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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Handling and Properties of Methanol as a Marine Fuel

Given the increasing concern around greenhouse gas emissions and the decline in the availability of fossil fuels, there is increasing global demand to develop alternate fuels for maritime transportation that are sustainable and which have lower greenhouse gas emissions. Methanol is one such alternative fuel that has garnered considerable attention given its potential to be produced by more sustainable processes and its more favorable greenhouse gas emission profile in comparison with current fossil fuels. Understanding the physical and chemical properties of methanol under a range of conditions is essential for its development as a marine fuel. In this study, we seek to define physical and chemical properties of different methanol samples to simulate real-world storage conditions as these data are lacking in the literature. Several methanol samples were evaluated: nearly pure methanol; International Organization for Standardization (ISO) marine methanol (MM) grades A, B, and C; and methanol plus higher alcohols. We first evaluated all methanol samples for impurities, acetic acid content, density, and distillation range. We then characterized the effects of water absorption and found that methanol can easily absorb unacceptable water content from humid air within hours, necessitating storage conditions that prevent this process. In eight-week aging experiments at 20 °C and 40 °C in ambient air, we did not observe significant oxidation for any of the methanol samples; however, we did observe increases in acid number. We assessed the impact of contamination of methanol with water, marine gas oil (MGO), and an MGO–biodiesel mixture on density, viscosity, distillation range, and lubricity. Finally, we show that MGO contamination of methanol results in a slight increase in sooting tendency. In aggregate, our results provide an in-depth analysis of physical and chemical properties of methanol as well as the impacts of storage conditions and impurities on the properties of fuel methanol.

09 BIOMASS FUELS↗
NASA NTRS1987

The surface composition of Charon - Tentative identification of water ice

The Mar. 3, 1987, Charon occultation by Pluto was observed in the infrared at 1.5, 1.7, 2.0, and 2.35 micrometers. Subtraction of fluxes measured between second and third contacts from measurements made before and after the event has yielded individual spectral signatures for each body at these wavelengths. Charon's surface appears depleted in methane relative to Pluto. Constancy of flux at 2.0 micrometers throughout the event shows that Charon is effectively black at this wavelength, which is centered on a very strong water absorption band. Thus, the measurements suggest the existence of water ice on Pluto's moon.

Marcialis, Robert L.↗
NASA NTRS2022

A Radiative Transfer Simulator for PACE: Theory and Applications

A radiative transfer simulator was developed to compute the synthetic data of all three instruments onboard NASA’s Plankton Aerosol, Cloud, ocean Ecosystem (PACE) observatory, at the top of the atmosphere (TOA). The instrument suite includes the ocean color instrument (OCI), the HyperAngular Rainbow Polarimeter 2 (HARP2), and the Spectro-Polarimeter for Planetary Exploration 1 (SPEXone). The PACE simulator is wrapped around a monochromatic radiative transfer model based on the successive order of scattering (RTSOS), which accounts for atmosphere and ocean coupling, polarization, and gas absorption. Inelastic scattering, including Raman scattering from pure ocean water, fluorescence due to chlorophyll, and colored dissolved organic matter (CDOM), is also simulated. This PACE simulator can be used to explore the sensitivity of the hyperspectral and polarized reflectance of the Earth system with tunable atmosphere and ocean parameters, which include aerosol and cloud number concentration, refractive indices, and size distribution, ocean particle microphysical parameters, and solar and sensor-viewing geometry. The PACE simulator is used to study two important case studies. One is the impact of the significant uncertainty in pure ocean water absorption coefficient to the radiance field in the ultraviolet (UV) spectral region, which can be as much as 6%. The other is the influence of different amounts of brown carbon aerosols and CDOM on the polarized radiance field at TOA. The percentage variation of the radiance field due to CDOM is mostly for wavelengths smaller than 600 nm, while brown aerosols affect the whole spectrum from 350 to 890 nm, primarily due to covaried soot aerosols. Both case studies are important for aerosol and ocean color remote sensing and have not been previously reported in the literature.

