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Interaction between clay minerals and organics in asteroid Ryugu

The Hayabusa 2 spacecraft brought back to Earth grains of the carbonaceous asteroid Ryugu. Such grains represent the pristine state of CI chondritic materials and have been preserved from exposure to Earth’s atmosphere. Here, we show evidence of the presence of organics trapped within the interlayer space of smectite layers in Ryugu grains. No such organics are found in the Orgueil CI meteorite. We put forward that the organics within the interlayer space of smectite in Orgueil CI meteorite were lost during their oxidation on Earth. Also, we propose that the presence of organics within the interlayers space of smectite might be responsible for the possible NH infrared signature observed in Ryugu particles and potentially to a few large C-type asteroids including Ceres

58 GEOSCIENCES↗

The Spatial Distribution of Organic Matter and Mineralogical Relationships in Carbonaceous Chondrites

Organic matter present within primitive carbonaceous meteorites represents the complex conglomeration of species formed in a variety of physically and temporally distinct environments including circumstellar space, the interstellar medium, the Solar Nebula & Jovian sub-nebulae and asteroids. In each case, multiple chemical pathways would have been available for the synthesis of organic molecules. Consequently these meteorites constitute a unique record of organic chemical evolution in the Universe and one of the biggest challenges in organic cosmochemistry has been in deciphering this record. While bulk chemical analysis has provided a detailed description of the range and diversity of organic species present in carbonaceous chondrites, there is virtually no hard experimental data as to how these species are spatially distributed and their relationship to the host mineral matrix, (with one exception). The distribution of organic phases is nevertheless critical to understanding parent body processes. The CM and CI chondrites all display evidence of low temperature (< 350K) interaction with aqueous fluids, which based on O isotope data, flowed along thermal gradients within the respective parent bodies. This pervasive aqueous alteration may have led to aqueous geochromatographic separation of organics and synthesis of new organics coupled to aqueous mineral alteration. To address such issues we have applied the technique of microprobe two-step laser desorption / photoionization mass spectrometry (L2MS) to map in situ the spatial distribution of a broad range of organic species at the micron scale in the freshly exposed matrices of the Bells, Tagish Lake and Murchison (CM2) carbonaceous chondrites.

Clemett, S. J.↗

Isotopes of H, N, and O in H Chondrite Xenoliths

Brecciated H chrondites host a variety of xenoliths, including unshocked, phyllosilate-rich carbonaceous chondrites (CCs) [1-2]. The brecciated H chondrite Zag (H3-6) is one of two chondrites to host macroscopic (1 - 5mm), xenolithic crystals of halite (NaCl) with aqueous fluid inclusions and organics [3-4]. A ~1cm CC xenolith in Zag (Zag clast) also encloses halite in its matrix, linking the halite and the xenolith to the same parent object. The Zag clast has mineralogy similar to CI chondrites, but it has a unique bulk oxygen isotopic composition among all meteorites (Δ17O = 1.49 ± 0.04 ‰, 𝛿18O = 22.38 ± 0.17 ‰) and is therefore derived from a uniquely sampled parent object [5-6]. Organics have high bulk 𝛿D and 𝛿15N values with isotopic "hotspots" similar to organics in CR chondrites and Bells (C2-ung.) [6-7]. Bulk 𝛿15N is also similar to CRs and Bells [7]. We provide further isotopic characterization of the Zag clast to constrain the formation temperature and origin of its primary and secondary components.

