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Friction and surface chemistry of some ferrous-base metallic glasses
The friction properties of some ferrous-base metallic glasses were measured both in argon and in vacuum to a temperature of 350 C. The alloy surfaces were also analyzed with X-ray photoelectron spectroscopy to identify the compounds and elements present on the surface. The results of the investigation indicate that even when the surfaces of the amorphous alloys, or metallic glasses, are atomically clean, bulk contaminants such as boric oxide and silicon dioxide diffuse to the surfaces. Friction measurements in both argon and vacuum indicate that the alloys exhibit higher coefficients of friction in the crystalline state than they do in the amorphous state.
Contamination control program for the Cosmic Background Explorer: An overview
Each of the three state of the art instruments flown aboard NASA's Cosmic Background Explorer (COBE) were designed, fabricated, and integrated using unique contamination control procedures to ensure accurate characterization of the diffuse radiation in the universe. The most stringent surface level cleanliness specifications ever attempted by NASA were required by the Diffuse Infrared Background Experiment (DRIBE) which is located inside a liquid helium cooled dewar along with the Far Infrared Absolute Spectrophotometer (FIRAS). The DRIBE instrument required complex stray radiation suppression that defined a cold primary optical baffle system surface cleanliness level of 100A. The cleanliness levels of the cryogenic FIRAS instrument and the Differential Microwave Radiometer (DMR) which were positioned symmetrically around the dewar were less stringent ranging from 300 to 500A. To achieve these instrument cleanliness levels, the entire flight spacecraft was maintained at level 500A throughout each phase of development. The COBE contamination control program is described along with the difficulties experienced in maintaining the cleanliness quality of personnel and flight hardware throughout instrument assembly.
Contamination control program for the Cosmic Background Explorer
Each of the three state of the art instruments flown aboard NASA's Cosmic Background Explorer (COBE) were designed, fabricated, and integrated using unique contamination control procedures to ensure accurate characterization of the diffuse radiation in the universe. The most stringent surface level cleanliness specifications ever attempted by NASA were required by the Diffuse Infrared Background Experiment (DRIBE) which is located inside a liquid helium cooled dewar along with the Far Infrared Absolute Spectrophotometer (FIRAS). The DRIBE instrument required complex stray radiation suppression that defined a cold primary optical baffle system surface cleanliness level of 100A. The cleanliness levels of the cryogenic FIRAS instrument and the Differential Microwave Radiometer (DMR) which were positioned symmetrically around the dewar were less stringent ranging from 300 to 500A. To achieve these instrument cleanliness levels, the entire flight spacecraft was maintained at level 500A throughout each phase of development. The COBE contamination control program is described along with the difficulties experienced in maintaining the cleanliness quality of personnel and flight hardware throughout instrument assembly.
Application of a Galerkin finite element method to atmospheric transport problems
Numerical simulation of the movement of a contaminant within the atmosphere presents difficulties due to the multidimensionality of the problem and the fact that the horizontal transport is usually convection dominated, that the boundary conditions are mixed, and that both slow and fast atmospheric chemical reactions can be important. In this study, numerical experiments using a Crank-Nicolson Galerkin finite element method to solve the time-dependent partial differential equations demonstrate the applicability and accuracy of this method for the variety of conditions encountered in atmospheric pollutant modeling. The Crank-Nicolson Galerkin method using piecewise linear, piecewise cubic Hermite polynomials, and upwind finite elements is shown to accurately model the pure convection of initial wave forms. Numerical results studying the interactions of convection, diffusion, chemical reaction, pollutant removal, and the effects of contaminant emission source strength, source location and multiple sources are also presented.
Release of Contaminants from Burning Liquids and Solids
This report details model development, theory, and a literature review focusing on the emission of contaminants on solid substrates in fires. This is the final report from a 2-year Nuclear Safety Research and Development (NSRD) project. The work represents progress towards a goal of having modeling and simulation capabilities that are sufficiently mature and accurate that they can be utilized in place of physical tests for determining safe handling practices. At present, the guidelines for safety are largely empirically based, derived from a survey of existing datasets. This particular report details the development, verification and calibration of a number of code improvements that have been implemented in the SIERRA suite of codes, and the application of those codes to three different experimental scenarios that have been subject of prior tests. The first scenario involves a contaminated PMMA slab, which is exposed to heat. The modeling involved a novel method for simulating the viscous diffusion of the particles in the slab. The second scenario involved a small pool fire of contaminated combustible liquid mimicking historical tests and finds that the release of contaminants has a high functionality with the height of the liquid in the container. The third scenario involves the burning of a contaminated tray of shredded cellulose. A novel release mechanism was formulated based on predicted progress of the decomposition of the cellulose, and while the model was found to result in release that can be tuned to match the experiments, some modifications to the model are desirable to achieve quantitative accuracy.
