O1-Br based front cells with the PTB7-Th:BTPSeV-4F based rear cells, the tandem organic solar cell demonstrates a power conversion efficiency of 19%. The results indicate that the suppression of triplet excitons formation in the near-infrared-absorbing acceptor by molecular design is an effective way to improve the photovoltaic performance of the tandem organic solar cells.

14 SOLAR ENERGY↗

Revealing origin of quasi-one dimensional current transport in defect rich two dimensional materials

The presence of defects in graphene have for a long time been recognized as a bottleneck for its utilization in electronic and mechanical devices. We recently showed that micro four-point probes may be used to evaluate if a graphene film is truly 2D or if defects in proximity of the probe will lead to a non-uniform current flow characteristic of lower dimensionality. In this work, simulations based on a finite element method together with a Monte Carlo approach are used to establish the transition from 2D to quasi-1D current transport, when applying a micro four-point probe to measure on 2D conductors with an increasing amount of line-shaped defects. Clear 2D and 1D signatures are observed at low and high defect densities, respectively, and current density plots reveal the presence of current channels or branches in defect configurations yielding 1D current transport. A strong correlation is found between the density filling factor and the simulation yield, the fraction of cases with 1D transport and the mean sheet conductance. The upper transition limit is shown to agree with the percolation threshold for sticks. Finally, the conductance of a square sample evaluated with macroscopic edge contacts is compared to the micro four-point probe conductance measurements and we find that the micro four-point probe tends to measure a slightly higher conductance in samples containing defects.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Relationship of dislocation density of silicon to solar cell current loss at low temperature.

Large decreases in short circuit current of silicon solar cells have been reported to occur as temperature is decreased below -60 C. Experimental results are presented which relate high dislocation density of the silicon bulk material of cells to the large current loss effect. These results reveal a direct relationship between low bulk dislocation density and low current loss at low temperature. Oxygen content does not appear to play a significant role in the low temperature-large current loss effect, since some Czochralski cells did not suffer from this effect whereas some float-zone cells did. Other float-zone silicon cells had only medium current losses at low temperature despite their high bulk dislocation density. It appears that use of low-dislocation-density silicon can eliminate the current loss problem in low temperature cell operation.

Mandelkorn, J.↗

High breakdown single-crystal GaN p-n diodes by molecular beam epitaxy

Molecular beam epitaxy grown GaN p-n vertical diodes are demonstrated on single-crystal GaN substrates. A low leakage current <3 nA/cm2 is obtained with reverse bias voltage up to −20 V. With a 400 nm thick n-drift region, an on-resistance of 0.23 mΩ cm2 is achieved, with a breakdown voltage corresponding to a peak electric field of ∼3.1 MV/cm in GaN. Single-crystal GaN substrates with very low dislocation densities enable the low leakage current and the high breakdown field in the diodes, showing significant potential for MBE growth to attain near-intrinsic performance when the density of dislocations is low.

Qi, Meng (ORCID:0000000299430056)↗

3D Graphitic Foams Derived from Chloroaluminate Anion Intercalation for Ultrafast Aluminum-Ion Battery

We present that a 3D graphitic foam vertically aligned graphitic structure and a low density of defects is derived through chloroaluminate anion intercalation of graphite followed by thermal expansion and electrochemical hydrogen evolution. Such aligned graphitic structure affords excellent Al-ion battery characteristics with a discharge capacity of ≈60 mA h g -1 under a high charge and discharge current density of 12 000 mA g -1 over ≈4000 cycles.

25 ENERGY STORAGE↗

Achievement of a high-density, high-confinement, and high-beta tokamak plasma regime in DIII-D, and implications for a lower-current path for ITER and FPP

Experiments on DIII-D have demonstrated a density-confinement synergy that enables sustainment of high performance in a previously unattained parameter regime of simultaneous very high energy confinement quality (H 98y2 ≥ 1.5), very high line-average density Greenwald fraction (ƒ Gr = πa 2 < n >/I P ≥ 1.4), and high toroidal beta (β T ≥ 3%). Tokamak operation in this regime is essential for a compact steady-state FPP, as well as for Q=10 with 500 MW of fusion power in ITER at I P << 15 MA. These experiments leveraged the knowledge that, in the high-poloidal-beta (β P ) regime, impurity and density gradients can enhance turbulence stabilization caused by high α MHD (α MHD ~(dβ P )⁄dr). This was described by theoretical predictions and gyrokinetic transport simulations [M.T. Kotschenreuther et al, 2024 Nucl. Fusion, 64 076033], and later confirmed by experiments on DIII-D [S. Ding et al, 2024 Nature 629 555]. To increase both β P and β T , the new experiments increased the ideal-wall stability β N -limit by using a smaller plasma-outer wall distance and higher triangularity in the plasma cross section (top/bottom average δ~0.9), enabled by the recent “shape & volume rise” (SVR) modification to the DIII-D divertor. The higher triangularity also contributed to achieving higher ƒ Gr by enabling higher pedestal density. At high density, the pedestal is ballooning limited and exhibits small and frequent ELMs, while the divertor is near detachment even without any impurity seeding. High plasma performance was attained and sustained reproducibly, with the eventual terminations brought about by an MHD mode destabilized as the current profile slowly continued to evolve. A path to stationary fully noninductive operation might include ECH injection to reduce both core impurity accumulation and the electron collisionality, thus increasing the bootstrap current. These experiments provide the first experimental demonstration of the ƒ Gr , H 98y2 , and β T values required simultaneously for ITER Q = 10 at I P < 10 MA, pointing to practical ways to improve the energy confinement in a fusion reactor.

