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The Strategy for the Second Phase of Aerobraking Mars Global Surveyor

On February 19, 1999, the Mars Global Surveyor (MGS) spacecraft was able to propulsively establish its mapping orbit. This event followed the completion of the second phase of aerobraking for the MGS spacecraft on February 4, 1999. For the first time, a spacecraft at Mars had successfully employed aerobraking methods in order to reach its desired pre-launch mapping orbit. This was accomplished despite a damaged spacecraft solar array. The MGS spacecraft was launched on November 7, 1996, and after a ten month interplanetary transit was inserted into a highly elliptical capture orbit at Mars on September 12, 1997. Unlike other interplanetary missions, the MGS spacecraft was launched with a planned mission delta-V ((Delta)V) deficit of nearly 1250 m/s. To overcome this AV deficit, aerobraking techniques were employed. However, damage discovered to one of the spacecraft's two solar arrays after launch forced major revisions to the original aerobraking planning of the MGS mission. In order to avoid a complete structural failure of the array, peak dynamic pressure levels for the spacecraft were established at a major spacecraft health review in November 1997. These peak dynamic pressure levels were roughly one-third of the original mission design values. Incorporating the new dynamic pressure limitations into mission replanning efforts resulted in an 'extended' orbit insertion phase for the mission. This 'extended' orbit insertion phase was characterized by two distinct periods of aerobraking separated by an aerobraking hiatus that would last for several months in an intermediate orbit called the "Science Phasing Orbit" (SPO). This paper describes and focuses on the strategy for the second phase of aerobraking for the MGS mission called "Aerobraking Phase 2." This description will include the baseline aerobraking flight profile, the trajectory control methodology, as well as the key trajectory metrics that were monitored in order to successfully "guide' the spacecraft to its desired mapping orbit. Additionally, the actual aerobraking progress is contrasted to the planned aerobraking flight profile. (A separate paper will describe the navigation aspects of MGS aerobraking in detail.) Key to the success of the MGS mission is the delivery of the spacecraft to its final mapping orbit and the synergy the instrument complement provides to its scientific investigators when science data is returned from that orbit. The MGS mapping orbit is characterized as a low altitude, near-circular, near-polar orbit that is Sun-synchronous with the descending equatorial crossing at 2:00 AM local mean solar time (LMST).

Johnston, M. D.↗

A Determination of the Precession and Rotation-Rate of Mars from Tracking and Altimetry Data

The doppler tracking of the MGS spacecraft and the laser altimetry acquired by the MOLA instrument on MGS have been used to measure the rotation of Mars. By observing the repeating pattern of gravity anomalies and the topography the direction of the rotation axis in both inertial space and body fixed coordinates, and the rate of rotation of the planet on its axis have been derived. The tracking of MGS in orbit about Mars by stations on Earth permit the orbit of MGS to be obtained in an inertial coordinate system enabling the periodic perturbation of the MGS orbit by Mars' gravity field to be used as a sensor to detect the vector rotation of Mars under the orbit of MGS. The altimetry data acquired by MOLA on MGS permit the topography to help define the orbit of MGS about Mars in a body fixed coordinate system thus enabling the pole of rotation of the planet to be determined in a coordinate system defined by the altimetry. Together they enable the precession of the rotation axis to be observed from which the moment of inertia can be derived, changes in length of day to be measured, and a method to check for possible Mars polar motion. Tracking data on the Mariner 9, Viking 1 and 2, from the 1970's have been analyzed with MGS data obtained in the mapping orbit in 1999 to provide a new estimate of the moment of inertia.

Smith, David E.↗

A comparison between anisotropic analytical and multigrid superposition dose calculation algorithms in radiotherapy treatment planning

