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At least 1,405 records · Page 78

Scalable preparation of oxygen carriers for chemical looping

Wet impregnation of active metal precursors into porous substrates, together with selective adsorption of the precursors on the pore surfaces, enables transition metal oxides derived from the precursors to disperse throughout the substrate, even at the nanoscale, without increased sintering or agglomeration, thereby forming oxygen carriers suitable for chemical looping. The porous substrate can be an oxide, for example SiO 2 . The oxygen carriers can comprise relatively large oxide loadings of over about 20 wt % and exhibit high reactivity over many regeneration cycles with substantially no loss in oxygen transport capacity or decrease in kinetics. The use of multiple transition metal oxides, for example NiO in addition to CuO, can greatly enhance chemical looping performance.

O′Malley, Kyle↗

Evaluating the Impact of Price-Responsive Load on Power Systems Using Integrated T&D Simulation

This paper explores the differences between simulating price-responsive load (PRL) interactions with power systems using integrated transmission and distribution (T&D) models and transmission-only (T-only) models. This analysis uses the Integrated Grid Modeling System (IGMS) software to capture 'ISO-to-appliance' simulations using a synthetic T&D model built on the PJM 5-Bus transmission network with multiple full-scale taxonomy feeders that include physics-based models of thousands of customers and PRLs. The results show important differences in the impacts of PRLs between integrated T&D and T-only models. Experiments with the synthetic integrated T&D dataset demonstrated that integrated T&D simulation revealed notably larger differences between the PRL and no-PRL cases for load, and prices compared to T-only simulation. Similarly, differences are observed between the price response of individual buildings and distribution feeders and the corresponding transmission bus in the integrated T&D simulations, which are difficult to capture in traditional T-only simulations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Microstructure-sensitive small fatigue crack growth assessment. Effect of strain ratio multiaxial strain state and geometric discontinuities

Fatigue crack initiation in the high cycle fatigue regime is strongly influenced by microstructural features. Research efforts have usually focused on predicting fatigue resistance against crack incubation without considering the early fatigue crack growth after encountering the first grain boundary. However, a significant fraction of the variability of the total fatigue life can be attributed to growth of small cracks as they encounter the first few grain boundaries, rather than crack formation within the first grain. Our paper builds on the framework previously developed by the authors to assess microstructure-sensitive small fatigue crack formation and early growth under complex loading conditions. Moreover, the scheme employs finite element simulations that explicitly render grains and crystallographic directions along with simulation of microstructurally small fatigue crack growth from grain to grain. The methodology employs a crystal plasticity algorithm in ABAQUS that was previously calibrated to study fatigue crack initiation in RR1000 Ni-base superalloy. Our work present simulations with non-zero applied mean strains and geometric discontinuities that were not previously considered for calibration. Results exhibit trends similar to those found in experiments for multiple metallic materials, conveying a consistent physical description of fatigue damage phenomena.

36 MATERIALS SCIENCE↗

Fracture behavior of large-scale thin-sheet aluminum alloy

A series of fracture tests on large-scale, pre-cracked, aluminum alloy panels is being carried out to examine and to characterize the process by which cracks propagate and link up in this material. Extended grips and test fixtures were specially designed to enable the panel specimens to be loaded in tension, in a 1780-kN-capacity universal testing machine. Twelve panel specimens, each consisting of a single sheet of bare 2024-T3 aluminum alloy, 3988 mm high, 2286 mm wide, and 1.016 mm thick are being fabricated with simulated through-cracks oriented horizontally at mid-height. Using existing information, a test matrix has been set up that explores regions of failure that are controlled by fracture mechanics, with additional tests near the boundary between plastic collapse and fracture. In addition, a variety of multiple site damage (MSD) configurations have been included to distinguish between various proposed linkage mechanisms. All tests but one use anti-buckling guides. At this writing seven specimens have been tested. Three were fabricated with a single central crack, three others had multiple cracks on each side of the central crack, and one had a single crack but no anti-buckling guides. Each fracture event was recorded on film, video, computer, magnetic tape, and occasionally optical microscopy. The visual showed the crack tip with a load meter in the field of view, using motion picture film for one tip and SVHS video tape for the other. The computer recorded the output of the testing machine load cell, the stroke, and twelve strain gages at 1.5 second intervals. A wideband FM magnetic tape recorder was used to record data from the same sources. The data were analyzed by two different procedures: (1) the plastic zone model based on the residual strength diagram; and (2) the R-curve. The first three tests were used to determine the basic material properties, and these results were then used in the analysis of the two subsequent tests with MSD cracks. There is good agreement between measured values and results obtained from the model.

