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At least 1,045 records · Page 58

Monitoring and modulating ion traffic in hybrid lipid/polymer vesicles

Controlling the traffic of molecules and ions across membranes is a critical feature in a number of biologically relevant processes and highly desirable for the development of technologies based on membrane materials. In this study, ion transport behavior of hybrid lipid/polymer membranes was studied in the absence and presence of ion transfer agents. A pH-sensitive fluorophore was used to investigate ion (H + /OH - ) permeability across hybrid lipid/polymer membranes as a function of the fraction of amphiphilic block copolymer. It was observed that vesicles with intermediate lipid/polymer ratios tend to be surprisingly more permeable to ion transport than the pure lipid or pure polymer vesicles. Hybrid vesicle permeability could be further modulated with valinomycin, nigericin, or gramicidin A, which significantly expedite the dissipation of externally-imposed pH gradients by facilitating the transport of the rate-limiting co-ions (e.g. K + ) ions across the membrane. For gramicidin A, ion permeability decreased with increasing polymer mole fraction, and the method of introduction of gramicidin A into the membrane played an important role. Finally, strategies to incorporate biofunctional molecules and facilitate their activity in synthetic systems are highly desirable for developing artificial organelles or other synthetic compartmentalized structures requiring control over molecular traffic across biomimetic membranes.

59 BASIC BIOLOGICAL SCIENCES↗

Prediction of the Lorentz Force Detuning and pressure sensitivity for a Pillbox cavity

The Lorentz Force Detuning (LFD) and the pressure sensitivity are two critical concerns during the design of a Superconducting Radio Frequency (SRF) cavity resonator. The mechanical deformation of the bare Niobium cavity walls, due to the electromagnetic fields and fluctuation of the external pressure in the Helium bath, can dynamically and statically detune the frequency of the cavity and can cause beam phase errors. The frequency shift can be compensated by additional RF power, that is required to maintain the accelerating gradient, or by sophisticated tuning mechanisms and control-compensation algorithms. Passive stiffening is one of the simplest and most effective tools that can be used during the early design phase, capable of satisfying the Radio Frequency (RF) requisites. This approach requires several multiphysics simulations as well as a deep mechanical and RF knowledge of the phenomena involved. In this paper, is presented a new numerical model for a pillbox cavity that can predict the frequency shifts caused by the LFD and external pressure. This method allows to greatly reduce the computational effort, which is necessary to meet the RF requirements and to keep track of the frequency shifts without using the time consuming multiphysics simulations.

43 PARTICLE ACCELERATORS↗

Alignment of the magnetic field in star-forming regions and why it might be difficult to observe

ABSTRACT Magnetic fields are an important component of the interstellar medium (ISM) and exhibit strongly varying field strengths and a non-trivial correlation with the gas density. Its dynamical impact varies between individual regions of the ISM and correlates with the orientation of the field with respect to the gas structures. Using high-resolution magneto-hydrodynamical simulations of the ISM, we explore the connection between the orientation of the field and the dynamical state of the gas. We find that the onset of gravitational instability in molecular gas above a density of $\rho \sim 10^{-21}\, \mathrm{g\, cm}^{-3}$$(n\sim 400\, \mathrm{cm}^{-3})$ coincides with an alignment of the magnetic field lines and the gas flow. At this transition, the gradient of the density changes from mainly perpendicular to preferentially parallel to the field lines. A connection between the three-dimensional alignment and projected two-dimensional observables is non-trivial, because of a large dispersion of the magnetic field orientation along the line of sight. The turbulent correlation lengths can be small compared to the typical integration lengths. As a consequence, the small-scale signal of the orientation can sensitively depend on the line of sight or the dynamical state of the cloud can fluctuate stochastically or be completely averaged out. With higher spatial resolution more small-scale structures are resolved, which aggravates the link between magneto-hydrodynamical quantities and projected observables.