Monte Carlo (MC) simulation is currently the most accurate dose calculation algorithm in radiotherapy planning but requires relatively long processing time. Faster model-based algorithms such as the anisotropic analytical algorithm (AAA) by the Eclipse treatment planning system and multigrid superposition (MGS) by the XiO treatment planning system are 2 commonly used algorithms. This study compared AAA and MGS against MC, as the gold standard, on brain, nasopharynx, lung, and prostate cancer patients. Computed tomography of 6 patients of each cancer type was used. The same hypothetical treatment plan using the same machine and treatment prescription was computed for each case by each planning system using their respective dose calculation algorithm. The doses at reference points including (1) soft tissues only, (2) bones only, (3) air cavities only, (4) soft tissue-bone boundary (Soft/Bone), (5) soft tissue-air boundary (Soft/Air), and (6) bone-air boundary (Bone/Air), were measured and compared using the mean absolute percentage error (MAPE), which was a function of the percentage dose deviations from MC. Besides, the computation time of each treatment plan was recorded and compared. The MAPEs of MGS were significantly lower than AAA in all types of cancers (p<0.001). With regards to body density combinations, the MAPE of AAA ranged from 1.8% (soft tissue) to 4.9% (Bone/Air), whereas that of MGS from 1.6% (air cavities) to 2.9% (Soft/Bone). The MAPEs of MGS (2.6%±2.1) were significantly lower than that of AAA (3.7%±2.5) in all tissue density combinations (p<0.001). The mean computation time of AAA for all treatment plans was significantly lower than that of the MGS (p<0.001). Both AAA and MGS algorithms demonstrated dose deviations of less than 4.0% in most clinical cases and their performance was better in homogeneous tissues than at tissue boundaries. In general, MGS demonstrated relatively smaller dose deviations than AAA but required longer computation time.

61 RADIATION PROTECTION AND DOSIMETRY↗

Compositional origin of unusual β-relaxation properties in La-Ni-Al metallic glasses

The β-relaxation of metallic glasses (MGs) bears nontrivial connections to their microscopic and macroscopic properties. In an effort to elucidate the mechanism of the β-relaxation, we studied by dynamical mechanical measurements the change of its properties on varying the composition of La{sub 60}Ni{sub 15}Al{sub 25} in various ways. The properties of the β-relaxation turn out to be very sensitive to the composition. It is found that the isochronal loss peak temperature of β-relaxation, T{sub β,peak}, is effectively determined by the total (La + Ni) content. When Cu is added into the alloy to replace either La, Ni, or Al, the T{sub β,peak} increases with decrease of the (La + Ni) content. The trend is in accordance with data of binary and ternary MGs formed from La, Ni, Al, and Cu. Binary La-Ni MGs have pronounced β-relaxation loss peaks, well separated from the α-relaxation. In contrast, the β-relaxation is not resolved in La-Al and La-Cu MGs, showing up as an excess wing. For the ternary La-Ni-Al MGs, increase of La or Ni content is crucial to lower the T{sub β,peak}. Keeping the Al content fixed, increase of La content lowers the T{sub β,peak} further, indicating the more important role La plays in lowering T{sub β,peak} than Ni. The observed effects on changing the composition of La{sub 60}Ni{sub 15}Al{sub 25} lead to the conclusion that the properties of the β-relaxation are mainly determined by the interaction between the largest solvent element, La, and the smallest element, Ni. From our data, it is further deduced that La and Ni have high mobility in the MGs, and this explains why the β-relaxation in this La-based MGs is prominent and well resolved from the α-relaxation as opposed to Pd- and Zr-based MGs where the solvent and largest atoms, Pd and Zr, are the least mobile.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Orbit Determination for Mars Global Surveyor During Mapping

The Mars Global Surveyor (MGS) spacecraft reached a low-altitude circular orbit on February 4, 1999, after the termination of the second phase of aerobraking. The MGS spacecraft carries the Mars Orbiter Laser Altimeter (MOLA) whose primary goal is to derive a global, geodetically referenced 0.2 deg x 0.2 deg topographic grid of Mars with a vertical accuracy of better than 30 meters. During the interim science orbits in the' Hiatus mission phase (October - November 1997), and the Science Phasing Orbits (March - April, 1998, and June - July 1998) 208 passes of altimeter data were collected by the MOLA instrument. On March 1, 1999 the first ten orbits of MOLA altimeter data from the near-circular orbit were successfully returned from MGS by the Deep Space Network (DSN). Data will be collected from MOLA throughout the Mapping phase of the MCS mission, or for at least one Mars year (687 days). Whereas the interim orbits of Hiatus and SPO were highly eccentric, and altimeter data were only collected near periapsis when the spacecraft was below 785 km, the Mapping orbit of MGS is near circular, and altimeter data will be collected continuously at a rate of 10 Hz. The proper analysis of the altimeter data requires that the orbit of the MGS spacecraft be known to an accuracy comparable to that of the quality of the altimeter data. The altimeter has an ultimate precision of 30 cm on mostly flat surfaces, so ideally the orbits of the MGS spacecraft should be known to this level. This is a stringent requirement, and more realistic goals of orbit error for MGS are ten to thirty meters. In this paper we will discuss the force and measurement modelling required to achieve this objective. Issues in force modelling include the proper modelling of the gravity field of Mars, and the modelling of non-conservatives forces, including the development of a 'macro-model', in a similar fashion to TOPEX/POSEIDON and TDRSS. During Cruise and Aerobraking, the high gain antenna (HGA) was stowed on the +X face of the spacecraft. On March 29, 1999 the HGA will be deployed on a meter long boom which will remain Earth-pointing while the instrument panel (including the MOLA instrument) remains pointed at nadir. The tracking data must be corrected for the regular motion of the high gain antenna with respect to the center of mass, and the success of the MGS determination during Mapping will depend on correctly accounting for this offset in the measurement model.

