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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Collisional evolution of rotating, non-identical particles

Hameen-Anttila's (1984) theory of self-gravitating collisional particle disks is extended to include the effects of particle spin. Equations are derived for the coupled evolution of random velocities and spins, showing that friction and surface irregularity both reduce the local velocity dispersion and transfer significant amounts of random kinetic energy to rotational energy. Results for the equilibrium ratio of rotational energy to random kinetic energy are exact not only for identical nongravitating mass points, but also if finite size, self-gravitating forces, or size distribution are included. The model is applied to the dynamics of Saturn's rings, showing that the inclusion of rotation reduces the geometrical thickness of the layer of cm-sized particles to, at most, about one-half, with large particles being less affected.

Salo, H.↗

Light and Airy: A Simple Solution for Relativistic Quantum Acceleration Radiation

We study the quantum radiation of particle production by vacuum from an ultra-relativistic moving mirror (dynamical Casimir effect) solution that allows (possibly for the first time) analytically calculable time evolution of particle creation and an Airy particle spectral distribution. The reality of the beta Bogoliubov coefficients is responsible for the simplicity, and the mirror is asymptotically inertial at the speed of light, with finite energy production. We also discuss general relations regarding negative energy flux, the transformation to the 1-D Schrödinger equation, and the incompleteness of entanglement entropy.

79 ASTRONOMY AND ASTROPHYSICS↗

Energetic storm particle events in the outer heliosphere

The evolution of energetic particle events with increasing heliocentric distance is studied through events of Pioneers 10 and 11. Beyond 12 AU the events become the dominant type of solar particle event at 1 AU, and the combined effects of adiabatic cooling and volume expansion rule out the possibility that the particles represent the confinement of the original particle population behind the shock. It is not established whether the particles originate from the solar wind by injection via post-shock enhancements or are energetic solar particles further energized by the shock, although their very long lifetime favors the solar wind origin.

Mcdonald, F.↗

Particle size of several plutonium-238 oxide fuel samples from oxalate precipitation processes

Particle size of 238 PuO 2 powders is an important factor in determining the structural integrity of fuel pellets hot-pressed from the oxide powder. Understanding the evolution of particle size during aqueous processing is a first step in assuring control of particle size throughout the pellet formation process. Measured particle sizes are reported here, and discussed in terms of measured particle size changes occurring during calcining, observed aggregation of particulate, and particle morphology. Morphology and aggregation are related to surface energy, which governs granule formation and hot pressing behavior. Results are discussed in terms of reported dependence of oxide morphology on process temperatures and reagent concentrations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Reconnection and particle acceleration in 3D current sheet evolution in moderately-magnetized astrophysical pair plasma

Magnetic reconnection, a plasma process converting magnetic energy to particle kinetic energy, is often invoked to explain magnetic energy releases powering high-energy flares in astrophysical sources including pulsar wind nebulae and black hole jets. Reconnection is usually seen as the (essentially 2D) nonlinear evolution of the tearing instability disrupting a thin current sheet. To test how this process operates in 3D, we conduct a comprehensive particle-in-cell simulation study comparing 2D and 3D evolution of long, thin current sheets in moderately-magnetized, collisionless, relativistically-hot electron- positron plasma, and find dramatic differences. We first systematically characterize this process in 2D, where classic, hierarchical plasmoid-chain reconnection determines energy release, and explore a wide range of initial configurations, guide magnetic field strengths, and system sizes. We then show that 3D simulations of similar configurations exhibit a diversity of behaviours, including some where energy release is determined by the nonlinear relativistic drift-kink instability. Thus, 3D current-sheet evolution is not always fundamentally classical reconnection with perturbing 3D effects, but, rather, a complex interplay of multiple linear and nonlinear instabilities whose relative importance depends sensitively on the ambient plasma, minor configuration details, and even stochastic events. It often yields slower but longer-lasting and ultimately greater magnetic energy release than in 2D. Intriguingly, nonthermal particle acceleration is astonishingly robust, depending on the upstream magnetization and guide field, but otherwise yielding similar particle energy spectra in 2D and 3D. Though the variety of underlying current-sheet behaviours is interesting, the similarities in overall energy release and particle spectra may be more remarkable.

