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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Reduction of uranyl and uranyl-organic complexes mediated by magnetite and ilmenite: A combined electrochemical AFM and DFT study

Reduction of mobile aqueous uranyl complexes can be hindered by the strength of the uranyl-ligand complex and the resistivity of the complexes to electron transfer. Semiconducting solids, such as magnetite (Fe 3 O 4 ) and ilmenite (FeTiO 3 ), can facilitate otherwise-slow electron transfer between the reductant and oxidant, especially if these species are adsorbed on their surfaces as inner-sphere complexes. Electrons can then be shuttled through the surface or the structure. This process can be facilitated by either finding a new electron transfer path or by weakening or destroying the ligand-uranyl complex. Using in situ electrochemical atomic force microscopy (EC-AFM), we imaged reduction products of uranyl as mediated by magnetite and ilmenite in the absence or presence of the organic ligands, ethylenediaminetetraacetate (EDTA) and oxalate. In situ images of uranyl reduction show gradual nucleation and growth of reduced uranium on the mineral surfaces with decreasing reduction potentials. X-ray photoelectron spectroscopy (XPS) measurements indicate pentavalent uranium as the dominant uranium species resulting from uranyl reduction mediated by magnetite and ilmenite. The reduction potentials of uranyl-organic species relevant to our reaction system, (U VI O 2 ∙oxalate) 0 and (U VI O 2 ∙HEDTA) - , are derived using quantum–mechanical modeling and compared with the midpoint potentials obtained from cyclic voltammetry measurements. The spectroscopic, electrochemical, and computational data suggest that the catalysis of Fe-bearing minerals facilitates the reduction of uranyl-organic complexes. U(VI)-oxalate complexes are redox-active and participate directly in the reduction mediated by magnetite. In the presence of EDTA, reduction of uranyl may proceed in concert with ligand exchange between metals (i.e., U and Fe) on the mineral surface. Finally, the proposed mechanism is the breaking of uranyl-organic bonds upon interaction with the mineral surface followed by the formation of Fe-organic bonds, thereby allowing the reduction of hexavalent uranyl to pentavalent one.

58 GEOSCIENCES↗
NASA NTRS2006

Electronics Shielding and Reliability Design Tools

It is well known that electronics placement in large-scale human-rated systems provides opportunity to optimize electronics shielding through materials choice and geometric arrangement. For example, several hundred single event upsets (SEUs) occur within the Shuttle avionic computers during a typical mission. An order of magnitude larger SEU rate would occur without careful placement in the Shuttle design. These results used basic physics models (linear energy transfer (LET), track structure, Auger recombination) combined with limited SEU cross section measurements allowing accurate evaluation of target fragment contributions to Shuttle avionics memory upsets. Electronics shielding design on human-rated systems provides opportunity to minimize radiation impact on critical and non-critical electronic systems. Implementation of shielding design tools requires adequate methods for evaluation of design layouts, guiding qualification testing, and an adequate follow-up on final design evaluation including results from a systems/device testing program tailored to meet design requirements.

Wilson, John W.↗
NASA NTRS1992

Scanning electron microscope observations of brine shrimp larvae from space shuttle experiments

Brine shrimp are encysted as gastrula stage embryos, and may remain dehydrated and encysted for years without compromising their viability. This aspect of brine shrimp biology is desirable for studying development of animals during space shuttle flight, as cysts placed aboard a spacecraft may be rehydrated at the convenience of an astronaut, guaranteeing that subsequent brine shrimp development occurs only on orbit and not on the pad during launch delays. Brine shrimp cysts placed in 5 ml syringes were rehydrated with salt water and hatched during a 9 day space shuttle mission. Subsequent larvae developed to the 8th larval stage in the sealed syringes. We studied the morphogenesis of the brine shrimp larvae and found the larvae from the space shuttle experiments similar in rate of growth and extent of development, to larvae grown in sealed syringes on the ground. Extensive differentiation and development of embryos and larvae can occur in a microgravity environment.

