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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Twisted, multifilament Nb3Sn superconductive ribbon

An experimental study of superconductor stabilization has resulted in the successful application of the concepts of filamentary structure and conductor twist to Nb3Sn ribbon. The Nb3Sn is formed in parallel, helical paths, which are continuous around the ribbon. Short lengths (12-18cm) of 1.27 cm wide superconductive ribbon were produced. The filamentary and twist characteristics are incorporated in the ribbon by means of an inert mask formed on the ribbon surface early in the fabrication process. Diffusion reaction of the niobium and tin is prevented at the filament boundaries. Described are the conductor methods of fabrication, and test results obtained. The technology required to adapt the processes for the production of long lengths of ribbon is available.

Coles, W. D.↗
DOE OSTI2024

Unified understanding of the impact of semiflexibility, concentration, and molecular weight on macromolecular-scale ring diffusion

Conformationally fluctuating, globally compact macromolecules such as polymeric rings, single-chain nanoparticles, microgels, and many-arm stars display complex dynamic behaviors due to their rich topological structure and intermolecular organization. Synthetic rings are hybrid objects with conformations that display both ideal random walk and compact globular features, which can serve as models of genomic DNA. To date, emphasis has been placed on the effect of ring molecular weight on their unusual behaviors. Here, we combine simulations and a microscopic force-level theory to build a unified understanding for how key aspects of ring dynamics depend on different tunable molecular properties including backbone rigidity, monomer concentration, degree of traditional entanglement, and molecular weight. Our large-scale molecular dynamics simulations of ring melts with very different backbone stiffnesses reveal unanticipated behaviors which agree well with our generalized theory. This includes a universal master curve for center-of-mass diffusion constants as a function of molecular weight scaled by a chemistry and thermodynamic state-dependent critical molecular weight that generalizes the concept of an entanglement cross-over for linear chains. The key physics is how backbone rigidity and monomer concentration induced changes of the entanglement length, interring packing, degree of interpenetration, and liquid compressibility slow down space-time dynamic-force correlations on macromolecular scales. A power law decay of the center-of-mass diffusion constant with inverse molecular weight squared is the first consequence, followed by an ultraslow activated hopping transport regime. Our results set the stage to address slow dynamics and kinetic arrest in different families of compact synthetic and biological polymeric systems.

Science & Technology - Other Topics↗
DOE OSTI2025

Thermally Stable Ruthenium Contact for Robust p‑Type Tellurium Transistors

Tellurium (Te) is attractive for p-channel transistors due to its high hole mobility. Despite having a low thermal budget suitable for back-end-of-line (BEOL) monolithic integration, the practical realization of Te transistors is hindered by its thermal stability. In this work, we investigate thermal stability for Te thin films grown via scalable thermal evaporation. Our findings identify ruthenium as a more thermally stable contact for p-type Te transistors, capable of withstanding temperatures up to 250 °C. Ruthenium exhibits significantly lower diffusivity in Te compared to other contact metals commonly used such as nickel and palladium. Using the transfer-length method, we measured a contact resistance of 1.25 kΩ·μm at the ruthenium-tellurium interface. Additionally, the incorporation of high-κ ZrO2 encapsulation not only suppresses the sublimation of the Te channel at elevated temperatures but also serves as the gate dielectric in top-gate devices operating at 1 V, achieving an on/off current ratio of 105.

Rahman, I K M Reaz↗
DOE OSTI2017

Charge segregation in weakly ionized microgels

Here we investigate microgels synthesized from N-isopropylacrylamide (NIPAM) copolymerized with a large mol% of acrylic acid, finding that when the acid groups are partially ionized at high temperatures, competition between ion-induced swelling and hydrophobic deswelling of poly(NIPAM) chains results in microphase separation. In cross-linked microgels, this manifests as a dramatic decrease in the ratio between the radius of gyration and the hydrodynamic radius to ~0.2, indicating that almost all the mass of the microgel is concentrated near the particle center. We also observe a concurrent decrease of the polymer network length scale via small-angle neutron scattering, confirming the presence of a dense, deswollen core surrounded by a diffuse, charged periphery. We compare these results to those obtained for a system of charged ultralow-cross-linked microgels; the form factor shows a distinct peak at high q when the temperature exceeds a threshold value. Lastly, we successfully fit the form factor to theory developed to describe scattering from weakly charged gels in poor solvents, and we tie this behavior to charge segregation in the case of the cross-linked microgels.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Mass Transport in Membrane Systems: Flow Regime Identification by Fourier Analysis

The numerical calculation of local mass distributions in membrane systems by computational fluid dynamics (CFD) offers indispensable benefits. However, the concept to calculate such distributions in response to separate variations of operation conditions (OCs) makes it difficult to address overall, flow-physics-related questions, which require the consideration of the collective interaction of OCs. It is shown that such understanding-related relationships can be obtained by the analytical solution of the advection–diffusion equation considered. A Fourier series model (FSM) is presented, which provides exact solutions of an advection–diffusion equation for a wide range of OCs. On this basis, a new zeroth-order model is developed, which is very simple and as accurate as the complete FSM for all conditions of practical relevance. Advection-dominated blocked and diffusion-dominated unblocked flow regimes are identified (depending on a Péclet number which compares the flow geometry with a length scale imposed by the flow), which implies relevant requirements for the use of lab results for pilot- and full-scale applications. Analyses reveal the equivalence of variations of OCs, which offers a variety of options to accomplish desired flow regime changes.

