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At least 145 records · Page 8

New Directions in Focused Ion Beam Induced Deposition for the Nanoprinting of Functional 3D Heterostructures

The focused ion beam (FIB) microscope is well established as a high-resolution machining instrument capable of site-selectively removing material down to the nanoscale. Beyond subtractive processing, however, the FIB can also add material via a technique known as focused ion beam induced deposition (FIBID). Using FIBID, the FIB can thus be employed for the direct-write of complex nanostructures. This work explores new directions in three-dimensional FIBID nanoprinting, harnessing unique features of helium and neon FIBs. In particular, the superior spatial resolution of these novel FIBs is leveraged to fabricate precise multimaterial architectures, an isotope effect is used to create satellite deposits, and dose-controlled implantation of the gaseous ions is used to engineer internal voids. In the context of voids, the fabrication of hollow nanopillars by helium-FIBID due to concurrent milling (as shown previously by others) is revisited. Insight into the chemical and structural composition of the nanostructures is obtained using advanced electron microscopy, accurately revealing buried interfaces, crystallite distributions, chemical compositions, and material transformations. Next-generation devices and technologies that could be enabled by the novel heterostructures demonstrated here are discussed, setting the stage for the potential evolution of FIBID into a versatile platform for functional nanomaterials design and fabrication.

FIBID

InAs Terahertz Metalens Emitter for Focused Terahertz Beam Generation

Metasurfaces have opened doors to combining multiple photonic functionalities in a single compact device. In particular, the ability to generate short terahertz (THz) pulses with precise wavefront engineering in a single THz metasurface redefined the role metasurfaces can play in THz systems. Here, an InAs metalens emitter which generates and focuses a THz pulse beam is demonstrated using a 130 nm thick InAs metasurface designed as a binary‐phase Fresnel zone plate. The THz beam is focused to a spot of ≈430 μm at 1 THz with a short focal length of 5 mm and large numerical aperture of 0.5. Nanoscale InAs Mie resonators comprising the metasurface enable THz generation with an amplitude as high as 20 times compared to plasmonic THz emitters and several times compared to a 1 mm thick ZnTe crystal. This InAs metasurface emitter provides a new paradigm for designing THz imaging, spectroscopy, and communication systems, where THz beam generation and shaping are performed with a single device without compromising the generation efficiency, while eliminating losses and avoiding limitations of phase matching of conventional nonlinear optics approaches.

47 OTHER INSTRUMENTATION

Optimized manufacturing process for multilayer two-dimensional focusing mirrors in laboratory X-ray applications

Recent advances in laboratory X-ray applications require high-performance optical components that achieve exceptional imaging resolution and beam uniformity within compact experimental setups. Montel mirrors have become a preferred solution due to their unique dual-reflection focusing mechanism and a space-efficient design. Here, in this study, we present an effective manufacturing process for producing Montel mirrors tailored to focus laboratory X-ray beams. The mirrors were fabricated from single-crystal silicon substrates, chosen for their high mechanical stability and compatibility with precision polishing techniques. Our approach begins with the integration of a deterministic chemo-mechanical polishing (CMP)-based pre-shaping step followed by ion beam figuring (IBF), significantly improving manufacturing efficiency. Subsequently, our custom-developed advanced metrology and IBF techniques were employed for fabricating an off-axis, elliptical cylinder Montel mirror system with a 6-mrad total slope, with stringent optical specifications. While post-IBF processes, including multilayer coating, dicing, and gluing, introduced minor surface errors, yet their impact on performance remained negligible. The Montel mirrors manufactured with the optimized process exhibited significantly improved beam uniformity and a reduced focal spot size. These findings validate our approach as a viable solution for high-precision Montel mirror fabrication and facilitate further advancements in laboratory X-ray applications.