Dewit, Roland↗

Topology optimization of finite strain viscoplastic systems under transient loads [Dynamic topology optimization based on finite strain visco-plasticity]

In this paper, a transient finite strain viscoplastic model is implemented in a gradient-based topology optimization framework to design impact mitigating structures. The model's kinematics relies on the multiplicative split of the deformation gradient, and the constitutive response is based on isotropic hardening viscoplasticity. To solve the mechanical balance laws, the implicit Newmark-beta method is used together with a total Lagrangian finite element formulation. The optimization problem is regularized using a partial differential equation filter and solved using the method of moving asymptotes. Sensitivities required to solve the optimization problem are derived using the adjoint method. To demonstrate the capability of the algorithm, several protective systems are designed, in which the absorbed viscoplastic energy is maximized. Finally, the numerical examples demonstrate that transient finite strain viscoplastic effects can successfully be combined with topology optimization.

42 ENGINEERING↗

Multiple-function multi-input/multi-output digital control and on-line analysis

The design and capabilities of two digital controller systems for aeroelastic wind-tunnel models are described. The first allowed control of flutter while performing roll maneuvers with wing load control as well as coordinating the acquisition, storage, and transfer of data for on-line analysis. This system, which employs several digital signal multi-processor (DSP) boards programmed in high-level software languages, is housed in a SUN Workstation environment. A second DCS provides a measure of wind-tunnel safety by functioning as a trip system during testing in the case of high model dynamic response or in case the first DCS fails. The second DCS uses National Instruments LabVIEW Software and Hardware within a Macintosh environment.

Hoadley, Sherwood T.↗

NovoGraph: Human genome graph construction from multiple long-read de novo assemblies

Genome graphs are emerging as an important novel approach to the analysis of high-throughput human sequencing data. By explicitly representing genetic variants and alternative haplotypes in a mappable data structure, they can enable the improved analysis of structurally variable and hyperpolymorphic regions of the genome. In most existing approaches, graphs are constructed from variant call sets derived from short-read sequencing. As long-read sequencing becomes more cost-effective and enables de novo assembly for increasing numbers of whole genomes, a method for the direct construction of a genome graph from sets of assembled human genomes would be desirable. Such assembly-based genome graphs would encompass the wide spectrum of genetic variation accessible to long-read-based de novo assembly, including large structural variants and divergent haplotypes. We present NovoGraph, a method for the construction of a human genome graph directly from a set of de novo assemblies. NovoGraph constructs a genome-wide multiple sequence alignment of all input contigs and creates a graph by merging the input sequences at positions that are both homologous and sequence-identical. NovoGraph outputs resulting graphs in VCF format that can be loaded into third-party genome graph toolkits. To demonstrate NovoGraph, we construct a genome graph with 23,478,835 variant sites and 30,582,795 variant alleles from de novo assemblies of seven ethnically diverse human genomes (AK1, CHM1, CHM13, HG003, HG004, HX1, NA19240). Initial evaluations show that mapping against the constructed graph reduces the average mismatch rate of reads from sample NA12878 by approximately 0.2%, albeit at a slightly increased rate of reads that remain unmapped.

59 BASIC BIOLOGICAL SCIENCES↗

Results of Use of Heat Flux Sensors on Liquid Hydrogen Tanks

Heat flux sensors were used to characterize the performance of insulation on the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER), a large-scale test article designed to simulate upper stage cryogenic propellant tank thermal performance in simulated space environments. Usually, the insulation heat loads are derived from calculations removing all other heat sources and attributing the residual heat load to the insulation system. Testing for SHIIVER included the tank being just insulated with spray-on-foam insulation as well as covering the domes with multilayer insulation while leaving the barrel section insulated with spray-on-foam. Heat flux sensors were located at multiple locations on both domes as well as on the barrel section of the tank. Results from the SHIIVER testing using the heat flux sensors are compared to other calculated heat inputs for both liquid nitrogen and liquid hydrogen testing as a function of tank fill level. Further investigation into the transient nature of the SHIIVER testing including the heat flux sensors provided insight into heat flow patterns that may not have been otherwise seen using temperature sensors and calculated insulation heat loads. While the demonstrated uncertainties in the absolute values in the heat flux sensors are high, the values and the trends match well with other calculation methods. The results of SHIIVER allow for the use of heat flux sensors for measurements of insulation performance and dynamic system thermal response for future applications.

