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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Analysis of Phase Separation in Czochralski Grown Single Crystal Ilmenite

Ilmenite (FeTiOs) is a wide bandgap semiconductor with an energy gap of 2.58 eV. Ilmenite has properties suited for radiation tolerant applications, as well as a variety of other electronic applications. Single crystal ilmenite has been grown from the melt using the Czochralski method. Growth conditions have a profound effect on the microstructure of the samples. Here we present data from a variety of analytical techniques which indicate that some grown crystals exhibit distinct phase separation during growth. This phase separation is apparent for both post-growth annealed and unannealed samples. Under optical microscopy, there appear two distinct areas forming a matrix with an array of dots on order of 5 pm diameter. While appearing bright in the optical micrograph, atomic force microscope (AFM) shows the dots to be shallow pits on the surface. Magnetic force microscope (MFM) shows the dots to be magnetic. Phase identification via electron microprobe analysis (EMPA) indicates two major phases in the unannealed samples and four in the annealed samples, where the dots appear to be almost pure iron. This is consistent with micrographs taken with a scanning probe microscope used in the magnetic force mode. Samples that do not exhibit the phase separation have little or no discernible magnetic structure detectable by the MFM.

Wilkins, R.↗

MOVPE of GaSb/InGaAsSb Multilayers and Fabrication of Dual Band Photodetectors

Metalorganic vapor phase epitaxy (MOVPE) of GaSb/InGaAsSb multilayer thin films and fabrication of bias-selectable dual band photodetectors are reported. For the dual band photodetectors the short wavelength detector, or the upper p- GaSb/n-GaSb junction photodiode, is placed optically ahead of the long wavelength one, or the lower photodiode. The latter is based on latticed-matched In0.13Ga0.87As0.11Sb0.89 with bandgap near 0.6 eV. Specifically, high quality multilayer thin films are grown sequentially from top to bottom as p+-GaSb/p-GaSb/n-GaSb/n-InGaAsSb/p-InGaAsSb/p-GaSb on undoped p-type GaSb substrate, and as n-GaSb/p-GaSb/p-InGaAsSb/n-InGaAsSb/n-GaSb on Te-doped n-type GaSb substrate respectively. The multilayer thin films are characterized by optical microscope, atomic force microscope (AFM), electron microprobe analyses etc. The photodiode mesa steps are patterned by photolithography with wet chemical etching and the front metallization is carried out by e-beam evaporation with Pd/Ge/Au/Ti/Au to give ohmic contact on both n- and p-type Sb based layer surfaces. Dark I-V measurements show typical diode behavior for both the upper and lower photodiodes. The photoresponsivity measurements indicate that both the upper and lower photodiodes can sense the infrared illumination corresponding to their cutoff wavelengths respectively, comparable with the simulation results. More work is underway to bring the long wavelength band to the medium infrared wavelength region near 4 micrometers.

Xiao, Ye-Gao↗

Single-sided lateral-field and phototransistor-based optoelectronic tweezers

Described herein are single-sided lateral-field optoelectronic tweezers (LOET) devices which use photosensitive electrode arrays to create optically-induced dielectrophoretic forces in an electric field that is parallel to the plane of the device. In addition, phototransistor-based optoelectronic tweezers (PhOET) devices are described that allow for optoelectronic tweezers (OET) operation in high-conductivity physiological buffer and cell culture media.

Ohta, Aaron↗

A Comparison of Bearing Measurements to Surface Features Generated Using Stereophotoclinometry and Surface Feature Navigation Techniques

The Origins Spectral Interpretation Resource Identification Security Regolith Explorer (OSIRIS-REx) mission to the asteroid Bennu completed successful two-and-a-half year proximity operations in May 2021. The mission comprehensively mapped Bennu at unprecedented detail and collected a sample of Bennu’s surface to return to Earth. Throughout proximity operations, the OSIRIS-REx navigation team used the maps made of Bennu’s surface to navigate in the Bennu environment with high accuracy through the use of precise and accurate optical navigation data, radiometric data, and force modelling. The primary type of optical navigation measurements extracted from the images captured by OSIRIS-REx (particularly after first entering orbit around Bennu) were observations of known features on Bennu’s surface. Two related but different techniques/tools were used to extract these observations from the images: the Goddard Image Analysis and Navigation Tool Surface Feature Navigation (GIANT SFN) and Stereophotoclinometry (SPC) Autoregister. In this paper we compare the differences between the observables extracted using GIANT SFN and SPC Autoregister, explain the differences, and discuss where each technique is best suited.

