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710 records · Page 7

Semi-Dynamic Leach Testing of Densified Silicon-based Iodine Waste Forms

Iodine waste forms (IWF) require a conceptual corrosion release model (CCRM) to provide iodine (I) release rates for performance modeling nuclear waste disposal repositories. To develop a CCRM, an understanding of the corrosion mechanisms of the IWF are required along with data from consistent test methods to parameterize the model. The present study has advanced both areas by providing and assessing the corrosion resistance of IWF types based on their processing history in minor variations of semi-dynamic leach tests. The test included a series of semi-dynamic leach tests using monolithic IWFs in deionized water (leachant). Several experiments were conducted under alternate test conditions with changes to temperature, leachant replacement, leachant pH, leachant volume, masking, and surface finish to elucidate if varying these conditions impacted IWF corrosion behavior. Tests were conducted on two classes of IWFs: (1) I-bearing silver-mordenite (AgZ) materials processed by hot isostatic pressing (HIP) at different temperatures, pressures, sizes, and times; and (2) I-bearing silver-functionalized silica aerogels (SFA) processed by either HIP or spark plasma sintering (SPS). The corrosion susceptibility of AgZ samples was influenced by HIP temperature and pressure. The SPS SFAs retained I far better than HIP SFAs. Additional findings in this study include: (1) The iodine dissolution rate decreased with decreasing temperature, (2) a common ion effect may occur and slow dissolution of the host phase if the leachant is not regularly replaced, (3) pH controls the dissolution rate, and (4) the iodine dissolution rate slows with extended test time (up to 224 days). Based on this work, these parameters should thus be represented when developing a CCRM.

corrosion

Pulsed Magnetic Field Driven Gas Core Reactors for Space Power & Propulsion Applications

The present results indicated that: 1. A pulsed magnetic driven fission power concept, PMD-GCR is developed for closed (NER) and semi-open (NTR) operations. 2. In power mode, power is generated at alpha less than 1 for power levels of hundreds of KW or higher 3. IN semi open NTR mode, PMD-GCR generates thrust at I(sub sp) approx. 5,000 s and jet power approx. 5KW/Kg. 4. PMD-GCR is highly subcritical and is actively driven to critically. 5. Parallel path with fusion R&D needs in many areas including magnet and plasma.

Samim Anghaie

Lunar Electrical Conductivity, Permeability and Temperature From Apollo Magnetometer Experiments

Magnetometers have been deployed at four Apollo sites on the Moon to measure remanent and induced lunar magnetic fields. Measurements from this network of instruments have been used to calculate the electrical conductivity, temperature, magnetic permeability, and iron abundance of the lunar interior. The measured lunar remanent fields range from 3 gammas (γ) minimum at the Apollo 15 site to 327 γ maximum at the Apollo 16 site. Simultaneous magnetic field and solar plasma pressure measurements show that the remanent fields at the Apollo 12 and 16 sites interact with, and are compressed by, the solar wind. Remanent fields at Apollo 12 and Apollo 16 are increased 16 γ and 32 γ, respectively, by a solar plasma bulk pressure increase of 1.5 x 10 -7 dynes/cm 2 . Global lunar fields due to eddy currents, induced in the lunar interior by magnetic transients, have been analyzed to calculate an electrical conductivity profile for the Moon. From nightside magnetometer data in the solar wind it has been found that deeper than 170 km into the Moon the conductivity rises from 3 x 10 -4 mhos/m to 10 -2 mhos/m at 1000-km depth. Recent analysis of data obtained in the geomagnetic tail, in regions free of complicating plasma effects, yields results consistent with nightside values. Conductivity profiles have been used to calculate the lunar temperature for an assumed lunar material of olivine. In the outer layer (~ 170 km thick) the temperature rises to 110° C, after which it gradually increases with depth to 1500° C at a depth of ~ 1000 km. Simultaneous measurements by magnetometers on the lunar surface and in orbit around the moon are used to construct a whole-moon hysteresis curve, from which the global lunar magnetic permeability is determined to be μ = 1.012 ± 0.006. The corresponding global induced dipole moment is 2 x 10 18 gauss-cm 3 for typical inducing fields of 10 -4 gauss in the lunar environment. Lunar free iron abundance corresponding to the global permeability is determined to be 2.5 ± 2.0 wt. %. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) is calculated for two assumed compositional models of the lunar interior. For a free iron/orthopyroxene lunar composition the total iron content is calculated to be 12.8 ± 1.0 wt. %; for a free iron/olivine composition, total iron content is 5.5 ± 1.2 wt. %. Other lunar models with an iron core and with a shallow iron-rich layer are also discussed in light of the measured global lunar permeability. Velocities and thicknesses of the Earth's magnetopause and bow shock have been estimated from simultaneous magnetometer measurements. Average speeds are determined to be about 50 km/s for the magnetopause and 70 km/s for the bow shock, although there are large variations in the measurement for any particular boundary crossing. Corresponding measured boundary thicknesses average about 2300 km for the magnetopause and 1400 km for the bow shock.