Frank, D.↗

Bulk Elemental Composition of Aggregate Material From Asteroid Bennu

On September 24, 2023, NASA’s OSIRIS-REx mission returned pristine carbonaceous material from asteroid Bennu. One key aspect required to understand this returned material is to establish its bulk chemical composition. This is primarily due to each chondrite group having a distinct elemental composition, which is important both as a classification tool and for establishing the connections between the different chondrite groups. As the carbonaceous and non-carbonaceous chondrites are thought to have formed in the inner and outer protoplanetary disk, respectively, measuring the bulk elemental composition of Bennu material will help test the mission hypothesis that “Bennu's parent body formed beyond the snow line by accretion of material in the protoplanetary disk”. In addition, two further mission hypotheses — paraphrased as Bennu’s bulk elemental composition reflects that of its parent asteroid and is similar to the composition of the Sun and Bennu’s dominant lithologies are comparable in composition to the most aqueously altered carbonaceous chondrites — can be directly tested by bulk elemental analyses. Elemental analyses were undertaken on sample OREX-803015-0, a 20.66 mg aggregate sourced from inside the sample collector. All analyses were conducted using an iCAP Q ICP-MS. Overall, all 54 elements analyzed for the Bennu aggregate sample show similar abundances to those of the average CI chondrite, and thus the solar photosphere composition and some of the most aqueously altered carbonaceous chondrites. The elemental data also show that Bennu is indeed a carbonaceous asteroid that formed beyond the snow line by accretion of material in the protoplanetary disk. This Bennu aggregate sample appears similar in elemental composition to samples of asteroid Ryugu, yet without the small refractory element enrichments seen in Ryugu.

P Koefoed↗

The Aguas Zarcas Breccia - Similarities to Surface Features of Asteroids Ryugu and Bennu

At 21:07 local time on 23rd April 2019, a meteorite fall occurred in Aguas Zarcas, San Carlos County, Alajuela province, Costa Rica. The rapid recovery of this brecciated carbonaceous chondrite after its fall provides an opportunity to investigate a freshly-fallen, relatively uncontaminated and highly-brecciated meteorite for comparison to the samples returned from C-group asteroids by the Hayabusa2 and OSIRIS-REx spacecraft. The study includes several pre-rain fragments. Our X-ray Computed Tomography(XCT) results show many different lithologies. In this study we describe the petrography and mineralogy of five different lithologies of the Aguas Zarcas meteorite. We also present bulk oxygen isotope data of some lithologies and results concerning the organic matter. We describe all the fragments in detail and attempt a classification of each lithology in order to understand the origin and the history of formation of the Aguas Zarcas' parent body. Our results show some lithologies of Aguas Zarcas similar to those in CM chondrites, but others are unique. The different lithologies [1] represent different levels of hydration and heating as well, which are good analogues for the types of materials returned from asteroids Bennu and Ryugu. Spectroscopic observations of the Ryugu and Bennu asteroids compared to laboratory measurements of meteorites suggest that the asteroids show some similarities to heated CM, heated CI or, CI chondrites [2-5]. Both asteroids are regarded to consist of materials altered by aqueous alteration (e.g., [5]) and formed by re-accretion after impact destruction and brecciation (e.g., [6-7]). Considering the various different lithologies in Aguas Zarcas [2] and other CM chondrites [8-9] these types of carbonaceous chondrites may be regarded as good analogues for samples from the Ryugu and Bennu asteroids. The presence of unique and rare lithologies in the Aguas Zarcas, that are distinct from typical CM chondrite lithologies, indicates a complex mixing of various materials in a highly dynamic environment.

Imene Kerraouch↗

The Aguas Zarcas Breccia - Similarities to Surface Features of C-Complex Asteroids Ryugu and Bennu

Knowledge of the materials originally present in the proto-solar nebula is one of the most significant constraints for models concerning the formation of our solar system. The physicochemical properties of these original materials can be determined through two distinct and complementary approaches: astronomical observations of nascent stellar systems and the dense clouds from which they originated; and laboratory studies of available astromaterials such as meteorites, interplanetary dust particles, comets, as well as returned mission samples (e.g., from Hayabusa -1 -2;OSIRIS -Rex). Laboratory study of these extraterrestrial materials provides valuable information about the first solids portion of the early solar system and their evolution. Here, we present petrographic and mineralogical characteristics of the polymic beccias Aguas Zarcas based on the research results of [1].On April 23, 2019, at 21:07 local time, a meteorite fall occurred in Aguas Zarcas, San Carlos County, Alajuela province, Costa Rica. The rapid recovery of this brecciated carbonaceous chondrite after its fall provides an opportunity to study a freshly fallen, relatively uncontaminated, and highly brecciated meteorite to compare with samples returned by theHayabusa2 and OSIRIS-REx spacecraft from C-group asteroids. The study includes several pre-rain fragments [1].The X-ray Computed Tomography (XCT) results show many different lithologies. We describe the petrography and mineralogy of five different lithologies of the Aguas Zarcas meteorite. We also present data on bulk oxygen isotopes. We describe all fragments in detail and attempt to classify each lithology in order to understand the origin and formation history of the Aguas Zarcas parent body. Our results show that some lithologies of Aguas Zarcas are similar to those in CM chondrites, but others are unique. The different lithologies [1] also represent different degrees of hydration and heating, which are good analogues for the types of materials returned by the Bennu and Ryugu asteroids. Spectroscopic observations of the Ryugu and Bennu asteroids compared to laboratory measurements of meteorites suggest that the asteroids have some similarities to heated CM, heated CI, or CI chondrites[2-5]. Both asteroids are thought to be composed of materials altered by aqueous alteration (e.g., [5]) and formed by reaccretion after destruction by impacts and brecciation (e.g., [6-7]). Considering the different lithologies in Aguas Zarcas [2] and other CM chondrites [8-9], these types of carbonaceous chondrites can be considered good analogues for samples from the Ryugu and Bennu asteroids. The presence of unique and rare lithologies in the Aguas Zarcas, different from the typical CM chondrite lithologies, suggests complex mixing of different materials in a highly dynamic environment.