Andrew Liounis↗

The Use of Remote Sensing to Resolve the Aerosol Radiative Forcing

Satellites are used for remote sensing of aerosol optical thickness and optical properties in order to derive the aerosol direct and indirect radiative forcing of climate. Accuracy of the derived aerosol optical thickness is used as a measure of the accuracy in deriving the aerosol radiative forcing. Several questions can be asked to challenge this concept. Is the accuracy of the satellite-derived aerosol direct forcing limited to the accuracy of the measured optical thickness? What are the spectral bands needed to derive the total aerosol forcing? Does most of the direct or indirect aerosol forcing of climate originate from regions with aerosol concentrations that are high enough to be detected from space? What should be the synergism ground-based and space-borne remote sensing to solve the problem? We shall try to answer some of these questions, using AVIRIS airborne measurements and simulations.

Kaufman, Y. J.↗

Simulation of collisional transport processes and the stability of planetary rings

The utility of the phase-space fluid method for the study of planetary ring dynamics is presently demonstrated through the numerical solution of a model kinetic equation for a flattened Keplerian disk. Attention is given to ringlets composed of single-sized particles, as well as to ringlets composed of two different-sized particles; in the latter case, the ringlets evolve in such a way that the lighter particles are confined by the heavier ones. The results obtained indicate that some natural process may sharpen the optical depth profile of edges even without an external forcing mechanism, and that intermediate optical depths are dynamically preferred in some cases.

Brophy, Thomas G.↗

Measuring Roughnesses Of Optical Surfaces

Report discusses use of scanning tunneling microscopy and atomic force microscopy to measure roughnesses of optical surfaces. These techniques offer greater spatial resolution than other techniques. Report notes scanning tunneling microscopes and atomic force microscopes resolve down to 1 nm.

Coulter, Daniel R.↗

Collaborative Research: Improved Efficiency and Coupling of the Radiation Code in the ACME Earth System Model (Final Report)

The complexity of radiative transfer, its importance to the exchange of energy in the climate system, and its high computational cost establishes importance of an accurate and efficient radiative transfer parameterization for climate simulation. Previous work by the proposing team at AER led to the development of the radiation code, RRTMG, which has been widely accepted by the global modeling community as a fast and accurate advancement over the previous generation of radiation codes. It has been in use in the NCAR CESM for many years, and it has been implemented in the initial version the DOE E3SM model. However, its computational cost remains high relative to other components in part due to its complexity and to its inefficient use of modern optimization strategies, and this project helped address this limitation for the code’s application in E3SM. Under other funding, the Investigators of this project led an effort to develop a high-performance broadband radiation code, called RTE+RRTMGP, which is a completely restructured code that will take advantage of modern computational capabilities to enhance its performance while retaining the strengths and accuracy of the original code. Designed to perform over a range of computer architectures, RTE+RRTMGP makes extensive use of Fortran 2003 features to improve both its efficiency and its use of memory. RTE+RRTMGP is expected to be adopted in the next generation of RTE+RRTMGP. This project allowed for advancements to the code’s computational capabilities and adding new and enhanced features. This included revising RTE+RRTMGP to run on GPU processors, analysis of and improvements to the code’s timing, modifying the gas optics in RRTMGP to increase the code’s accuracy, extensive validation of computed fluxes, heating rates and forcings, generating a cloud optical property and vertical sampling capabilities for RTE+RRTMGP, implementing a fast and accurate longwave scattering capability, and groundwork for the inclusion of a capability to specify solar variability. Many of the accomplishment in this project necessitated significant collaboration with the E3SM development team. The result of this project was optimization of a key physical component (radiative transfer calculations) of E3SM, directly supporting E3SM’s overarching global modeling objectives. More broadly, this project provided overall advancements in the use of radiative transfer calculations in atmospheric modeling and simulation, particularly for climate.

58 GEOSCIENCES↗

Active liquid crystals powered by force-sensing DNA-motor clusters

Significance Single-molecule techniques have elucidated how isolated molecular motors generate piconewton forces with unprecedented detail. However, in diverse biological and synthetic settings, force-generating proteins collectively power nonequilibrium dynamics, including continuous large-scale rearrangements and persistent fluid flows. Characterizing motor-generated forces in these dense and dynamical environments remains a challenge. We assembled a reversible DNA-based force-sensing probe that, by an optical readout, reveals the molecular arrangements and the force loads experienced by kinesin motors. These probes provide insight into motor-generated forces that collectively power the unique dynamics of microtubule-based active nematics, a noteworthy example of an internally driven active matter system. DNA-based force probes can be extended to study forces and stresses in various synthetic systems as well as diverse cellular environments.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Impact of COVID-19-related Air Traffic Reductions on the Coverage and Radiative Effects of Linear Persistent Contrails over Conterminous United States and Surrounding Oceanic Routes