short duration↗
NASA NTRS1982

Studies of beam plasma interactions in a space simulation chamber using prototype Space Shuttle instruments

In March, 1981, electron beam experiments were conducted in a large space simulation chamber using equipment destined to be flown aboard NASA's Office of Space Science-1 pallet (OSS-1). Two major flight experiments were involved. They include the Vehicle Charging and Potential (VCAP) experiment and the Plasma Diagnostics Package (PDP). Apparatus connected with VCAP included a Fast Pulse Electron Gun (FPEG), and a Charge and Current Probe (CCP). A preliminary view is provided of the results obtained when the electron emissions were held steady over relatively long periods of time such that steady state conditions could be obtained with respect to the electron beam interaction with the neutral gases and plasma of the vacuum chamber. Of particular interest was the plasma instability feature known as the Beam Plasma Discharge. For the present experiments the FPEG was used in a dc mode with a range of currents of 2 to 80 mA at a beam energy of 970 eV. Attention is given to the emissions of VLF and HF noise associated with the dc beam.

Banks, P. M.↗
NASA NTRS1996

Improved Supportability Analysis

The University of Dayton is pleased to submit this report to the National Aeronautics and Space Administration (NASA), Langley Research Center, which updates recently developed computer models and data bases used in determining operational capabilities and support requirements during the conceptual design of proposed space systems. This research has resulted in some revisions of the reliability and maintainability (R&M) model, the development of several electronic data bases which capture the original data used in the R&M model, the collection of more recent R&M aircraft data and the integration of new shuttle data into the electronic data base and the R&M model. Descriptions of the model updates and of the electronic data bases are the subject of this report. Other details concerning the R&M model and the O&S costing model may be found in previous reports accomplished under this grant (NASA Research Grant NAG- 1-1327) which are referenced in paragraph 1.3.

Ebeling, Charles E.↗
NASA NTRS1987

Electromagnetic fields from pulsed electron beam experiments in space - Spacelab-2 results

During the Spacelab-2 mission a small satellite carrying various plasma diagnostic instruments was released from the Shuttle to coorbit at distances up to 300 m. During a magnetic conjunction of the Shuttle and the satellite an electron beam modulated at 1.22 kHz was emitted from the Shuttle during a 7 min period. The spatial structure of the electromagnetic fields generated by the beam was observed from the satellite out to a distance of 153 m perpendicular to the beam. The magnetic field amplitude of the strongest harmonics were comparable to the amplitude of simultaneously observed whistlers, while the electric field amplitudes were estimated to 1-10 mV/m.

Bush, R. I.↗
NASA NTRS1975

The prevention of electronical breakdown and electrostatic voltage problems in the space shuttle and its payloads. Part 2: Design guides and operations considerations

The specific electrical discharge problems that can directly affect the shuttle vehicle and its payloads are addressed. General design guidelines are provided to assist flight hardware managers in minimizing these kinds of problems. Specific data are included on workmanship practices and system testing while in low pressure environments. Certain electrical discharge problems that may be unique to the design of the shuttle vehicle itself and to its various mission operational models are discussed.

Whitson, D. W.↗
NASA NTRS1989

The plasma wake of the Shuttle Orbiter

One of the objectives of the Plasma Diagnostics Package (PDP) instrumentation on Spacelab 2 was to obtain information about the plasma wake of the Shuttle Orbiter. Plasma density and electron temperature data are presented, which were obtained while the PDP was attached to the Shuttle remote manipulator system, and while the PDP was a free-flying satellite. Wake crossings by the PDP from about 40 m to about 240 m behind the Orbiter provide information about the structure of the mid and far wake of the Orbiter. As expected, the wake is characterized by density depressions, relative to the ambient ionospheric plasma, and by enhancements of the electron temperature, particularly in the near and mid wake. The observed electron temperature enhancements appear to be in line with previous spacecraft observations.