P Dyal

Evaluation of Low-Energy Hydrogen Separation Method Using Metal-Organic Frameworks (MOFs) for Closed-Loop ECLSS Air Revitalization (CLEAR)

The State-of-the-Art (SOA) air revitalization architecture onboard the International Space Station (ISS) recovered approximately 50% of the oxygen (O 2 ) from metabolic carbon dioxide (CO 2 ) via the Sabatier process from 2011 to 2017. O 2 recovery is currently constrained by the limited availability of reactant hydrogen (H 2 ) preventing complete conversion of CO 2 to H 2 O. Increasing O 2 recovery within Closed-Loop ECLSS is essential to reducing resupply mass for long-duration manned missions; specifically focusing on water (H 2 O) which supplies H 2 for Sabatier via water electrolysis. Past ground test endeavors at Marshall Space Flight Center (MSFC) have attempted to recover H 2 from Sabatier-produced CH 4 using technologies such as carbon vapor deposition (CVD) and plasma pyrolysis. The byproducts of these technologies can act as a catalyst poison or reactor deadload to the Sabatier reactor. Hydrogen separation techniques must be utilized to maintain the Sabatier catalyst during gas recycling and must be scalable, non-energy intensive, and safe to operate in a habitation setting. Research indicated that metal-organic frameworks (MOFs) could meet these criteria and were tested for their capability to capture the various carbon-based gaseous products of CVD and plasma pyrolysis such as acetylene (C 2 H 2 ), ethylene (C 2 H 4 ), ethane (C 2 H 6 ), and carbon monoxide (CO) which would purify the hydrogen gas stream passing through the MOF. A sub-scale adsorption column was developed by Marshall Space Flight Center to test three MOF candidates against a synthetic gas mixture comprised of process-relevant carbonous gases and hydrogen to evaluate the separation capability of the MOFs. The results of the hydrogen separation capability, isothermal desorption capability, and demonstrated cyclic reuse of the MOF are presented in this paper.

Kagen Crawford

Observational evidence for Criegee intermediate oligomerization reactions relevant to aerosol formation in the troposphere

Criegee intermediates are reactive intermediates that are implicated in transforming the composition of Earth’s troposphere and in the formation of secondary organic aerosol, impacting Earth’s radiation balance, air quality and human health. Yet, direct identification of their signatures in the field remains elusive. Here, from particulate and gas-phase mass-spectrometric measurements in the Amazon rainforest, we identify sequences of masses consistent with the expected signatures of oligomerization of the CH 2 OO Criegee intermediate, a process implicated in ozonolysis-driven aerosol formation. In this study, we assess the potential contributions of oligomerization through laboratory ozonolysis experiments, direct kinetic studies of Criegee intermediate reactions, and high-level theoretical calculations. Global atmospheric models built on these kinetics results indicate that Criegee intermediate chemistry may play a larger role in altering the composition of Earth’s troposphere than is captured in current atmospheric models, especially in areas of high humidity. However, the models still capture only a relatively small fraction of the observed signatures, suggesting considerable underestimates of Criegee intermediate concentrations and reactivity and/or the dominance of other, presently uncharacterized, oxidation mechanisms. Resolving the remaining uncertainties in emission inventories and the effects of atmospheric water vapour on key chemical reactions will be required to definitively assess the role of Criegee intermediate oligomerization reactions.

