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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Dry Process for Making Polyimide/ Carbon-and-Boron-Fiber Tape

A dry process has been invented as an improved means of manufacturing composite prepreg tapes that consist of high-temperature thermoplastic polyimide resin matrices reinforced with carbon and boron fibers. Such tapes are used (especially in the aircraft industry) to fabricate strong, lightweight composite-material structural components. The inclusion of boron fibers results in compression strengths greater than can be achieved by use of carbon fibers alone. The present dry process is intended to enable the manufacture of prepreg tapes (1) that contain little or no solvent; (2) that have the desired dimensions, fiber areal weight, and resin content; and (3) in which all of the fibers are adequately wetted by resin and the boron fibers are fully encapsulated and evenly dispersed. Prepreg tapes must have these properties to be useable in the manufacture of high-quality composites by automated tape placement. The elimination of solvent and the use of automated tape placement would reduce the overall costs of manufacturing.

Belvin, Harry L.↗

Improving Interlaminar Shear Strength

To achieve NASA's mission of space exploration, innovative manufacturing processes are being applied to the fabrication of complex propulsion elements.1 Use of fiber-reinforced, polymeric composite tanks are known to reduce weight while increasing performance of propulsion vehicles. Maximizing the performance of these materials is needed to reduce the hardware weight to result in increased performance in support of NASA's missions. NASA has partnered with the Mississippi State University (MSU) to utilize a unique scalable approach of locally improving the critical properties needed for composite structures. MSU is responsible for the primary development of the concept with material and engineering support provided by NASA. The all-composite tank shown in figure 1 is fabricated using a prepreg system of IM7 carbon fiber/CYCOM 5320-1 epoxy resin. This is a resin system developed for out-of-autoclave applications. This new technology is needed to support the fabrication of large, all composite structures and is currently being evaluated on a joint project with Boeing for the Space Launch System (SLS) program. In initial efforts to form an all composite pressure vessel using this prepreg system, a 60% decrease in properties was observed in scarf joint regions. Inspection of these areas identified interlaminar failure in the adjacent laminated structure as the main failure mechanism. This project seeks to improve the interlaminar shear strength (ILSS) within the prepreg layup by locally modifying the interply region shown in figure 2.2

Jackson, Justin↗

Recertification and Equivalency Test Results for IM7/8552-1 Following Extended Freezer Storage

In 2015, the Composites for Exploration Upper Stage (CEUS) Project established an equivalency test program to reduce the scope of laminate coupon tests within the project. The material selected was IM7/8552-1, a variant of the IM7/8552 prepreg used to populate a National Center for Advanced Materials Performance (NCAMP) database. The CEUS successor program, Composites Technology for Exploration (CTE), kicked off in 2017 with the remaining CEUS prepreg planned for use. The IM7/8552-1 prepreg was recertified through an in-house defined set of pass/fail criteria then evaluated for equivalency to the NCAMP database. Over the course of recertification and equivalency panel fabrication, the time of freezer storage ranged from 19 - 22 months. Panels for recertification and equivalency tests were fiber placed at NASA Marshall Space Flight Center (MSFC) and NASA Langley Research Center (LARC).

carbon fiber/epoxy↗

Re-Certification and Equivalency Test Results for IM7/8552-1 Following Extended Freezer Storage

In 2015, the Composites for Exploration Upper Stage (CEUS) Project established an equivalency test program to reduce the scope of laminate coupon tests within the project. The material selected was IM7/8552-1, a variant of the IM7/8552 prepreg used to populate a National Center for Advanced Materials Performance (NCAMP) database. The CEUS successor program, Composites Technology for Exploration (CTE), kicked off in 2017 with the remaining CEUS prepreg planned for use. The IM7/8552-1 prepreg was recertified through an in-house defined set of pass/fail criteria then evaluated for equivalency to the NCAMP database. Over the course of recertification and equivalency panel fabrication, the time of freezer storage ranged from 19-23 months. Panels for recertification and equivalency tests were fiber placed at NASA Marshall Space Flight Center (MSFC) and NASA Langley Research Center (LARC).