Garofalo, Andrea M. [General Atomics, San Diego, C↗

Engineering current density over 5 kA mm -2 at 4.2 K, 14 T in thick film REBCO tapes

We report on remarkably high in-field performance at 4.2 K achieved in >4 $μ$m thick rare earth barium copper oxide (REBCO) samples with Zr addition. Two different samples have been measured independently at Lawrence Berkeley National Laboratory and the National High Magnetic Field Laboratory, achieving critical current densities ( J c ) of 12.21 MA cm -2 and 12.32 MA cm -2 at 4.2 K, 14 T ($\small{B}$|| c ), respectively, which corresponds to equivalent critical current ( I c ) values of 2247 and 2119 A/4 mm. These I c values are about two times higher than the best reported performance of REBCO tapes to date and more than five times higher than the commercial HTS tapes reported in a recent study. The measured J c values, with a pinning force of ~1.7 T N m -3 are almost identical to the highest value reported for thin (~1 $μ$m thick) REBCO at the field and temperature, but extended to very thick (>4 μm) films. This results in an engineering current density ( J e ) above 5 kA mm -2 at 4.2 K, 14 T, which is more than five times higher than Nb 3 Sn and nearly four times higher than the highest reported value of all superconductors other than REBCO at this field and temperature. The reported results have been achieved by utilizing an advanced metal organic chemical vapor deposition system. This study demonstrates the remarkable level of in-field performance achievable with REBCO conductors at 4.2 K and strong potential for high-field magnet applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Design and synthesis of N-doped mesoporous carbon@ NiCo2O4 nanocomposites with various morphologies for high electrochemical performance applied in supercapacitors

Highlights: • Various morphologies of N-doped mesoporous carbon@ NiCo{sub 2}O{sub 4}, such as sea urchins-like structure NiCo{sub 2}O{sub 4}, litchi chinensis-like structure of 0.1 g NC@ NiCo{sub 2}O{sub 4} and waxyberry-like structure of 0.2 g NC@ NiCo{sub 2}O{sub 4} are successfully synthesized by a facile hydrothermal method. • Waxberry-like structure of 0.2 g NC@ NiCo{sub 2}O{sub 4} shows the best electrochemical performancee among these three structures. • Waxberry-like structure of 0.2 g NC@ NiCo{sub 2}O{sub 4} has a considerable specific capacitance of 1624 F g{sup −1} at a current density of 1A g{sup −1} with superior electrochemical stability after 10000 cycles. - Abstract: Hybrid nanostructures of N-doped mesoporous carbon@NiCo{sub 2}O{sub 4} with controllable compositions are prepared by a facile hydrothermal method. Various morphologies of N-doped mesoporous carbon@NiCo{sub 2}O{sub 4} are successfully synthesized including sea urchins-like structure of free NiCo{sub 2}O{sub 4}, litchi chinensis-like structure of NC-100@ NiCo{sub 2}O{sub 4} and waxberry-like structure of NC-200@ NiCo{sub 2}O{sub 4}. All samples exhibit excellent rate capability and cycle stability. The incorporation of N-doped mesoporous carbon causes a dominant capacitance increase. Free NiCo{sub 2}O{sub 4} only possesses a specific capacitance of 1038 F g{sup −1} at 1 A g{sup −1}, while NC-200@ NiCo{sub 2}O{sub 4} renders a much higher specific capacitance of 1624 F g{sup −1}, which shows a distinct improvement of 56.4%. Moreover, NC-200@ NiCo{sub 2}O{sub 4} still performs a high specific capacitance of 1360 F g{sup -1} even at a high current density of 10 A g{sup −1}. Besides, the final capacitance can still maintain 94.3% of the initial capacitance even after 10,000 cycles.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Cr{sub 2}O{sub 5} as new cathode for rechargeable sodium ion batteries