Gregory R. Werner↗

Multiscale Cryo Electron Microscopy Reveals Interfacial Degradation and Stabilization in Battery Electrodes

Electrochemical interfaces are dynamic systems, evolving based on their local environment and reactant surface structures. The electrode-electrolyte interface in Li-ion batteries can be protective, limiting parasitic reactions with the electrolyte to passivate the surface [1]. Additionally, this interphase has an impact on the Li-ion transport through that layer based on its composition, bonding environment, and thickness. These parameters are challenging to collect and may vary depending on the electrode surface site investigated relative to its spatial position in a coin cell. This study will detail a multiscale cryogenic electron microscopy approach where millimeter-scale cross-sections through the coin cell batteries were made using a cryogenic stage within a fs-laser plasma focused ion beam (laser PFIB) with complementary energy dispersive X-ray spectroscopy able to detect variations in the composition at electrode interfaces [2]. Microscale cross-sectioning and lamella sample preparation of battery electrodes was conducted at the Center for Integrated Nanotechnologies using a Ga-ion focused ion beam (FIB) with air-free and cryo-transfer [3], followed by nanoscale mapping of composition and bonding within the CEI through cryo-scanning transmission electron microscopy (cryo-STEM) electron energy loss spectroscopy [4]. This multiscale approach enabled identification of millimeter-scale features of a battery stack with visualization of degradation in electrodes such as cracks in cathode particles, gas evolution, and SEI evolution; microscale interfacial characteristics, such as heterogeneity in the SEI or barrier layer and identification of electrolyte networks to the electrode surfaces; and nanoscale measurement of the CEI thickness, mapping of transition metal bonding within the cathode particles to identify loss of active materials, and identification of beneficial electrolyte additives incorporated into the CEI structure. This multiscale approach allows for a statistical understanding of the primary mechanisms and parasitic degradation pathways that impact performance by limiting the ion transport pathways within Li+ batteries.

36 MATERIALS SCIENCE↗

Space Weather Investigation Frontier (SWIFT)

The Space Weather Investigation Frontier (SWIFT) mission will aim at making major discoveries on the three-dimensional structure and dynamics of heliospheric structures that drive space weather. The focus will be on Interplanetary Coronal Mass Ejections (ICMEs) that originate from massive expulsions of plasma and magnetic flux from the solar corona. They cause the largest geomagnetic storms and solar energetic particle events, threatening to endanger life and disrupt technology on Earth and in space. A big current problem, both regarding fundamental solar-terrestrial physics and space weather, is that we do not yet understand spatial characteristics and temporal evolution of ICMEs and that the existing remote-sensing and in-situ observatories are not suited for resolving multi-layered and evolutionary structures in these massive storm drivers. Here, we propose a groundbreaking mission concept study using solar sail technology that, for the first time, will make continuous, in-situ multi-point observations along the Sun-Earth line beyond the Lagrange point L1 (sub-L1). This unique position, in combination with L1 assets, will allow distinguishing between local and global processes, spatial characteristics, temporal evolution, and particle energization mechanisms related to ICMEs. In addition, measurements of the magnetic field in earthbound ICMEs and their sub-structures from the SWIFT location will double the current forecasting lead-times from L1. This concept also paves the way for missions with increasingly longer forecasting lead-times, addressing NASA and NOAA’s space weather goals, as set forth by the Decadal Survey. The objective of this communication is to inform the community of the ongoing effort, including plans to further develop the mission concept, supported by the Heliophysics Flight Opportunities Studies (HFOS) program under NASA’s Research Opportunities in Space and Earth Sciences (ROSES).

