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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Fluorescent Detection of Carbon Disulfide by a Highly Emissive and Robust Isoreticular Series of Zr-Based Luminescent Metal Organic Frameworks (LMOFs)

Carbon disulfide (CS 2 ) is a highly volatile neurotoxic species. It is known to cause atherosclerosis and coronary artery disease and contributes significantly to sulfur-based pollutants. Therefore, effective detection and capture of carbon disulfide represents an important aspect of research efforts for the protection of human and environmental health. In this study, we report the synthesis and characterization of two strongly luminescent and robust isoreticular metal organic frameworks (MOFs) Zr 6 (µ 3- O) 4 (OH) 8 (tcbpe) 2 (H 2 O) 4 (here termed 1) and Zr 6 (µ 3- O) 4 (OH) 8 (tcbpe-f) 2 (H 2 O) 4 (here termed 2) and their use as fluorescent sensors for the detection of carbon disulfide. Both MOFs demonstrate a calorimetric bathochromic shift in the optical bandgap and strong luminescence quenching upon exposure to carbon disulfide. The interactions between carbon disulfide and the frameworks are analyzed by in-situ infrared spectroscopy and computational modelling by density functional theory. These results reveal that both the Zr metal node and organic ligand act as the preferential binding sites and interact strongly with carbon disulfide.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Structure Formation Through Magnetohydrodynamical Instabilities in Primordial Disks

The shear flow instabilities under the presence of magnetic fields in the primordial disk can greatly facilitate the formation of density structures that serve as seeds prior to the onset of the gravitational Jeans instability. We evaluate the effects of the Parker, magnetorotational and kinematic dynamo instabilities by comparing the properties of these instabilities. We calculate the mass spectra of coagulated density structures by the above mechanism in the radial direction for an axisymmetric magnetohydrodynamic (MHD) torus equilibrium and power density profile models. Our local three-dimensional MHD simulation indicates that the coupling of the Parker and magnetorotational instability creates spiral arms and gas blobs in an accretion disk, reinforcing the theory and model. Such a mechanism for the early structure formation may be tested in a laboratory. The recent progress in experiments involving shear flows in rotating tokamak, field reversed configuration (FRC) and laser plasmas may become a key element to advance in nonlinear studies.

Noguchi, Koichi↗
DOE OSTI2016

Stark broadening of high-order radio recombination lines toward the Orion nebula

We report the results of observations and analyses of 41 Δn=1,…,5 hydrogen radio recombination lines from the Orion nebula (M42) at 5.5 to 6.5 GHz, with a spectral sensitivity (channel-to-channel standard deviation) of ≈2 mJy. Observations were conducted at the Australia Telescope Compact Array. A 1 GHz bandwidth allowed simultaneous detection of up to 11 spectral lines of equal Δn that were stacked to enable accurate measurement of line widths. Collisional widths in the range of principal quantum numbers n from 100 to 179 are found to be consistent with predictions of electron impact Stark broadening theory. An Orion nebula model with density inhomogeneities (clumps) and gradients of temperature and density is consistent with our data. We reanalyze the data of Smirnov et al. and Bell et al. and find excellent agreement between all statistically significant measurements and theory. Our findings confirm the absence of line narrowing for n = 100...179.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1970

Axially symmetric model planetary nebulae

Planetary nebulae NGC 7662 and NGC 7009 axially symmetric models from density distributions, H continuum threshold optical depths and central star temperatures

Kirkpatrick, R. C.↗
NASA NTRS1974

Coronal density structures in regions of type III activity

The density of the corona over the active regions generating the type III exciters are examined, taking into account radio data together with daily white light coronal observations obtained with a K-coronameter. The intensity profiles and the synoptic maps derived from the K-corona data make it possible to distinguish between dense structures and low intensity regions. A deconvolution technique developed by Leblanc et al. (1970) is applied to calculate the electron density of these structures. For the low intensity regions van de Hulst's (1950) method has been used to compute the electron density of models.

Leblanc, Y.↗
NASA NTRS1976

Effects of a magnetic field gradient on the lower hybrid drift instability

The effect of a magnetic field gradient on the lower hybrid drift instability is examined in the low drift velocity regime (i.e., of the order of the ion thermal velocity). The theoretical model includes density and temperature gradients, and considers only waves propagating perpendicular to the ambient magnetic field with wavelengths of the order of the electron Larmor radius. It is found, for the case of a finite ratio of the electron pressure to the magnetic field pressure, that a magnetic gradient drift-wave resonance can be important and is stabilizing or destabilizing depending upon the physical conditions. Substantial plasma heating and a large anomalous resistivity can also occur.

Huba, J. D.↗
NASA NTRS1979

Shape of the ocean surface and implications for the Earth's interior: GEOS-3 results

A new set of 1 deg x 1 deg mean free air anomalies was used to construct a gravimetric geoid by Stokes' formula for the Indian Ocean. Utilizing such 1 deg x 1 deg geoid comparisons were made with GEOS-3 radar altimeter estimates of geoid height. Most commonly there were constant offsets and long wavelength discrepancies between the two data sets; there were many probable causes including radial orbit error, scale errors in the geoid, or bias errors in altitude determination. Across the Aleutian Trench the 1 deg x 1 deg gravimetric geoids did not measure the entire depth of the geoid anomaly due to averaging over 1 deg squares and subsequent aliasing of the data. After adjustment of GEOS-3 data to eliminate long wavelength discrepancies, agreement between the altimeter geoid and gravimetric geoid was between 1.7 and 2.7 meters in rms errors. For purposes of geological interpretation, techniques were developed to directly compute the geoid anomaly over models of density within the Earth. In observing the results from satellite altimetry it was possible to identify geoid anomalies over different geologic features in the ocean. Examples and significant results are reported.

