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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Ti‐Gradient Doping to Stabilize Layered Surface Structure for High Performance High‐Ni Oxide Cathode of Li‐Ion Battery

Abstract High‐Ni layered oxide cathodes are considered to be one of the most promising cathodes for high‐energy‐density lithium‐ion batteries due to their high capacity and low cost. However, surfice residues, such as NiO‐type rock‐salt phase and Li 2 CO 3 , are often formed at the particle surface due to the high reactivity of Ni 3+ , and inevitably result in an inferior electrochemical performance, hindering the practical application. Herein, unprecedentedly clean surfaces without any surfice residues are obtained in a representative LiNi 0.8 Co 0.2 O 2 cathode by Ti‐gradient doping. High‐resolution transmission electron microscopy (TEM) reveals that the particle surface is composed of a disordered layered phase (≈6 nm in thickness) with the same rhombohedra structure as its interior. The formation of this disordered layered phase at the particle surface is electrochemically favored. It leads to the highest rate capacity ever reported and a superior cycling stability. First‐principles calculations further confirm that the excellent electrochemical performance has roots in the excellent chemical/structural stability of such a disordered layered structure, mainly arising from the improved robustness of the oxygen framework by Ti doping. This strategy of constructing the disordered layered phase at the particle surface could be extended to other high‐Ni layered transition metal oxides, which will contribute to the enhancement of their electrochemical performance.

Kong, Defei↗
DOE OSTI2019

Interconnected Vertically Stacked 2D-MoS2 for Ultrastable Cycling of Rechargeable Li-Ion Battery

2D layer structured material is often high-capacity ionic storage material with fast ionic transport within the layers. This appears to be the case for non-conversion layer structure, such as graphite. However, this is not the case for conversion-type layered structure such as transition metal sulfide, in which localized congestion of ionic species adjacent to the surface will induce localized conversion, leading to the blocking of the fast diffusion channels and fast capacity fading, which therefore constitutes one of the critical barriers for the application of transition metal sulfide layered structure. In this work, we report the tackling of this critical barrier through nanoscale engineering. We discover that vertically-stacked 2D-MoS2 can dramatically enhance the cycling stability. Atomic level in-situ TEM observation reveals that the MoS2 nanocakes assembled with tangling (100)-terminated nanosheets offer abundant open channels for Li+ insertion through the (100) surface, featuring an enhanced cyclability performance for over 200 cycle with a capacity retention of 90%. In contrast, (001)-terminated MoS2 nanoflowers only retains 10% of original capacity after 50 cycles. The present work demonstrates a general principle and opens a new route of crystallographic design to enhance electrochemical performance for assembling 2D materials for energy storage.

Sun, Congli↗
DOE OSTI2019

Nanoscale LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode materials for lithium ion batteries via a polymer-assisted chemical solution method

A novel and facile polymer-assisted chemical solution method is successfully developed for the synthesis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NCM) with unique morphology and nanoparticle nature as cathodes for lithium-ion batteries. At calcination temperature up to 800°C and 900°C, NCM with hexagonal crystal structure of layered α-NaFeO 2 ( R 3 ¯ m spacing group) is formed and a lower degree of Ni/Li cation mixing for sample heated at 900°C is determined by XRD Rietveld refinement. SEM and TEM images reveal the uniform size distribution of nanoparticles. HRTEM confirms the single crystalline nature of particles with layered structure. XPS verifies the oxidation state of Co 3+ , Mn 4+ , Ni 2+ and Ni 3+ . As compared with the sample prepared at 800°C, the sample heated at 900°C exhibits a higher initial discharge specific capacity of 189 mAh g -1 being charged to 4.5 V at a current rate of 0.05 C, and better cyclability at 4.3 V cutoff voltage at a current density of 1 C. This method has demonstrated easy tuning compositions and particle sizes of cathode materials.