M. Akhavan-Tafti↗

Exploring chemistry with single-molecule and -particle fluorescence microscopy

The evolution of single-molecule and -particle fluorescence microscopy imaging techniques for the investigation of chemical reactions yielded achievements at all fronts, from synthetic organic chemistry to materials science. The removal of ensemble averaging effects uncovers unique, otherwise hidden reaction intermediates, reactivity, and kinetics. Thus, new insights can be obtained even for well-explored chemical reactions and processes. The aim of this article is to serve as a guide and a source of inspiration for scientists who wish to develop single-molecule and -particle fluorescence microscopy to answer questions in chemistry. Here, we describe the current status of technical accomplishments in the field and point out technical and conceptual obstacles for overcoming in the near future, with focus on improvement of bench-scale synthetic reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A gas dynamic perspective on particle lifting in electrostatic discharge-like devices using multiphase particle-in-cell approach

Although particle–laden electrostatic discharges are widely used in laboratories as well as in industrial applications, the mechanism of particle lifting for particles initially at rest in such highly unsteady systems is not well understood. A multiphase gas–particle solver is developed using the multiphase particle-in-cell (MP-PIC) approach to emulate the interaction of a compressible shock-dominated gas phase with the dense particle phase. First, the two-way coupled solver is initially used to study the interaction of a planar traveling shock with a vertical curtain of particulates. The gas and particle phase evolution was found to be in good agreement with a similar experimental study in Ling et al. [Phys. Fluids 24, 113301 (2012)]. Second, the MP-PIC code is used to study the interaction of an expanding blast wave with a thick bed of particles. The simulation considered forces such as quasi-steady drag, pressure-gradient, added-mass, Saffman, and Magnus forces. We observe that the vertical liftoff particles close to the shock impingement point in this configuration are associated with the quasi-steady drag, pressure gradient, and added-mass forces. Also, the Saffman lift and Magnus forces contribute to lifting particles located radially farther away from the shock impingement point. In addition, the study finds a decrease in particle lifting efficiency with decreasing plasma kernel length and shock strength.

42 ENGINEERING↗

Unsteady turbulent shear flow in shock tube discontinuities

A pressure-ruptured shock tube and an arc driven shock tube, have been used to study the evolution of turbulent fluctuations at contact surfaces with N2O4-2NO2 mixtures and at ionizing shock fronts in argon. The study has focused on point density diagnostics derived from crossed light beam correlations and electric probes. Turbulent bursts are found for which dynamical and spectral analyses suggest a particle-like evolution of fluctuation segments with a unique and characteristic frequency, independent of flow history and overall flow conditions.

Johnson, J. A., III↗

Accretion and Heating of Particles by Supersonic Planetesimals

Recently, nebular shock waves have become one of the leading candidates for explaining the presence of chondrules in primitive meteorites. While shocks have been shown to be capable of explaining many of the features of chondrules, a major problem with the theory is that the source of the shocks remains unidentified. Among the suggested sources of the shocks are bow shocks created by supersonic planetesimals in the nebula. Recently, we studied the structure of the shocks that would form around such supersonic planetesimals. We found that particles that encountered the shocks at distances greater than 2 planetesimal radii from the planetesimal would cool too quickly to form the textures observed in chondrules. While the region of the shock far away from the planetesimal may not allow chondrules to form, the region closer in has not been studied in detail. In this work we consider the dynamical and thermal evolution of particles that encounter supersonic planetesimals in this region.

Ciesla, F. J.↗

Multi-scale modeling of the electric field assisted sintering process

The electric field assisted sintering (EFAS) process involves tightly coupled physics that influence microstructural evolution in the particles being compacted. It is also an inherently multi-scale phenomenon, with the microstructure of the compact influencing the subsequent engineering-scale response of the sintering system. To improve understanding of how processing parameters influence microstructural evolution, we have developed a multi-scale modeling approach that couples a continuum-level model of the sintering system with a phase-field model for microstructural evolution of particles within the compact. The phase-field model couples the effect of chemical and electrical driving forces on microstructural evolution and includes the effect of charged defect segregation to surfaces and grain boundaries; this segregation leads to enhanced defect transport and heat generation at these interfaces in response to applied electric field. The effect of enhanced heat generation on particle neck growth and the influence of microstructural evolution on the engineering-scale model are demonstrated.