The radiative effects of the large-scale air traffic slowdown during Apr and May 2020 due to the international response to the COVID-19 pandemic are estimated by comparing the coverage (CC), optical properties, and radiative forcing of persistent linear contrails over the conterminous United States and two surrounding oceanic air corridors during the slowdown period and a similar baseline period during 2018 and 2019 when air traffic was unrestricted. The detected CC during the slowdown period decreased by an area-averaged mean of 41% for the three analysis boxes. The retrieved contrail optical properties were mostly similar for both periods. Total shortwave contrail radiative forcings during the slowdown were 34 and 42% smaller for Terra and Aqua, respectively. The corresponding differences for longwave contrail radiative forcing were 33% for Terra and 40% for Aqua. To account for the impact of any changes in the atmospheric environment between baseline and slowdown periods on detected CC amounts, the contrail formation potential (CFP) was computed from reanalysis data. In addition, a filtered CFP (fCFP) was also developed to account for factors that may affect contrail formation and visibility of persistent contrails in satellite imagery. The CFP and fCFP were combined with air traffic density data to create empirical models that estimated CC during the baseline and slowdown periods and were compared to the detected CC. The models confirm that decreases in CC and radiative forcing during the slowdown period were mostly due to the reduction in air traffic, and partly due to environmental changes.

contrails↗

Soil Analysis Micro-Mission Concepts Derived from the MSP 2001 Mars Environmental Compatibility Assessment (MECA)

The Mars Environmental Compatibility Assessment (MECA) will evaluate the Martian environment for soil and dust-related hazards to human exploration as part of the Mars Surveyor Program 2001 Lander. The integrated MECA payload contains a wet-chemistry laboratory, a microscopy station, an electrometer to characterize the electrostatic environment, and arrays of material patches to study abrasion and adhesion. Heritage will be all-important for low cost micro-missions, and adaptations of instruments developed for the Pathfinder, '98 and '01 Landers should be strong contenders for '03 flights. This talk has three objectives: (1) Familiarize the audience with MECA instrument capabilities; (2) present concepts for stand-alone and/or mobile versions of MECA instruments; and (3) broaden the context of the MECA instruments from human exploration to a comprehensive scientific survey of Mars. Due to time limitations, emphasis will be on the chemistry and microscopy experiments. Ion-selective electrodes and related sensors in MECA's wet-chemistry laboratory will evaluate total dissolved solids, redox potential, pH, and the concentration of many soluble ions and gases in wet Martian soil. These electrodes can detect potentially dangerous heavy-metal ions, emitted pathogenic gases, and the soil's corrosive potential, and experiments will include cyclic voltammetry and anodic stripping. For experiments beyond 2001, enhancements could allow multiple use of the cells (for mobile experiments) and reagent addition (for quantitative mineralogical and exobiological analysis). MECA's microscopy station combines optical and atomic-force microscopy (AFM) in an actively focused, controlled illumination environment to image particles from millimeters to nanometers in size. Careful selection of substrates allows controlled experiments in adhesion, abrasion, hardness, aggregation, magnetic and other properties. Special tools allow primitive manipulation (brushing and scraping) of samples. Soil particle properties including size, shape, color, hardness, adhesive potential (electrostatic and magnetic), will be determined using an array of sample receptacles and collection substrates. The simple, rugged atomic-force microscope will image in the submicron size range and has the capability of performing a particle-by-particle analysis of the dust and soil. Future implementations might enhance the optical microscopy with spectroscopy, or incorporate advanced AFM techniques for thermogravimetric and chemical analysis.

