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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

An interactive modular design for computerized photometry in spectrochemical analysis

A general functional description of totally automatic photometry of emission spectra is not available for an operating environment in which the sample compositions and analysis procedures are low-volume and non-routine. The advantages of using an interactive approach to computer control in such an operating environment are demonstrated. This approach includes modular subroutines selected at multiple-option, menu-style decision points. This style of programming is used to trace elemental determinations, including the automated reading of spectrographic plates produced by a 3.4 m Ebert mount spectrograph using a dc-arc in an argon atmosphere. The simplified control logic and modular subroutine approach facilitates innovative research and program development, yet is easily adapted to routine tasks. Operator confidence and control are increased by the built-in options including degree of automation, amount of intermediate data printed out, amount of user prompting, and multidirectional decision points.

Bair, V. L.↗
NASA NTRS1979

Petrographic and chemical characterization of igneous lithic clasts from mesosiderites and howardites and comparison with eucrites and diogenites

Petrographic, electron microprobe, and instrumental neutron activation analysis (INAA) studies of igneous lithic clasts separated from mesosiderites and howardites and INAA investigation of whole rock eucrites and diogenites are presented. The trace element abundances in basaltic lithic clasts indicate more complex differentiation episodes than in eucrites which include sequential melting and expulsion of liquid from the source region and remelting of cumulate materials. Pyroxenites from mesosiderites show slight enrichments in Sc and Mn than diogenites suggesting that these pyroxenites are not fragments of diogenites. It is concluded that the heat source characteristics are spatially and temporally variable, suggesting that heating of the differentiated meteorite parent bodies may have partly come from outside the parent body.

Mittlefehldt, D. W.↗
NASA NTRS1979

Petrology, chemistry, and chronology of Apollo 14 KREEP basalts

The results of petrographic, major and trace element geochemical, and Rb-Sr isotopic studies of four crystalline matrix breccias and two intergranular to subophitic basalts are reported. Emphasis is placed on the relationship of the basalt fragments to other Apollo 14 KREEP basalts, and the origin of this group as a whole. Considering the high siderophile element content, the balance of evidence favors origin of the Apollo 14 KREEP basalts by impact melting, probably a single melt with slight chemical and isotopic heterogeneities.

Mckay, G. A.↗
NASA NTRS1979

The compositional-petrographic search for pristine nonmare rocks - Third foray

In the present paper, eleven nonmare samples are characterized petrographically and by composition, including numerous key trace elements (siderophiles and incompatibles). At least eight of the samples were identified as positively pristine, which means that they preserve faithfully the compositional variety of the original lunar crust. Anorthosites, troctolites, and norites appear to be the major 'primary' constituents of the crust.

Warren, P. H.↗
NASA NTRS1979

Lunar and Planetary Science Conference, 10th, Houston, Tex., March 19-23, 1979, Proceedings. Volume 2 - Early solar system and lunar regolith

Papers are presented concerning studies of the lunar regolith, the remote sensing of the surface compositions of the moon and planets, and the origin and evolution of the solar system. Specific topics include the stratigraphy and depositional history of the Apollo 17 deep drill core, the trace element and metallic iron abundances in fractions of the Apollo 15 deep drill core, the surface chemistry of lunar impact glasses, cosmic ray-produced noble gases in lunar samples, and the properties of microcraters and cosmic dust less than 1000 A in diameter. Attention is also given to the remote sensing of mare surface titanium concentrations, Viking Lander multispectral images, star and planetary system formation in collapsing, viscous, rotating clouds and the importance of planet size to basaltic volcanism.

Merrill, R. B.↗
NASA NTRS1979

The Apollo 17 drill core - Chemical systematics of grain size fractions

Data for 35 major, minor, and trace elements in 40 bulk and size fractions of core 70005-70003 (140-250 cm) are presented. The core is heterogeneous with depth. Moreover, the 1000 to 90 micron coarse fractions are nearly identical but quite different from the less than 20 micron fine fraction. The bulk soil chemistry is governed by the coarse fractions, because of their greater weight proportion in the sample. The 1000-90 micron fraction contains more ilmenite basalt and less orange glass components than the 90-20 micron fraction. The less than 20 micron fraction is consistently enriched in highland material at all depths in the drill core.