equivalency↗

Consolidation of Braided Carbon Fiber/ Thermoplastic Tubes by Induction Heating

Thermoplastic composites have experienced renewed enthusiasm within the U.S. aerospace industry, due in part to opportunities for rapidly manufacturing large structures. Unlike the lengthy cure cycles required by thermosets, the thermoplastic matrix prepreg requires only heat and pressure to consolidate consecutive layers of material; with sufficient inter-ply contact time to develop a strong interface. The manufacturing requirements for thermoplastics provide manufacturing flexibility and of particular interest are in-situ consolidation processes; i.e consolidation during layup on a tool. In-situ consolidation removes the time-consuming and costly secondary processing step of autoclave or press consolidation. Process variables which contribute to laminate quality include temperature, heat transfer, inter-ply contact time, and consolidation pressure. Most of the work to date related to in-situ consolidation has been in conjunction with automated fiber placement (AFP), where prepreg tows are consolidated when placed on the tool. Considering this process for a braided structure adds complexity relative to AFP due to the rapid lay-down rate of the braider and simultaneous placement of a multiple prepreg tows. Processes considered for consolidation during AFP could not be applied to a braided part. Alternatively, a fully braided preform could be consolidated on the tool using well established thermoplastic welding techniques. The goal of this effort was to evaluate the effectiveness of induction welding to consolidate braided carbon fiber/thermoplastic composite tubes up to eight plies in thickness. The manufacturing process, thermal characterization, and initial mechanical property data of the consolidated tubes are reported.

In-situ consolidation, induction heating/welding, ↗

RapidClave® Technology Demonstrations – II Hat Stiffener

This project sought to evaluate the cost and performance of both polymeric and metallic tooling for use with the RapidClave® composite process. Teijin’s rapid cure carbon/epoxy prepreg, Q183, was selected to fabricate demonstration components, of aerospace design, which currently are fabricated via compression molding using matched steel tooling. The ability to fabricate components using this prepreg in the RapidClave®, and using low cost single sided tooling, could significantly reduce the cost of part manufacture and shorten production lead times for tooling fabrication. The component demonstration article was a “hat stiffener” geometry typically used to reinforce fuselage or wing skins of an aircraft. A rapid preforming process was demonstrated and rapid process cycle times similar to compression molding were achieved by placing the preform on hot tooling, thus avoiding the time and energy associated with typical thermal cycling. A 90% reduction in tooling cost was achieved through the use of single sided aluminum or polymeric additive tooling when compared to compression molding matched steel tooling. In addition to rapid cycle times, RapidClave® offers the ability to change out tooling in minutes such that multiple part geometries can be fabricated in one shift.

36 MATERIALS SCIENCE↗

Validation of Material Models For Automotive Carbon Fiber Composite Structures Via Physical And Crash Testing (VMM Composites Project)

