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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Fuel Oxidizer Reaction Products (FORP) Contamination of Service Module (SM) and Release of N-nitrosodimethylamine(NDMA)in a Humid Environment from Crew EVA Suits Contaminated with FORP

The Service Module (SM) is an element of the Russian Segment of the International Space Station (ISS). One of the functions of the SM is to provide attitude control for the ISS using thrusters when the U.S. Control Moment Gyros (CMG's) must be desaturated. Prior to an Extravehicular Activity (EVA) on the Russian Segment, the Docking Compartment (DC1) is depressurized, as it is used as an airlock. When the DC1 is depressurized, the CMG's margin of momentum is insufficient and the SM attitude control thrusters need to fire to desaturate the CMG's. SM roll thruster firings induce contamination onto adjacent surfaces with Fuel Oxidizer Reaction Products (FORP). FORP is composed of both volatile and non-volatile components. One of the components of FORP is the potent carcinogen N-nitrosdimethylamine (NDMA). Since the EVA crewmembers often enter the area surrounding the thrusters for tasks on the aft end of the SM and when translating to other areas of the Russian Segment, the presence of FORP is a concern. This paper will discuss FORP contamination of the SM surfaces, the release of NDMA in a humid environment from crew EVA suits, if they happen to be contaminated with FORP, and the toxicological risk associated with the NDMA release.

Schmidl, William↗

Inadvertently programmed bits in Samsung 128 Mbit flash devices: a flaky investigation

JPL's X2000 avionics design pioneers new territory by specifying a non-volatile memory (NVM) board based on flash memories. The Samsung 128Mb device chosen was found to demonstrate bit errors (mostly program disturbs) and block-erase failures that increase with cycling. Low temperature, certain pseudo- random patterns, and, probably, higher bias increase the observable bit errors. An experiment was conducted to determine the wearout dependence of the bit errors to 100k cycles at cold temperature using flight-lot devices (some pre-irradiated). The results show an exponential growth rate, a wide part-to-part variation, and some annealing behavior.

flash memory program disturb wearout erase fail re↗

Evaluation of Radiation Effects in Flash Memories

Features of flash memories: Flash memories are non-volatile; that is they do not require power to retain the information in its memory. They can be erased and written to while the device is still in the circuit.

Radiation effects↗

Development and Testing of the Contaminant Insensitive Sublimator

Sublimators have been used for heat rejection for a variety of space applications including the Apollo Lunar Module and the Extravehicular Mobility Unit (EMU). Some of the attractive features of sublimators are that they are compact, lightweight, and self-regulating. One of the drawbacks of previous designs has been sensitivity to non-volatile contamination in the feedwater, which can clog relatively small pores (approx.3-6 microns) in the porous plates where ice forms and sublimates. A new design that is less sensitive to contaminants is being developed at the Johnson Space Center. This paper describes the design, fabrication, and testing of the Contaminant Insensitive Sublimator (CIS) Engineering Development Unit (EDU).

Leimkuehler, Thomas O.↗

An Evaluation of the Vapor Phase Catalytic Ammonia Removal Process for Use in a Mars Transit Vehicle

An experimental program has been developed to evaluate the potential of the Vapor Phase Catalytic Ammonia Reduction (VPCAR) technology for use as a Mars Transit Vehicle water purification system. Design modifications which will be required to ensure proper operation of the VPCAR system in reduced gravity are also evaluated. The VPCAR system is an integrated wastewater treatment technology that combines a distillation process with high temperature catalytic oxidation. The distillation portion of the system utilizes a vapor compression distillation process to provide an energy efficient phase change separation. This portion of the system removes any inorganic salts and large molecular weight, organic contaminates, i.e., non-volatile, from the product water stream and concentrates these contaminates into a byproduct stream. To oxidize the volatile organic compounds and ammonia, a vapor phase, high temperature catalytic oxidizer is used. This catalytic system converts these compounds along with the aqueous product into CO2, H2O, and N2O. A secondary catalytic bed can then be used to reduce the N2O to nitrogen and oxygen (although not evaluated in this study). This paper describes the design specification of the VPCAR process, the relative benefits of its utilization in a Mars Transit Vehicle, and the design modification which will be required to ensure its proper operation in reduced gravity. In addition, the results of an experimental evaluation of the processors is presented. This evaluation presents the processors performance based upon product water purity, water recovery rates, and power.