Laul, J. C.↗
NASA NTRS1980

Chemical fractionations in meteorites. XI - C2 chondrites

Measurements of the compositions of 20 trace elements in the representative C2 chondrites Boriskino, Cold Bokkeveld, Erakot, Essebi, Haripura, Santa Cruz and Al Rais are reported. The contents of Ag, Au, Bi, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Sn, Te, Tl, U, and Zn were determined by radiochemical neutron activation analysis. The siderophile abundances of the C2 chondrites are found to be less uniform than those of other carbonaceous chondrites, while the C2R chondrite Al Rais is systematically lower in 12 volatiles than the C2M chondrites. Enrichment of Bi and Tl found in Erakot and Haripura indicate the possible presence of the late condensate mysterite. Volatile abundances are shown to agree with matrix contents for meteorites that have suffered little aqueous alteration, however to be 20-30% lower for the more altered meteorites. Finally, the decline of element abundance with volatility is shown to be consistent with the sigmoid curve explained by the two-component model.

Wolf, R.↗
NASA NTRS1980

An interactive modular design for computerized photometry in spectrochemical analysis

An interactive, top-down structured program design is described which produces a general flexible description of totally automatic photometry of emission spectra in an operating environment in which sample compositions and analysis procedures are low-volume and nonroutine. The use of this type of programming is illustrated by a project to computerize trace elemental determinations including the automated reading of spectrographic plates produced by a 3.4-m Ebert mount spectrograph using a dc-arc in an argon atmosphere.

Bair, V. L.↗
NASA NTRS1980

Hg and Pt-metals in meteorite carbon-rich residues - Suggestions for possible host phase for Hg

Carbon-rich and oxide residual phases have been isolated from Allende and Murchison by acid demineralization for the determination of their Hg, Pt-metal, Cr, Sc, Co, and Fe contents. Experimental procedures used eliminated the possibility of exogenous and endogenous contaminant trace elements from coprecipitating with the residues. Large enrichments of Hg and Pt-metals were found in Allende but not in Murchison residues. Hg-release profiles from stepwise heating experiments suggest a sulfide as the host for Hg. Diffusion calculations for Hg based on these experiments indicate an activation energy of 7-8 kcal/mol, the same as that for Hg in troilite from an iron meteorite. This is further support for a sulfide host phase for Hg. Equilibration of Hg with this phase at approximately 900 K is indicated. Reasons for the presence of Pt-metals in noncosmic relative abundances are explored.

Jovanovic, S.↗
NASA NTRS1980

Moon and earth - Compositional differences inferred from siderophiles, volatiles, and alkalis in basalts

A comparison of RNAA analyses of 18 trace elements in 25 low-Ti lunar and 10 terrestrial oceanic basalts indicated that the volatiles such as Ag, Bi, and Br are depleted in lunar basalts by nearly constant factors of 0.026 relative to terrestrial basalts. This constancy is not consistent with models that derive the moon's volatiles from partial recondensation of the earth's mantle or from partial degassing of a captured body; it is consistent with models which derive planetary volatiles from a thin veneer of C-chondrite material. Chalcogens (Se and Te) have almost constant and identical abundances in lunar and terrestrial basalts; siderophiles show abundant Ni in lunar basalts, while Ir, Re, Ge, and Au are depleted.

Wolf, R.↗
NASA NTRS1981

Compositional inhomogeneities in a single Icelandic tholeiite flow

New trace element analyses of 25 basalt samples from a vertical traverse in an 11 m thick flow of Icelandic tholeiite show compositional differences which exceed analytical uncertainties and are random with respect to height. These variations suggest a short-range segregation model in which the amounts of phenocrysts, groundmass materials, and residual liquid vary randomly in different samples of the flow; a least-squares method is applied to determine if these variations reflect different proportions of crystallizing phases and residual liquid. Monte Carlo computations indicate that short-range segregation results in inhomogeneity of a magnitude of interflow compositional differences; this causes incoherence in elements with different geochemical behaviors while preserving coherence in elements of similar behavior.

Lindstrom, M. M.↗
NASA NTRS1980

Hafnium isotope variations in oceanic basalts

Hafnium isotope ratios generated by the beta(-) decay of Lu-176 are investigated in volcanic rocks derived from the suboceanic mantle. Hf-176/Hf-177 and Lu/Hf ratios were determined to precisions of 0.01-0.04% and 0.5%, respectively, by routine, low-blank chemistry. The Hf-176/Hf-177 ratio is found to be positively correlated with the Nd-143/Nd-144 ratio and negatively correlated with the Sr-87/Sr-86 and Pb-206/Pb-204 ratios, and to increase southwards along the Iceland-Reykjanes ridge traverse. An approximate bulk earth Hf-176/Hf-177 ratio of 0.28295 is inferred from the bulk earth Nd-143/Nd-144 ratio, which requires a bulk earth Lu/Hf ratio of 0.25, similar to the Juvinas eucrite. Midocean ridge basalts are shown to account for 60% of the range of Hf isotope ratios, and it is suggested that Lu-Hf fractionation is decoupled from Sm-Nd and Rb-Sr fractionation in very trace-element-depleted source regions as a result of partial melting.