Chapman, M. E.↗
NASA NTRS1980

Semiconductor technology program. Progress briefs

Measurement technology for semiconductor materials, process control, and devices is reviewed. Activities include: optical linewidth and thermal resistance measurements; device modeling; dopant density profiles; resonance ionization spectroscopy; and deep level measurements. Standardized oxide charge terminology is also described.

Bullis, W. M.↗
NASA NTRS1983

Response of amphibian egg cytoplasm to novel gravity orientation and centrifugation

The effects of inversion and centrifugation on the compartmentalization of cytoplasm in Xenopus laevis eggs are investigated experimentally. The rearrangement of yolk-platelet compartments (YPC) characterized by morphology, density, and viscosity differences is studied in fertilized, unfertilized, and unfertilized electrically activated eggs in normal, and inverted positions and with and without centrifugation at 10-183 x g for 5 min. The eggs are fixed and embedded in plastic or paraffin prior to sagittal sectioning (0.5, 4, or 8 microns) and microscopic examination; the results are presented in a diagram and discussed. A density-compartment model combining both animal/vegetal and dorsal/ventral polarities is proposed: YPC determined without gravity orientation during oogenesis respond to both sperm entrance point and gravity after fertilization, and the response involves breaking of the radial symmetry of the egg. It is predicted that Xenopus eggs in a microgravity environment will encounter difficulties in establishing a primary embryonic axis.

Neff, A. W.↗
NASA NTRS1986

Constitutive Equations of Aging in Polymers

Theoretical paper presents solutions of equations that describe polymeric aging. Solutions apply under such loading conditions as constant strain (stress relaxation), constant strain rate, and stress relaxation with sudden change of cross-link density. Theoretical models form framework for predicting chemomechanical aging behavior of elastomers and polymers.

Peng, S. T. J.↗
NASA NTRS1985

Study of the potential usefulness of superfine holographic x-ray gratings in AXAF and astrophysics in general

Present day high energy electron storage rings and insertion devices (wigglers and undulators) provide the necessary technology to manufacture superfile (line density or=100,00/mm) holographic X-ray gratings. The usefulness in future astrophysical research of such gratings is determined, as a function of the grating size and line density. A model design is given for an instrument which would fit within the (presently specified) constraints of the planned Advanced X-ray Astrophysics Facility (AXAF).

Csonka, P. L.↗
NASA NTRS1986

An adaptive guidance algorithm for an aerodynamically assisted orbital plane change maneuver

Using analysis results from the post trajectory optimization program, an adaptive guidance algorithm is developed to compensate for density, aerodynamic and thrust perturbations during an atmospheric orbital plane change maneuver. The maneuver offers increased mission flexibility along with potential fuel savings for future reentry vehicles. Although designed to guide a proposed NASA Entry Research Vehicle, the algorithm is sufficiently generic for a range of future entry vehicles. The plane change analysis provides insight suggesting a straight-forward algorithm based on an optimized nominal command profile. Bank angle, angle of attack, and engine thrust level, ignition and cutoff times are modulated to adjust the vehicle's trajectory to achieve the desired end-conditions. A performance evaluation of the scheme demonstrates a capability to guide to within 0.05 degrees of the desired plane change and five nautical miles of the desired apogee altitude while maintaining heating constraints. The algorithm is tested under off-nominal conditions of + or -30% density biases, two density profile models, + or -15% aerodynamic uncertainty, and a 33% thrust loss and for various combinations of these conditions.

Blissit, J. A.↗
NASA NTRS1985

Processing of laser formed SiC powder

Superior SiC characteristics can be achieved through the use of ideal constituent powders and careful post-synthesis processing steps. High purity SiC powders of approx. 1000 A uniform diameter, nonagglomerated and spherical were produced. This required major revision of the particle formation and growth model from one based on classical nucleation and growth to one based on collision and coalescence of Si particles followed by their carburization. Dispersions based on pure organic solvents as well as steric stabilization were investigated. Although stable dispersions were formed by both, subsequent part fabrication emphasized the pure solvents since fewer problems with drying and residuals of the high purity particles were anticipated. Test parts were made by the colloidal pressing technique; both liquid filtration and consolidation (rearrangement) stages were modeled. Green densities corresponding to a random close packed structure (approx. 63%) were achieved; this highly perfect structure has a high, uniform coordination number (greater than 11) approaching the quality of an ordered structure without introducing domain boundary effects. After drying, parts were densified at temperatures ranging from 1800 to 2100 C. Optimum densification temperatures will probably be in the 1900 to 2000 C range based on these preliminary results which showed that 2050 C samples had experienced substantial grain growth. Although overfired, the 2050 C samples exhibited excellent mechanical properties. Biaxial tensile strengths up to 714 MPa and Vickers hardness values of 2430 kg/sq mm 2 were both more typical of hot pressed than sintered SiC. Both result from the absence of large defects and the confinement of residual porosity (less than 2.5%) to small diameter, uniformly distributed pores.

Haggerty, J. S.↗
NASA NTRS1987

Structure and kinematics of the molecular spiral arms in M51

Mapping of the CO(1-0) emission from the spiral galaxy was made with the Onsala 20 m antenna. The observations show that the emission is considerably enhanced in spiral arms which appear to originate as intense ridges of emission about 1 kpc from the nucleus. One of the main objectives for the 1986 observations was to study the variations of the tangential velocity component of molecular gas across a spiral arm. The radial velocity was found to have a velocity shift similar to that predicted by the density wave theory. The present (1986) observations of the inner southern spiral arm of M51 show that the tangential velocity component also behaves in a way which conforms with the density wave model. The molecular arms were compared with the H alpha ionized gas arms of Tully (1974) and it was found that the ionized gas appears to have its maximum intensity slightly outside the molecular arm.

Rydbeck, G.↗