Cryogenic Fluid Management↗

Results of Use of Heat Flux Sensors on Liquid Hydrogen Tanks

ABSTRACT: Heat flux sensors were used to characterize the performance of insulation on the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER), a large-scale test article designed to simulate upper stage cryogenic propellant tank thermal performance in simulated space environments. Usually, the insulation heat loads are derived from calculations removing all other heat sources and attributing the residual heat load to the insulation system. Testing for SHIIVER included the tank being just insulated with spray-on-foam insulation as well as covering the domes with multilayer insulation while leaving the barrel section insulated with spray-on-foam. Heat flux sensors were located at multiple locations on both domes as well as on the barrel section of the tank. Results from the SHIIVER testing using the heat flux sensors are compared to other calculated heat inputs for both liquid nitrogen and liquid hydrogen testing as a function of tank fill level. Further investigation into the transient nature of the SHIIVER testing including the heat flux sensors provided insight into heat flow patterns that may not have been otherwise seen using temperature sensors and calculated insulation heat loads. While the demonstrated uncertainties in the absolute values in the heat flux sensors are high, the values and the trends match well with other calculation methods. The results of SHIIVER allow for the use of heat flux sensors for measurements of insulation performance and dynamic system thermal response for future applications.

Cryogenic Fluid Management↗

Enhanced Pu emission with solution-loaded laser ablation modified sources (SLLAMS) for thermal ionization mass spectrometry

This study presents a new approach to filament modification by laser ablation for analysis of femtograms of plutonium (Pu) by thermal ionization mass spectrometry (TIMS). This method simplifies the often rigorous and labor-intensive sample loading necessary for low-level analyses by TIMS with solution-loaded laser ablation modified sources (SLLAMS). By applying a para-film coating to the surface of the filament and then ablating through the film to reveal metal beneath, a point source is created. A solution containing ppt-levels of Pu can then be applied over the ablated region, dried slowly into the crater, and then carburized. All analyses were made by multiple ion counting system of a Nu Instruments TIMS. Furthermore, we report errors of 10% 2σ for 240 Pu/ 239 Pu of CRM-137 samples totaling 5 – 7 femtograms (fg; 1E-15 g) with an average sample utilization efficiency of 1.3%. Results from SLLAMS demonstrate an improvement in precision, accuracy and ease of use over resin bead loads.

47 OTHER INSTRUMENTATION↗

Summer 2015 Internship Abstract

Green fluorescent protein (GFP) visually shows the expression of proteins by fluorescing when exposed to certain wavelengths of light. The GFP in this experiment was used to identify cells actively releasing viruses. The experiment focused on the effect of microgravity on the GFP expression of Akata B-cells infected with Epstein Barr Virus (EBV). Two flasks were prepared with 30 million cells each and two bioreactors were prepared with 50 million cells each. All four cultures were incubated for 16 days and fed every four days. Cellometer readings were taken on the feeding days to find cell size, viability, and GFP expression. In addition, the cells were treated with Propodium monoazide (PMA) and run through real time PCR to determine viral load on the feeding days. On the International Space Station air samples are taken to analyze the bacterial and fungal organisms in the air. The Sartorius Portable Airport is being investigated for potential use on the ISS to analyze for viral content in the air. Multiple samples were taken around Johnson Space Center building 37 and in Clear Lake Pediatric Clinic. The filter used was the gelatin membrane filter and the DNA was extracted directly from the filter. The DNA was then run through real time PCR for Varicella Zoster Virus (VZV) and EBV as well as GAPDH to test for the presence of DNA. The results so far have shown low DNA yield and no positive results for VZV or EBV. Further inquiry involves accurately replicating an atmosphere with high viral load from saliva as would be found on the ISS to run the air sampler in. Another line of research is stress hormones that may be correlated to the reactivation of latent viruses. The stress hormones from saliva samples are analyzed rather than blood samples. The quantity found in saliva shows the quantity of the hormones actually attached to cells and causing a reaction, whereas in the blood the quantity of hormones is the total amount released to cause a reaction. The particular hormones tested for were cortisol, alpha-amylase, and DHEA. The DHEA was very high in the two control samples tested. Regularly, samples came into the lab from local clinics to be tested for various viruses. Saliva, blood, body scrapes, and tears were received from the clinics and then run for VZV, EBV, and Human Simplex Virus 1 (HSV-1) with the results then reported back to the clinician. Blood, saliva, and urine from astronauts were also tested for viruses and logged. In addition, several cell cultures were brought up and grown, including adherent Human Lung Fibroblast (HFL) cells infected with VZV, and Akata B-cells infected with EBV.

