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602 records · Page 7

Density Functional Theory Analysis of Candidate Tritium Permeation Barriers for Vanadium Alloys as a Fusion Structural Material

Vanadium alloys are being considered as a candidate structural material for the breeder blanket component of future fusion reactors due to their good thermal conductivity, low activation, and chemical compatibility with FLiBe. However, vanadium has a high hydrogen solubility, resulting in hydrogen diffusion and trapping in the vanadium structural alloy and lower than expected tritium breeding ratios. To mitigate the permeation of hydrogen into the structural alloy, a tritium permeation barrier will be coated onto the vanadium alloy. Multiple materials have been proposed as candidate tritium permeation barriers, but the extent to which each of these materials impacts hydrogen diffusion and trapping is still unknown. In this project, we perform atomic-scale calculations to narrow down the list of potential tritium permeation barrier candidates and to understand the mechanisms through which hydrogen diffusion is affected in these materials.

36 MATERIALS SCIENCE

Surface phase diagrams from nested sampling

From nested sampling, we compute the partition function and, from that, the phase diagram of gas adsorbates, including their anharmonic and configurational degrees of freedom, on flat and stepped surfaces of the Lennard-Jones solid.

Chemistry

Design of A CVD Reactor for the Deposition of Diamond in A Microgravity Environment

There is a growing body of theoretical and experimental evidence suggesting that the uniformity, rate, adhesion, quality, and other key properties of Chemical Vapor Deposition (CVD) diamond coatings are influenced by the gas mixing kinetics in the thermal plasma environment of the reaction chamber. The implementation of, for example, Microwave Plasma Enhanced Chemical Vapor Deposition (MPECVD) process in microgravity has, thus, been suggested. Such a diamond deposition system, which overcomes the limitations of present systems and which is distiguishable from them by the use of high pressure MPECVD and recirculation of the would be effluent hydrogen and carbon, is described. Given the key fact that there is nothing in the effluent of the MPECVD process that is truly a byproduct or 'waste', the system can, at least in principle, lend itself to being closed loop yet dynamic. The exhaust contains hydrogen and carbon species which can be recirculated to the plasma reactor, that is, since there are no unusable reaction byproducts, the effluent can be fed back to the reaction chamber with no detriment, thus allowing deployment in a microgravity environment.

M L Languell

Defect-induced displacement of topological surface state in quantum magnet MnBi2Te4

The topological magnet MnBi2⁢Te4 (MBT), with gapped topological surface state, is an attractive platform for realizing quantum anomalous Hall and axion insulator states. However, the experimentally observed surface state gaps fail to meet theoretical predictions, although the exact mechanism behind the gap suppression has been debated. Recent theoretical studies suggest that intrinsic antisite defects push the topological surface state away from the MBT surface, closing its gap and making it less accessible to scanning probe experiments. Here, we report on the local effect of defects on the MBT surface states and demonstrate that high defect concentrations lead to a displacement of the surface states well into the MBT crystal, validating the theorized mechanism. The local and global influence of antisite defects on the topological surface states are studied with samples of varying defect densities by combining scanning tunneling microscopy, angle-resolved photoemission spectroscopy, and density functional theory. Our findings identify a combination of increased defect density and reduced defect spacing as the primary factors underlying the displacement of the surface states and suppression of surface gap, guiding further development of topological quantum materials.

Lupke, Felix [Carnegie Mellon University (CMU)]

Multifaceted Considerations for Fission Surface Power Radiation Shielding Design

The purpose of the Fission Surface Power (FSP) nuclear system is to provide energy on the Moon and Mars for supporting their exploration and colonization. The FSP design and deployment can leverage the past research and development work in areas, such as reactor design, but such crucial components as radiation shielding and instrumentation still need material and manufacturing studies, modeling, and testing. The shielding components are needed for the protection of humans, electronics, and sensitive components. They are essential system components, but they are often the heaviest components of the system for which each kilogram matters. Different material combinations and layouts are possible. The studies presented were focused on the evaluation of several options. The initial analysis included their performance assessment, initial temperature distribution evaluation and manufacturability considerations. Several feasible shield design options were identified and discussed in this paper, as well.

