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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Organic synthesis in a simulated Jovian atmosphere. III - Synthesis of aminonitriles

The products from spark and semicorona discharges through mixtures simulating the Jovian atmosphere were analyzed by gas chromatography combined with mass spectrometry. When the reaction was performed at -80 C, 3-ethylaminopropionitrile and a number of higher homologs were formed. On the other hand, at +20 C, higher molecular-weight material appeared which yielded aminonitrile-derived fragments on mass spectrometry. Although the spectra were not identical, there were notable similarities between these and the mass spectra of some compounds present in the Murray and Orgeuil meteorites. Aminonitriles may occur as minor constituents of the Jovian atmosphere and perhaps by cyclization may produce pyrimidines.

Molton, P. M.↗
NASA NTRS1974

Decameter type IV bursts associated with coronal transients

The characteristics of four moving type IV burst observed with a 65- to 20-MHz swept-frequency interferometer are discussed. All four bursts were associated with depletions in the electron content of the white light corona. Characteristics of the bursts are not unique i.e., they differ in source size, structure, duration, and their association with other radio bursts. Following Smerd and Dulk (1971), it is assumed that a shock wave, moving out from the flare site is responsible for the expansion of a magnetic arch or the ejection of a plasmoid which is observed as the usual type IV burst. Behind the shock wave, the compressed coronal gas moves outward, and as it expands it causes a depletion of electrons in the inner corona. After the passage of the shock wave, sometimes the coronal magnetic field structure is restored to its initial situation, as evidenced by the observation of homologous transients.

Gergely, T. E.↗
NASA NTRS1974

Observations of coronal disturbances from 1 to 9 solar radii. II - Second event of 1973 January 11

Observations of a coronal disturbance on Jan. 11, 1973, commencing at 1801 hr UT are described. The event is homologous with an earlier disturbance from the same region of the corona. The observations suggest that a cloud of coronal gas containing about 4 x 10 to the 39th electrons propagated outward to more than 5 solar radii behind a piston-driven shock wave traveling at a velocity of 800 to 1200 km/sec.-

Stewart, R. T.↗
NASA NTRS1975

Aminonitriles - Possible role in chemical evolution

The formation of HCN, ammonium cyanide, alkylnitriles, aminoacetonitrile and its C- and N-methyl homologs was demonstrated earlier in a simulated Jovian atmosphere. The polymeric material resulting in these experiments was shown to give glycine, alanine, sarcosine, aspartic acid and some imino dibasic acids on acid hydrolysis, suggesting thereby the participation of the monomeric nitriles in the formation of the polymeric product(s). Further examination of products resulting from semicorona and arc discharge through a mixture of methane and ammonia has provided evidence for the formation of alkylaminopropionitriles as a complex mixture and also some pyridyl and pyrimidyl type heterocyclic compounds. A gas chromatograph/mass spectrometer examination of the heterocyclics showed resemblance with those found in some carbonaceous chondrites. The significance of these findings in relation to chemical evolution is discussed.

Chadha, M. S.↗
NASA NTRS1975

Generalized photoclinometry for Mariner 9

A theory is developed for the photoclinometric determination of topography when the photometric function of a planetary surface is not restricted beyond the expectation that it is a function of phase angle, angle of incidence, and angle of emergence. Several versions of such an operational theory are presented together with several approaches to the numerical analysis. Reasons for the differences in numerical techniques are discussed. A preliminary result is considered which has been produced for an early Mariner 9 frame wherein the dust-laden atmosphere seems to exhibit standing-wave patterns. It is shown that if the assumption of homologous departures from plane-parallel atmospheric configuration is valid, the photoclinometry implies that laminar flow lines in the optically observable dust layer undergo a near-sinusoidal rise and fall of about 40 to 50 meters.

Wildey, R. L.↗
NASA NTRS1976

H alpha observations of the 12 August 1975 type 3-RS bursts

H alpha filtergram observations of a number of the Type III-RS (reverse slope) bursts that occurred on August 12, 1975 are presented. Solar radio emission was peculiar on that date in that a large number, and proportion, of the usually rare reverse slope bursts were observed. The radio bursts are shown to coincide in time with a homologous set of H alpha flares located at the limbward edge of spot group Mt. Wilson 19598. A model is proposed in which the reverse slope bursts are the downward branches of U bursts, whose upward branches are hidden behind the coronal density enhancement over the spot group.