Lemoine, F. G.↗

Intrinsic and extrinsic effects on the fracture toughness of ductile metallic glasses

The potential application of metallic glasses (MGs) as structural materials demands accurate measurements of their toughness and the understanding of the underlying factors affecting it. Currently, it is challenging to precisely measure the toughness of MGs, especially ductile MGs. Measured toughness values are widely scattered, even for MGs with identical compositions. That is attributed to the combined effect of intrinsic and extrinsic factors including processing, sample geometries, and loading conditions. A fundamental understanding of the influences of these elements is thus of great significance. In the present study, molecular dynamics simulations are performed to investigate the influence of intrinsic and extrinsic effects on the fracture toughness of CuZr MGs. In particular, focused is placed on the effects of cooling rate, notch shape and size, strain rate, and temperature. The results indicate that the fracture toughness of a MG scales with the cooling rate used to prepare it. This is attributed to increased free volume content generated at high cooling rates, which enhances plastic deformation and amplifies the associated energy dissipation during plastic deformation events. Fracture toughness also increases with the strain rate, arguably due to strain rate-induced crack extension delay. Overall, the results demonstrate that the largest fracture toughness are achieved when MG samples are fabricated at high cooling rates and subjected to high strain rate deformation. In addition, results suggest that the fracture toughness decreases with increasing temperature, due to the significant decrease in strength. Here, the correlations revealed between these crucial intrinsic and extrinsic parameters and the calculated MG fracture toughness support the development of a framework to understand the root of the discrepancies in the measurement of the toughness of MGs and provide insights into the design of tough MGs for structural applications.

36 MATERIALS SCIENCE↗

Power–Law Feature of Structure in Metallic Glasses

The atomic packing in metallic glasses (MGs) is a long-standing issue. We investigate the atomic packing on different length scales for various MGs by X-ray diffraction and small-angle X-ray scattering techniques. Our findings are that (1) a noncubic power–law relationship exists between both normalized average basic volume (Va = M / (ρ × N), where N is the Avogadro constant and M and ρ are the molar mass and density of the sample, respectively) and the center of mass of the first four peaks (qi) of structural factors in reciprocal space, having an exponent of about 2.52 ± 0.15 on the length scale of about 2.2–3.1 Å for 25 studied MGs, (2) a power–law relationship of the normalized scattering intensity vs q vector has an exponent of about 2.62 ± 0.12 on the length scale of about 250–785 Å for 5 studied MGs, and (3) in contrast, normalization of Va and ri (the center of mass of the first four peaks of pair correlation functions) in real space for 25 studied MGs reveals an exponent close to 3, similar to crystals. This discrepancy is elucidated by the fact that the pair correlation functions link with the atomic distribution along the radial direction but neglect how they are spatially packed on each shell. The perspective of the power–law relations on both length scales for the studied MGs deepens the understanding of the atomic packing structures in MGs.

36 MATERIALS SCIENCE↗

Spatial correlation of elastic heterogeneity tunes the deformation behavior of metallic glasses