PACE↗
NASA NTRS1984

Predicting Moisture Absorption in Composite Materials

Heat transport programs adaptable for absorption analysis. Lightweight sandwich panel specimen used for comparison of water absorption measurements with program predictions. In program model, moisture -- like heat in heat-transport problem moves through variety of materials and structures along complex paths.

Haines, J. R.↗
NASA NTRS1994

Spectral control of an alexandrite laser for an airborne water-vapor differential absorption lidar system

A narrow-linewidth pulsed alexandrite laser has been greatly modified for improved spectral stability in an aircraft environment, and its operation has been evaluated in the laboratory for making water-vapor differential absorption lidar measurements. An alignment technique is described to achieve the optimum free spectral range ratio for the two etalons inserted in the alexandrite laser cavity, and the sensitivity of this ratio is analyzed. This technique drastically decreases the occurrence of mode hopping, which is commonly observed in a tunable, two-intracavity-etalon laser system. High spectral purity (greater than 99.85%) at 730 nm is demonstrated by the use of a water-vapor absorption line as a notch filter. The effective cross sections of 760-nm oxygen and 730-nm water-vapor absorption lines are measured at different pressures by using this laser, which has a finite linewidth of 0.02 cm(exp -1) (FWHM). It is found that for water-vapor absorption linewidths greater than 0.04 cm(exp -1) (HWHM), or for altitudes below 10 km, the laser line can be considered monochromatic because the measured effective absorption cross section is within 1% of the calculated monochromatic cross section. An analysis of the environmental sensitivity of the two intracavity etalons is presented, and a closed-loop computer control for active stabilization of the two intracavity etalons in the alexandrite laser is described. Using a water-vapor absorption line as a wavelength reference, we measure a long-term frequency drift (approximately 1.5 h) of less than 0.7 pm in the laboratory.

Ponsardin, Patrick↗
NASA NTRS1994

Extraction of Dry Leaf Spectral Features from Reflectance Spectra of Green Vegetation

Reflectance spectra of green vegetation in the 1.4-2.5 micrometer region are dominated by liquid water absorptions. In this article, we describe the analysis of a set of reflectance spectra of green vegetation, dry vegetation, and liquid water measured in a laboratory using a nonlinear least squares spectral matching technique. We conclude that both the liquid water and the dry materials contribute to the reflectance spectra of green vegetation in the 1.0-2.5 micrometer region. Our matching of data acquired with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) over two vegetated areas in Oregon Transect with a pure water spectrum also shows a residual absorption feature near 1.72 micrometers.

Gao, Bo-Cai↗
DOE OSTI2025

Bio-Oil Impact on Water Diffusion and Durability of Bitumen: Influence of Aging and Salinity

Bio-oils derived from inexpensive biomass offer environmentally friendly options for modifying bitumen for improved durability or rejuvenating aged material, although their impact on bitumen moisture resistance can be mixed. A better understanding of water diffusion into bitumen and its interactions with bio-oil compounds would aid the development of effective bio-oils. In this study, the effect of water exposure on bio-oil-modified bitumen blends was examined by de-wetting contact angle measurements and differential FTIR spectroscopy. The bio-oils improved the anti-stripping behavior of the bitumen but also increased water absorption which could weaken cohesive strength. Short-term thermal aging increased water diffusion for all bitumen blends including the control, probably due to the presence of more oxidized compounds. Negative peaks of alkanes and polar groups in the differential FTIR data suggest the co-diffusion of surfactant molecules towards the bitumen-water interface. Basic pH increased de-wetting of some bitumen blends from silica, possibly by attacking the silica surface itself. The presence of salt in solution altered the bitumen surface composition through the formation of salt complexes with bitumen or bio-oil compounds. In particular, the formation of calcium-carboxylate complexes appeared to greatly improve anti-stripping effects of bio-oils. Water diffusion into most of the bitumen blends was insensitive to pH or salt concentration except for a few notable outliers. Identifying the compounds responsible for increasing or decreasing water diffusion in these outlier cases would be valuable developing future bio-oil formations that avoid or promote those compounds.