25 ENERGY STORAGE↗
NASA NTRS1993

Altitude profile of aerosols on Mars from measurements of its thermal radiation on limb

Measurements of the thermal (range 7 - 13 micrometers) radiation of Mars with the high space resolution (approximately 2 km) were made by the TERMOSKAN experiment of the Phobos mission. Some of the results were published earlier but only the surface radiation was analyzed in detail. However some part of these measurements was made near the limb of the planet. The atmosphere gives an important input here in the planetary thermal radiation. Beyond the limb the atmosphere is the only source. The task of this work is to estimate some characteristics of the atmosphere using brightness profiles of the thermal radiation near the limb. An appropriate model of the temperature profile T(h) is necessary for such an analysis. A set of T(h) models (nominal, maximal and minimal) was defined using various sources including MARSGRAM, Viking-1 lander data, its theoretical considerations and boundary layer models. On the next step the possible input of the atmospheric gaseous emissions (wing of CO2 15 micrometer band) was estimated. It was found that even for the maximal T(h) this input is no more than a few percents of the measured radiation beyond the limb. Consequently the aerosols are responsible for almost all measured emission. The analysis of the observed profile showed that these aerosols have two components: (1) exponential with the scale height about 10 km and (2) some layered structure (two layers with maxima about 23 and 33 km consisted probably of ice).

Moroz, V. I.↗
NASA NTRS2017

New Perspectives on Blowing Snow Transport, Sublimation, and Layer Thermodynamic Structure over Antarctica

Blowing snow over Antarctica is a widespread and frequent event. Satellite remote sensing using lidar has shown that blowing snow occurs over 70% of the time over large areas of Antarctica in winter. The transport and sublimation of blowing snow are important terms in the ice sheet mass balance equation and the latter is also an important part of the hydrological cycle. Until now the only way to estimate the magnitude of these processes was through model parameterization. We present a technique that uses direct satellite observations of blowing snow and model (MERRA-2) temperature and humidity fields to compute both transport and sublimation of blowing snow over Antarctica for the period 2006 to 2016. The results show a larger annual continent-wide integrated sublimation than current published estimates and a significant transport of snow from continent to ocean. The talk will also include the lidar backscatter structure of blowing snow layers that often reach heights of 200 to 300 m as well as the first dropsonde measurements of temperature, moisture and wind through blowing snow layers.

Palm, Steve↗
NASA NTRS2021

Reflectivity, Emissivity, and Brightness from Multilayered Soil with Linearly Varying Permittivity at P- and L- bands

Passive sensing of root zone soil moisture is theoretically investigated using P and L band frequencies. The soil is considered to be a stratified medium. The reflectivity from the soil surface is found by considering the soil to be composed of a finely layered structure with layer widths that are small compared to a wavelength. A well-known transmission line algorithm is then used to compute the reflectivity at the surface. Emissivity is obtained as (1 – reflectivity). It assumed that the soil is at a constant temperature of 300o K when determining the brightness temperature. A soil moisture profile consisting of two homogeneous layers separated by a layer of linearly varying soil moisture is investigated. The study is made at an incident angle of 40O for horizontal polarization at 0.8 and 1.4 GHz. Two variations of the basic profile are considered: a transition from a layer of lesser moisture to a layer of greater moisture and the opposite. In both cases the P band signal shows greater penetration than the L band case. There is greater penetration in the transition to drier soils. In both cases the L band signals show sensitivity to only the upper surface of the soil as expected.

Ming Li↗
DOE OSTI2023

Structural Stability of Graphene-Supported Pt Layers: Diffusion Monte Carlo and Density Functional Theory Calculations

In this study, we used a combination of diffusion Monte Carlo and density functional theory calculations to investigate the stability and interlayer binding of various layered structures of Pt atoms adsorbed on graphene. Our findings show that vertically buckled Pt monolayer and bilayer with (111)-packing order are more energetically favorable than the corresponding buckled (100) or flat (100)-packing structures. This can be attributed to the significant lattice mismatch (>10%) between pristine graphene and a free-standing (100)-packing Pt layer. Additionally, our calculations reveal that among the (100)-packing Pt layers, an incommensurate structure with a Pt/C atomic ratio less than 1/2 may be more stable than the commensurate structures registered at the bridge sites, which aligns with recent experimental findings of incommensurate (100)-packing Pt layers on graphene. The interlayer binding between the Pt layer and graphene is found to be primarily driven by van der Waals interaction, except for the AA-stacked buckled-(100) Pt bilayer where the bottom Pt atoms show chemisorption to the graphene surface. In conclusion, this research offers a comprehensive examination of the stability and interlayer binding of metallic Pt layers, providing valuable insights for potential applications as a next-generation catalyst.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Magnetoelastically actuated MEMS device and methods for its manufacture