Metallic glasses (MGs) possess remarkably high strength but often display only minimal tensile ductility due to the formation of catastrophic shear bands. Purposely enhancing the inherent heterogeneity to promote distributed flow offers new possibilities in improving the ductility of monolithic MGs. Here, we report the effect of the spatial heterogeneity of elasticity, resulting from the inherently inhomogeneous amorphous structures, on the deformation behavior of MGs, specifically focusing on the ductility using multiscale modeling methods. A highly heterogeneous, Gaussian-type shear modulus distribution at the nanoscale is revealed by atomistic simulations in Cu 64 Zr 36 MGs, in which the soft population of the distribution exhibits a marked propensity to undergo the inelastic shear transformation. By employing a mesoscale shear transformation zone dynamics model, we find that the organization of such nanometer-scale shear transformation events into shear-band patterns is dependent on the spatial heterogeneity of the local shear moduli. A critical spatial correlation length of elastic heterogeneity is identified for the simulated MGs to achieve the best tensile ductility, which is associated with a transition of shear-band formation mechanisms, from stress-dictated nucleation and growth to structure-dictated strain percolation, as well as a saturation of elastically soft sites participating in the plastic flow. This discovery is important for the fundamental understanding of the role of spatial heterogeneity in influencing the deformation behavior of MGs. We believe that this can facilitate the design and development of new ductile monolithic MGs by a process of tuning the inherent heterogeneity to achieve enhanced ductility in these high-strength metallic alloys.

36 MATERIALS SCIENCE↗

Dynamic Microgrids With Self-Organized Grid-Forming Inverters in Unbalanced Distribution Feeders

In contrast to conventional static microgrids (MGs), MGs with dynamic and adjustable territories (i.e., dynamic MGs) are proposed and implemented in this paper. Dynamic MGs are commonly dominated by grid-forming inverters and nested in unbalanced distribution feeders. Unlike balanced systems where only positive-sequence components exist, proper operation of unbalanced dynamic MGs presents additional challenges. A distributed secondary control strategy is developed in this study for distributed generators (DGs) interfaced with gridforming inverters in unbalanced dynamic MGs by providing coordinated regulations on both positive- and negative-sequence system models. System frequency and voltage are under constant regulation, along with voltage unbalance (VU) management for multiple critical load buses (CLB). The proposed control strategy enables seamless system transition during unbalanced dynamic MGs reconfiguration, and guarantees proportional positive- and negative-sequence power sharing among connected DGs with respect to system topology variation. Detailed controller designs are provided and stability analyses are derived. The proposed control strategy is fully implemented in hardware controllers and validated on a Hardware-in-the-Loop (HIL) MG testbed.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Mars Global Surveyor Ka-Band Frequency Data Analysis

The Mars Global Surveyor (MGS) spacecraft, launched on November 7, 1996, carries an experimental space-to-ground telecommunications link at Ka-band (32 GHz) along with the primary X-band (8.4 GHz) downlink. The signals are simultaneously transmitted from a 1.5-in diameter parabolic high gain antenna (HGA) on MGS and received by a beam-waveguide (BWG) R&D 34-meter antenna located in NASA's Goldstone Deep Space Network (DSN) complex near Barstow, California. The projected 5-dB link advantage of Ka-band relative to X-band was confirmed in previous reports using measurements of MGS signal strength data acquired during the first two years of the link experiment from December 1996 to December 1998. Analysis of X-band and Ka-band frequency data and difference frequency (f(sub x)-f(sub ka)/3.8) data will be presented here. On board the spacecraft, a low-power sample of the X-band downlink from the transponder is upconverted to 32 GHz, the Ka-band frequency, amplified to I-W using a Solid State Power Amplifier, and radiated from the dual X/Ka HGA. The X-band signal is amplified by one of two 25 W TWTAs. An upconverter first downconverts the 8.42 GHz X-band signal to 8 GHz and then multiplies using a X4 multiplier producing the 32 GHz Ka-band frequency. The frequency source selection is performed by an RF switch which can be commanded to select a VCO (Voltage Controlled Oscillator) or USO (Ultra-Stable Oscillator) reference. The Ka-band frequency can be either coherent with the X-band downlink reference or a hybrid combination of the USO and VCO derived frequencies. The data in this study were chosen such that the Ka-band signal is purely coherent with the X-band signal, that is the downconverter is driven by the same frequency source as the X-band downlink). The ground station used to acquire the data is DSS-13, a 34-meter BWG antenna which incorporates a series of mirrors inside beam waveguide tubes which guide the energy to a subterranean pedestal room, providing a stable environment for the feed and electronics equipment. A dichroic plate is used to reflect the X-band energy and pass the Ka-band energy to another mirror. The RF energy for each band is then focused onto a feed horn and low-noise amplifier package. After amplification and RF/IF downconversion, the IF signals are sent to the Experimental Tone Tracker (ETT), a digital phase-lock-loop receiver, which simultaneously tracks both X-band and Ka-band carrier signals. Once a signal is detected, the ETT outputs estimates of the SNR in a I -Hz bandwidth (Pc/No), baseband phase and frequency of the signals every I -sec. Between December 1996 and December 1998, the Ka-band and X-band signals from MGS were tracked on a regular basis using the ETT. The Ka-band downlink frequencies described here were referenced to the spacecraft's on-board USO which was also the X-band frequency reference (f(sub ka)= 3.8 f(sub x)). The ETT estimates of baseband phase at I -second sampled time tags were converted to sky frequency estimates. Frequency residuals were then generated for each band by removing a model frequency from each observable frequency at each time tag. The model included Doppler and other effects derived from spacecraft trajectory files obtained from the MGS Navigation Team. A simple troposphere correction was applied to the data. In addition to residuals, the USO frequencies emitted by the spacecraft were estimated. For several passes, the USO frequencies were determined from X-band data and from Ka-band data (referred to X-band by dividing by 3.8) and were found to be in good agreement. In addition, X-band USO frequency estimates from MGS Radio Science data acquired from operational DSN stations were available for comparison and were found to agree within the I Hz level. The remaining sub-Hertz differences were attributed to the different models and software algorithms used by MGS Radio Science and KaBLE-11. A summary of the results of a linear fit of the USO frequency versus time (day of year) is presented in Table I for an initial segment of passes.