Hung, Albert M.↗
NASA NTRS1976

Optimization of absorption air-conditioning for solar energy applications

Improved performance of solar cooling systems using the lithium bromide water absorption cycle is investigated. Included are computer simulations of a solar-cooled house, analyses and measurements of heat transfer rates in absorption system components, and design and fabrication of various system components. A survey of solar collector convection suppression methods is presented.

Perry, E. H.↗
DOE OSTI2023

Performance of hydrophobic physical solvents for pre-combustion CO 2 capture at a pilot scale coal gasification facility

Here, in this paper, we present the first pilot plant data for hydrophobic physical solvents for CO 2 and H 2 S removal from coal-derived H 2 -rich syngas. Four physical solvents were tested under pre-combustion CO 2 capture conditions at bench scale and pilot plant scale: one baseline hydrophilic solvent and three hydrophobic solvents. The solvents were: (1) polyethylene-glycol-dimethyl ether (PEGDME), a hydrophilic solvent analog for the commercial process Selexol, (2) tributyl- phosphate (TBP), a commercially available hydrophobic solvent, (3) polyethylene glycol-poly(dimethylsiloxane) (PEG-PDMS-3), and (4) diethyl sebacate (CASSH-1), a novel, computationally screened hydrophobic solvent developed by the National Energy Technology Laboratory (NETL). All solvents were studied under pure gas (CO 2 /N 2 /H 2 /CH 4 ) equilibrium conditions at NETL followed by pilot plant testing with syngas at the University of North Dakota Energy & Environmental Research Center (UND EERC). Long term performance of CASSH-1 and PEDGME was then assessed with results compared to process simulation predictions. Within experimental uncertainties, all solvents showed comparable CO 2 absorption performance at above room temperature operation while the hydrophobic solvents had limited water uptake and low vapor pressure, which alleviates concerns related to corrosion, water absorption, and solvent loss to evaporation. These results indicate low viscosity, low vapor pressure hydrophobic solvents are a promising option for lower cost CO 2 capture from high pressure syngas applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

Recovery of Atmospheric Water Vapor Total Column Abundance from Imaging Spectrometer Data Around 940 nm - Sensitivity Analysis and Application to Airborne Visible/Infrared Imaging Spectrometer (AVIRI

Twosimple techniques to retrieve path precipitable water fromthe Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) high spectral resolution radiance data (Continuum Interpolated Band Ratio, CIBR, and Narrow/Wide Ratio, N/W), using the 940 nm water absorption band, are compared.

water present surface reflectance atmospheric catt↗
NASA NTRS2014

A Synthesis of Light Absorption Properties of the Arctic Ocean: Application to Semi-analytical Estimates of Dissolved Organic Carbon Concentrations from Space

The light absorption coefficients of particulate and dissolved materials are the main factors determining the light propagation of the visible part of the spectrum and are, thus, important for developing ocean color algorithms. While these absorption properties have recently been documented by a few studies for the Arctic Ocean [e.g., Matsuoka et al., 2007, 2011; Ben Mustapha et al., 2012], the datasets used in the literature were sparse and individually insufficient to draw a general view of the basin-wide spatial and temporal variations in absorption. To achieve such a task, we built a large absorption database at the pan-Arctic scale by pooling the majority of published datasets and merging new datasets. Our results showed that the total non-water absorption coefficients measured in the Eastern Arctic Ocean (EAO; Siberian side) are significantly higher 74 than in the Western Arctic Ocean (WAO; North American side). This higher absorption is explained 75 by higher concentration of colored dissolved organic matter (CDOM) in watersheds on the Siberian 76 side, which contains a large amount of dissolved organic carbon (DOC) compared to waters off 77 North America. In contrast, the relationship between the phytoplankton absorption (a()) and chlorophyll a (chl a) concentration in the EAO was not significantly different from that in the WAO. Because our semi-analytical CDOM absorption algorithm is based on chl a-specific a() values [Matsuoka et al., 2013], this result indirectly suggests that CDOM absorption can be appropriately erived not only for the WAO but also for the EAO using ocean color data. Derived CDOM absorption values were reasonable compared to in situ measurements. By combining this algorithm with empirical DOC versus CDOM relationships, a semi-analytical algorithm for estimating DOC concentrations for coastal waters at the Pan-Arctic scale is presented and applied to satellite ocean color data.

