Laboratory simulation of solar wind - earth interaction
Measurement of change in plasma potential and magnetic field of hydrogen plasma impinging on magnetic dipole - simulation of solar wind-earth interaction
Chubb, D. L.↗
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Fast magnetization of a high-to-low-beta plasma beam
The magnetization of a high-beta (plasma energy density/magnetic-field energy density) hydrogen-plasma beam injected into a vacuum transverse magnetic field is studied experimentally. Nominal parameters were Ti = 1 eV, Te = 5 eV, n = 3 x 10 to the 13th/cu cm or less, v(i) = 7 x 10 to the 6th cm/sec or less, t(pulse) less than 70 microsec, and Bz = 300 G or less. Plasma characteristics were measured for a wide beam and a downstream distance, x = 300 rho(i) or less, where x is the downstream distance and rho(i) is the ion gyroradius. A brief initial state of diamagnetic propagation is observed, followed by magnetized propagation accompanied by beam compression transverse to B with as much as a factor of 4 increase in density and a slight drift of the beam in the ion Lorentz force direction.
Song, J. J.↗
A nonequilibrium model for a moderate pressure hydrogen microwave discharge plasma
This document describes a simple nonequilibrium energy exchange and chemical reaction model to be used in a computational fluid dynamics calculation for a hydrogen plasma excited by microwaves. The model takes into account the exchange between the electrons and excited states of molecular and atomic hydrogen. Specifically, electron-translation, electron-vibration, translation-vibration, ionization, and dissociation are included. The model assumes three temperatures, translational/rotational, vibrational, and electron, each describing a Boltzmann distribution for its respective energy mode. The energy from the microwave source is coupled to the energy equation via a source term that depends on an effective electric field which must be calculated outside the present model. This electric field must be found by coupling the results of the fluid dynamics and kinetics solution with a solution to Maxwell's equations that includes the effects of the plasma permittivity. The solution to Maxwell's equations is not within the scope of this present paper.
Scott, Carl D.↗
Transversal plasma wave instabilities in two counterstreaming plasmas without external fields.
Transverse and longitudinal plasma wave instabilities for two counterstreaming neutral hydrogen plasmas without external fields
PLASMA WAVE↗
Synthesis of silane and silicon in a non-equilibrium plasma jet
The feasibility of using a non-equilibrium hydrogen plasma jet as a chemical synthesis tool was investigated. Four possible processes were identified for further study: (1) production of polycrystalline silicon photovoltaic surfaces, (2) production of SiHCl3 from SiCl4, (3) production of SiH4 from SiHCl3, and (4) purification of SiCl4 by metal impurity nucleation. The most striking result was the recognition that the strongly adhering silicon films, amorphous or polycrystalline, produced in our studies could be the basis for preparing a photovoltaic surface directly; this process has potential advantages over other vapor deposition processes.
Calcote, H. F.↗
Chemical and electrochemical pathways to low-carbon iron and steel
Currently, the iron and steel industry is responsible for 7% of global CO 2 emissions. In this review, we summarize the operational principles of current emissions-intensive steelmaking technologies and review emerging low- and zero-carbon technologies that could substantially reduce emissions. Current technologies that are discussed include blast furnaces, electric arc furnaces, and smelting. Promising low-carbon routes include use of alternative reductants for ore processing (hydrogen direct reduction, hydrogen plasma-smelting, hydrogen smelting, and ammonia-based reduction), electrolytic iron production (with aqueous and molten oxide electrolytes) and biocarbon-based electric arc furnace operation. Advantages of each approach are presented, and remaining research hurdles are identified.
36 MATERIALS SCIENCE↗
Cold plasma processing of local planetary ores for oxygen and metallurgically important metals
The utilization of a cold plasma in chlorination processing is described. Essential equipment and instruments were received, the experimental apparatus assembled and tested, and preliminary experiments conducted. The results of the latter lend support to the original hypothesis: a cold plasma can both significantly enhance and bias chemical reactions. In two separate experiments, a cold plasma was used to reduce TiCl4 vapor and chlorinate ilmenite. The latter, reacted in an argon-chlorine plasma, yielded oxygen. The former experiment reveals that chlorine can be recovered as HCl vapor from metal chlorides in a hydrogen plasma. Furthermore, the success of the hydrogen experiments has lead to an analysis of the feasibility of direct hydrogen reduction of metal oxides in a cold plasma. That process would produce water vapor and numerous metal by-products.