A magnetoelastically actuated device includes a microscale cantilever arm supported at a standoff distance from a substrate. The cantilever arm is formed as a laminar magnetic actuator configured to bend when it is subjected to a magnetic field. The cantilever arm includes a film of magnetostrictive material. Also provided is a method for fabricating the magnetoelastically actuated device. The method includes defining an actuator mold in a layer of photoresist on a structural layer of the cantilever arm and electrodepositing a layer of a magnetostrictive alloy containing cobalt and iron onto the structural layer within the actuator mold.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Attenuation of Spin Precession in Manganite/Normal Metal Heterostructures

Abstract—Temperature dependence of attenuation of magnetic spin precession in two-layer structures with a Pt top layer based on a La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) epitaxial manganite film is studied by measuring the width of a ferromagnetic resonance (FMR) line. Ferromagnetic resonance in thin ferromagnetic manganite films is used for the creation of a spin current at the interface between the metallic and ferromagnetic layers. A significant increase in a width of a line in FMR spectrum in two-layer structures due to generation of a spin current, heterogeneity of a ferromagnetic layer, two-magnon scattering, and eddy current is discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1991

Whiskerless Schottky diode

A Schottky diode for millimeter and submillimeter wave applications is comprised of a multi-layered structure including active layers of gallium arsenide on a semi-insulating gallium arsenide substrate with first and second insulating layers of silicon dioxide on the active layers of gallium arsenide. An ohmic contact pad lays on the silicon dioxide layers. An anode is formed in a window which is in and through the silicon dioxide layers. An elongated contact finger extends from the pad to the anode and a trench, preferably a transverse channel or trench of predetermined width, is formed in the active layers of the diode structure under the contact finger. The channel extends through the active layers to or substantially to the interface of the semi-insulating gallium arsenide substrate and the adjacent gallium arsenide layer which constitutes a buffer layer. Such a structure minimizes the effect of the major source of shunt capacitance by interrupting the current path between the conductive layers beneath the anode contact pad and the ohmic contact. Other embodiments of the diode may substitute various insulating or semi-insulating materials for the silicon dioxide, various semi-conductors for the active layers of gallium arsenide, and other materials for the substrate, which may be insulating or semi-insulating.

Bishop, William L.↗
DOE OSTI2019

Dual function composite oxygen transport membrane

A dual function composite oxygen transport membrane having a layered structure of mixed conducting oxygen transport materials on a first side of a porous substrate and a reforming catalyst layer on an opposing second side of the porous substrate. The layered structure of the mixed conducting oxygen transport materials contains an intermediate porous layer of mixed conducting oxygen transport materials formed on the porous substrate with a dense impervious layer of mixed conducting oxygen transport materials over the intermediate porous layer, and an optional surface exchange layer of mixed conducting oxygen transport materials over the dense impervious layer. The layered structure and the reforming catalyst layer are formed in separate steps.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Modularization of Ceramic Hollow Fiber Membrane Technology for Air Separation

This proposed project is aimed at studying high performance and economically competitive ceramic membrane technology for air separation and high-purity oxygen production using hollow fiber ceramic membrane stack and module technology. The design of the single permeate membrane is a hollow fiber substrate-supported thin tri-layer structure. Radially well-aligned micro-channels are embedded in the thick substrate and open at the inner surface of the substrate, enabling facile air/gas diffusion. The tri-layer structure of thin dense membrane layer (~ 10 µm) sandwiched by porous surface layer on either side is then built on the substrate using advanced fabrication process. The tri-layer structure design allows different materials to be used in different layers, where the materials of surface layers have high surface exchange coefficients while the material of dense layer has high bulk diffusivity. Such a synergetic combination leads to high permeation performance. The focus of the proposed project will be on membrane stack/module development using the developed single hollow fiber membranes, including: 1) fabrication and characterization of novel single hollow fiber membranes; 2) membrane stack design and assembly using fabricated single membranes; 3) stack modeling and analysis to guide membrane stack designs; 4) permeation performance testing and characterization of membrane stacks. The hollow fiber feature and simple sealing requirement enable very compact design of membrane stacks, which have excellent flexibility for further modularizations at different scales. The operations of such membrane stack and module may employ the exhaust heat from other components of Integrated Gasification Combined Cycle and oxy-combustion systems. Therefore, modularization of such an air separation membrane technology can be incorporated into the DOE’s REMS (radically engineered modular systems)-gasification skid and support the oxidant feed of an oxygen-blown REMS gasifier scaled to different ranges.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS2005