Girichidis, Philipp (ORCID:0000000293009914)↗

Space-Based Ornithology: On the Wings of Migration and Biophysics

Understanding bird migration and avian biodiversity is one of the most compelling and challenging problems of modern biology with major implications for human health and conservation biology. Migration and conservation efforts cross national boundaries and are subject to numerous international agreements and treaties. Public interest is high with concerns about avian flu, Katrina and its impacts, and the recent sightings of the ivory-billed woodpecker. Space based technology gives us new opportunities to shed light on the distribution and movement of organisms on the planet and their sensitivity to human disturbances and environmental changes. Together with the USGS and other agencies, we are creating ecological forecasting tools for science and application users to address the consequences of loss of wetlands, flooding, drought or other natural disasters such as hurricanes on avian biodiversity and bird migration. In our work, we use individual organism biophysical models of energy and water balance and drive these models with satellite measurements of spatio-temporal gradients in climate and habitat. Dynamic state variable modeling provides an additional tool for studying bird migration across multiple scales and can be linked to our mechanistic models describing the time and energy budget states of migrating birds. Such models yield an understanding of how a migratory flyway and its component habitats function as a whole and link stop-over ecology with biological conservation and management. We also build upon the canopy done by the Environmental Laboratory over the past few years.

Smith, James A.↗

Long-Term Measurements Show Little Evidence for Large Increases in Total U.S. Methane Emissions Over the Past Decade

Recent studies show conflicting estimates of trends in methane (CH 4 ) emissions from oil and natural gas (ONG) operations in the United States. We analyze atmospheric CH 4 measurements from 20 North American sites in the National Oceanic and Atmospheric Administration Global Greenhouse Gas Reference Network and determined trends for 2006–2015. Using CH 4 vertical gradients as an indicator of regional surface emissions, we find no significant increase in emissions at most sites and modest increases at three sites heavily influenced by ONG activities. Our estimated increases in North American ONG CH 4 emissions (on average approximately 3.4 ± 1.4 %/year for 2006–2015, ±σ) are much smaller than estimates from some previous studies and below our detection threshold for total emissions increases at the east coast sites that are sensitive to U.S. outflows. We also find an increasing trend in ethane/methane emission ratios, which has resulted in major overestimation of oil and gas emissions trends in some previous studies.

54 ENVIRONMENTAL SCIENCES↗

Theoretical and experimental studies of baroclinic processes

The geophysical fluid flow simulation code, GEOSIM, is being used to study the phenomenon of vacillation in the baroclinic annulus. Having verified that the code predicts vacillation for the same points as the experiments, the work is aiming toward explaining the mechanics of vacillation and pointing out some of the sensitivities of the results to the numerical method. Researchers are finding that there is a structural change associated with amplitude vacillation, where the structural changes are in the vertical. The results disagree with the premise of Lindzen et al, that the vacillation is due to constructive and destructive interference of neutral modes with different phase speeds. The researchers are continuing to study the Spacelab 3 Geophysical Fluid Flow Cell (GFFC) results with horizontal temperature gradients and heating from below. GEOSIM has been used to compute a wide range of cases, and these are being compared with the observations. The computations and observations compare well, and the model is being used to extend the results beyond cases studied in the experiments and to study the mechanics and predictability of the flows. The study of fully nonlinear baroclinic instability using the GFFC apparatus is proceeding with the numerical code. While the first instability that occurs is of planetary scale, secondary instabilities consisting of small-scale, penetrative convection occurs where cold fluid flows over a warm surface. The simultaneous modeling of the planetary scale and the convective scale is possible because of the nonhydrostatic formulation of the model. Some of these results have been animated on the Stardent computer, which shows the explosive nature of the small-scale convection.

Miller, Tim↗

Topological structure of the magnetotail as a function of interplanetary magnetic field direction

Magnetic reconnection between the interplanetary magnetic field (IMF) and the geomagnetic field is thought to play a major role in the transfer of solar wind momentum and energy to the magnetosphere. As the angle between the IMF and the geomagnetic field is changed at the bow of the magnetosphere, the topological record of the location of the reconnection region should be recorded in the magnetosheath and on the magnetopause along the flanks of the tail, because the super fast flow freezes strong magnetic gradients formed in the bow reconnection regions into the plasma downstream. In this report, we present results from a three-dimensional, magnetohydrodynamic (MHD), global numerical simulation code for the location of the separatrix between unconnected IMF magnetosheath field lines and reconnected field lines which penetrate the magnetopause and connect to the polar ionosphere. The angle between the IMF direction and the line where the separatrix crosses the magnetopause is shown to be a sensitive function of the IMF clock angle. We also explain how this behavior can be used to derive an approximate relation for the dependence of the cross-polar voltage on the IMF clock angle. We conclude with a note of caution concerning the importance of physical boundary conditions in magnetoplasma simulations.