Morabito, D.↗

Improving biodiesel monoglyceride determination by ASTM method D6584-17

Biodiesels produced from commercial and non-traditional feedstocks were analyzed by ASTM D6584-17 for monoglyceride (monoacylglycerol, or MG) content. It was found that D6584-17 as currently written may not accurately determine MGs from conventional feedstocks due to significant differences in retention time using modern instrumentation. For biodiesel from non-traditional feedstocks, D6584-17 did not sufficiently account for MGs containing fatty acids outside of C16 and C18 species. This led to under- and over-reporting of MGs, as critical components were not accurately measured. Improvements to the method were made through a three-step process. First, a standard mixture of MGs was run to determine the retention time of individual MGs that could be present in the samples from C10 to C24. An additional analysis for the fatty acid methyl ester (FAME) profile was used to determine the major MG species present in the biodiesel samples, using the assumption that the MG profile was proportional to the FAME profile. The biodiesel samples were analyzed by D6584-17, and the MGs were identified using retention time matching, based on the major species expected from measuring the FAME profile. Here, by combining these two methods, the accuracy of MG determination by D6584-17 was improved for biodiesels prepared from all feedstocks.

30 DIRECT ENERGY CONVERSION↗

Shape memory effect in metallic glasses

Shape memory effect (SME), mainly present in crystalline Ti-Ni alloys, is basically missing in metallic glasses (MGs) that lack the long-range periodic order of crystals. In this work, we report experimental results of SME in annealed MGs, in which the low-energy configuration state recovery is observed by both differential scanning calorimetry and X-ray photon correlation spectroscopy. We elucidate the origin of SME in MGs under the potential energy landscape framework, i.e., after annealing, the energy of MGs enters into a deep basin and atoms are located in the low-energy configuration state. Albeit deviating from their relative stable configurations by temperature changes, atoms in the annealed MGs tend to return to the low-energy atomic configurations along certain trajectories as pre-annealing temperature is approached, These results could extend the application of MGs as functional materials by directionally manipulating their energy states via annealing and rejuvenation.

36 MATERIALS SCIENCE↗

Strengthening and toughening metallic glasses: The elastic perspectives and opportunities

There exist general conflicts between strength and toughness in crystalline engineering materials, and various strengthening and toughening strategies have been developed from the dislocation motion perspectives. Metallic glasses (MGs) have demonstrated great potentials owing to their unique properties; however, their structural applications are strictly limited. One of the key problems is that the traditional strengthening and toughening strategies and mechanisms are not applicable in MGs due to the absence of dislocations and crystalline microstructures. Here, we show that the strength and toughness, or equivalently the shear modulus and Poisson's ratio, are invariably mutually exclusive in MGs. Accordingly, the MGs can be categorized into four groups with different levels of integrated mechanical properties. It is further revealed that the conflicts originate fundamentally from the atomic bonding structures and the levels of strength-toughness combinations are indeed dominated by the bulk modulus. Moreover, we propose novel strategies for optimizing the mechanical properties of MGs from the elastic perspectives. We emphasize the significance of developing high bulk modulus MGs to achieve simultaneously both high strength and good toughness and highlight the elastic opportunities for strengthening and toughening materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Aerobraking at Venus and Mars: A Comparison of the Magellan and Mars Global Surveyor Aerobraking Phases