Lynch, D. C.↗
Microwave plasma generation of hydrogen atoms for rocket propulsion
A flow microwave plasma reaction system is used to study the conversion of hydrogen to hydrogen atoms as a function of pressure, power density, cavity tuning, cavity mode, and time in the plasma zone. Hydrogen atom concentration is measured down-stream from the plasma by NOCl titration. Extensive modeling of the plasma and recombination zones is performed with the plasma zone treated as a backmix reaction system and the recombination zone treated as a plug flow. The thermodynamics and kinetics of the recombination process are examined in detail to provide an understanding of the conversion of recombination energy to gas kinetic energy. It is found that cavity tuning, discharge stability, and optimum power coupling are critically dependent on the system pressure, but nearly independent of the flow rate.
Chapman, R.↗
Heating of thermal helium in the equatorial magnetosphere - A simulation study
The heating of He(+) ions observed by the GEOS satellite at L of about seven starting from an initial anisotropic proton distribution is studied. A simulation of electromagnetic ion cyclotron waves in a plasma consisting of hot anisotropic protons, a dominant thermal hydrogen plasma, and a minority species of helium ions is utilized. It is shown that the thermal ions are heated to 100 times their initial temperature due to the growth of large-amplitude ion cyclotron waves. He(+) ions are heated mainly in the perpendicular direction, and they are heated more than cold H(+) ions. The He(+) ions are heated in a two-step process. First, they are set into oscillations by the growing wave until some of the ions reach a parallel velocity on the order of the resonant velocity; then, strong heating occurs.
Omura, Y.↗
Focussed discharge from pulsed plasma guns
Coaxial gun with covergent barrel for focusing high speed blobs of hydrogen plasma
Cheng, D. Y.↗
Hydrogen Sensor via Plasma Techniques Development
Currently, NASA Kennedy Space Center’s Exploration Ground Systems (EGS) uses liquid hydrogen (LH2) as fuel for launches and ensures hydrogen is no longer in the fill lines by sampling gas into a controlled environment. Then they use a catalytic sensor that detects when hydrogen interacts with oxygen. However, this procedure requires repeatedly backfilling and flushing with helium, which can be wasteful during a global helium shortage and expensive for each sampling port. Therefore, the team at KSC set out to establish proof-of-concept of a plasma-based hydrogen sensor that is anaerobic – and can in fact detect in most environments and below atmospheric pressures – and with a small footprint and more sensitive than other hydrogen sensors currently on the market. The technology development was done by testing known concentrations of hydrogen in argon gas fed through a vacuum cube containing an electrode feedthrough at varying pressures. The resultant emission spectra were recorded with a fiber optic spectrometer and analyzed to determine the instrument's accuracy. Throughout testing, efforts were made to prove the off-the-shelf capabilities of the setup. The traditional high voltage AC-power source was switched to an affordable, handheld plasma lighter. Additionally, the spectrometer was supplemented with a double photodiode circuit to take targeted measurements of the Balmer-α and - β lines in the hydrogen spectrum. From this, we established a proof of concept sensor. SLS required it to detect as low as 100 ppm whereas we detected hydrogen in concentrations as low as 50 ppm and in an anaerobic environment.
plasma↗
Laser production and heating of plasma for MHD application
Experiments have been made on the production and heating of plasmas by the absorption of laser radiation. These experiments were performed to ascertain the feasibility of using laser-produced or laser-heated plasmas as the input for a magnetohydrodynamic (MHD) generator. Such a system would have a broad application as a laser-to-electricity energy converter for space power transmission. Experiments with a 100-J-pulsed CO2 laser were conducted to investigate the breakdown of argon gas by a high-intensity laser beam, the parameters (electron density and temperature) of the plasma produced, and the formation and propagation of laser-supported detonation (LSD) waves. Experiments were also carried out using a 1-J-pulsed CO2 laser to heat the plasma produced in a shock tube. The shock-tube hydrogen plasma reached electron densities of approximately 10 to the 17th/cu cm and electron temperatures of approximately 1 eV. Absorption of the CO2 laser beam by the plasma was measured, and up to approximately 100 percent absorption was observed. Measurements with a small MHD generator showed that the energy extraction efficiency could be very large with values up to 56 percent being measured.
Jalufka, N. W.↗
Invariant criteria for bound states, degree of ionization, and plasma phase transition
Basis invariant characterizations of bound states and bound fraction of a partially ionized hydrogen plasma are given in terms of properties of the spectrum of eigenvalues and eigenfunctions of the equilibrium quantum statistical one-proton-one-electron reduced density matrix. It is suggested that these can be used to place theories of a proposed plasma-ionization phase transition on a firm foundation. This general approach may be relevant to cosmological questions such as the quark deconfinement-confinement transition.