Fedder, J. A.↗

Multi-channel, multi-template event reconstruction for SuperCDMS data using machine learning

SuperCDMS SNOLAB uses kilogram-scale germanium and silicon detectors to search for dark matter. Each detector has Transition Edge Sensors (TESs) patterned on the top and bottom faces of a large crystal substrate, with the TESs electrically grouped into six phonon readout channels per face. Noise correlations are expected among a detector's readout channels, in part because the channels and their readout electronics are located in close proximity to one another. Moreover, owing to the large size of the detectors, energy deposits can produce vastly different phonon propagation patterns depending on their location in the substrate, resulting in a strong position dependence in the readout-channel pulse shapes. Both of these effects can degrade the energy resolution and consequently diminish the dark matter search sensitivity of the experiment if not accounted for properly. We present a new algorithm for pulse reconstruction, mathematically formulated to take into account correlated noise and pulse shape variations. This new algorithm fits N readout channels with a superposition of M pulse templates simultaneously - hence termed the N$\times$M filter. We describe a method to derive the pulse templates using principal component analysis (PCA) and to extract energy and position information using a gradient boosted decision tree (GBDT). We show that these new N$\times$M and GBDT analysis tools can reduce the impact from correlated noise sources while improving the reconstructed energy resolution for simulated mono-energetic events by more than a factor of three and for the 71Ge K-shell electron-capture peak recoils measured in a previous version of SuperCDMS called CDMSlite to $<$ 50 eV from the previously published value of $\sim$100 eV. These results lay the groundwork for position reconstruction in SuperCDMS with the N$\times$M outputs.

Albakry, M. F. [British Columbia U.; TRIUMF]↗

Sensitive ion detection device and method for analysis of compounds as vapors in gases

An ion mobility spectrometer (IMS) for the detection of trace gaseous molecular compounds dissolved or suspended in a carrier gas, particularly in ambient air, without preconcentration or the trapping of analyte particles. The IMS of the invention comprises an ionization volume of greater than 5 cm.sup.3 and preferably greater than 100 cm.sup.3. The larger size ionizers of this invention enable analysis of trace (<1 ppb) of sample compounds in the gas phase. To facilitate efficient ion motion through the large volume ionization and reaction regions of the IMS, an electric field gradient can be provided in the ionization region or in both the ionization and reaction regions. The systems can be implemented with radioactive ionization sources, corona discharge ion sources or ions can be formed by photoionization. In specific embodiments, particularly when the sample gas is ambient air, the sample gas is heater prior to entry into the instrument, the instrument is run at temperatures above ambient, and the instrument can be heated by contact with heated sample gas exiting the instrument.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

$$\Lambda $$ polarization in very high energy heavy ion collisions as a probe of the quark–gluon plasma formation and properties

Abstract We have studied the spin polarization of $$\Lambda $$ Λ hyperons in heavy ion collisions at center-of-mass energies $$\sqrt{s_\textrm{NN}}= 200$$ s NN = 200 GeV and $$\sqrt{s_\textrm{NN}}= 5.02$$ s NN = 5.02 TeV carried out at RHIC and LHC colliders. We have calculated the mean spin vector at local thermodynamic equilibrium, including all known first-order terms in the gradients of the thermo-hydrodynamic fields, assuming that the hadronization hypersurface has a uniform temperature. We have also included the feed-down contributions to the polarization of $$\Lambda $$ Λ stemming from the decays of polarized $$\Sigma ^*$$ Σ ∗ and $$\Sigma ^0$$ Σ 0 hyperons. The obtained results are in good agreement with the data. In general, the component of the spin vector along the global angular momentum, orthogonal to the reaction plane, shows strong sensitivity to the initial longitudinal flow velocity. Furthermore, the longitudinal component of the spin vector turns out to be very sensitive to the bulk viscosity of the plasma at the highest LHC energy. Therefore, the azimuthal dependence of spin polarization can effectively constrain the initial hydrodynamic conditions and the transport coefficients of the quark gluon plasma.