Heinz, Stefan (ORCID:0000000248712416)↗
NASA NTRS1973

Hydrogen and hydrocarbon diffusion flames in a weightless environment

An experimental investigation was performed on laminar hydrogen-, ethylene-, and propylene-air diffusion burning in a weightless environment. The flames burned on nozzles with radii ranging from 0.051 to 0.186 cm with fuel Reynolds numbers at the nozzle exit from 9 to 410. Steady-state diffusion flames existed in a weightless environment for all the fuels tested. A correlation was obtained for their axial length as a function of Schmidt number, Reynolds numbers, and stoichiometric mole fraction. The maximum flame radii were correlated with the ratio of nozzle radius to average fuel velocity. The flames of ethylene and propylene on nozzles with radii 0.113 or larger appeared to be constantly changing color and/or length throughout the test. No extinguishment was observed for any of the gases tested within the 2.2 seconds of weightlessness.

Haggard, J. B., Jr.↗
NASA NTRS1978

The dynamical halo and the variation of cosmic-ray path length with energy

It is shown that the dynamical halo model offers a natural explanation for the form of the variation of the cosmic-ray path length with energy. The variation above approximately 1 GeV/nucleon can be understood as due to the variation of the diffusion coefficient, and hence the resident time, with energy. The flattening of the curve below 1 GeV/nucleon is seen to mark a transition to a convection dominated regime where coefficient is no longer the determining parameter. A fit to the observations yields a halo outflow velocity of 8 km sec/1. An attempt is made to determine the overall scale of the halo and the diffusion coefficient using recent Be-10 flux measurements but the data do not agree well enough to pin down these variables to within less than four or five orders of magnitude.

Jones, F. C.↗
NASA NTRS1985

Anderson localization and the theory of dirty superconductors

A study is made of the effect of Anderson localization in dirty superconductors. The scale dependence of the diffusion in the vicinity of the mobility edge results in a strong renormalization of the zero-temperature coherence length. This implies the breakdown of the Ginzburg criterion close to the metal-insulator transition and thus the importance of fluctuations in this regime. The upper critical field is calculated, and possible experiments are also discussed.

Kapitulnik, A.↗
NASA NTRS1990

Fractal dimension of bioconvection patterns

Shallow cultures of the motile algal strain, Euglena gracilis, were concentrated to 2 x 10 to the 6th organisms per ml and placed in constant temperature water baths at 24 and 38 C. Bioconvective patterns formed an open two-dimensional structure with random branches, similar to clusters encountered in the diffusion-limited aggregation (DLA) model. When averaged over several example cultures, the pattern was found to have no natural length scale, self-similar branching, and a fractal dimension (d about 1.7). These agree well with the two-dimensional DLA.

Noever, David A.↗
NASA NTRS1993

Vortex generation and mixing in three-dimensional supersonic combustors

The generation and evolution of the flow vorticity established by instream injector ramps in a high Mach number/high enthalpy scramjet combustor flow-field are described in detail for a number of computational cases. Classical fluid dynamic circulation is presented for these cases in order to clarify the spatial distribution and convection of the vorticity. The ability of the simulations to accurately represent Stokes Law of circulation is discussed and shown. In addition, the conservation of swirl (effectively the moment-of-momentum theorem) is presented for these flows. The impact of both turbulent diffusion and the vortex/ramp non-uniformity on the downstream mixing rate is clearly illustrated. A correlation over the length of the combustor between fuel-air mixing and a parameter called the vortex stirring length is demonstrated. Finally, computational results for a representative ramp injector are compared with experimental data. Influence of the stream vorticity on the effective turbulent Prandtl number used in the simulation is discussed.

Riggins, D. W.↗
NASA NTRS1994

Modification of the MML turbulence model for adverse pressure gradient flows

Computational fluid dynamics is being used increasingly to predict flows for aerospace propulsion applications, yet there is still a need for an easy to use, computationally inexpensive turbulence model capable of accurately predicting a wide range of turbulent flows. The Baldwin-Lomax model is the most widely used algebraic model, even though it has known difficulties calculating flows with strong adverse pressure gradients and large regions of separation. The modified mixing length model (MML) was developed specifically to handle the separation which occurs on airfoils and has given significantly better results than the Baldwin-Lomax model. The success of these calculations warrants further evaluation and development of MML. The objective of this work was to evaluate the performance of MML for zero and adverse pressure gradient flows, and modify it as needed. The Proteus Navier-Stokes code was used for this study and all results were compared with experimental data and with calculations made using the Baldwin-Lomax algebraic model, which is currently available in Proteus. The MML model was first evaluated for zero pressure gradient flow over a flat plate, then modified to produce the proper boundary layer growth. Additional modifications, based on experimental data for three adverse pressure gradient flows, were also implemented. The adapted model, called MMLPG (modified mixing length model for pressure gradient flows), was then evaluated for a typical propulsion flow problem, flow through a transonic diffuser. Three cases were examined: flow with no shock, a weak shock and a strong shock. The results of these calculations indicate that the objectives of this study have been met. Overall, MMLPG is capable of accurately predicting the adverse pressure gradient flows examined in this study, giving generally better agreement with experimental data than the Baldwin-Lomax model.