As automotive fuel economy requirements increase, the push for reducing overall vehicle weight will likely include the consideration of materials that have not previously been part of mainstream vehicle design and manufacturing, including carbon fiber composites. Vehicle manufacturers currently rely on computer-aided engineering (CAE) methods as part of the design and development process, so going forward, the ability to accurately and predictably model carbon fiber composites will be necessary. If composites are to be used for structural components, this need applies to both, crash and quasi-static modeling. This final report covers the results of a five-year, $6.89M, 50% cost-shared research project between Department of Energy (DOE) and the US Advanced Materials Partnership (USAMP) under Cooperative Agreement DE-EE-0005661 known as “Validation of Material Models for Automotive Carbon Fiber Composite Structures Via Physical and Crash Testing (VMM).” The objective of the VMM Composites Project was to validate and assess the ability of physics-based material models to predict crash performance of automotive primary load-carrying carbon fiber composite structures. Simulation material models that were evaluated included micro-mechanics based meso-scale models developed by the University of Michigan (UM) and micro-plane models by Northwestern University (NWU) under previous collaborations with the DOE and Automotive Composites Consortium/USAMP, as well as five commercial crash codes: LS-DYNA, RADIOSS, VPS/PAM-CRASH, Abaqus, and GENOA-MCQ. CAE predictions obtained from seven organizations were compared with experimental results from quasi-static testing and dynamic crash testing of a thermoset carbon fiber composite front-bumper and crush-can (FBCC) system gathered under multiple loading conditions. This FBCC design was developed to demonstrate progressive crush, virtual simulation, tooling, fabrication, assembly, non-destructive evaluation and crash testing advances in order to assess the correlation of the predicted results to the physical tests. The FBCC was developed to meet a goal of 30-35% mass reduction while aiming for equivalent energy absorption as a steel component for which baseline experimental results were obtained from testing in the same crash modes. The project also evaluated crash performance of thermoplastic composite structures fabricated from commercial prepreg materials and low cost carbon fiber sourced from Oak Ridge National Laboratory. The VMM Project determined that no set of predictions from a CAE supplier were found to be universally accurate among all the six crash modes evaluated. In general, crash modes that were most dependent on the properties of the prepreg were more accurate than those that were dependent on the behavior of the joints. The project found that current CAE modeling methods or best practices for carbon fiber composites have not achieved standardization, and accuracy of CAE is highly reliant on the experience of its users. Coupon tests alone are not sufficient to develop an accurate material model, but it is necessary to bridge the gap between the coupon data and performance of the actual structure with a series of subcomponent level tests. Much of the unreliability of the predictions can be attributed to shortcomings in our ability to mathematically link the effects of manufacturing and material variability into the material models. This is a subject of ongoing research in the industry. The final report is organized by key technical tasks to describe how the validation project developed, modeled and compared crash data obtained on the composite FBCC to the multiple sets of CAE predictions. Highlights of the report include a discussion of the quantitative comparison between predictions and experimental data, as well as an in-depth discussion of remaining technological gaps that exist in the industry, which are intended to spur innovations and improvements in CAE technology.

36 MATERIALS SCIENCE↗

Heat resistant composite structure for shuttle applications (Ryton-B)

A program was undertaken to characterize Ryton-B resin, develop graphite filament prepregs, undirectional laminates and determine the strength and heat resistance of the composite system. Through the use of a water soluble resin binder, high quality prepreg tape, three inches wide with 4 tows of HM-S were produced. The tape laminated to 0.00175 inch per ply. A wide range of properties in the cured resin and laminate were found using different curing conditions. The thermal stability and strength of molded laminates appears to be very dependent upon the cure cycle used for polymerization.

Source record↗

Development of lightweight graphite/polyimide sandwich panels.

Lightweight graphite/polyimide composite honeycomb core and sandwich panels were fabricated and tested. Honeycomb cores of 1/4-in. and 3/8-in. cell sizes of hexagonal configuration were produced from thin plus or minus 45 deg cross plied sheets of prepreg producing core weights between 1.8 and 3.6 lb/cu ft. Thin gauge prepreg using Hercules graphite tow and Monsanto Skybond 710 polyimide resin were manufactured to produce cured ply thicknesses of 0.001 to 0.002 in. Graphite core properties measured at temperatures from -150 to 600 F are reported. Core properties which are superior to available materials were obtained. Sandwich panels weighing less than 0.5 lb/sq ft were designed and fabricated which meet the support structure loads for the shuttle orbiter thermal protection system.

Poesch, J. G.↗

LaRC-160 - A new 550 F polyimide laminating resin

A new addition polyimide, LaRC-160, based on liquid monomers has been prepared. The essentially solventless prepreg retains good drape and tack. Unidirectional HT-S composites were fabricated and tested before and after aging at temperatures between 505 K and 589 K (450 F and 600 F). Excellent retention of mechanical properties was realized after 2000 hours at 547 K (525 F). This material should be a candidate for solventless prepregging due to the liquid nature of the monomeric mixture.

St. Clair, T. L.↗

Technical assessment for quality control of resins

Survey visits to companies involved in the manufacture and use of graphite-epoxy prepregs were conducted to assess the factors which may contribute to variability in the mechanical properties of graphite-epoxy composites. In particular, the purpose was to assess the contributions of the epoxy resins to variability. Companies represented three segments of the composites industry - aircraft manufacturers, prepreg manufacturers, and epoxy resin manufacturers. Several important sources of performance variability were identified from among the complete spectrum of potential sources which ranged from raw materials to composite test data interpretation.