Girardeau, M. D.↗
Process Research of Polycrystalline Silicon Material (PROPSM)
A passivation process (hydrogenation) that will improve the power generation of solar cells fabricated from presently produced, large grain, cast polycrystalline silicon (Semix), a potentially low cost material are developed. The first objective is to verify the operation of a DC plasma hydrogenation system and to investigate the effect of hydrogen on the electrical performance of a variety of polycrystalline silicon solar cells. The second objective is to parameterize and optimize a hydrogenation process for cast polycrystalline silicon, and will include a process sensitivity analysis. The sample preparation for the first phase is outlined. The hydrogenation system is described, and some early results that were obtained using the hydrogenation system without a plasma are summarized. Light beam induced current (LBIC) measurements of minicell samples, and their correlation to dark current voltage characteristics, are discussed.
Culik, J. S.↗
EBIC investigation of hydrogenation of crystal defects in EFG solar silicon ribbons
Changes in the contrast and resolution of defect structures in 205 Ohm-cm EFG polysilicon ribbon subjected to annealing and hydrogenation treatments were observed in a JEOL 733 Superprobe scanning electron microscope, using electron beam induced current (EBIC) collected at an A1 Schottky barrier. The Schottky barrier was formed by evaporation of A1 onto the cleaned and polished surface of the ribbon material. Measurement of beam energy, beam current, and the current induced in the Schottky diode enabled observations to be quantified. Exposure to hydrogen plasma increased charge collection efficiency. However, no simple causal relationship between the hydrogenation and charge collection efficiency could be inferred, because the collection efficiency also displayed an unexpected thermal dependence. Good quality intermediate-magnification (1000X-5400X) EBIC micrographs of several specific defect structures were obtained. Comparison of grown-in and stress-induced dislocations after annealing in vacuum at 500 C revealed that stress-induced dislocations are hydrogenated to a much greater degree than grown-in dislocations. The theoretical approximations used to predict EBIC contrast and resolution may not be entirely adequate to describe them under high beam energy and low beam current conditions.
Sullivan, T.↗
Toward understanding the conical arc-chamber driver
The mechanical and electrical characteristics of the conical arc-chamber driver and the 1450-microfarad capacitor bank are described. The system dynamic performance can be approximated by a second-order nonlinear equation. The discharge of the capacitor bank into the conical arc-chamber was investigated at a variety of initial conditions. Details of the discharge are explained and compared for typical performance with both hydrogen and helium arc-chamber gases. At peak current the hydrogen plasma resistivity is significantly higher than that of the helium plasma and this, in part, accounts for the better shock speed performance with hydrogen. The lower melting and boiling point exploding wires of aluminum, copper, and stainless steel produced higher shock speed performance than the apparently nonexploding tungsten wire.
Livingston, F. R.↗
Laser-heated rocket studies
CW laser heated rocket propulsion was investigated in both the flowing core and stationary core configurations. The laser radiation considered was 10.6 micrometers, and the working gas was unseeded hydrogen. The areas investigated included initiation of a hydrogen plasma capable of absorbing laser radiation, the radiation emission properties of hot, ionized hydrogen, the flow of hot hydrogen while absorbing and radiating, the heat losses from the gas and the rocket performance. The stationary core configuration was investigated qualitatively and semi-quantitatively. It was found that the flowing core rockets can have specific impulses between 1,500 and 3,300 sec. They are small devices, whose heating zone is only a millimeter to a few centimeters long, and millimeters to centimeters in radius, for laser power levels varying from 10 to 5,000 kW, and pressure levels of 3 to 10 atm. Heat protection of the walls is a vital necessity, though the fraction of laser power lost to the walls can be as low as 10% for larger powers, making the rockets thermally efficient.
Kemp, N. H.↗
Laser thermal propulsion
Laser thermal propulsion (LTP) is studied for the case in which laser power is absorbed by a small very high-temperature plasma (about 20,000 K) and transferred to the remainder of the pure hydrogen propellant by radiation and mixing. This concept could lead to the realization of a lightweight orbital transfer vehicle propulsion system having a specific impulse in the range 1000-2000 s. Approximately 12 percent of the input power may be radiated to the thruster walls, and 15 percent of the total propellant flow must be heated to 20,000 K to provide a bulk temperature of 5000 K prior to expansion. Three principal research issues identified are: (1) conditions for hydrogen plasma ignition, (2) control of the plasma position within the laser beam, plasma stability, and plasma absorption efficiency, and (3) characterization of the mixing of the plasma and buffer flows.
Keefer, D.↗