Chromium oxide, Cr{sub 2}O{sub 5}, was synthesized by pyrolyzing CrO{sub 3} at 350 °C and employed as a new cathode in rechargeable sodium ion batteries. Cr{sub 2}O{sub 5}/Na rechargeable batteries delivered high specific capacities up to 310 mAh/g at a current density of C/16 (or 20 mA/g). High-resolution solid-state {sup 23}Na NMR both qualitatively and quantitatively revealed the reversible intercalation of Na ions into the bulk electrode and participation of Na ions in the formation of the solid-electrolyte interphase largely at low potentials. Amorphization of the electrode structure occurred during the first discharge revealed by both NMR and X-ray diffraction data. CrO{sub 3}-catalyzed electrolyte degradation and loss in electronic conductivity led to gradual capacity fading. The specific capacity stabilized at >120 mAh/g after 50 charge-discharge cycles. Further improvement in electrochemical performance is possible via electrode surface modification, polymer binder incorporation, or designs of new morphologies. - Graphical abstract: Electrochemical profile of a Cr{sub 2}O{sub 5}/Na battery cell and high-resolution solid-state {sup 23}Na MAS NMR spectrum of a Cr{sub 2}O{sub 5} electrode discharged to 2 V. - Highlights: • Cr{sub 2}O{sub 5} was synthesized and used as a new cathode in rechargeable Na ion batteries. • A high capacity of 310 mAh/g and an energy density of 564 Wh/kg were achieved. • High-resolution solid-state {sup 23}Na NMR was employed to follow the reaction mechanisms.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A multidimensional approach to quantum state tomography of photoelectron wavepackets

There is a growing interest in reconstructing the density matrix of photoelectron wavepackets, in particular in complex systems where decoherence can be introduced either by a partial measurement of the system or through coupling with a stochastic environment. To this end, several methods to reconstruct the density matrix, quantum state tomography protocols, have been developed and tested on photoelectrons ejected from noble gases following absorption of extreme ultraviolet (XUV) photons from attosecond pulses. It remains a challenge to obtain model-free, single scan protocols that can reconstruct the density matrix with high fidelities. Current methods require extensive measurements or involve complex fitting of the signal. Efficient single-scan reconstructions would be of great help to increase the number of systems that can be studied. We propose a new and more efficient protocol that is able to reconstruct the continuous variable density matrix of a photoelectron in a single time delay scan. It is based on measuring the coherences of a photoelectron created by absorption of an XUV pulse using a broadband infrared (IR) probe that is scanned in time and a narrowband IR reference that is temporally fixed to the XUV pulse. We illustrate its performance for a Fano resonance in He as well as mixed states in Ar arising from spin-orbit splitting. We show that the protocol results in excellent fidelities and near-perfect estimation of the purity.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Spectral broadening measurement of the lower hybrid waves during long pulse operation in Tore Supra

On many tokamaks (C-Mod, EAST, FTU, JET, HT-7, TS), a decrease in current drive efficiency of the Lower Hybrid (LH) waves is observed in high electron density plasmas. The cause of this behaviour is believed to be: Parametric Instabilities (PI) and Scattering from Density Fluctuations (SDF). For the ITER LH system, our knowledge must be improved to avoid such effects and to maintain the LH current drive efficiency at high density. The ITPA IOS group coordinates this effort [1] and all experimental data are essential to validate the numerical codes in progress. Usually the broadening of the LH wave frequency spectrum is measured by a probe located in the plasma edge. For this study, the frequency spectrum of a reflected power signal from the LH antenna was used. In addition, the spectrum measurements are compared with the density fluctuations observed on RF probes located at the antenna mouth. Several plasma currents (0.6 to 1.4 MA) and densities up to 5.2 × 10{sup 19} m−3 have been realised on Tore Supra (TS) long pulses and with high injected RF power, up to 5.4 MW-30s. This allowed using a spectrum analyser to make several measurements during the plasma pulse. The side lobe amplitude, shifted by 20-30MHz with respect to the main peak, grows with increasing density. Furthermore, for an increase of plasma current at the same density, the spectra broaden and become asymmetric. Some parametric dependencies are shown in this paper.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

SiN sub x passivation of silicon surfaces

The objectives were to perform surface characterization of high efficiency n+/p and p+/n silicon cells, to relate surface density to substrate dopant concentration, and to identify dominant current loss mechanisms in high efficiency cells. The approach was to measure density of states on homogeneously doped substrates with high frequency C-V and Al/SiN sub x/Si structures; to investigate density of states and photoresponse of high efficiency N+/P and P+/N cells; and to conduct I-V-T studies to identify current loss nechanisms in high efficiency cells. Results are given in tables and graphs.

Olsen, L. C.↗