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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Mechanical Properties of Degraded PMR-15 Resin

Thermo-oxidative aging produces a non-uniform degradation state in PMR-15 resin. A surface layer, usually attributed to oxidative degradation, forms. This surface layer has different properties from the inner material. A set of material tests was designed to separate the properties of the oxidized surface layer from the properties of interior material. Test specimens were aged at 316 C in either air or nitrogen, for durations of up to 800 hours. The thickness of the oxidized surface layer in air aged specimens, and the shrinkage and Coefficient of Thermal Expansion (CTE) of nitrogen aged specimens were measured directly. Four-point-bend tests were performed to determine modulus of both the oxidized surface layer and the interior material. Bimaterial strip specimens consisting of oxidized surface material and unoxidized interior material were constructed and used to determine surface layer shrinkage and CTE. Results confirm that the surface layer and core materials have substantially different properties.

Tsuji, Luis C.↗
NASA NTRS1973

A model of wind shear and turbulence in the surface boundary layer

A model of wind and turbulence has been described for the surface boundary layer. The wind structure in the surface layer is considered to be a function of the surface parameters, stability, and height. The surface parameters considered are: (1) the surface roughness length; (2) the surface friction velocity; and (3) the zero plane displacement height. The stability parameter, Z/L, where L is the Monin-Obukov stability length, describes the thermal effect on the wind profile. The logarithmic wind profile is used to describe the mean wind field in the neutral boundary layer, and a logarithmic profile with a stability defect is used to describe the stable and unstable atmospheric conditions. For the very stable conditions, the logarithmic wind law does not hold. Under this condition, the layers of the atmosphere become disconnected and large scale frontal motions are the predominate factor in defining the wind profile. Figures are presented which represent some typical wind profiles in the very stable condition.

Luers, J. K.↗
NASA NTRS2000

Mechanical Properties of Degraded PMR-15 Resin

Thermo-oxidative aging produces a nonuniform degradation state in PMR-15 resin. A surface layer, usually attributed to oxidative degradation, forms. This surface layer has different properties from the inner material. A set of material tests was designed to separate the properties of the oxidized surface layer from the properties of interior material. Test specimens were aged at 316 C in either air or nitrogen, for durations of up to 800 hr. The thickness of the oxidized surface layer in air aged specimens, and the shrinkage and coefficient of thermal expansion (CTE) of nitrogen aged specimens were measured directly. The nitrogen-aged specimens were assumed to have the same properties as the interior material in the air-aged specimens. Four-point-bend tests were performed to determine modulus of both the oxidized surface layer and the interior material. Bimaterial strip specimens consisting of oxidized surface material and unoxidized interior material were constructed and used to determine surface layer shrinkage and CTE. Results confirm that the surface layer and core materials have substantially different properties.

Tsuji, Luis C.↗
DOE OSTI2025

Thermodynamics of MgO Atomic Layer Deposition Surface Reactions

The realities of atomic layer deposition (ALD) surface reactions often deviate from the simple ligand exchange frequently used to illustrate the technique. A detailed understanding of these reactions is necessary to develop greater surface synthetic control including chemical selectivity for patterning or to target defects. Here, the thermodynamics of surface reactions relevant to MgO ALD were investigated using pyroelectric calorimetry to measure the time-resolved heat generation. These reactions show exothermic heat generation of 0.12 mJ/cm 2 and 0.15 mJ/cm 2 for alternating Mg(CpEt) 2 and H 2 O reactions, respectively. The total reaction heat closely matches the standard reaction enthalpy for bulk MgO, supplemented with first-principles molecular calculations. First-principles models further reveal that while simple ligand exchange is favorable during surface reactions, the required increase in Mg-coordination number from two in the precursor to six in bulk MgO requires additional coverage-dependent surface reactions, which depend on the availability and stability of proximal surface hydroxyls.

36 MATERIALS SCIENCE↗
NASA NTRS2000

The Martian Surface Boundary Layer

The difference between surface and atmospheric temperature measured by MPF can help constrain surface albedo, thermal inertia, and infrared emissivity.

Wilson, G. R.↗
NASA NTRS1992

Microporous structure with layered interstitial surface treatment, and method and apparatus for preparation thereof

A microporous structure with layered interstitial surface treatments, and the method and apparatus for its preparation are disclosed. The structure is prepared by sequentially subjecting a uniformly surface treated structure to atomic oxygen treatment to remove an outer layer of surface treatment to a generally uniform depth, and then surface treating the so exposed layer with another surface treating agent. The atomic oxygen/surface treatment steps may optionally be repeated, each successive time to a lesser depth, to produce a microporous structure having multilayered surface treatments. The apparatus employs at least one side arm from a main oxygen-containing chamber. The side arm has characteristic relaxation times such that a uniform atomic oxygen dose rate is delivered to a specimen positioned transversely in the side arm spaced from the main gas chamber.

Koontz, Steven L.↗
NASA NTRS1994

Microporous structure with layered interstitial surface treatment, and method and apparatus for preparation thereof

A microporous structure with layered interstitial surface treatments, and method and apparatus for preparation thereof is presented. The structure is prepared by sequentially subjecting a uniformly surface-treated structure to atomic oxygen treatment to remove an outer layer of surface treatment to a generally uniform depth, and then surface treating the so exposed layer with another surface treating agent. The atomic oxygen/surface treatment steps may optionally be repeated, each successive time to a lesser depth, to produce a microporous structure having multilayered surface treatments. The apparatus employs at least one side arm from a main atomic oxygen-containing chamber. The side arm has characteristic relaxation times such that a uniform atomic oxygen dose rate is delivered to a specimen positioned transversely in the side arm spaced from the main gas chamber.