Gosnell, R. B.↗

Solventless LARC-160 Polyimide Matrix Resin

The addition polyimide, LARC-160, which was originally synthesized from low cost liquid monomers as a laminating resin in ethanol, was prepared as a solventless, high viscosity, neat liquid resin. The resin was processed by hot-melt coating techniques into graphite prepreg with excellent tack and drape. Comparable data on graphite reinforced laminates made from solvent-coated and various hot-melt coated prepreg were generated. LARC-160, because of its liquid nature, can be easily autoclave processed to produce low void laminates. Liquid chromatographic fingerprints indicate good reaction control on resin scale ups. Minor changes in monomer ratios were also made to improve the thermal aging performance of graphite laminates.

Stclair, T. L.↗

Composite lamination method

A process was developed for preparing relatively thick composite laminate structure wherein thin layers of prepreg tapes are assembled, these thin layers are cut into strips that are partially cured, and stacked into the desired thickness with uncured prepreg disposed between each layer of strips. The formed laminate is finally cured and thereafter machined to the desired final dimensions.

Dickerson, G. E.↗

Bismaleimide resins for flame resistant honeycomb sandwich panels

Bismaleimide resins are prime candidates for nonflammable aircraft interior panels. Three resin types with different structures and processing characteristics were formulated. Resin M 751 was used to fabricate 100 kg of glass fabric prepregs which were used for the preparation of face sheets for honeycomb sandwich panels. Prepreg characteristics and curing cycles for laminate fabrication are provided. In order to advance beyond the current solvent resin technology for fibre and fabric impregnation, a hot melt solvent-less resin system was prepared and characterized. Preliminary tests were performed to develop a wet bonding process for the fabrication of advanced sandwich honeycomb panels by use of polybismaleimide glass fabric face sheets and polybismaleimide Nomex honeycomb core. B-stage material was used for both the core and the face sheet, providing flatwise tensile properties equivalent to those obtained by the state-of-the-art 3-step process which includes an epoxy adhesive resin.

Stenzenberger, H. D.↗

LaRC fabrication development

The results of in-house efforts in support of the Supersonic Cruise Research (SCR) Program to develop fabrication procedures for the manufacture of GR/PI wing panels for the NASA YF-12 airplane are reported. In addition, manufacturing procedures are outlined for the fabrication of structures in support of the CASTS Project. The results of studies directed toward the development of GR/PI prepreg manufacturing capability, assembly of structural elements from prepreg, final processing of GR/PI structural shapes, and techniques for verification of structural integrity are presented.

Baucom, R. M.↗

HPLC for quality control of polyimides

High Pressure Liquid Chromatography (HPLC) as a quality control tool for polyimide resins and prepregs are presented. A data base to help establish accept/reject criteria for these materials was developed. This work is intended to supplement, not replace, standard quality control tests normally conducted on incoming resins and prepregs. To help achieve these objectives, the HPLC separation of LARC-160 polyimide precursor resin was characterized. Room temperature resin aging effects were studied. Graphite reinforced composites made from fresh and aged resin were fabricated and tested to determine if changes observed by HPLC were significant.

Young, P. R.↗

Quality assurance of PMR-15

Controls on the PMR-15 resin and/or prepreg were established to ensure a solid base for the subsequent process development task. The effort was divided into subtasks which included evaluation of commercially available graphite/PMR-15 polyimide prepregs, detailed evaluation of materials and selection of chemical test procedures. During the initial phase of the program a variability problem was detected in the PMR-15 resin. The manufacturing and/or storage of the PMR-15 resin/esters was identified as the chief cause for the variability.

Hunter, A. B.↗

Reproducibility of PMR-15 graphite polymide material

Investigation was made into the reproducibility of PMR polyimide/graphite prepreg reinforcement and the influence of these variabilities on processing characteristics and final composite properties. The purpose of these investigations was to establish specification controls and limits of acceptance/rejection on incoming materials. Prepreg samples were chemically analyzed and the results compared to the processing and property results of the resulting composites. The findings from these comparisons are discussed.

Hoggatt, J. T.↗