Imene Kerraouch↗

Chemical characterization of a unique chondrite - Allan Hills 85085

Allan Hills 85085 is a new and very important addition to the growing list of unique carbonaceous chondrites because of its unique chemical and mineralogical properties. This chemical study provides more precise data on the major, minor, and trace element characteristics of ALH85085. ALH85085 has compositional, petrological, and isotopic affinities to AL Rais and Renazzo, and to Bencubbin-Weatherford. The similarities to Al Rais and Renazzo suggest similar formation locations and thermal processing, possibly in the vicinity of CI chondrites. Petrologic, compositional and isotopic studies indicate that the components that control the abundance of the various refractory and volatile elements were not allowed to equilibrate with the nebula as conditions changed, explaining the inconsistencies in the classification of these meteorites using known taxonomic parameters.

Gosselin, David C.↗

Identification of solar nebula condensates in interplanetary dust particles and unequilibrated ordinary chondrites

Orthopyroxene and olivine grains, low in FeO, but containing MnO contents up to 5 wt percent were found in interplanetary dust particles (IDP) collected in the stratosphere. The majority of olivines and pyroxenes in meteorites contain less than 0.5 wt percent MnO. Orthopyroxenes and olivines high in Mn and low in FeO have only been reported from a single coarse grained chondrule rim in the Allende meteorite and from a Tieschitz matrix augite grain. The bulk MnO contents of the extraterrestrial dust particles with high MnO olivines and pyroxenes are close to CI chondrite abundances. High MnO, low FeO olivines and orthopyroxenes were also found in the matrix of Semarkona, an unequilibrated ordinary chondrite. This may indicate a related origin for minerals in extraterrestrial dust particles and in the matrix of unequilibrated ordinary chondrites.

Kloeck, W.↗

Rb-Sr studies of CI and CM chondrites

Rb-Sr whole rock analyses have been performed on 2 CI and 3 CM chondrites. Four of these stones (Ivuna, Orgueil, Cold Bokkeveld and Erakot) were previously studied in this laboratory and were shown to be discordant from a 4.6 Gyr isochron. The fifth, Murchison, was not previously studied. The new data support the discordance of the first four stones, and indicate that Murchison is also discordant. Studies of Sr isotope ratios in unspiked Orgueil show that the discordance is not due to inhomogeneities in the Sr-84/Sr-86 ratio caused by incomplete mixing of nucleosynthesis products. In order to gauge the effects of weathering, two leaching experiments were performed on fresh, interior samples of Murchison; one for a period of 1.5 hr and the other for 117 hr. The results indicate that the relative solubility of nonradiogenic Sr is approximately twice that of Rb and radiogenic Sr is more soluble than the nonradiogenic Sr.