58 GEOSCIENCES

FAST Spacecraft Battery Design and Performance

The Fast Auroral Snapshot (FAST) Explorer spacecraft is to study the physical processes that produce the aurora borealis and aurora australis. It is a unique plasma physics experiment that will take fundamental measurements of the magnetic and electrical fields. This investigation will add significantly to our understanding of the near-earth space environments and its effect. The FAST has a 1 year requirement and 3-year goal for its mission life in low earth orbit. The FAST power power system topology is a Direct Energy Transfer (DET) system based on the SAMPEX design. The FAST flight battery supplies power to the satellite during pre-launch operations, the launch phase, the eclipse periods for all mission phases, and when the load is about 50 watts.

Jung, David S.

NASA Talks: Harsh Lunar Environments

NASA Talks - Exploration drives technology, and as NASA works toward sustained operations on the lunar surface for a permanent moonbase, it is critical to understand how the location drives what’s needed to accomplish these goals. This is especially important as we land on the lunar South Pole, which will be different and riskier than the previous Apollo landing sites. The thermal conditions will be much colder, the lighting environment is challenged with low sun angles, the regolith holds a charge in the plasma sheath, and the radiation is significantly higher than in low Earth orbit (LEO). Stephanie Sipila, Deputy Manager of Extravehicular Activity and Human Surface Mobility Program (EHP) Technology, Integration and Partnerships Office, provided knowledge and insight into the game-changing technologies NASA is exploring to mitigate these risks.

Stephanie Sipila

Experimental Effects of Scaling on the Performance of Ion Rockets Employing Electron-Bombardment Ion Sources

A scaling program was undertaken to establish the relations between performance parameters and the size of the electron bombardment ion source. The experimental results of this investigation are the subject of this paper. Two geometrically similar sources, a 5- and a 20-cm-diameter beam source, were scaled from a 10-cm-diameter source to allow a performance comparison to be made. The three ion sources are compared for ion chamber characteristics and overall engine efficiency. The results of the chamber investigations are compared with scaling variations indicated by simple plasma theory. The effects of size on operating limits are also discussed. Mercury was used as the propellant in this investigation.

Power Supply

Overview of the Center for Advanced Space Propulsion

The mission of the Center for Advanced Space Propulsion (CASP), a Center for the Commercial Development of Space (CCDS), is to strengthen U.S. competitiveness in space technology, foster cooperative research with industry and government, assist industry in developing commercial products and services, and perform research in advanced space propulsion. Current areas of focus are (1) advanced chemical propulsion, including high area ratio nozzle performance, variable thrust engine performance, and spray combustion stability; (2) artificial intelligence propulsion applications, including health monitoring of rocket engines, fault pattern detection and diagnosis, and intelligent hypertext applications; (3) microgravity fluid management, including liquid storage and transfer, a subscale orbital fluid transfer experiment, and helical, two-phase flow; (4) electric propulsion, including magnetic annular arc thruster, ion thrustor, and electrostatic plasma accelerator; and (5) laser materials processing.

George W Garrison

Material Compatibility Testing of Green Hydrazine

Green Hydrazine Propellant Blend (GHPB) is a new green propellant developed by Aerojet Rocketdyne and selected for continued testing at NASA’s Goddard Space Flight Center (GSFC). It primarily differs from previous "green” propellants by maintaining traditional hydrazine as the base constituent, along with additives that are intended to increase handling safety by lowering the concentration of hydrazine in the vapor. GSFC has performed material compatibility testing. The scope of this campaign included materials that are common in spacecraft or ground support equipment (GSE), and also included typical safety materials (e.g. permeation rates through gloves). The conclusion in a broad sense is that GHPB is less reactive than hydrazine, including the absorption of metals into the propellant, as examined by Inductively-Coupled Plasma (ICP) analysis of metals uptake.