Labonte, B. J.↗
NASA NTRS1976

Alloy softening in binary iron solid solutions

An experimental study was conducted to determine whether alloy softening in Fe alloys is dependent on electron concentration and to provide a direct comparison of alloy softening and hardening in several binary Fe alloy systems having the same processing history. Alloy additions to Fe included the elements in the Periods 4-6 and the Groups IV-VIII with the exception of technetium. A total of 19 alloy systems was investigated, and hardness testing was the primary means of evaluation. Testing was carried out at four temperatures over a homologous temperature range of 0.043-0.227 times the absolute melting temperature of unalloyed Fe. Major conclusions are that the atomic radius ratio of solute-to-Fe is the key factor in controlling low-temperature hardness of the binary Fe alloys and that alloy softening rates at 77 K and alloy hardening rates at 411 K are correlated with this atomic radius ratio for 15 of the binary alloy systems. Mechanisms of alloy softening and hardening are proposed.

Stephens, J. R.↗
NASA NTRS1976

Transition probabilities of Br II

Absolute transition probabilities of the three most prominent visible Br II lines are measured in emission. Results compare well with Coulomb approximations and with line strengths extrapolated from trends in homologous atoms.

Bengtson, R. D.↗
NASA NTRS1976

H-alpha observations of the August 12, 1975 Type III-RS bursts

We present H-alpha filtergram observations of a number of the Type III-RS (reverse slope) bursts that occurred on August 12, 1975. Solar radio emission was peculiar on that date in that a large number, and proportion, of the usually rare reverse slope bursts were observed (Tarnstrom and Zehntner, 1975). We show that the radio bursts coincide in time with a homologous set of H-alpha flares located at the limbward edge of spot group Mt. Wilson 19598. We propose a model in which the reverse slope bursts are the downward branches of U bursts, whose upward branches are hidden behind the coronal density enhancement over the spot group.

Labonte, B. J.↗
NASA NTRS1978

A measure of the denseness of a phylogenetic network

An objective measure of phylogenetic denseness is developed to examine various phylogenetic criteria: alpha- and beta-hemoglobin, myoglobin, cytochrome c, and the parvalbumin family. Attention is given to the number of nucleotide replacements separating homologous sequences, and to the topology of the network (in other words, to the qualitative nature of the network as defined by how closely the studied species are related). Applications include quantitative comparisons of species origin, relation, and rates of evolution.

Holmquist, R.↗
NASA NTRS1978

Phytanyl-glycerol ethers and squalenes in the archaebacterium Methanobacterium thermoautotrophicum

Gas chromatographic and mass- and infrared-spectrometric techniques are used to assay the lipids of a thermophilic chemolithotroph, Methanobacterium thermoautotrophicum. Of the chloroform-soluble lipids, 79% are polar and 21% non-polar. Attention is given to the detection of squalene and hydrosqualene derivatives, which, coupled with 16S r-RNA sequence homologies, indicate that the extreme halophiles and the methanogens share a common ancestor.

Tornabene, T. G.↗
NASA NTRS1978

Thermal rearrangements of unsaturated polymers

Thermal anaerobic uncatalyzed cyclizations and cis-trans isomerizations observed in unsaturated hydrocarbon polymers are surveyed. Three main types of cyclizations are described. Type I is a radical reaction which is caused by chain rupture and gives rise to six-membered rings; this reaction occurs during pyrolysis of polymers with double bonds in a 1,5- or 1,6-diene configuration. Type II is a (2 + 2) thermal cycloaddition of double bonds in certain polymers with a 1,6-diene structure; bicycloheptane structures result. Type III is an intramolecular ene reaction. Many polymers containing a double bond linking CH units display thermal cis-trans isomerization. The common activation energy is approximately 130 kJ/mol, and the initial rate constants are lower, for homologous polymers, the greater the separation of the carbon-carbon double bonds.

Golub, M. A.↗
NASA NTRS1979

Planetary radio astronomy observations from Voyager 2 near Jupiter

The Voyager 2 Planetary Radio Astronomy experiment to Jupiter has confirmed and extended to higher zenomagnetic latitudes results from the identical experiment carried by Voyager 1. The kilometric emissions discovered by Voyager 1 often extended to 1 megahertz or higher on Voyager 2 and often consisted of negatively, or less frequently, positively drifting narrowband bursts. On the basis of tentative identification of plasma wave emissions similar to those detected by Voyager 1, the plasma torus associated with Io appeared somewhat denser to Voyager 2 than it did to Voyager 1. The paper reports on quasi-periodic sinusoidal or impulsive bursts in the broadcast band range of wavelengths (800 to 1800 kHz). A Faraday effect appears at decametric frequencies, which probably results from propagation of the radiation near its sources on Jupiter. Finally, the occurrence of decametric emission in homologous arc families is discussed.