36 MATERIALS SCIENCE

MS25: Materials Science-Focused Benchmark Data Set for Machine Learning Interatomic Potentials

Here, we present MS25, a benchmark data set for evaluating machine learning interatomic potentials (MLIPs) across diverse materials-relevant systems including MgO surfaces, liquid water, zeolites, a catalytic Pt surface reaction, high-entropy alloys (HEAs), and disordered Zr-oxides. Five MLIP architectures (MACE, NequIP, Allegro, MTP, and Torch-ANI) are trained and tested, focusing not only on traditional metrics (energies, forces, and stresses) but also explicitly validating derived physical observables such as lattice constants, volumes, and reaction barriers. We find that most models reach comparable accuracy on standard error metrics across the simple systems, although equivariant MLIPs offer 1.5–2× improvements over nonequivariant MLIPs in energy and force error for structurally complex or compositionally disordered environments such as HEAs and Zr–O systems. Our analysis highlights that low errors in energy and force predictions do not guarantee reliable observables, emphasizing the necessity of explicit validation. We demonstrate limitations in cross-framework transferability, as models trained on one zeolite framework (CHA) fail to reliably generalize to predictions of structurally distinct frameworks (e.g., MFI). Size-extensive tests show some dependence on system size for MgO, resulting from forced periodicity. The HEA and Zr–O data sets are identified as challenging tests for future benchmarks and MLIP model architecture developments as they show significant differentiation in error between MLIP architectures and are still relatively difficult at 1000 training images. Moving forward, we recommend that benchmarking efforts shift their focus from marginal accuracy improvements in energy and force errors toward identifying and understanding model failure modes, rigorously assessing transferability, and evaluating how their errors affect observable predictions. For researchers looking to choose an MLIP architecture, we suggest selecting equivariant MLIP architectures if the complexity of the system is a challenge. For simple materials problems, auxiliary features such as integration with molecular dynamics engines, trade-offs between computational data set generation cost vs MLIP inference speed, and framework integration may play a more important decision factor than small differences in error metrics that are unlikely to matter for production-level research.

chemical structure

X-ray free-electron lasing in a flying-focus undulator

Laser-driven free-electron lasers (LDFELs) replace magnetostatic undulators with the electromagnetic fields of a laser pulse. Because the undulator period is half the wavelength of the laser pulse, LDFELs can amplify X rays using lower electron energies and over shorter interaction lengths than a traditional free-electron laser. In LDFELs driven by conventional laser pulses, the undulator uniformity required for high gain necessitates large laser-pulse energies. Here, we show that a flying-focus pulse provides the undulator uniformity required to reach high gain with a substantially lower energy than a conventional pulse. The flying-focus pulse features an intensity peak that travels in the opposite direction of its phase fronts. This enables an LDFEL configuration where an electron beam collides head-on with the phase fronts and experiences a near-constant undulator strength as it co-propagates with the intensity peak. Three-dimensional simulations of this configuration demonstrate the generation of megawatts of coherent X-ray radiation with 20 × less energy than a conventional laser pulse.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Laser wakefield acceleration driven by a discrete flying focus

Laser wakefield acceleration (LWFA) may enable the next generation of TeV-scale lepton colliders. Reaching such energies will likely require multiple LWFA stages to overcome limitations on the energy gain achievable in a single stage. The use of stages, however, introduces challenges such as alignment, adiabatic matching between stages, and a lower average accelerating gradient. Here, we propose a discrete flying focus that can deliver higher energy gain in a single stage, thereby reducing the number of stages required for a target energy. A sequence of laser pulses with staggered focal points and delays drives a plasma wave in which an electron beam experiences a near-constant accelerating gradient over distances beyond those attainable with a conventional pulse. Simulations demonstrate that a discrete flying focus with a total energy of 150 J can transfer 40 GeV per electron to a 50-pC beam in a single 30-cm stage, corresponding to 50 dephasing lengths.

laser wakefield acceleration

Manufacturability-based optical design optimization for advanced Kirkpatrick–Baez X-ray focusing mirrors

The advanced Kirkpatrick–Baez (AKB) mirror setup is an effective and compelling solution to provide stable X-ray nano-focusing for synchrotron radiation or free-electron laser beamlines. We propose an AKB mirror design optimization approach to mitigate the difficulties associated with mirror fabrication by minimizing the total slope ranges of the four curved mirrors while achieving the expected focusing performance. In the optimization, we have considered geometry constraints to ensure the beam acceptance with the required clear aperture, the diffraction-limited focal size with the adequate numerical aperture, and the desired mirror gaps for adjustment and the necessary working distance for the sample stage. Additionally, practical constraints linked to mirror metrology and fabrication, such as mirror length limits and curvature uncertainty in measurement, are taken into account. Furthermore, progressive objective optimization eliminates the need for any initial guess, fully automating the AKB optimization process. This approach facilitates the development of an elegant Wolter-I or Wolter-III type AKB design solution that satisfies these multiple constraints. In cases where constraints cannot be simultaneously satisfied, the optimization results provide valuable insights into areas where trade-offs need to be considered. Simulations with ray tracing and wavefront propagation validate the optimized AKB design showing high tolerance to the beam incident angle.