36 MATERIALS SCIENCE↗

Multi-scale modeling of the electric field assisted sintering process

The electric field assisted sintering (EFAS) process involves tightly coupled physics that influence microstructural evolution in the particles being compacted. It is also an inherently multi-scale phenomenon, with the microstructure of the compact influencing the subsequent engineering-scale response of the sintering system. To improve understanding of how processing parameters influence microstructural evolution, we have developed a multi-scale modeling approach that couples a continuum-level model of the sintering system with a phase-field model for microstructural evolution of particles within the compact. The phase-field model couples the effect of chemical and electrical driving forces on microstructural evolution and includes the effect of charged defect segregation to surfaces and grain boundaries; this segregation leads to enhanced defect transport and heat generation at these interfaces in response to applied electric field. The effect of enhanced heat generation on particle neck growth and the influence of microstructural evolution on the engineering-scale model are demonstrated.

36 - MATERIALS SCIENCE↗

Mechanism-Resolved PFM of Ferroionic and Ferroelectric Responses in Thickness-Gradient Hf 0.5 Zr 0.5 O 2 Libraries

Resolving growth mechanisms and thickness evolution of functional properties is one of the key tasks in materials discovery and optimization involving thin-film materials, traditionally requiring significant experimental budgets. Here we introduce the combination of thickness-gradient libraries and automated scanning probe microscopy as a systematic pathway to elucidate growth modes and disentangle ferroelectric and electrochemical contributions in ferroelectric thin films. As a model system, we explore the Hf 0.5 Zr 0.5 O 2 (HZO) gradient thin films grown on La x Sr 1-x MnO 3 (LSMO) bottom electrode thin films. Automated piezoresponse force microscopy, spectroscopy, and lithography reveals that irreversible topographic deformation arises from electrochemical activity at the LSMO surface, whereas reversible phase inversion in HZO reflects ferroelectric switching. Automated topography height-map scans are used to further quantify nucleation density, particle-size evolution, and roughness correlations across the thickness-gradient, demonstrating that improved plume stabilization during growth suppresses interfacial reactions and promotes dense, fine-grained HZO conducive to ferroelectric phase formation. This combined materials-engineering and automated-SPM framework establishes a platform for high-throughput, mechanism-resolved characterization of ferroionic and ferroelectric responses in complex oxide films.

FOS: Physical sciences↗

Theory and simulation of electromagnetic beam modes and whistlers

Using particle-in-cell simulations and analytical methods, a study of the nonlinear evolution of electromagnetic instabilities driven by an anisotropic electron beam in an external magnetic field is performed. The unstable waves are either whistlerlike or beam-mode-like depending on the external field strength and beam velocity. The evolution of the particle distribution differs significantly in the two regimes. Even in the presence of a faster electrostatic instability, the electromagnetic waves grow to a significant amplitude. In certain cases, an energetic tail is formed, resulting in enhanced Cerenkov emission of electrostatic waves. The initial evolution of the particle distribution is explained in terms of the interaction of a given linearly unstable wave with the self-consistent perturbed distribution.