Physics↗

A study of the influence of satellite data on GLA analyses over the Atlantic Ocean during a period of blocking anticyclone development

This paper presents a statistical diagnosis of the differences between two Goddard Laboratory for Atmospheres analysis representations of temperature and wind speed, one containing satellite data influences (SAT analyses) and one without (NOSAT analyses), for a case of oceanic blocking anticyclone development. Results, obtained using area means and standard deviations of the two fields and correlation coefficients and root-mean-square differences between the two fields, indicate that the inclusion of satellite data can have significant impact on ocean-domain analyses. This is especially evident if one examines higher-order fields that represent gradients in the basic variable fields or contain covariances between two different variables (e.g., advections). More specifically, the inclusion of satellite data resulted in a cold (warm) temperature bias at low (high) levels and weaker temperature gradients, stronger winds, weaker vertical wind shears, and a warm-air advection bias at most levels. The SAT analyses also exhibited larger standard deviations than the NOSAT for wind speed, relative vorticity, vorticity advection, temperature advection, and 500-mb height tendencies, suggesting that for this case the spatial variability of the circulation features were enhanced by the inclusion of satellite data. Even so, since height tendencies forced by vorticity and temperature advection were less sensitive to the addition of satellite data than were the advection quantities themselves, the dynamics of the blocking system was apparently less influenced by the presence of satellite data than was the structure of the system.

Lamberty, Gregory L.↗

Vegetation structural complexity and biodiversity in the Great Smoky Mountains

Vegetation structural complexity and biodiversity tend to be positively correlated, but understanding of this relationship is limited in part by structural metrics tending to quantify only horizontal or vertical variation, and that do not reflect internal structure. We developed new metrics for quantifying internal vegetation structural complexity using terrestrial LiDAR scanning and applied them to 12 NEON forest plots across an elevational gradient in Great Smoky Mountains National Park, USA. We asked (1) How do our newly developed structure metrics compare to traditional metrics? (2) How does forest structure vary with elevation in a high-biodiversity, high topographic complexity region? (3) How do forest structural metrics vary in the strength of their relationships with vascular plant biodiversity? Our new measures of canopy density (Depth) and structural complexity (σDepth), and their canopy height-normalized counterparts, were sensitive to structural variations and effectively summarized horizontal and vertical dimensions of structural complexity. Forest structure varied widely across plots spanning the elevational range of GRSM, with taller, more structurally complex forests at lower elevation. Vascular plant biodiversity was negatively correlated with elevation and more strongly positively correlated with vegetation structure variables. The strong correlations we observed between canopy structural complexity and biodiversity suggest that structural complexity metrics could be used to assay plant biodiversity over large areas in concert with airborne and spaceborne platforms.

Jonathan A. Walter↗

Reduced chemistry model calibration using unsteady flames with repetitive extinction and ignition

In this paper, combustion in a narrow channel with an imposed temperature gradient is used to calibrate a reduced chemical mechanism. The focus is placed on unsteady flames with repetitive extinction and ignition (FREI) at high pressure. The reduced mechanism follows a hybrid approach, combining a small fuel-dependent submechanism with a detailed fuel-independent submechanism for the core species chemistry. The fuel-dependent submechanism consists of three species and nine reactions describing both the low and high-temperature fuel decomposition pathways. The sensitivity of the extinction and ignition locations to the fuel-dependent reactions is assessed and multiple reactions are found to affect the FREI behavior. The sensitive reactions are calibrated following a Bayesian approach. The calibrated reduced model is compared to a detailed model and good agreement in ignition delay times and laminar flame speeds is observed. Finally, this illustrates the potential of a micro flow reactor with a controlled temperature profile to test fuels, calibrate chemical models, and infer kinetic data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Biogeochemical Cycling of Redox-Sensitive Elements in Permafrost-Affected Ecosystems