36 MATERIALS SCIENCE

Modal focal adaptive optics for Bessel-focus two-photon fluorescence microscopy

Adaptive optics (AO) improves the spatial resolution of microscopy by correcting optical aberrations. While its application has been well established in microscopy modalities utilizing a circular pupil, its adaptation to systems with non-circular pupils, such as Bessel-focus two-photon fluorescence microscopy (2PFM) with an annular pupil, remains relatively uncharted. Herein, we present a modal focal AO (MFAO) method for Bessel-focus 2PFM. Measuring and correcting aberration using a spatial light modulator placed in conjugation with the focal plane of the microscope objective, MFAO employs Zernike annular polynomials — a first in AO implementation — to achieve performance on par with a previous zonal AO method, but with a notably simplified optical configuration. We validated the performance of MFAO in correcting artificial and sample-induced aberrations, as well as in in vivo imaging of zebrafish larvae and mouse brains. By expanding the application of modal AO to annular pupils as well as aberration measurement and correction to a wavefront modulator at the objective focal plane, MFAO represents a notable advancement in the implementation of AO in microscopy.

47 OTHER INSTRUMENTATION

High speed laser-induced refractive index change in ophthalmic HEMA hydrogel using a line focus

Laser-induced refractive index change (LIRIC) techniques typically focus femtosecond laser pulses to a tight spot to achieve the high intensities required to alter ophthalmic materials. A line-focus implementation using 800 nm pulses at 1 kHz repetition rate has been shown to greatly increase the effective writing speed of the process, but the high pulse energies used led to nonlinear propagation effects, presenting challenges for the fabrication of ophthalmic correctors. By taking advantage of the lower effective order of multiphoton absorption for 514 nm pulses, power levels may be reduced, allowing overlapped pulse writing. We demonstrate that this allows high-quality phase bars and devices to be made at high speeds.

Manning, Zachary A. [University of Rochester, NY (

Shrub Expansion Simulations at Trail Valley Creek Tundra site using E3SM Land Model (ELM) Arctic-focused Version

The warming of the Arctic is causing substantial compositional, structural, and functional changes in tundra vegetation including shrub and densification in parts of the Arctic. Assessing the impact of these changes in vegetation composition on the Arctic’s carbon and energy budgets is important to constrain projected local and global surface-atmosphere exchanges. We conduct a sensitivity analysis of the projected surface energy fluxes, soil carbon pools, and carbon dioxide fluxes (net ecosystem exchange, gross primary production, and ecosystem respiration) between present day and 2100 to different shrub expansion rates and air temperature increases under future emission scenarios (intermediate – RCP4.5, and high – RCP8.5) using the Arctic-focused version of the Energy Exascale Earth System Model (E3SM) Land Model (ELM). We focus on Trail Valley Creek (TVC), a mineral upland tundra site located in the western Canadian Arctic, which is experiencing tall shrub densification and expansion. In this study, we run TVC under two different warming scenarios RCP4.5 and RCP 8.5 and simulate different shrubification rates projected until year 2100. In this repository, we include all the forcing, input, parameters, and output data corresponding to all the simulations performed. flmd.csv includes a detailed description of the datasets files.

54 ENVIRONMENTAL SCIENCES

Living-off-the-land Techniques Unlikely to Supplant Energy Sector-Focused OT-Specific Malware

Despite increased reports of energy sector-focused threat actors using living-off-the-land (LOTL) techniques, it is unlikely LOTL techniques will wholly supplant malware in energy sector operational technology (OT)-focused cyber operations. Threat actors leverage LOTL techniques to access energy sector networks, abstracting process information and maintaining persistence. Although threat actors using LOTL techniques have successfully interrupted energy sector industrial control environments, designed features of OT-specific malware likely increase the cyber-physical impact of an attack and delay recovery of critical functions and services. Malicious actors will very likely continue to use LOTL techniques for stealth, while designing malware to bolster final impacts on cyber-physical systems in energy sector OT environments.