Mittlefehldt, D. W.↗

SXRF determination of trace elements in chondrule rims in the unequilibrated CO3 chondrite, ALH A77307

The concentrations of Ni, Cu, Zn, Ga, Ge, and Se in five chondrule rims in the CO3 chondrite ALH A77307 (3.0) using the synchrotron x-ray fluorescence (SXRF) microprobe at Brookhaven National Laboratory were determined. The data show that the trace element chemistry of rims on different chondrules is remarkably similar, consistent with data obtained for the major elements by electron microprobe. These results support the idea that rims are not genetically related to individual chondrules, but all sampled the same reservoir of homogeneously mixed dust. Of the trace elements analyzed Zn and Ga show depletions relative to CI chondrite values, but in comparison with bulk CO chondrites all the elements are enriched by approximately 1.5 to 3.5 x CO. The high concentrations of the highly volatile elements Se and Ga and moderately volatile Zn (1.5 to 2 x CO) in rims show that matrix is the major reservoir of volatile elements in ALH A77307.

Brearley, Adrian J.↗

The Nature and Origin of Interplanetary Dust: High Temperature Components

The specific parent bodies of individual interplanetary dust particles (IDPs) are un-known, but the anhydrous chondritic-porous (CP) sub-set has been linked directly to cometary sources [1]. The CP IDPs escaped the thermal processing and water-rock interactions that have severely modified or destroyed the original mineralogy of primitive meteorites. Their origin in the outer regions of the solar system suggests they should retain primitive chemical and physical characteristics from the earliest stages of solar system formation (including abundant presolar materials). Indeed, CP IDPs are the most primitive extraterrestrial materials available for laboratory studies based on their unequilibrated mineralogy [2], high concentrations of carbon, nitrogen and volatile trace elements relative to CI chondrites [3, 4, 5], presolar hydrogen and nitrogen isotopic signatures [6, 7] and abundant presolar silicates [8].

Keller, L. P.↗

Evidence for Extended Aqueous Alteration in CR Carbonaceous Chondrites

We are currently studying the chemical interrelationships between the main rockforming components of carbonaceous chondrites (hereafter CC), e.g. silicate chondrules, refractory inclusions and metal grains, and the surrounding meteorite matrices. It is thought that the fine-grained materials that form CC matrices are representing samples of relatively unprocessed protoplanetary disk materials [1-3]. In fact, modern non-destructive analytical techniques have shown that CC matrices host a large diversity of stellar grains from many distinguishable stellar sources [4]. Aqueous alteration has played a role in homogeneizing the isotopic content that allows the identification of presolar grains [5]. On the other hand, detailed analytical techniques have found that the aqueously-altered CR, CM and CI chondrite groups contain matrices in which the organic matter has experienced significant processing concomitant to the formation of clays and other minerals. In this sense, clays have been found to be directly associated with complex organics [6, 7]. CR chondrites are particularly relevant in this context as this chondrite group contains abundant metal grains in the interstitial matrix, and inside glassy silicate chondrules. It is important because CR are known for exhibiting a large complexity of organic compounds [8-10], and only metallic Fe is considered essential in Fischer-Tropsch catalysis of organics [11-13]. Therefore, CR chondrites can be considered primitive materials capable to provide clues on the role played by aqueous alteration in the chemical evolution of their parent asteroids.

Trigo-Rodriquez, J. M.↗

Aqueous alteration of Cb-type asteroid Ryugu

The samples from the asteroid Ryugu, which returned to Earth in the winter of 2020 [1], were stored under pure Nitrogen conditions at the Extraterrestrial Materials Curation Center of ISAS. After basic description [2-3], they were distributed to six initial analysis teams in Japan in June 2021. The initial analysis "Stone" team, which was responsible for the analysis of coarse particles (>1 mm in size), consisted of about 150 scientists from Japan and abroad, and conducted a series of analyses We analyzed sixteen coarse Ryugu particles 1 ~ 8 mm in size: six from the 1st touch-down site and ten from the 2nd touch-down site. Individual coarse samples were cut by Xe-FIB or wire-saw to expose particular objects or textures to be exposed on the surface based on 3D structure and element distribution obtained by synchrotron X-ray CT analysis and XRF analysis, respectively. FE-SEM/EDS and FE-EPMA/WDS analysis were made on all polished sections. TEM observation of many FIB sections was made to see microstructures and to compare with carbonaceous chondrites. Many other analyses were carried out to characterize mineralogical and compositional properties and summary of the analysis procedures is described in [4]. X-ray CT analysis showed that all sixteen Ryugu particles are composed of fine-grained material, with no chondrules and CAIs larger than 100 μm in size. FE-EPMA observation showed that Ryugu samples are breccias, consisting of many small rock fragments of different compositions, lithologies, and histories. The most common lithology includes Mg-rich saponite and serpentine, dolomite, magnesite, hydroxyapatite, pyrrhotite, and magnetite as main constituents. The mineralogy of this major lithology supports the classification of Ryugu samples as CI chondrites, which experienced extensive aqueous alteration in Ryugu’s parent asteroid. Based on the obtained mineralogical properties, we performed chemical modeling of aqueous alteration of Ryugu’s parent asteroid [5]. Numerical simulations [6-8] to reproduce thermal history and impact-induced destruction of the Ryugu’s parent asteroid were also carried out using mineralogical and physical properties of the Ryugu samples. In the talk, I would like to explain the conditions of aqueous alteration occurred in the parent asteroid of Ryugu in order to show how the water in the asteroid changed the mineralogy and chemistry of the nebular dust.