Warwick, J. W.↗
NASA NTRS1981

Recrystallization of polycrystalline silicon

Optical metallography is used to investigate the recrystallization properties of polycrystalline semiconductor-grade silicon. It is found that polycrystalline silicon recrystallizes at 1380 C in relatively short times, provided that the prior deformation is greater than 30%. For a prior deformation of about 40%, the recrystallization process is essentially complete in about 30 minutes. Silicon recrystallizes at a substantially slower rate than metals at equivalent homologous temperatures. The recrystallized grain size is insensitive to the amount of prestrain for strains in the range of 10-50%.

Lall, C.↗
NASA NTRS1981

On the outburst of flare activity of 26 November, 1973

The possible source of a strong 30 hour-long outburst of homologous flare activity, and an unusual growth and brightening of coronal loops in the active region McMath 12628, on the eastern solar hemisphere, on Nov. 1973, as seen from Skylab are analyzed. Prior to that date, not many flares and subflares in the region were associated with radio bursts. However, almost all flares after that date were accompanied by microwaves and type III bursts until the last flare of this kind appeared at 03:52 on the 27th. All the type III bursts were accompanied by type U-bursts, giving evidence for strong closed fields rooted in the site of the radio bursts. It is recorded that U-bursts stopped after 07:18 on Nov. 26, and a change noted is attributed to the occurrence of two two-ribbon flares at the site of the recurrent activity which could have destroyed the U-type favorable situation. A two-ribbon flare, according to Kopp and Pneuman (1976), opens the magnetic field-configuration, and it is therefore suggested that a newly emerging magnetic flux was the source of the complex solar situation. It is suggested that this kind of activity should be studied during the FBS-ALERT periods in 1980-81.

Howard, R.↗
NASA NTRS1981

The estimation of genetic divergence

Consideration is given to the criticism of Nei and Tateno (1978) of the REH (random evolutionary hits) theory of genetic divergence in nucleic acids and proteins, and to their proposed alternative estimator of total fixed mutations designated X2. It is argued that the assumption of nonuniform amino acid or nucleotide substitution will necessarily increase REH estimates relative to those made for a model where each locus has an equal likelihood of fixing mutations, thus the resulting value will not be an overestimation. The relative values of X2 and measures calculated on the basis of the PAM and REH theories for the number of nucleotide substitutions necessary to explain a given number of observed amino acid differences between two homologous proteins are compared, and the smaller values of X2 are attributed to (1) a mathematical model based on the incorrect assumption that an entire structural gene is free to fix mutations and (2) the assumptions of different numbers of variable codons for the X2 and REH calculations. Results of a repeat of the computer simulations of Nei and Tateno are presented which, in contrast to the original results, confirm the REH theory. It is pointed out that while a negative correlation is observed between estimations of the fixation intensity per varion and the number of varions for a given pair of sequences, the correlation between the two fixation intensities and varion numbers of two different pairs of sequences need not be negative. Finally, REH theory is used to resolve a paradox concerning the high rate of covarion turnover and the nature of general function sites as permanent covarions.

Holmquist, R.↗
NASA NTRS1982

Galactic mass loss - A mild evolutionary correction to the angular size test

Galactic mass loss due to gas production by an evolving stellar population and removal due to supernovae or some other energy source can alter the size of a galaxy over a long time through the adiabatic invariants of the orbits. Numerical and analytic results show that if the mass profile changes homologously, the scale size of the galaxy does also. Under conventional assumptions about galaxy age and initial mass function, this bloating is smaller than the differences between open and flat cosmologies at z = 0.5. If, however, some elliptical galaxies maintain star formation until recent epochs and then lose a (correspondingly) larger fraction of their mass, the effect may be important. It may also be important in decreasing the size of cD galaxies as a result of gas accretion.

Richstone, D. O.↗
NASA NTRS1981

Interstellar chemistry - Polycyanoacetylene formation

It is argued that interstellar polycyanoacetylenes are formed not on dust grains by catalytic buildup or by dissociation of longer molecules, but rather by gas phase ion-molecule reactions. The primary evidence for this view is the detection of deuterated cyanoacetylene in an interstellar cloud. It is also argued that the relative abundance of successive homologs of polycyanoacetylenes rules out the grain catalysis theory.

Langer, W. D.↗