Smith, Courtney↗

Evaluating the Impact of Price-Responsive Load on Power Systems Using Integrated T&D Simulation: Preprint

This paper explores the advantages and challenges of simulating price-responsive load (PRL) interactions with large-scale power systems using integrated transmission and distribution (T&D) models. This analysis uses the Integrated Grid Modeling System (IGMS) software to capture 'ISO-to-appliance' simulations using a synthetic T&D model built on the PJM 5 Bus transmission network with multiple full-scale taxonomy feeders that include physics-based models of thousands of PRLs. The results show substantial differences in the impacts of PRLs between integrated T&D and transmission-only (T-only) models. Similarly differences are observed between the price response of individual distribution feeders and the corresponding transmission bus in the integrated T&D simulations, which cannot be captured in T-only simulations. Experiments include both traditional price responsive load reductions and price-driven load increases during low net demand periods driven by high daytime generation from distributed generation-based photovoltaics (DGPV).

24 POWER TRANSMISSION AND DISTRIBUTION↗

Simulation of the NuScale SMR and Investigation of the Effect of Load-Following on Component Lifetimes

The NuScale SMR has been modelled using the Virtual Environment for Reactor Applications (VERA) multiphysics environment and the results compared with the publicly reported data in the Design Certification Application (DCA). The results show an excellent agreement for the compared axial and radial power distributions, temperature coefficients of reactivity, boron and control rod worths, and fast neutron flux. This NuScale model is then used to investigate the effect of different operational modes on reactor components to determine how flexible load-following operation may affect control rod and reactor pressure vessel (RPV) lifetimes. The control rod degradation is confirmed to primarily affect the silver-indium-cadmium (AIC) rod tip. The degradation rate is observed to follow a non-linear function of core power level where the increase in degradation decreases with insertion depth. For the variation in core power levels expected with current load-following schemes, the total control rod degradation is found to be mild, at 5-10% of usable life per cycle for a reactor operating at <80% power. Nonetheless, this enables load following strategies to be confirmed and/or modified to ensure that control rods do not need to be replaced during the 60+ year life of the reactor. The RPV degradation was found to be almost directly proportional to the core power level and was not overly sensitive to flux shape perturbations. Future work is planned using these damage functions to optimize operation over multiple NuScale SMR units and develop strategies for prognostics and health management.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A phase-field model for hydride formation in polycrystalline metals: Application to δ-hydride in zirconium alloys

We report a phase-field model for simulating metal hydride formation involving large volume expansion in single- and polycrystals. As an example, we consider δ-hydride formation in α-zirconium (Zr), which involves both displacive crystallographic structural change and hydrogen diffusion process. Thermodynamic Gibbs energy functions are extracted from the available thermodynamic database based on the sublattice model for the interstitial solid solutions. Solute-grain boundary interactions and inhomogeneous elasticity of polycrystals are taken into consideration within the context of diffuse-interface description. The stress-free transformation strains of multiple variants for hcp -Zr (α) to fcc -hydride (δ) transformation are derived based on the well-established orientation relationship between the α and δ phases as well as the corresponding temperature-dependent lattice parameters. In particular, to account for the large volume expansion, we introduced the mixed interfacial coherency concept between those phases—basal planes are coherent and prismatic planes are semi-coherent in computing the strain energy contribution to the thermodynamics. We analyzed the morphological characteristics of hydrides involving multiple structural variants and their interactions with grain boundaries. Moreover, our simulation study allows for the exploration of the possible hydride re-orientation mechanisms when precipitating under applied tensile load, taking into account the variation in the interfacial coherency between hydrides and matrix, their elastic interactions with the applied stress, as well as their morphology-dependent interactions with grain boundaries. Here, the phase-field model presented here is generally applicable to hydride formation in any binary metal–hydrogen systems.