Murphy, G. B.↗
NASA NTRS1990

Injection of an overdense electron beam in space

A three-dimensional particle simulation model is used to study the injection and propagation of an overdense electron beam in the vicinity of a conductor in space. Beam electrons with a density of more than 100 times the ambient electron density are modeled using large-scale plasma simulations; in these simulations the surface area of the conductor is several thousands times that of the beam cross section at the injection point. The parameters of the simulations are chosen to allow the realistic simulation of active space experiments such as the Space Shuttle's Spacelab 2 electron beam mission. These simulations confirm space observations that an overdense electron beam can at least partially escape the near vicinity of the spacecraft, even in a fully ionized plasma. Once they have escaped from the vicinity of the spacecraft, these beam electrons should be able to propagate away freely until their energy is dissipated. It is suggested that such large-scale simulations could be useful in interpreting data from space experiments.

Okuda, Hideo↗
NASA NTRS1985

Artificial plasma density structures produced by energetic electron beams from rockets and spacecraft

Recent rocket and Space Shuttle experiments have demonstrated the capability to launch electron beams of moderate power (100 W to 10 kW) into the earth's ionosphere and magnetosphere. This letter describes how such beams, when fired from rockets or satellites, can create significant ionization in the E- and F-regions of the ionosphere. Through proper selection of beam-related parameters, an interesting variety of plasma density structures, including plasma sheets and plasma filaments, can be created and studied over periods of 30 minutes to 1 hour, depending on the rate of plasma recombination and the density of the ambient plasma. Observations of these structures can give new information relating to the physics of plasma density structures in the ionosphere, and the effects these features have upon the scattering of radio waves. It is also possible that observations of the density structures will provide a new means for studying neutral winds and electrodynamic phenomena in the ionosphere.

Banks, P. M.↗
NASA NTRS1982

Cost effective development of a Shuttle-based astronomical instrument control system

The high level language FORTH is used for the electronic control of the Space Shuttle-based Ultraviolet Imaging Telescope, in a flight computer system which minimizes costs. The greater part of the breadboard version of the flight computer is assembled from commercially available components, reducing novel circuit design features and permitting simultaneous development of both hardware and software. The commercial boards are then refabricated on aluminum core heat conducting stock, using high reliability parts to produce the flight versions of the system. The system's ground support equipment employs a MINC-25 minicomputer which performs such functions as flight computer software development, PROM programming, test and integration support, and flight operations support. The implementation of these concepts in flight computer telescope controls is described.

Parise, R. A.↗
NASA NTRS1986

Measurements of plasma parameters in the vicinity of the Space Shuttle

A Langmuir probe flown as part of the Plasma Diagnostics Package aboard the third Space Shuttle flight was used to determine electron densities, temperatures, and plasma potential in the vicinity of the Shuttle Orbiter. Measurements taken both in the cargo bay and 10 m above the cargo bay on the Remote Manipulator System arm are consistent with small satellite and laboratory results, in that reduced densities and elevated temperatures are observed in the Shuttle wake. The primary difference in the Shuttle measurements is one of magnitude; i.e., orders-of-magnitude density decreases and factor-of-five temperature enhancements. Analysis of data taken in (Delta N)/N turbulence can be as high as a few percent, and the most intense turbulence seems to occur near regions with a steep gradient in plasma pressure.

Murphy, G.↗
NASA NTRS1976

The Space Shuttle's testing gauntlet

The Space Shuttle verification program is detailed, with verification network flowcharts. Performance qualification tests, life endurance tests, structural verification tests, and vibration/dynamic tests of components, subsystems, and major systems at various test levels are dealt with. Ground tests, static firings of the Shuttle main engine, external-tank separation tests, ground vibration tests of vehicle mated to external tank, and main propulsion tests and test scheduling are described. Functions of the Shuttle avionics integration laboratory and electronic systems test laboratory are discussed. Test preparations and procedures for orbital flight testing, launch pad tests, and Shuttle approach- and landing-tests are described.