T. Nakamura↗

Formation of Primitive Bodies in the Protoplanetary Nebula

We have developed a simple model of global transport of solids in the protoplanetary nebula, including radial drift of large particles and diffusion of small ones. The model has been applied to the formation and redistribution of the Ca-A1 rich refractory mineral inclusions (CAIs) found in primitive chondrites. These objects form at much higher temperatures, and appear to be 1-3 million years older than, the dominant (chondrule) components found in the same parent bodies. A widespread concern has been the retention of CAIs for this long against gas-drag-induced radial drift into the sun. We show that outward radial diffusion in a weakly turbulent nebula can overwhelm inward drift, and prevent significant numbers of CAI-size particles from being lost into the sun for tines on the order of several Myr. An element of this model is rapid inward radial drift of boulder-sized primitive (carbon-rich) silicate material, more like Halley-dust than CI chondrites in the early days of the nebula. Thls process can enrich the abundance of silicate and carbon material in the inner nebula, and may provide possible explanations for both chemical and isotopic properties of CAIs. The predicted enhancement of CO relative to water might be of relevance to recent IR astronomical observations of CO in the inner disks of several actively accreting T Tauri stars. This process has applications to the transport and redistribution of volatiles in general. Depending on the rubble particle size distribution, rapid radial drift of boulder-sized solids can bring more material inwards across a condensation front, to evaporate, than can subsequently be removed by nebula advection or diffusion, until a strong local enhancement is produced which allows diffusive loss to balance the drifting source. Application of this process to enhancement of the abundance of water near the "ice line" will be discussed. Supported by the Origins of Solar Systems program.

Cuzzi, Jeffrey N.↗

The Lithophile Element Budget of Earth's Core

Abstract The relative composition of Earth's core and mantle were set during core formation. By determining how elements partition between metal and silicate at high pressures and temperatures, measurements of the mantle composition and geophysical observations of the core can be used to understand the mechanisms by which Earth formed. Here we present the results of metal‐silicate partitioning experiments for a range of nominally lithophile elements (Al, Ca, K, Mg, O, Si, Th, and U) and S to 85 GPa and up to 5400 K. With our results and a compilation of literature data, we developed a parameterization for partitioning that accounts for compositional dependencies in both the metal and silicate phases. Using this parameterization in a range of planetary growth models, we find that, in general, lithophile element partitioning into the metallic phase is enhanced at high temperatures. The relative abundances of FeO, SiO 2 , and MgO in the mantle vary significantly between planetary growth models, and the mantle abundances of these elements can be used to provide important constraints on Earth's accretion. To match Earth's core mass and mantle composition, Earth's building blocks must have been enriched in Fe and depleted in Si compared with CI chondrites. Finally, too little Mg, Si, and O are partitioned into the core for precipitation of oxides to be a major source of energy for the geodynamo. In contrast, several ppb of U can be partitioned into the core at high temperatures, and this energy source must be accounted for in thermal evolution models.

Chidester, B. A.↗

Early fluid activity on Ryugu inferred by isotopic analyses of carbonates and magnetite

Samples from asteroid Ryugu returned by the Hayabusa2 mission contain evidence of extensive alteration by aqueous fluids and appear related to the CI chondrites. To understand the sources of the fluid and the timing of chemical reactions occurring during the alteration processes, we investigated the oxygen, carbon and 53 Mn– 53 Cr systematics of carbonate and magnetite in two Ryugu particles. Here we find that the fluid was initially between 0 and 20 °C and enriched in 13 C, 17 O and 18 O, and subsequently evolved towards lighter carbon and oxygen isotopic compositions as alteration proceeded. Carbonate ages show that this fluid–rock interaction took place within approximately the first 1.8 million years of Solar System history, requiring early accretion either in a planetesimal less than ~20 km in diameter or within a larger body that was disrupted and reassembled.