36 MATERIALS SCIENCE↗

A Multi-Model Framework for Assessing Long- and Short-Term Climate Influences on the Electric Grid

Climate change influences many aspects of the electric grid, but prior work and industry practices often ignore the potential effects of changing climate, or they only consider a single effect or individual effects in isolation. Challenges vary with each grid and include adapting to long-term trends such as changing temperature and precipitation or shorter-term events such as drought or storms that could increase in frequency or intensity. Here we present a multi-model framework designed to analyze the effects of long and short-term climate impacts in combination. This framework couples capacity expansion and production cost models with hydrologic models and future climate scenario data to analyze alternative climate and energy futures at high spatial, temporal, and process resolutions. Furthermore, we constructed and evaluated the results of a suite of simulated scenarios exploring climate impacts on capacity investment and stress-tested the resulting future infrastructures using hourly dispatch modeling under alternative drought and load conditions. We demonstrate the approach through a case study of the U.S. Western Interconnection, where climate impacts depend on interactions between temperature-induced load, water availability for hydropower, technology competitiveness, and demand flexibility. Changes in 2038 generating capacity range from -8.5-16.6 GW, and changes in 2038 transmission capacity range from -1-2 GW. Capacity increases are driven by higher load from higher temperatures, while capacity reductions can be achieved in scenarios with higher future hydropower availability and increased demand flexibility. Scenarios requiring additional capacity cost an additional $\$5$-$\$17$ billion (discounted) from 2018 to 2038; however, scenarios with capacity reductions cost $\$1$-$\$18$ billion less. Stress tests on four 2038 infrastructures demonstrated that the identified systems were able to serve at least 99.999% of load and 99.96% of reserves. However, drought and unexpected high-load conditions can result in reduced capacity to respond to contingency events we did not model. Although these results are system and scenario specific, they highlight the importance of considering multiple climate change impacts simultaneously in long-term planning efforts and demonstrate a multi-model, multiscale approach that can be flexibly applied to any system and set of climate change concerns.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Shock recompaction of spall damage

Spall fracture is a high strain-rate damage phenomenon associated with shock or impulsive loading events. When a material that has been subjected to shock compression is allowed to release, rarefaction waves propagate into the sample and reduce the internal stress to zero. If multiple rarefaction waves intersect, they generate tension which, if sufficient, can nucleate voids in the material. It has been observed in several works investigating spall fracture that although the shock-wave profiles suggested spall occurred, imaging of the recovered sample revealed no voids or cracks. In this study, we aim to determine whether a second shock event could recompact existing spall damage, and if so, what form does the microstructure at the recompaction interface have? Through a series of gas-gun flyer-plate impact experiments, we demonstrate that modest shock stresses of 2 GPa–3 GPa are enough to both fully compact a damaged copper target back to a state of zero porosity and, furthermore, drive recrystallization of the interface such that there is a new bond formed where the free surfaces were brought together.

42 ENGINEERING↗

Radiation Damage Analysis of FNSF Components Using McCad and MCNP

The Fusion Energy System Studies Fusion Nuclear Science Facility (FESS-FNSF) concept represents a transitional step between ITER and a commercial fusion power plant. The FNSF is a conceptualized D-T fueled tokamak with 518 MW of fusion power that has been extensively used to explore and optimize design features. The energetic 14.1-MeV neutrons can produce significant localized heating and activations, and can cause damage to plasma-facing components, which can determine maintenance/outage scheduling needs and also impact the lifetime of the device as a whole. This study illustrates a neutronics analysis that was conducted on a 22.5-degree symmetric sector of the FNSF with the goal of understanding the neutron heating and radiation damage that can be characterized by quantifying the displacements per atom (dpa). Concurrently, this study also focused on the development of analysis capabilities by converting a three-dimensional computer-aided design model of the FNSF into MCNP6.2 input using the McCad code. Accordingly, some confirmatory results on tritium production and the tritium breeding ratio (TBR) are provided to support model validation. The results produced by MCNP6.2 simulations showed that the highest heating and damage occurred in the outboard region, which concentrated approximately 290 MW of the total nuclear heating, in contrast to 97 MW within the inboard region. These results are consistent with previous studies that employed earlier versions of the FNSF concept and different modeling approaches. Furthermore, this study also provides additional details on neutron wall loading, as well as total heating from neutrons and gammas, results which show the total heating of the device (16 sectors) is approximately 477.83 ± 0.80% MW, indicating a neutron energy multiplication factor of 1.15. Additionally, the capability to calculate hydrogen and helium production, as well as dpa, is illustrated. Finally, the neutronics effects of using alternative materials to tungsten carbide were evaluated for the vacuum vessel, low-temperature shield, and structural ring components, which showed that compounds like YH 2 , Mg(BH 4 ) 2 , and ZrH 2 could reduce the total heating on the magnet and also reduce the TBR.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