Fission Surface Power

An Overview of CMIP5 and CMIP6 Simulated Cloud Ice, Radiation Fields, Surface Wind Stress, Sea Surface Temperatures and Precipitation over Tropical and Subtropical Oceans

The potential links between ice water path (IWP), radiation, circulation, sea surface temperature (SST) and precipitation over the Pacific and Atlantic Oceans resulting from the falling ice radiative effects (FIREs) are examined from present day model outputs of CMIP5 and CMIP6. The latter is divided into two subsets with (SON6) and without FIREs (NOS6) as more models with FIREs are included in CMIP6 than in CMIP5. Improvement in floating cloud ice (~20 g m-2) is noticeable over convective regions in CMIP6 relative to CMIP5. The inclusion of FIREs in SON6 subset may contribute to reduce biases of overestimated outgoing longwave radiation and downward surface shortwave and overestimated reflected shortwave at the top of the atmosphere (TOA) by magnitudes of 4?8 W m-2 over convective regions against CERES, compared to NOS6 subset. The reduced biases in radiative fluxes in convective regions stabilize the atmosphere and lead to circulation, SST, cloud and precipitation changes over the trade-wind regions, as seen from improved radiative fluxes (4?15 W m-2), surface wind stress biases, SST (0.2?0.8 K) and precipitation (1 mm day-1) biases. The significant improvement from NOS6 to SON6 leads to improved multi-model means for CMIP6 relative to CMIP5 for radiation fields over the trade wind regions but the degradation over convective zones is attributed to NOS6 subset. The results suggest that other sources of uncertainty and deficiencies in climate models may play significant roles for reducing discrepancies although FIREs, via radiation-circulation coupling, may be one of the factors that help to reduce regional biases.

Jui-Lin F Li

Surface science insight note: A linear algebraic approach to elucidate native films on Fe 3 O 4 surface

Standard materials are often used to obtain spectra that can be compared to those from unknown samples. Spectra measured from these known substances are also used as a means of computing sensitivity factors to allow quantification by X-ray photoelectron spectroscopy (XPS) of less well-defined materials. Spectra from known materials also provide line shapes suitable for inclusion in spectral models which, when fitted to spectra, permit the chemical state for a sample to be assessed. Both types of information depend on isolating photoemission signals from the inelastically scattered signal. In this Insight note, technical issues associated with the use of XPS of as received Fe 3 O 4 powder sample surface are discussed. The Insight note is designed to show how linear algebraic techniques applied to data collected from a sample marketed as pure Fe 3 O 4 powder are used to verify that XPS has been performed on chemistry representative of the sample. The methods described in this Insight note can further be utilized in elucidating complex XPS data obtained from thin films formed or evolved during cyclic/non-steady use of complex (electro)catalyst surfaces, especially in the presence of contaminants.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Surface Tension Driven Convection Experiment (STDCE)

Results are reported of the Surface Tension Driven Convection Experiment (STDCE) aboard the USML-1 (first United States Microgravity Laboratory) Spacelab which was launched on June 25, 1992. In the experiment 10 cSt silicone oil was placed in an open circular container which was 10 cm wide by 5 cm deep. The fluid was heated either by a cylindrical heater (1.11 cm dia.) located along the container centerline or by a CO 2 laser beam to induce thermocapillary flow. The flow field was studied by flow visualization. Several thermistor probes were placed in the fluid to measure the temperature distribution. The temperature distribution along the liquid free surface was measured by an infrared imager. Tests were conducted over a range of heating powers, laser beam diameters, and free surface shapes. In conjunction with the experiments an extensive numerical modeling of the flow was conducted. In this paper some results of the velocity and temperature measurements with flat and curved free surfaces are presented and they are shown to agree well with the numerical predictions.

S Ostrach

Using Satellite Surface Temperature Data to Monitor Urban Heat Island

Exposure to heat is a growing concern nationwide. Temperatures can be elevated in cities compared to surrounding rural areas, referred to as an “urban heat island” (UHI) effect, which is intensified during heat waves. The lack of dense networks of air temperature measurements results in few studies on urban heat. Now, a vast amount of high spatial and temporal satellite data on land surface temperature is available. We identified satellite datasets with the longest surface temperature records but different spatial and temporal resolutions: Landsat (1985-current, biweekly at 60 m and 100 m spatial resolution) and the Moderate Resolution Imaging Spectroradiometer (MODIS) data from the Terra and Aqua satellites (2000-current, daily at 1 km spatial resolution). We investigated how satellites with different spatial and temporal resolutions detect UHI effects differently. We hypothesized that 1) a dataset’s spatial resolution impacts the precision of detected UHIs spatially, since high spatial resolution Landsat data better captures spatial variability in temperature, and 2) daily surface temperature data can detect temporal patterns of UHIs and heatwave frequencies. We analyzed Landsat and MODIS satellite data in the Washington, D.C. and Baltimore region. We found that Landsat describes higher spatial variability of the UHI effect than MODIS data. However, MODIS data shows more consistent seasonal surface temperature patterns than Landsat when compared to in situ air temperature measurements. MODIS data was also able to consistently measure the frequency of heat waves. This study demonstrates the value of NASA satellite data for urban heat and climate change studies.