58 GEOSCIENCES↗

Mineralogical evidence for hydrothermal alteration of Bennu samples

Samples of asteroid (101955) Bennu delivered by the OSIRIS-REx mission offer the opportunity to study pristine planetary materials unchanged by exposure to the terrestrial environment. Here we use a combination of X-ray diffraction and various electron microscopy techniques to explore the detailed mineralogy of Bennu samples and determine the alteration history of the planetesimal protolith from which they originated. The samples consist largely of hydrated sheet-silicate minerals, namely nanoscale serpentine and saponite of varied grain size, which are decorated with micro- to nanoscale Fe-sulfides, magnetite and carbonates. We observe sheet silicates parallel and normal to sulfide surfaces and as inclusions in sulfides; sulfur-rich veins transecting the sheet-silicate matrix; zoned carbonates and phosphates and sulfide and magnetite grains exhibiting embayment. The mineralogical evidence indicates alteration of accreted minerals by a fluid that evolved with time, leading to etching, dissolution and reprecipitation. Sulfide compositions indicate alteration at ~25 °C, similar to conditions inferred for asteroid (162173) Ryugu and Ivuna-type (CI) chondrite meteorites. The fluid probably evolved from neutral to alkaline, culminating with the precipitation of highly soluble salts. We conclude that Bennu’s protolith comprised mainly nanometre to micrometre silicates, with fewer chondrules and calcium–aluminium-rich inclusions than those of most chondrite groups.

Zega, T J↗

Comprehensive geoneutrino analysis with Borexino

This paper presents a comprehensive geoneutrino measurement using the Borexino detector, located at Laboratori Nazionali del Gran Sasso (LNGS) in Italy. The analysis is the result of 3262.74 days of data between December 2007 and April 2019. The paper describes improved analysis techniques and optimized data selection, which includes enlarged fiducial volume and sophisticated cosmogenic veto. The reported exposure of ( 1.29 ± 0.05 ) × 10 32 protons × year represents an increase by a factor of two over a previous Borexino analysis reported in 2015. By observing 52.6 - 8.6 + 9.4 ( stat ) - 2.1 + 2.7 ( sys ) geoneutrinos (68% interval) from U 238 and Th 232 , a geoneutrino signal of 47.0 - 7.7 + 8.4 ( stat ) - 1.9 + 2.4 ( sys ) TNU with - 17.2 + 18.3 % total precision was obtained. This result assumes the same Th/U mass ratio as found in chondritic CI meteorites but compatible results were found when contributions from U 238 and Th 232 were both fit as free parameters. Antineutrino background from reactors is fit unconstrained and found compatible with the expectations. The null-hypothesis of observing a geoneutrino signal from the mantle is excluded at a 99.0% C.L. when exploiting detailed knowledge of the local crust near the experimental site. Measured mantle signal of 21.2 - 9.0 + 9.5 ( stat ) - 0.9 + 1.1 ( sys ) TNU corresponds to the production of a radiogenic heat of 24.6 - 10.4 + 11.1 TW (68% interval) from U 238 and Th 232 in the mantle. Assuming 18% contribution of K 40 in the mantle and 8.1 - 1.4 + 1.9 TW of total radiogenic heat of the lithosphere, the Borexino estimate of the total radiogenic heat of the Earth is 38.2 - 12.7 + 13.6 TW , which corresponds to the convective Urey ratio of 0.78 - 0.28 + 0.41 . These values are compatible with different geological predictions, however there is a ~ 2.4 σ tension with those Earth models which predict the lowest concentration of heat-producing elements in the mantle. In addition, by constraining the number of expected reactor antineutrino events, the existence of a hypothetical georeactor at the center of the Earth having power greater than 2.4 TW is excluded at 95% C.L. Particular attention is given to the description of all analysis details which should be of interest for the next generation of geoneutrino measurements using liquid scintillator detectors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