On February 4, 1999 the Mars Global Surveyor spacecraft became the second spacecraft to successfully aerobrake into a nearly circular orbit about another planet. This paper will highlight some of the similarities and differences between the aerobraking phases of this mission and the first mission to use aerobraking, the Magellan mission to Venus. Although the Mars Global Surveyor (MGS) spacecraft was designed for aerobraking and the Magellan spacecraft was not, aerobraking MGS was a much more challenging task than aerobraking Magellan, primarily because the spacecraft was damaged during the initial deployment of the solar panels. The MGS aerobraking phase had to be completely redesigned to minimize the bending moment acting on a broken yoke connecting one of the solar panels to the spacecraft. Even if the MGS spacecraft was undamaged, aerobraking at Mars was more challenging than aerobraking at Venus for several reasons. First, Mars is subject to dust storms, which can significantly change the temperature of the atmosphere due to increased solar heating in the low and middle altitudes (below 50 km), which in turn can significantly increase the density at the aerobraking altitudes (above 100 km). During the first part of the MGS aerobraking phase, a regional dust storm was observed to have a significant and very rapid effect on the entire atmosphere of Mars. Computer simulations of global dust storms on Mars indicate that even larger density increases are possible than those observed during the MGS aerobraking phases. For many aerobraking missions, the duration of the aerobraking phase must be kept as short as possible to minimize the total mission cost. For Mars missions, a short aerobraking phase means that there will be less margin to accommodate atmospheric variability, so the operations team must be ready to propulsively raise periapsis by tens of kilometers on very short notice. This issue was less of a concern on Venus, where the thick lower atmosphere and the slow planet rotation resulted in more predictable atmospheric densities from one orbit to the next.

Lyons, Daniel T.↗

Uncovering metallic glasses hidden vacancy-like motifs using machine learning

Vacancies are a ubiquitous type of defect in crystalline materials that can affect their properties and behavior, including atomic diffusivity, deformation processes, thermal conductivity, and electrical conductivity. While well-defined in crystals, it is challenging to identify such topological footprints in the amorphous structure of metallic glasses (MGs). Here, we uncover an unforeseen vacancy-like structural motif named Q7, which refers to an atomic Voronoi polyhedron with seven quadrangular faces, by investigating MG local atomic configurations with the help of machine learning. The Q7 motif exhibits characteristics similar to crystalline vacancies and plays a significant role in short-range structural disorder in MGs. The atoms at the center of the Q7 motif display larger local entropy, atomic volume, and local tension. Additionally, its concentration follows an Arrhenius-like relationship with temperature, accurately indicating the glass transition temperature, and is strongly correlated with the yield and failure of MGs during mechanical deformation. The discovery of the Q7 motif provides new insights into understanding the intricate relationship between local disorder and structural relaxation in MGs, offering a remarkable ability to predict their thermal and mechanical behavior. This potentially paves the way for enhancements in the design and manufacturing processes of MGs and other amorphous materials.

36 MATERIALS SCIENCE↗

Effects of rejuvenation modes on the microstructures and mechanical properties of metallic glasses

This study systematically investigates the effects of three rejuvenation modes, namely biaxial loading, thermal pressure loading, and cryogenic thermal cycling, on the microstructures and mechanical properties of Cu 64 Zr 36 metallic glasses (MGs) using molecular dynamics (MD) simulations. The simulation results demonstrate that biaxial tension application during loading results in a rejuvenated glassy state with high strength. Specifically, we find that the yield stress, Young's modulus, and shear modulus of the rejuvenated glass obtained by biaxial tensile loading decreased by 2.8%, 2.1%, and 2.7%, respectively, compared to an as-cast MG reference. We also find that MGs achieve the greatest degree of rejuvenation, at the expense of strength, with the use of thermal pressure loading. Interestingly, the application of cryogenic thermal cycling results in a rejuvenated state with a lower strength drop compared to thermal pressure loading. Furthermore, analysis of the potential energy and medium-range-order (MRO) size indicates that the microstructures of MGs achieves a high-energy ordered glass state after thermal pressure loading, but a high-energy disordered glass state after biaxial tensile loading and cryogenic thermal cycling. Furthermore, these findings provide meaningful insights into the effect of rejuvenation modes on the microstructures and mechanical properties of MGs, as well as useful guidelines for designing MGs with high strength and superior plasticity for prospective applications in industry.

36 MATERIALS SCIENCE↗