Estimating and Forecasting Time-Varying Groundwater Recharge in Fractured Rock: A State-Space Formulation with Preferential and Diffuse Flow to the Water Table
Rapid infiltration following precipitation may result in groundwater contamination from surface contaminants or pathogens. In fractured rock, contaminants can migrate rapidly to points of groundwater withdrawals. In contrast to the temporal availability of groundwater quality chemical indicators, meteorological and groundwater level observations are available in real-time to estimate time-varying recharge, which can act as a surrogate to identify periods of rapid infiltration that may indicate contamination susceptibility. Estimating recharge using methods, such as base-flow recession, unsaturated infiltration models, or Water-Table Fluctuations (WTF), cannot capitalize on currently available technologies and telecommunication infrastructure to conduct real-time recharge estimation at scales relevant to characterizing rapid infiltration. We present a linear, physics-based State-Space (SS) model of one-dimensional infiltration to estimate recharge, which includes preferential and diffuse-flow to the water table. The model can take advantage of real-time data for water-table altitude, precipitation, and evapotranspiration. Model parameters are calibrated over an observation period, and the Kalman Filter (KF) is subsequently applied to continuously update the observed (water-table altitude) and unobserved (groundwater recharge) system states and predict future states as new data become available. The SS/KF algorithm is demonstrated at the Masser Groundwater Recharge Site in Pennsylvania, USA and comparisons are made with recharge estimates from WTF methods. Model results indicate that the frequency of observations (daily versus sub-daily) dictates the allocation between preferential and diffuse flow. Additionally, because infiltration processes encompass many nonlinearities, model parameters estimated from observation periods need to be updated at least seasonally to account for changing recharge conditions.
Advanced detectors and signal processing for bubble memories
The feasibility of combining silicon and magnetic bubble technologies is demonstrated. Results of bubble film annealing indicate that a low temperature silicon on garnet technology is the most likely one to succeed commercially. Annealing ambients are also shown to have a major effect on the magnetic properties of bubble films. Functional MOSFETs were fabricated on bubble films coated with thick (approximately 1 micron) SiO2 layers. The two main problems with these silicon on garnet MOSFETs are low electron mobilities and large gate leakage currents. Results indicate that the laser recrystallized silicon and gate oxide (SiO2) layers are contaminated. The data suggest that part of the contaminating ions originate in the sputtered oxide spacer layer and part originates in the bubble film itself. A diffusion barrier, such as silicon nitride, placed between the bubble film and the silicon layer should eliminate the contamination induced problem.
XMM-Newton Observations of Solar Wind Charge Exchange Emission
We present an XMM-Newton spectrum of diffuse X-ray emission from within the solar system. The spectrum is dominated by O VII and O VIII lines at 0.57 keV and 0.65 keV, O VIII (and possibly Fe XVII) lines at approximately 0.8 keV, Ne IX lines at approximately 0.92 keV, and Mg XI lines at approximately 1.35 keV. This spectrum is consistent with what is expected from charge exchange emission between the highly ionized solar wind and either interstellar neutrals in the heliosphere or material from Earth's exosphere. The emission is clearly seen as a low-energy ( E less than 1.5 keV) spectral enhancement in one of a series of observations of the Hubble Deep Field North. The X-ray enhancement is concurrent with an enhancement in the solar wind measured by the ACE satellite. The solar wind enhancement reaches a flux level an order of magnitude more intense than typical fluxes at 1 AU, and has ion ratios with significantly enhanced higher ionization states. Whereas observations of the solar wind plasma made at a single point reflect only local conditions which may only be representative of solar wind properties with spatial scales ranging from less than half of an Earth radii (approximately 10 s) to 100 Earth radii, X-ray observations of solar wind charge exchange are remote sensing measurements which may provide observations which are significantly more global in character. Besides being of interest in its own right for studies of the solar system, this emission can have significant consequences for observations of more cosmological objects. It can provide emission lines at zero redshift which are of particular interest (e.g., O VII and O VIII) in studies of diffuse thermal emission, and which can therefore act as contamination in objects which cover the entire detector field of view. We propose the use of solar wind monitoring data, such as from the ACE and Wind spacecraft, as a diagnostic to screen for such possibilities.