Mcintosh, G. P.↗
NASA NTRS1986

Whistler-mode radiation from the Spacelab 2 electron beam

During the Spacelab 2 mission the Plasma Diagnostics Package (PDP) performed a fly-around of the Shuttle at distances of up to 300 meters while an electron beam was being ejected from the Shuttle. A magnetic conjunction of the Shuttle and the PDP while the electron gun was operating in a steady (DC) mode is discussed. During this conjunction, the PDP detected a clear funnel-shaped emission that is believed to be caused by whistler-mode emission from the beam. Ray-path calculations show that the shape of the funnel can be accounted for by whistler-mode waves propagating near the resonance cone. Because the beam and waves are propagating in the same direction, the radiation must be produced by a Landau interaction with the beam. Other types of waves generated by the beam are also described.

Gurnett, D. A.↗
DOE OSTI2024

A reversible four-electron Sn metal aqueous battery

Sn is a promising metal anode for aqueous batteries, with up to four-electron redox available per atom (903 mAh g −1 Sn ). However, practically harnessing the four-electron Sn(OH) 6 2− /Sn reversibility remains challenging due to limited mechanistic understanding. Here, in this study, we reveal a kinetically asymmetric redox pathway involving a successive four-electron plating and a stepwise 2 + 2 electron stripping through a Sn(OH) 3 − intermediate. The crossover of Sn(OH) 3 − induces a reversible self-discharge that reduces Coulombic efficiency but does not impact cyclability, demonstrated by four-electron Sn-Ni full cells that sustain >800 h of stable cycling. By tuning the ion selectivity of the separator to suppress Sn(OH) 3 − crossover while allowing OH − transport, we further demonstrate high Sn utilization (67%) and high energy density (143.1 Wh L −1 cell). The results provide key understandings of the tradeoffs in engineering reversible multi-electron metal anodes and define a new benchmark for practical energy density that exceeds any Sn-based aqueous batteries to date.

SN anode↗
NASA NTRS1996

Tectonics and Volcanism of East Africa as Seen Using Remote Sensing Imagery

The East African Rift is the largest area of active continental geology. The tectonics of this area has been studied with remote sensing data, including AVHRR, Landsat MSS and TM, SPOT, and electronic still camera from Shuttle. Lineation trends have been compared to centers of volcanic and earthquake activity as well as the trends shown on existing geologic maps. Remote sensing data can be used effectively to reveal and analyze significant tectonic features in this area.

Hutt, Duncan John↗
NASA NTRS1996

STS-75 Flight Day 1

On this first day of the STS-75 mission, the flight crew, Cmdr. Andrew Allen, Pilot Scott Horowitz, Payload Cmdr. Franklin Chang-Diaz, Payload Specialist Umberto Guidoni (Italy), and Mission Specialists Jeffrey Hoffman, Maurizio Cheli (ESA) and Claude Nicollier (ESA), were shown performing pre-launch and launching activities. This international space mission's primary objective is the deployment of the Tethered Satellite System Reflight (TSS-1R) to a 12 mile length from the shuttle, a variety of experiments, and the satellite retrieval. These experiments include: Research on Orbital Plasma Electrodynamics (ROPE); TSS Deployer Core Equipment and Satellite Core Equipment (DCORE/SCORE); Research on Electrodynamic Tether Effects (RETE); Magnetic Field Experiments for TSS Missions (TEMAG); Shuttle Electrodynamic Tether Systems (SETS); Shuttle Potential and Return Electron Experiment (SPREE); Tether Optical Phenomena Experiment (TOP); and Observations at the Earth's Surface of Electromagnetic Emissions by TSS (OESSE). The mission's secondary objectives were those experiments found in the United States Microgravity Payload-3 (USMP-3), which include: Advanced Automated Directional Solidification Furnace (AADSF); Material pour l'Etude des Phenomenes Interessant la Solidification sur Terre et en Orbite (MEPHISTO); Space Acceleration Measurement System (SAMS); Orbital Acceleration Research Experiment (OARE); Critical Fluid Scattering Experiment (ZENO); and Isothermal Dendritic Growth Experiment (IDGE).

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