Newman, David L.↗

Physicochemical and Molecular Insights into the Boundary Layer and Free Troposphere Aerosol Interactions over the Southern Great Plains

Ambient aerosols’ vertical profiles are critical for evaluating the role of aerosols in atmospheric chemistry and radiative transfer, but limited data on these profiles hinders our ability to fully assess their impact on the Earth's radiative balance. Here, in this study, we investigated the size-, time-, and altitude resolved composition of individual particles and bulk molecular composition of particle samples collected by an uncrewed aerial system–ArcticShark over the Southern Great Plains. Single particle microanalysis shows that, the free tropospheric (FT) samples are dominated (56-66%) by carbonaceous sulfate particles, while boundary layer (BL) samples are dominated (57-74%) by carbonaceous particles. Back trajectory simulations suggest that FT particles are likely influenced by long-range transport and have undergone aqueous-phase processing. Conversely, in-situ size distribution data shows evidence of particle growth in the upper BL and just below the FT. This observation may indicate vertical transport of particles from an elevated aerosol layer in the FT, possibly linked to a new particle formation event. This observation is further supported by high resolution molecular composition data, which reveals particle volatility increasing with increasing size, which aligns with the growth event. This study aids in fundamental understanding of the compositional and molecular specificity of vertically resolved organic aerosols to provide insights into particle size evolution for future atmospheric models.

ArcticShark↗

Simulated aging processes of black carbon and its impact during a severe winter haze event in the Beijing-Tianjin- Hebei region

Black carbon (BC) can mitigate or worsen air pollution through perturbing meteorological conditions. BC aging processes are important for the evolution of particle size, concentration, and optical properties of BC that determines its influence on the meteorology. Here we use the online coupled Weather Research and Forecasting-Chemistry (WRF-Chem) model to quantify the role of BC aging processes, including physical processes (PP) and absorption enhancements (AE), in exerting BC-induced meteorological changes and the associated feedback to PM2.5 (particulate matter less than 2.5 µm in diameter) and O3 concentrations during a severe haze event in Beijing-Tianjin-Hebei (BTH) region during 21-27 February 2014. Our results show that, compared to the simulation without the PP treatment, the simulated near-surface BC concentration and BC mass loading in BTH region is lowered by 6.6 % and 12.1 %, respectively, during the haze event with the PP included. PP increases the proportion of large-size BC (particle diameter greater than 0.312 µm) from 28 %-33 % to 59 %-64 % below 1000 m in BTH region. Both PP and AE enhance the “dome effect” of BC. With both PP and AE considered, a reduction in PBL height due to BC-PBL interaction is 116.3 m (20.7 %), compared to 75.7 m (13.5 %) without AE and 66.6 m (11.9 %) without both PP and AE. However, during this haze event, anomalous northeasterly winds are produced by the direct radiative effect of BC, which further affects the mixing and transport of aerosols. When PBL height is decreased (from 10:00 to 21:00), combining all the impacts on multiple meteorological factors, BC effect without PP and AE, without AE, and with PP and AE, respectively, increases surface concentrations of PM2.5 by 8.3 µg m-3 (6.1 % relative to the mean value), 6.1 µg m-3 (4.5 %) and 9.6 µg m-3 (7.0 %) but decreases surface O3 concentrations by 2.8 ppbv (7.4 %), 4.0 ppbv (9.0 %) and 5.0 ppbv (10.8 %) in BTH region averaged over 21-27 February 2014. Our results highlight the importance of the aging processes and absorption enhancements of BC in simulating weather and air quality.

Chen, Donglin↗

Phase transition amplification of proton number fluctuations in nuclear collisions from a transport model approach

The time evolution of particle number fluctuations in nuclear collisions at intermediate energies (E lab = 1.23–10⁢A GeV) is studied by means of the UrQMD-3.5 transport model. The transport description incorporates baryonic interactions through a density-dependent potential. This allows for an implementation of a first-order phase transition including a mechanically unstable region at large baryon density. The scaled variance of the baryon and proton number distributions is calculated in the central cubic spatial volume of the collisions at different times. A significant enhancement of fluctuations associated with the unstable region is observed. This enhancement persists to late times, reflecting a memory effect for the fluctuations. The presence of the phase transition has a much smaller influence on the observable event-by-event fluctuations of protons in momentum space.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