99 GENERAL AND MISCELLANEOUS

Characterizing the Impact of Heliostat Size, Focus Method, and Optical Error on Concentrating Solar Tower Systems

Concentrating Solar Power (CSP) tower systems use heliostat fields to direct solar energy to a central receiver. The efficiency of the heliostat field is crucial for achieving thermal generation targets and is also the largest cost component, making up 30-40% of total project costs. Developers face a tradeoff: reducing heliostat costs may decrease optical performance and increase land use, while improving performance could raise manufacturing costs (through higher precision). The optimal design depends on land, labor, and manufacturing costs. Additionally, inherent performance limitations exist - optical errors result in larger solar images as heliostats move farther from the receiver, increasing spillage and attenuation losses. Ultimately, there exists a point where receiver design power can no longer be achieved at design conditions for a given solar field area. This point depends on key heliostat field design parameters including field layout, heliostats size, focus method, and heliostat optical error. In this work, we explore and characterize the performance trade-offs between heliostat size, focus method, and optical error using Monte Carlo ray-tracing simulations using NREL's high performance computing resources. The goal of this fundamental investigation is to understand practical heliostat design performance impacts that can be used to produce more cost-effective heliostat fields while still achieving plant thermal generation targets.

14 SOLAR ENERGY

Absolute focus lock for microscopes

Mechanism absolutely immobilizes microscope stage at a preset focus, preserving focus indefinitely. The lock is a second-class lever consisting of a straight body having a fulcrum with a cylindrical bearing surface at one end and a thumbscrew at the other end.

Cone, C. D., Jr.

Focusing of Finite-Amplitude Cylindrical and Spherical Sound Waves in a Viscous and Heat-Conducting Medium

The focusing of acoustic pulses is studied analytically by considering the region of study in three parts: the converging, interaction and diverging regions. First, the linear problem of a pulse of infinitesimal amplitude is studied. For the spherical case, the expected phase change as a result of focusing is verified. The nonlinear case of finite-amplitude pulses leads to the development of M-waves, as determined by applying the method of matched-asymptotic expansions to Burges equation.

Chu, T.

Neutron production mechanism in a plasma focus.

The neutrons emitted by a plasma focus were analyzed by using a time-of-flight method. Flight paths as large as 80 m were used to obtain better than 10% energy resolution. The energy spectrum of neutrons from d-d reactions in the plasma focus shows a sharp onset with average maximum energies of 2.8 and 3.2 MeV in the radial and the axial directions, respectively. The average half-width of the energy spectrum was 270 keV with a shot-to-shot variation between 150 and 400 keV. Simultaneous measurements in the axial and radial directions showed no appreciable difference in the half-widths and thus indicated randomly oriented ion velocities in the plasma. A converging ion model is described which is found to be in agreement with the measured quantities.

Lee, J. H.

Nearly spherical constant power detonation waves driven by focused radiation

Shape and inner flow of a tridimensional spark are studied. The spark is created by focusing a laser beam in a gas. A second order fully non-linear equation is derived for the radial velocity on the axis of symmetry in the neighborhood of the origin. Solutions to that equation display the existence of a forbidden region near the focus, thus indicating the limits of applicability of a small perturbation solution.

George, Y. H.

Study of self-focusing and self-phase-modulation in the picosecond-time regime.

Study of the propagation of a single picosecond pulse of a mode-locked Nd-glass laser in CS2 nitrobenzene and toluene by observations of the birefringence and spectral changes in self-focused laser light. Multiple second-harmonic probing beams are used for birefringence measurements in a single IR pulse in various portions of the active cell. The orientational Kerr effect is found to be the prime factor of induced birefringence in nitrobenzene and toluene. The results for CS2 are also consistent with this mechanism and show that the duration of an IR pulse in the focal volume is less than that of the incident pulse. The properties of beams which are focused within the cell by an external lens are also investigated.

Reintjes, J.