Eric H Cardiff

Diagnostics development for the Electric Propulsion Orbital Platform

We describe the development of the diagnostics systems for the first flight of the Electric Propulsion Orbital Platform (EPOP), which will center around the in-flight characterization of a 1.8 kW hydrogen arcjet system. In particular, we discuss a spacecraft communications experiment involving ground-to-spacecraft communications of the EPOP carrier; electrical probe measurements in the arcjet plume; and spectrally resolved plume imaging measurements of the same plume. The communications experiment is designed to measure small noise on the communications link which results from arcjet operation. The other two measurements primarily serve the purpose of characterization of the plume plasma. These measurements will be compared to similar measurements performed in a ground chamber to establish whether systematic differences exist between ground-based and in-flight performance of the arcjet system.

Wilhelmus M. Ruyten

Comparative neutron-irradiation effects on thermal conductivity degradation and dimensional stability of TiC, TiB 2 , and ZrB 2 at 200–1000 °C

Ultra-high-temperature ceramics (UHTCs), including TiC, Ti 11 B₂, and Zr 11 B₂, show great potential for plasma-facing components due to their excellent high-temperature properties prior to irradiation. However, their response to neutron irradiation remains insufficiently understood, limiting robust assessment of their viability for fusion energy applications. Here, this study examines the thermal conductivity, dimensional stability and microstructure of TiC, TiB₂, and ZrB₂ following neutron irradiation at temperatures of 200–1000 °C and fast neutron fluences of 2.0 × 10 25 to 1.1 × 10 26 n/m 2 (E > 0.1 MeV). Lattice swelling measured by synchrotron X-ray diffraction in all three UHTCs was maximized at 200 °C and decreased with increasing irradiation temperature, with no evidence of amorphization observed at 200 °C. Above 600 °C, significant macroscopic volume swelling was observed in irradiated Ti 11 B₂ and Zr 11 B₂, but not in TiC, likely due to cavity formation in the diborides. The post-irradiation thermal conductivity, measured at the irradiation temperature, ranged from 28 to 45 W/m·K, representing a 34–45% reduction relative to the unirradiated material. Notably, neutron-irradiated UHTCs exhibit recoverable thermal conductivity at elevated temperatures, comparable to ferritic–martensitic steels and potentially superior to W when transmutation effects are considered, highlighting promise for shielding or armor plasma-facing components. At 600 °C, both thermal conductivity degradation and lattice swelling saturated at doses exceeding 2–4 dpa.

fusion materials

NASA's Advanced Control Law Program for the F-8 Digital Fly-By-Wire Aircraft

This paper briefly describes the NASA F-8 Digital Fly-By-Wire (DFBW) program and Langley Research Center's role in investigating and promoting advanced control laws for possible flight experimentation. The primary purpose of the paper is to provide background material for papers describing some of the F-8 DFBW adaptive control law studies. The paper provides a brief description of the Phase II DFBW F-8 aircraft and its control system, discusses some of the advanced control law study objectives and guidelines, and provides some mathematical models which are useful in the control analysis problem.

Optimal Control

NASA's Advanced Control Law Program for the F-8 Digital Fly-By-Wire Aircraft

This paper briefly describes the NASA F-8 Digital Fly-By-Wire (DFBW) and Langley Research Center's role in investigating and promoting advanced control laws for possible flight experimentation. The primary purpose of the paper is to provide background material for the papers that follow which describe some of the F-8 DFBW adaptive control law studies. The paper provides a brief description of the Phase II DFBW F-8 aircraft and its control system, discusses some of the advanced control law study objectives and guidelines, and provides some mathematical models which are useful in the control analysis problem.

Aerospace Materials

Supervisory genset control in range-extended electric vehicle

A controls system for a range-extended electric vehicle comprising an overall system control unit, an engine control module configured to control a range extender of the range-extended electric vehicle, power electronics configured to control a generator of the range-extended electric vehicle, and a supervisory control module coupled between the overall system control unit and the engine control module and the power electronics, the supervisory control module configured to receive information from the overall system control unit and provide commands to the engine control module and the power electronics.

Li, Ke