Patchett, P. J.↗
NASA NTRS1981

The Antarctic achondrite ALHA 76005 - A polymict eucrite

ALHA 76005 is a basaltic achondrite containing few, if any, orthopyroxenes. Its bulk major and trace element composition is like that of a non-cumulate eucrite, and unlike that of a howardite. It contains a variety of igneous clasts which differ in their textures, pyroxene/plagioclase ratios and pyroxene and plagioclase compositions. One clast, No. 4, was found to have the REE pattern of a cumulate eucrite and an oxygen isotopic composition different from that of the bulk meteorite. Both the chemical and oxygen isotopic composition of clast No. 4 suggest that it was derived from a source different from its host. These observations lead to the conclusion that ALHA 76005 is a polymict eucrite.

Grossman, L.↗
NASA NTRS1981

Recent progress in exobiology and planetary biology

Recent work in the fields of exobiology, the study of the possible characteristics of extraterrestrial life, and planetary biology, the study of life forms as a function of planetary conditions, is reviewed. Searches conducted for life on Mars by the Viking Landers and on Titan by Voyager 1 are considered, and the origin of life on earth is considered in relation to the question of the inorganic trace elements in living systems that are required for life. The question of the origin of terrestrial life from spores carried through the interstellar medium is examined, and the unlikelihood of the survival of such spores except within meteorites or dust particles is pointed out. Studies of organic molecules present in the interstellar medium are indicated as evidence that the conditions necessary for the formation of life can exist in various locations throughout the universe. Investigations of the molecular evolution of life on earth and of life under extreme conditions of heat, cold, drought and ultraviolet radiation, and of the organic compounds found in meteorites and comets are also discussed. The importance of a mechanism of heredity, such as terrestrial DNA, to the evolution of terrestrial and possible extraterrestrial life is pointed out.

Jukes, T. H.↗
NASA NTRS1981

Metal and Bi/Pb microdistribution studies of an L3 chondrite - Their implications for a meteorite parent body

Strong localizations relative to bulk are reported of Bi, and to a lesser extent Pb, in some of the kamacite grains in Khohar, while other kamacite grains show no such enrichments. Distinctive and correlated differences in the Ni content are found in the two kamacite populations, with the Bi/Pb-rich kamacite grains having consistently lower Ni levels than the 6-7% typical of the Bi/Pb-poor kamacite. The Bi/Pb-rich kamacite grains also exhibit a highly reactive attack upon etching, which may be due to a finely polycrystaline microstructure. It is concluded that the trace element microdistributions were not established in the nebula, and that the enrichments were not likely to have occurred with slow cooling in the presence of a vapor phase during the kamacite-taenite phase transitions.

Woolum, D. S.↗
NASA NTRS1981

Lu-Hf total-rock age for the Amitsoq gneisses, West Greenland

Lu-Hf total-rock data for the Amitsoq gneisses of West Greenland yield an age of 3.55 + or - 0.22 billion years, based on the decay constant for Lu-176 of 1.96 x 10 to the -11th/year, and an initial Hf-176/Hf-177 ratio of 0.280482 + or - 33. The result is in good agreement with Rb-Sr total-rock and U-Pb zircon ages. In spite of severe metamorphism of the area at 2.9 billion years, zircons from two of the samples have remained on the total-rock line, and define points close to the initial Hf ratio. The initial Hf-176/Hf-177 lies close to a chondritic Hf isotopic evolution curve from 4.55 billion years to present. This is consistent with the igneous precursors to the Amitsoq gneisses having been derived from the mantle at or shortly before 3.6 billion years. Anomalous relationships between Hf concentration and the Lu-176/Hf-177 ratio may suggest that trace element abundances in the Amitsoq gneisses are partly controlled by processes related to metamorphism.

Pettingill, H. S.↗
NASA NTRS1981

Identification of the projectile at the Brent crater, and further considerations of projectile types at terrestrial craters

An analysis of impact melt samples from a drill hole at the Brent crater in Ontario for siderophile trace elements indicative of meteoritic contamination, has resulted in 823-857 m-deep basalt melt zone samples enriched in Ir, Os, Pd, Ni, Co, Cr and Se over basement. The abundance pattern suggests a chondritic projectile and, from a Ni-Cr correlation of 10 melt samples, an L or LL chondrite is inferred. Data from the Manicouagan, Mitastin, and Zhamanshin craters are also assessed, and large differences in siderophile element concentrations are found among the tektites which otherwise have similar chemical compositions. There are now four known craters formed by chondrites, with Brent being the smallest among them.

Palme, H.↗