An extended source for CN jets in Comet P/Halley
We examined radial intensity profiles of CN jets in comparison with the diffuse, isotropic component of the CN coma of Comet P/Halley. All images were bias-subtracted, flat-fielded, and continuum-subtracted. We calculated the diffuse profiles by finding the azimuthal mean of the coma least contaminated by jets yielding profiles similar to those of vectorial and Haser models of simple photodissociation. We found the jet profiles by calculating a mean around a Gaussian-fitted center in r-theta space. There is an unmistakable difference between the profiles of the CN jets and the profiles of the diffuse CN. Spatial derivatives of these profiles, corrected for geometrical expansion, show that the diffuse component is consistent with a simple photodissociation process, but the jet component is not. The peak production of the jet profile occurs 6000 km from the nucleus at a heliocentric distance of 1.4 AU. Modeling of both components of the coma indicate results that are consistent with the diffuse CN photochemically produced, but the CN jets need an additional extended source. We found that about one-half of the CN in the coma of Comet P/Halley originated from the jets, the rest from the diffuse component. These features, along with the width of the jet being approximately constant, are consistent with a CHON grain origin for the jets.
Assessment of contamination in the Shuttle bay
The results of an analytical study to determine the contamination potential of the Galileo probe instruments while in the STS bay are presented. The study covered conditions wherein the instruments weren't covered, covers were used with vent paths of varying sizes, and if the instruments were sealed and a nitrogen purge was employed. The contamination limits for each of the Galileo instruments are considered. Analytic approximations are devised for the diffusion of particles from surfaces and materials in the Shuttle bay during the ascent phase, using Fick's second law of diffusion. It is recommended that an instrument purge be implemented during the first 15 min of Shuttle flight in order to carry the contaminants from both the bay fixtures and from the instruments into space. Covers are suggested as necessary for the most sensitive instruments.
Mass spectrometer use in a large chamber
The early satellites were somewhat insensitive to contamination produced during the construction and testing phases. The On-Orbit lifetime was such that contamination effects went either unnoticed or unrecognized. With today's On-Orbit lifetimes approaching 10+ years, contamination has become a paramount concern. The scientific payloads have increased in complexity and sensitivity. The ability to clean a contaminated sensor has greatly diminished. This requires better pumping systems and methods for improved monitoring. The conversion from diffusion pumped thermal vacuum chambers to cryo pumped chambers with the use of Misner traps and selective cold traps has reduced contamination. Witness samples supply a record of the condensates that remain after a testing cycle, but impart no knowledge of the contaminant migration during the cycle that may be a month in duration. Due to a customer's request that mass spectrometry be used during the testing of their spacecraft, a consultant was contracted to install a mass spectrometer to determine the feasibility of the instrument. The equipment and methodology described will start with the original system and its evolution to GE's present system.
Preparation and cleanliness verifications of a space simulation chamber for contamination sensitive test specimens
Contamination sensitive optical devices were to be evaluated under thermal vacuum conditions. Test specifications called for an extremely clean chamber environment, ambient temperature chamber walls, and optical surface temperatures at approximately - 30 C. Chamber preparation included the replacement of diffusion pumps with cryopumps and the cleaning of the chamber walls to reduce contamination levels. Chamber cleaning using vacuum bake was tried and abandoned as time consuming and ineffective. Chemical cleaning and cleanliness verification methods were developed. Gas chromatograph analysis techniques were used extensively throughout the cleaning process to verify cleanliness levels prior to evacuating the chamber. A chamber cleanliness verification test using a thermoelectric quartz crystal microbalance and witness samples was performed to demonstrate that an appropriate cleanliness level was achieved.