Hecht, M. H.↗

Optical Properties of High Area-to-Mass Objects at GEO

There exists at GEO a significant population of faint debris (R > 15th magnitude) with high area-to-mass ratios (AMR) (1 to 30 sq m/kg). Their orbital elements (particularly eccentricity and inclination) are observed to change on the time-scale of a week. The consensus is that these objects may be fragments of multi-layer insulation (MLI) blankets. Their orbits are primarily perturbed by solar radiation pressure. In this paper we will report preliminary results from an international collaboration to investigate the unresolved optical properties of these objects. This population was originally discovered by the ESA Space Debris Telescope, and the bulk of the objects to be described here are based on discoveries made with this telescope. Additional objects were supplied by both Russia and the US Air Force. Follow-up optical observations were obtained for a sample of a dozen objects by MODEST (the Michigan Orbital DEbris Survey Telescope) located at Cerro Tololo Inter-American Observatory in Chile. Sequences of calibrated observations in filters B, V, Broad R, and I were obtained under photometric conditions. Multi-color photometric observations in B, V, R, and I band of the same objects were also acquired at the Zimmerwald 1-meter telescope, located near Bern, Switzerland. Light curves of selected high AMR objects will be shown with a temporal resolution of a few seconds and typically span about 10 minutes. Photometric observations of these objects were acquired at the Crimean Astrophysical Observatory (CrAO). This data set includes light curves of objects having high variability of brightness and observed with 2.6 m and 0.64 m class instruments. We will present an analysis of the observed magnitudes and colors, and their correlations (or lack of correlation) with orbital elements, and with predicted values for MLI fragments. This represents the first such collaborative observational program on faint debris at GEO.

Seitzer, Patrick↗

The albedo field and cloud radiative forcing produced by a general circulation model with internally generated cloud optics

A general circulation model (GCM) study is presented in which cloud radiative properties are computed from cloud liquid water content inferred from the GCM hydrological cycle. Model-generated and satellite albedos are in rough agreement. Analysis of the cloud radiative forcing indicates that cloud albedo effects overcome cloud infrared opacity effects in most regions. Both computed and observed albedo of clouds decrease from low to high altitudes. The model with variable cloud optics produces significantly different regional albedos from the same one with fixed cloud optics, especially over the tropics. The cloud droplet size distribution also has a significant impact on the model albedos. The temperature of the tropical upper troposphere is somewhat sensitive to the microphysical characteristics of the model cirrus clouds.

Charlock, T. P.↗

Localized Plasmonic Heating for Single-Molecule DNA Rupture Measurements in Optical Tweezers

To date, studies on the thermodynamic and kinetic processes that underlie biological function and nanomachine actuation in biological- and biology-inspired molecular constructs have primarily focused on photothermal heating of ensemble systems, highlighting the need for probes that are localized within the molecular construct and capable of resolving single-molecule response. Here we present an experimental demonstration of wavelength-selective, localized heating at the single-molecule level using the surface plasmon resonance of a 15 nm gold nanoparticle (AuNP). Our approach is compatible with force-spectroscopy measurements and can be applied to studies of the single-molecule thermodynamic properties of DNA origami nanomachines as well as biomolecular complexes. We further demonstrate wavelength selectivity and establish the temperature dependence of the reaction coordinate for base-pair disruption in the shear-rupture geometry, demonstrating the utility and flexibility of this approach for both fundamental studies of local (nanometer-scale) temperature gradients and rapid and multiplexed nanomachine actuation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A Multimodel Assessment of the Influence of Regional Anthropogenic Emission Reductions on Aerosol Direct Radiative Forcing and the Role of Intercontinental Transport

In this study, we assess changes of aerosol optical depth (AOD) and direct radiative forcing (DRF) in response to the reduction of anthropogenic emissions in four major pollution regions in the Northern Hemisphere by using results from nine global models in the framework of the Hemispheric Transport of Air Pollution (HTAP). DRF at top of atmosphere (TOA) and surface is estimated based on AOD results from the HTAP models and AOD-normalized DRF (NDRF) from a chemical transport model. The multimodel results show that, on average, a 20% reduction of anthropogenic emissions in North America, Europe, East Asia, and South Asia lowers the global mean AOD (all-sky TOA DRF) by 9.2% (9.0%), 3.5% (3.0%), and 9.4% (10.0%) for sulfate, particulate organic matter (POM), and black carbon (BC), respectively. Global annual average TOA all-sky forcing efficiency relative to particle or gaseous precursor emissions from the four regions (expressed as multimodel mean +/- one standard deviation) is -3.5 +/-0.8, -4.0 +/- 1.7, and 29.5+/-18.1mW / sq m per Tg for sulfate (relative to SO2), POM, and BC, respectively. The impacts of the regional emission reductions on AOD and DRF extend well beyond the source regions because of intercontinental transport (ICT). On an annual basis, ICT accounts for 11 +/- 5% to 31 +/- 9% of AOD and DRF in a receptor region at continental or subcontinental scale, with domestic emissions accounting for the remainder, depending on regions and species. For sulfate AOD, the largest ICT contribution of 31 +/- 9% occurs in South Asia, which is dominated by the emissions from Europe. For BC AOD, the largest ICT contribution of 28 +/- 18% occurs in North America, which is dominated by the emissions from East Asia. The large spreads among models highlight the need to improve aerosol processes in models, and evaluate and constrain models with observations.

Europe↗