Conley, Julianne M.↗
NASA NTRS1990

Nonlinear phase-space diffusion approach to turbulent organized structures

The study deals with the approximation of the effect of all velocity-increment moments on the spatial evolution of the pdf for maximally correlated structures by the effect of the second moment alone by assuming independence of separated length scales. The dependence of the two-point velocity statistics on length-scale or separation is found to be governed by the gradients of the stress, rather than of the velocity. This may provide a new approach for predicting the domain patterns observed in turbulent flows and a new means of characterizing or classifying different structures, namely, by their nonlinear diffusion coefficient.

Shen, Hubert H.↗
DOE OSTI2019

Space Charge Effects on Ion Mobility Spectrometry

We study the space charge limited maximal current density j″ of mobility-selected ions that can be transmitted in ion mobility spectrometry (IMS). Theory and experiments focus on differential mobility analyzers (DMAs), but are readily generalizable to other IMS devices. Repulsion between the ions in the cloud leads to beam spreading, with significant broadening once the ion number density n becomes comparable to the space charge saturation limit n{sub sat} = ε{sub o}E{sub o}/(eΔ). Δ is the distance traversed by the ions in the direction of an externally imposed electric field E{sub o}, and e is the charge on each ion. For ions of electrical mobility Z, j″ is then limited below j″{sub sat} = ZE{sub o}en{sub sat} = Zε{sub o}E{sub o}{sup 2}/Δ. A theory including diffusion and space charge effects is developed that reduces to Burgers’ exactly solvable equation. The theory is tested in experiments with room temperature electrosprays (ES) of 100 mM [ethyl{sub 3}N{sup +}-formate{sup −}] in methanol. This spray produces primarily a single ionic species at very high initial concentration n, which may be tuned above or below n{sub sat} by varying the distance from the ES emitter to the inlet slit of the DMA. Mobility-selected ion densities n > 3.10{sup 8} ions/cm{sup 3} are achieved, with n~n{sub sat}, and with drastically broadened mobility peak shapes having the approximate top hat-predicted shapes. However, the largest n values approaching n{sub sat} are not quantitatively measurable because the densest sprays do not fill the outlet slit length. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

On the use of LES-based turbulent thermal-stress models for rod bundle simulations

An alternative methodology is proposed here to overcome the excessive cost of large eddy simulations (LES) of full-length heated rod bundle calculations, while improving the inaccurate results typically obtained with Reynolds-averaged Navier-Stokes equations (RANS). While the cost of the full-length LES is generally too high, LES of a small section of a single rod is usually affordable. The idea presented here consists of using the information granted by the small LES calculation to determine the appropriate turbulence viscosity or turbulent thermal diffusivity that can be used to solve only for the temperature field in a pseudo-RANS approach. The study has been performed with single-rod simulations with a P/D of 1.12 and 1.24, considering rod lengths that are representative of reactor applications, for the cases of uniform heat flux and a more realistic cosine-like axial heat distribution. Here, the spectral element code Nek5000 has been used for all LES, RANS, and pseudo-RANS simulations. The recently proposed Nek5000 steady-state solver has been used for solving the temperature field in the pseudo-RANS approach and has proved significantly faster than transient schemes. Prediction of thermal quantities is compared with classical linear and nonlinear RANS models. LES for the full-length rods has also been performed and is used as a reference. Results of the proposed method show significant improvements with respect to those obtained with RANS.

42 ENGINEERING↗
DOE OSTI2017

Composite Boson Description of a Low-Density Gas of Excitons

Ground-state properties of a fermionic Coulomb gas are calculated using the fixed-node diffusion Monte Carlo method. The validity of the composite boson description is tested for different densities. We extract the exciton–exciton s-wave scattering length by solving the four-body problem in a harmonic trap and mapping the energy to that of two trapped bosons. The equation of state is consistent with the Bogoliubov theory for composite bosons interacting with the obtained s-wave scattering length. The perturbative expansion at low density has contributions physically coming from (a) exciton binding energy, (b) mean-field Gross–Pitaevskii interaction between excitons, and (c) quantum depletion of the excitonic condensate (Lee–Huang–Yang terms for composite bosons). In addition, for low densities we find a good agreement with the Bogoliubov bosonic theory for the condensate fraction of excitons. The equation of state in the opposite limit of large density is found to be well described by the perturbative theory including (a) mixture of two ideal Fermi gases and (b) exchange energy. We find that for low densities both energetic and coherent properties are correctly described by the picture of composite bosons (excitons).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