Designing a Decontamination Solution for the Low-Earth-Orbit, Cryogenic SPHEREx Mission
To address the scientific goals of NASA’s astrophysics division, the JPL and Caltech’s SPHEREx mission conducts the first near-infrared all-sky spectral survey in low-earth-orbit using a passively-cooled, cryogenic telescope. Several unique water contamination issues arise due to the combination of cryogenic operation temperatures and the limited temperature control authority of passive cooling. Because water molecules have adsorption bands within the wavelengths of interest for SPHEREx’s survey, it is imperative that water contamination be controlled and minimized. In this work, a model is developed for the SPHEREx mission to predict the transport and accumulation of outgassed water onto sensitive payload components. The model utilizes the time dependent thermal profiles of the individual payload components, initial water content, and spacecraft geometry to calculate the time dependent water diffusion, transport, and adsorption. This model is subsequently used to predict water contamination risks and design decontamination solutions for each risk. Two major water contamination risks were predicted, water accumulation during cooldown and on cryogenic surfaces during the mission. The first risk occurs during the cooldown of the payload to cryogenic temperatures, predicting water accumulation on optical surfaces in excess of the allowable levels. To mitigate this accumulation, the temperature of the optical surfaces is controlled during cooldown through a combination of heaters and spacecraft pointing. The second risk is that over the course of the mission, is unavoidable water accumulation onto the payload thermal system’s cryogenic surfaces, possibly jeopardizing thermal performance and temperature stability, both of which are required for science success. To decontaminate any water that had collected onto cryogenic thermal system surfaces, a decontamination maneuver was designed. In this decontamination maneuver, cryogenic surfaces of the thermal system are warmed to a temperature where water will desorb by spacecraft pointing while still meeting all avoidance constraints, and thereby avoiding undue risk to the observatory hardware. Through application of the developed analytical model and inclusion of the decontamination maneuver in the mission design, SPHEREx can confidently demonstrate that it is able to decontaminate, at the start of and during the mission as needed to meet its end of life science performance requirements.
Preventing Molecular and Particulate Infiltration in a Confined Volume
Contaminants from an instrument's self-generated sources or from sources external to the instrument may degrade its critical surfaces and/or create an environment which limits the instrument's intended performance. Analyses have been carried out on a method to investigate the required purging flow of clean, dry gas to prevent the ingestion of external contaminants into the instrument container volume. The pressure to be maintained and the required flow are examined in terms of their effectiveness in preventing gaseous and particulate contaminant ingestion and abatement of self-generated contaminants in the volume. The required venting area or the existing volume venting area is correlated to the volume to be purged, the allowable pressure differential across the volume, the external contaminant partial pressure, and the sizes of the ambient particulates. The diffusion of external water vapor into the volume while it was being purged was experimentally obtained in terms of an infiltration time constant. That data and the acceptable fraction of the outside pressure into the volume indicate the required flow of purge gas expressed in terms of volume change per unit time. The exclusion of particulates is based on the incoming velocity of the particles and the exit flow speed and density of the purge gas. The purging flow pressures needed to maintain the required flows through the vent passages are indicated. The purge gas must prevent or limit the entrance of the external contaminants to the critical locations of the instrument. It should also prevent self- contamination from surfaces, reduce material outgassing, and sweep out the outgassed products. Systems and facilities that can benefit from purging may be optical equipment, clinical facilities, manufacturing facilities, clean rooms, and other systems requiring clean environments.
Use of cryopumps on large space simulation systems
The need for clean, oil free space simulation systems has demanded the development of large, clean pumping systems. The assurance of optically dense liquid nitrogen baffles over diffusion pumps prevents backstreaming to a large extent, but does not preclude contamination from accidents or a control failure. Turbomolecular pumps or ion pumps achieve oil free systems but are only practical for relatively small chambers. Large cryopumps were developed and checked out which do achieve clean pumping of very large chambers. These pumps can be used as the original pumping system or can be retrofitted as a replacement for existing diffusion pumps.
An analysis of LDEF-exposed silvered FEP teflon thermal blanket material
The characterization of selected silvered fluorinated ethylene propylene (FEP) teflon thermal blanket material which received 5 years and 9 months of exposure to the LEO environment on the Long Duration Exposure Facility is reported. X-ray photoelectron spectroscopy, infrared, and thermal analyses did not detect a significant change at the molecular level as the result of this exposure. However, various microscopic analyses revealed a roughening of the coating surface due to atomic oxygen erosion which resulted in some materials changing from specular reflectors of visible radiation to diffuse reflectors. The potential effect of silicon-containing molecular contamination on these materials is addressed.
Ultra-High-Performance Grout for Encapsulation of Solid Secondary Waste
Ultra-high-performance grout (UHPG); Low H2O/CM; Small aggregate; May include fibers; Admix UHPG has excellent contaminant transport properties: Strong moisture retention; Low porosity; Low permeability; Diffusivity; High resistance to chloride penetration (− < 50 coulombs; ASTM C 1202)