NiAl-Based Approach For Rocket Combustion Chambers

A multi-layered component, such as a rocket engine combustion chamber, includes NiAl or NiAl-based alloy as a structural layer on the hot side of the component. A second structural layer is formed of material selected form Ni-based superalloys, Co-based alloys, Fe-based alloys, Cu, and Cu-based alloys. The second material is more ductile than the NiAl and imparts increased toughness to the component. The second material is selected to enhance one or more predetermined physical properties of the component. Additional structural layers may be included with the additional material(s) being selected for their impact on physical properties of the component.

Michael V Nathal↗
NASA NTRS2005

NiAl-based approach for rocket combustion chambers

A multi-layered component, such as a rocket engine combustion chamber, includes NiAl or NiAl-based alloy as a structural layer on the hot side of the component. A second structural layer is formed of material selected from Ni-based superalloys, Co-based alloys, Fe-based alloys, Cu, and Cu-based alloys. The second material is more ductile than the NiAl and imparts increased toughness to the component. The second material is selected to enhance one or more predetermined physical properties of the component. Additional structural layers may be included with the additional material(s) being selected for their impact on physical properties of the component.

Nathal, Michael V.↗
NASA NTRS1997

The CSSL (combined sporadic structures and layers) payload: In situ observations of mesospheric sodium and related parameters

The objectives, design and results of the sensor systems for the combined sporadic structures and layers (CSSL) payload are analyzed. The CSSL main objectives were to: validate current models of mesospheric sodium chemistry; explore the relationship between turbulence and Na fluctuations; and to explore the relationship between high latitude electric fields and the formation of Na anomalies.

Machuga, David W.↗
NASA NTRS2000

Three-Layered Atmospheric Structure in Accretion Disks Around Stellar-Mass Black Holes

Modeling of the x-ray spectra of the Galactic superluminal jet sources GRS 1915+105 and GRO J1655-40 reveals a three-layered atmospheric structure in the inner region of the inner accretion disks. Above the cold and optically thick disk with a temperature of 0.2 to 0.5 kiloelectron volts, there is a warm layer with a temperature of 1.0 to 1.5 kiloelectron volts and an optical depth around 10. Sometimes there is also a much hotter, optically thin corona above the warm layer, with a temperature of 100 kiloelectron volts or higher and an optical depth around unity. The structural similarity between the accretion disks and the solar atmosphere suggests that similar physical processes may be operating in these different systems.

Zhang, S. N.↗
DOE OSTI2019

A novel optical polarization conversion structure designed by multi-layered thin film structures at the wavelength of 10.6 μm

Polarization conversion performance is one of the most important design contents of optical devices. At present, there are many ways to implement polarization conversion. However, they are mostly based on the form of split ring resonator or equivalent plasma, which are not conducive to the miniaturization of electromagnetic devices, particularly in the field of laser applications. In this paper, a novel optical polarization conversion structure has been designed by multi-layered PS/PTFE thin film structures at the wavelength of 10.6 μm based on the equivalent medium theory. Then it was verified that the proposed structure can effectively convert the linear polarized wave to circular polarized wave by the EM full-wave simulation. Compared with the current laser polarization manipulation devices, the proposed novel polarization converter has advantages of ultrathin thickness of structure, simple structure, good light transmission and no electromagnetic loss. Although the structural parameters in this paper are designed for EM wave the wavelength of 10.6 μm, the proposed design idea of the polarization conversion structure is also suitable for the electromagnetic wave at other wavelengths.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