Northern high latitudes are experiencing rapid changes in climate that drive permafrost thaw and shifts in hydrology and soil saturation. These factors regulate redox conditions across permafrost-affected landscapes, potentially altering carbon storage in soils and exacerbating climate change through accelerated decomposition of soil organic matter. Redox conditions impact soil carbon storage directly by influencing rates and pathways of organic matter decomposition, and indirectly by moderating the bioavailability of organic molecules and nutrients. Indeed, the ability of increased plant growth to offset C losses in permafrost regions will be regulated by nutrient availability (e.g., N, P) that varies across redox gradients. The purpose of this review is to examine how redox conditions shape biogeochemical cycling of ecologically important elements (P, N, S, Fe) in permafrost-affected ecosystems. Although carbon cycling in these regions continues to be widely studied, relatively little information is available on the elements that regulate C cycling. We discuss the complex feedbacks between climate change, hydrology, and landscape change that control redox conditions, then examine how these factors regulate biogeochemical cycles. We identify key gaps in our understanding of how changing climate may alter biogeochemical cycles and carbon storage in northern high-latitude ecosystems.

Herndon, Elizabeth↗

Feedback Power Cost Optimization in Power Distribution Networks with Prosumers

Here, we propose a feedback control approach for solving optimal power flow (OPF) problems in power distribution networks (DNs) based on a projected gradient scheme, where the cost is given by the sum of functions of local power injections. This approach does not require detailed knowledge of the grid model and enables real-time tracking of the optimal generation configuration. Moreover, the communication burden is minimal: only a broadcast from a central entity, called the Network Supervisor (NS), to the agents in the network is needed. Hence, agents do not have to share local information that can be sensitive, e.g., their power injections or the value of the local costs. Our approach is then used to solve a particular OPF problem targeting DNs with high penetration of distributed energy resources (DERs) in which the energy cost is given by the remuneration that the DERs owners receive for the service they provide.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Interactions between the Space Station and the environment: A preliminary assessment of EMI

A review of the interactions between proposed Space Station systems/payloads and the environment that contribute to electromagnetic interference was performed. Seven prime sources of interference have been identified. These are: The Space Station power system; active experiments such as beam injection; ASTROMAG; ram and wake density gradients; pick up ions produced by vented or offgassed clouds; waves produced by current loops that include the plasma and structure; arcing from high voltage solar arrays (or possible ESD in polar orbit). This review indicates that: minimizing leakage current from the 20 kHz power system to the structure; keeping the surfaces of the Space Station structure, arrays, and radiators nonconducting; minimizing venting of payloads or systems to non-operational periods; careful placement of payloads sensitive to magnetic field perturbations or wake noise; and designing an operational timeline compatible with experiment requirement are the most effective means of minimizing the effects of this interference. High degrees of uncertainty exist in the estimates of magnitudes of gas emission induced EMI, radiation of 20 kHz and harmonics, ASTROMAG induced interference, and arc threshold/frequency of the solar array. These processes demand further attention so that mitigation efforts are properly calibrated.

Murphy, G. B.↗

Toward accurate measurement of electromagnetic field by retrieving and refining the center position of non-uniform diffraction disks in Lorentz 4D-STEM

Recent advancement in scanning transmission electron microscopy (STEM) allows the use of 4D-STEM, a technique that captures an electron diffraction pattern at each scan point in STEM, to measure electrostatic and magnetic potential and field in materials. However, accurate measurement, separation of the magnetic and electric signals, and removal of artifacts remain challenging, especially in the presence of complex non-uniform diffraction contrast within the disks. In this work, based on dynamic simulations of 4D-STEM patterns built upon superstructures consisting of millions of atoms to account for different sample thickness and edge geometries, we show how the shape and intensity distribution of the central disk are affected by multiple scattering. We propose a robust refinement procedure through iteration of the spin-sensitive peak position of the disk-center in the circular Hough transform filtered images from experimental Lorentz 4D-STEM dataset after minimizing the possible artifacts, such as those due to the change of thickness, dynamic scattering, and scanning process. We verify that caution must be taken as in practice the rigid-disk-shift model used to reconstruct induction maps can easily break down due to disk-protrusion when there exists a nonconstant phase gradient or thickness within the width of the probe. Through quantitative analysis and comparing experiment with calculation the effect of the non-spin-related intensity distribution inside the disk as well as that causes the disk shift due to the intensity-protrusion can be removed, and high-quality magnetic field mapping is possible.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