landsat

Simulating the Lunar Thermal Environment for the Surface-Deployed LEMS Artemis III TVAC Test

The Lunar Environment Monitoring Station (LEMS) is an autonomous, survive-the lunar-night seismic suite to be deployed on the Lunar surface by the Artemis III crew and designed to operate continuously for two years. It will see the extremes of the Lunar south pole thermal environment where surface temperatures range from -200°C to +20°C and where nighttime duration is at least 354 hours. Given power and mass constraints, the thermal system is limited to 2.5 Watts of heat during the lunar night. Presented is the system thermal vacuum test plan and configuration to validate the thermal control system performance in a flight-like environment. The test will measure the nighttime heat leaks for the bus and 18 seismometers to ensure lunar night survival and operability.

Thermal

Simulating the Lunar Thermal Environment for the Surface-Deployed LEMS Artemis III TVAC Test

The Lunar Environment Monitoring Station (LEMS) is an autonomous, survive-the lunar-night seismic suite to be deployed on the Lunar surface by the Artemis III crew and designed to operate continuously for two years. It will see the extremes of the Lunar south pole thermal environment where surface temperatures range from -200°C to +20°C and where nighttime duration is at least 354 hours. Given power and mass constraints, the thermal system is limited to 2.5 Watts of heat during the lunar night. Presented is the system thermal vacuum test plan and configuration to validate the thermal control system performance in a flight-like environment. The test will measure the nighttime heat leaks for the bus and 18 seismometers to ensure lunar night survival and operability.

Thermal

Simulating the Lunar Thermal Environment for the Surface-Deployed LEMS Artemis III TVAC Test

The Lunar Environment Monitoring Station (LEMS) is an autonomous, survive-the lunar-night seismic suite to be deployed on the Lunar surface by the Artemis III crew and designed to operate continuously for two years. It will see the extremes of the Lunar south pole thermal environment where surface temperatures range from -200°C to +20°C and where nighttime duration is at least 354 hours. Given power and mass constraints, the thermal system is limited to 2.5 Watts of heat during the lunar night. Presented is the system thermal vacuum test plan and configuration to validate the thermal control system performance in a flight-like environment. The test will measure the nighttime heat leaks for the bus and 18 seismometers to ensure lunar night survival and operability.

TVAC

JWST Reveals Spectral Tracers of Recent Surface Modification on Europa

Europa has been modified by a variety of geologic processes, exposing internally-derived materials that are heavily irradiated by charged particles trapped in Jupiter’s magnetosphere. Prior spectral analysis of H2O ice on Europa relied on low signal-to-noise data at wavelengths >2.5 µm, limiting assessment of a 3.1 µm Fresnel peak that is diagnostic of exposed crystalline ice. We report new measurements of H2O ice spectral features using high signal-to-noise data collected by the NIRSpec spectrograph (1.48 – 5.35 µm) on the James Webb Space Telescope. These data reveal a narrow 3.1 µm crystalline H2O ice Fresnel peak, which is primarily located at southern latitudes in Tara and Powys Regiones. Our analysis indicates that crystalline ice exposed in these low-latitude regiones is likely sustained by ongoing thermal (re)crystallization outpacing charged particle amorphization of the top ∼10 µm of Europa’s regolith over short timescales (<15 days). We also measured H2O ice features centered near 1.5 µm, 1.65 µm, and 2.0 µm, and a broad 3.6 µm H2O continuum peak, which are all stronger at northern latitudes, in contrast to the 3.1 µm Fresnel peak identified at southern latitudes. These results support the hypothesis that H2O ice in Europa’s regolith is vertically stratified, with amorphous ice grains dominating its exposed surface, except in Tara and Powys Regiones. We also find that a previously detected 4.38 µm 13CO2 feature is present almost exclusively at southern latitudes in Tara and Powys Regiones, likely derived from an internal source of carbon-bearing material.

Surface processes (2116)