Pan-Arctic↗
NASA NTRS2003

Columbia Accident Investigation Board Report. Volume Four

This is Volume Four of a set of six reports produced by NASA and other organizations which were provided to the Columbia Accident Investigation Board (CAIB) in support of its inquiry into the February 1, 2003 destruction of the Space Shuttle Columbia. The Technical Documents included in this volume are: Appendix F.1 Water Absorption by Foam; Appendix F.2 Follow the TPS; Appendix F.3 MADS Sensor Data; Appendix F.4 ET Cryoinsulation; Appendix F.5 Space Shuttle STS-107 Columbia Accident Investigation, and External Tank Working Group Final Report - Volume 1.

CRYOINSULATION↗
DOE OSTI2026

Hidden features in the OH-stretching spectra of amino acid decorated air–water interfaces

Chemical reactivity at the air–water interface is governed by the interfacial solvation of reactive species. For instance, during aqueous amino acid-based CO 2 absorption, water reorganizes around the reactive sites and couples dynamically with reaction pathways, facilitating the reaction. In this context, surface-sensitive vibrational sum-frequency generation (vSFG) spectroscopy can probe the OH stretch vibrations of interfacial water and determine the solvation structures around reactants and products, thereby furthering our understanding of the role of interfacial solvation. However, vSFG spectra of the air–water interface in the presence of charged species can be remarkably complex; key species-bound local water structures with distinct orientations may be hidden beneath prominent vSFG peaks arising from water–water hydrogen bonds and remain difficult to resolve. Here, we measure and compute vSFG spectra of the water OH stretch at air–water interfaces decorated with amino acids in their zwitterionic and anionic forms, as well as equimolar mixtures of these forms with bicarbonate. The latter represents post-CO 2 -absorption conditions. We find that computing depth- and frequency-dependent spectral densities—decomposed into contributions from water molecules hydrogen-bonded exclusively to other water molecules, exclusively to amines, exclusively to carboxylates, or shared between these polar/charged groups—is indispensable for accurate interpretation of the vSFG spectra. Key findings include orientational flip-flop in water sub-layers, strong carboxylate-water H-bonding, and water orientational ordering extending into the bulk aqueous phase induced by anionic amino acids. Here, this study provides a computational spectroscopic platform for improved understanding of interfacial solvation relevant to interfacial reactivity.

Air-water interface↗
DOE OSTI2021

Solvation Dynamics of Wet Ethaline: Water is the Magic Component

The past two decades witnessed the development of a new type of solvent system, named deep eutectic solvents, which have become increasingly investigated because they offer new and potentially favorable properties, such as wide tunability in electrochemical, mechanical, and transport properties. Deep eutectic solvent (DES) systems are composed of at least one main solvent and an additional component that is meant to interrupt the original solvent/solvent interactions, thereby introducing lower melting points relative to each individual component. Ethaline (a 1:2 mole% mixture of choline chloride and ethylene glycol) is one of the most promising DES systems. However, it is also known to be very hygroscopic, which is a constant concern because water absorption during the use of ethaline alters its properties. Within this work, we demonstrate that modest amounts of water addition (1-10%) to ethaline are of little concern for practical use and can even lead to performance improvements, such as accelerated relaxation and solvation. In contrast, very small amounts of <1% of water lead to additional slowing of the solvent response. Thus, we suggest that the attempt to dry ethaline below 1% moisture is rather counter-productive if one attempts to achieve effective solvation and charge transport properties from DESs. This study investigates the effect of water content on the diffusional relaxation dynamics of ethaline. A set of independent spectroscopic experiments and computational simulations are aimed to provide insight into the solvent response of the DES system using femtosecond time-resolved absorption spectroscopy (fs-TA), broadband dielectric spectroscopy (BDS), nuclear magnetic resonance (NMR) diffusometry and broadband relaxometry, and molecular dynamics simulations (MDS) on ethaline with 0, 0.1, 1, 10, and 28.5wt% added water. For dry ethaline, we identify choline chloride as the rate-limiting solvation component in ethaline. However, the role of the solvent components changes gradually as water is added. Further, we provide quantitative solvent relaxation rates using the different presented time-resolved spectroscopic techniques and find remarkable agreement between them. Based on the solvent relaxation rates and combined with MDS, we develop a molecular understanding of the individual solvent components and their interactions in dry and wet ethaline with varying amounts of water content.