Flynn, Michael↗

Removal of Perfluorinated Grease Components from NTO Oxidizer

Perfluorinated greases are typically used as a thread lubricant in the assembly of non-welded nitrogen tetroxide (NTO) oxidizer systems. These greases, typically a perfluoroalkylether, with suspended polytetrafluoroethylene (PTFE) micro-powder, have attractive lubricating properties toward threaded components and are relatively chemically inert toward NTO oxidizers. A major drawback, however, is that perfluoroalkylether greases are soluble or dispersible in NTO oxidizers and can contaminate the propellant. The result is propellant that fails the non-volatile residue (NVR) specification analyses and that may have negative effects on test hardware performance and lifetime. Consequently, removal of the grease contaminants from NTO may be highly desirable. Methods for the removal of perfluorinated grease components from NTO oxidizers including distillation, adsorption, filtration, and adjustment of temperature are investigated and reported in this work. Solubility or dispersibility data for the perfluoroalkylether oil (Krytox(tm)143 AC) component of a perfluorinated grease (Krytox 240 AC) and for Krytox 240 AC in NTO were determined and are reported.

McClure, Mark B.↗

High sensitivity real-time NVR monitor

A real time non-volatile residue (NVR) monitor, which utilizes surface acoustic wave (SAW) resonators to detect molecular contamination in a given environment. The SAW resonators operate at a resonant frequency of approximately 200 MHz-2,000 MHz which enables the NVR monitor to detect molecular contamination on the order of 10.sup.-11 g-cm.sup.-2 to 10.sup.-13 g-cm.sup.2. The NVR monitor utilizes active temperature control of (SAW) resonators to achieve a stable resonant frequency. The temperature control system of the NVR monitor is able to directly heat and cool the SAW resonators utilizing a thermoelectric element to maintain the resonators at a present temperature independent of the environmental conditions. In order to enable the direct heating and cooling of the SAW resonators, the SAW resonators are operatively mounted to a heat sink. In one embodiment, the heat sink is located in between the SAW resonators and an electronic circuit board which contains at least a portion of the SAW control electronics. The electrical leads of the SAW resonators are connected through the heat sink to the circuit board via an electronic path which prevents inaccurate frequency measurement.

Bowers, William D.↗

A-site- and/or B-site-modified PbZrTiO3 materials and (Pb, Sr, Ca, Ba, Mg) (Zr, Ti, Nb, Ta)O3 films having utility in ferroelectric random access memories and high performance thin film microactuators

A modified PbZrTiO.sub.3 perovskite crystal material thin film, wherein the PbZrTiO.sub.3 perovskite crystal material includes crystal lattice A-sites and B-sites at least one of which is modified by the presence of a substituent selected from the group consisting of (i) A-site substituents consisting of Sr, Ca, Ba and Mg, and (ii) B-site substituents selected from the group consisting of Nb and Ta. The perovskite crystal thin film material may be formed by liquid delivery MOCVD from metalorganic precursors of the metal components of the thin film, to form PZT and PSZT, and other piezoelectric and ferroelectric thin film materials. The thin films of the invention have utility in non-volatile ferroelectric memory devices (NV-FeRAMs), and in microelectromechanical systems (MEMS) as sensor and/or actuator elements, e.g., high speed digital system actuators requiring low input power levels.

Roeder, Jeffrey F.↗

A-SITE-AND/OR B-SITE-MODIFIED PBZRTIO3 MATERIALS AND (PB, SR, CA, BA, MG) (ZR, TI,NB, TA)O3 FILMS HAVING UTILITY IN FERROELECTRIC RANDOM ACCESS MEMORIES AND HIGH PERFORMANCE THIN FILM MICROACTUATORS

A modified PbZrTiO.sub.3 perovskite crystal material thin film, wherein the PbZrTiO.sub.3 perovskite crystal material includes crystal lattice A-sites and B-sites at least one of which is modified by the presence of a substituent selected from the group consisting of (i) A-site substituents consisting of Sr, Ca, Ba and Mg, and (ii) B-site substituents selected from the group consisting of Nb and Ta. The perovskite crystal thin film material may be formed by liquid delivery MOCVD from metalorganic precursors of the metal components of the thin film, to form PZT and PSZT, and other piezoelectric and ferroelectric thin film materials. The thin films of the invention have utility in non-volatile ferroelectric memory devices (NV-FeRAMs), and in microelectromechanical systems (MEMS) as sensor and/or actuator elements, e.g., high speed digital system actuators requiring low input power levels.

Roeder, Jeffrey F.↗