25 ENERGY STORAGE↗
NASA NTRS1987

Remote sensing of leaf water status

Relative water content (RWC) measurements were made concurrently with spectral reflectance measurements from individual snapbean leaves. The relationships between spectra and RWC were described using second order polynomial equations. The middle infrared bands most sensitive to changes in leaf RWC also had the highest water absorption coefficients, as published by Curcio Petty (1951). The relationship between reflectance at 2100nm and total water potential for a single leaf was found to be linear.

Ripple, William J.↗
NASA NTRS2002

Remote Sensing of Suspended Sediments and Shallow Coastal Waters

Ocean color sensors were designed mainly for remote sensing of chlorophyll concentrations over the clear open oceanic areas (case 1 water) using channels between 0.4 and 0.86 micrometers. The Moderate Resolution Imaging Spectroradiometer (MODIS) launched on the NASA Terra and Aqua Spacecrafts is equipped with narrow channels located within a wider wavelength range between 0.4 and 2.5 micrometers for a variety of remote sensing applications. The wide spectral range can provide improved capabilities for remote sensing of the more complex and turbid coastal waters (case 2 water) and for improved atmospheric corrections for Ocean scenes. In this article, we describe an empirical algorithm that uses this wide spectral range to identifying areas with suspended sediments in turbid waters and shallow waters with bottom reflections. The algorithm takes advantage of the strong water absorption at wavelengths longer than 1 micrometer that does not allow illumination of sediments in the water or a shallow ocean floor. MODIS data acquired over the east coast of China, west coast of Africa, Arabian Sea, Mississippi Delta, and west coast of Florida are used in this study.

Li, Rong-Rong↗
NASA NTRS2002

A Technique for Remote Sensing of Suspended Sediments and Shallow Coastal Waters Using MODIS Visible and Near-IR Channels

We have developed an algorithm to detect suspended sediments and shallow coastal waters using imaging data acquired with the Moderate Resolution Imaging SpectroRadiometer (MODIS). The MODIS instruments on board the NASA Terra and Aqua Spacecrafts are equipped with one set of narrow channels located in a wide 0.4 - 2.5 micron spectral range. These channels were designed primarily for remote sensing of the land surface and atmosphere. We have found that the set of land and cloud channels are also quite useful for remote sensing of the bright coastal waters. We have developed an empirical algorithm, which uses the narrow MODIS channels in this wide spectral range, for identifying areas with suspended sediments in turbid waters and shallow waters with bottom reflections. In our algorithm, we take advantage of the strong water absorption at wavelengths longer than 1 micron that does not allow illumination of sediments in the water or a shallow ocean floor. MODIS data acquired over the east coast of China, west coast of Africa, Arabian Sea, Mississippi Delta, and west coast of Florida are used in this study.

Li, Rong-Rong↗
DOE OSTI2022

Improving Reliability, Weight and Cost of Gas-Fired Absorption Heat Pumps

The objective of the project was to identify and verify a viable path for the use of aluminum tubes in evaporators for gas-fired ammonia-water absorption heat pumps (GAHP), via identification of a suitable alloy, coating, inhibitor, process, or combination, for the purpose of achieving weight and cost reduction.

03 NATURAL GAS↗