Koontz, Steven L.↗
NASA NTRS1999

The Martian Surface Boundary Layer

The acquisition of meteorological data from the surface of Mars by the two Viking Landers and Mars Pathfinder make it possible to estimate atmospheric boundary layer parameters and surface properties at three different locations on the planet. Because the Martian atmosphere is so thin the majority of the solar radiance is converted to heat at the surface. The difference between surface and atmospheric temperature can also constraint surface albedo, thermal inertia, and infrared emissivity. The Mars Pathfinder Atmospheric Structure Instrument/Meteorological package (ASI/MET) was the most capable weather monitoring system ever sent to the surface of another planet to date. One of the prime objectives of the ASI/MET package is to characterize the surface boundary layer parameters, particularly the heat and momentum fluxes, scaling temperature and friction velocity, and estimate surface roughness. Other important boundary layer parameters, such as Richardson Number, Monin-Obukhov length, analysis of turbulence characteristics of wind and temperature, and atmospheric stability class can also be determined from these measurements.

Wilson, G. R.↗
NASA NTRS1991

Surface disordering of Pb(110)

A molecular dynamics simulation of Pb(110), using embedded atom method energy functional and two-body potential derived for the purpose, shows that near 400 K the three surface layers begin to disorder well before the bulk (interior) layers. Transfer of atoms from the first subsurface layer to the surface layer occurs. Disordering propagates beyond the top three layers above 550 K, accompanied by formation of an adlayer and vacancies in the top three layers. Behavior of the two-dimensional layer structure factors indicates that disordering is anisotropic. Simulation results are consistent with experimental observations of surface roughening near 400 K and more extensive surface ordering above 525 K. Results are consistent with simulations for Ni and Al.

Tibbits, P.↗
NASA NTRS2018

Effect of Distributed Patch of Smooth Roughness Elements on Transition in a High-Speed Boundary Layer

Surface roughness is known to have a substantial impact on the aerothermodynamic loading of hypersonic vehicles, particularly via its influence on the laminar-turbulent transition process within the boundary layer. Numerical simulations are performed to investigate the effects of a distributed region of densely packed, smooth-shaped roughness elements on the laminar boundary layer over a 7-degree half-angle, circular cone for flow conditions corresponding to a selected trajectory point from the ascent phase of the HIFiRE-1 flight experiment. For peak-to-valley roughness heights of 50 percent or less in comparison with the thickness of the unperturbed boundary layer, the computations converge to a stationary flow, suggesting that the flow is globally stable. Analysis of convective instabilities in the wake of the roughness patch indicates two dominant families of unstable disturbances, namely, a high frequency mode that corresponds to Mack mode waves modified by the wake and a lower frequency mode that corresponds to shear layer instabilities associated with the streaks in the roughness wake. Even though the peak growth rate of the later mode is more than 35 percent greater than the peak growth rates of the Mack modes, the latter modes achieve higher amplification ratios, and hence, are likely to dominate the onset of transition, which is estimated to occur slightly later than that in the unperturbed, i.e., smooth surface boundary layer. Additional computations are performed to investigate the effects of various roughness patch configurations on a Mach 3.5 flat plate boundary layer, to help guide an upcoming experiment in the Mach 3.5 Supersonic Low Disturbance Tunnel at NASA Langley Research Center. In this case, the cumulative reinforcement of basic state distortion over the length of the roughness patch is predicted to yield a significantly earlier transition than that over a smooth plate or a plate with a shorter length roughness patch.

Meelan Choudhari↗
NASA NTRS1985

Specification of Surface Roughness Over Oceans in the GLAS Fourth Order GCM

The surface roughness height z sub 0 is a parameter which measures the effect of surface irregularities on the mean profiles which occur in the atmospheric surface layer. Over land surfaces, z sub 0 is a function of soil composition, plant canopy type and distribution and other factors such as buildings and structures. Over open water, z sub 0 depends only on the distribution of waves, wavelets and other surface irregularities. These, in turn, are thought to be determined by the mean wind within the surface layer. Large and Pond have derived an empirical relationship between the mean wind speed U sub 10 at the ten meter level over open water and the neutral drag coefficient C sub DN. Their relationship covers the range U sub 10 or = M/S. Earlier, Kondo had computed a relationship between U sub 10 and C sub DN on the basis of laboratory observations which extended down to the range of infinitely small wind speeds. An interpretation between the relationships of Large and Pond for large wind speed and of Kondo for small wind speed is presented.

Helfand, H. M.↗
NASA NTRS1994

Growth of Au on Ni(110): a BFS Modelling of Surface Alloy Phases

Recent experiments using scanning tunneling microscopy show evidence for the formation of surface alloys of otherwise immiscible metals. Such is the case for Au deposited in Ni(11), where experiments by Pleth Nielsen et al. indicate that at low Au coverage (less than 0.5 ML), Au atoms replace Ni atoms in the surface layer forming a surface alloy while the Ni atoms form islands on the surface. In this work, we present results of a theoretical modeling of this phenomenon using the recently developed BFS method for alloys. We provide results of an extensive analysis of the growth process which strongly support the conclusions drawn from the experiment; at very low coverages, there is tendency for dimer formation on the overlayer, which later exchange positions with Ni atoms in the surface layer, thus accounting for the large number of substituted dimers. Ni island formations as well as other alternative short range order patterns are discussed.

Bozzolo, Guillermo↗
NASA NTRS1995

Growth of Au on Ni(110): A Semiempirical Modeling of Surface Alloy Phases

Recent experiments using scanning tunneling microscopy show evidence for the formation of surface alloys of otherwise immiscible metals. Such is the case for Au deposited in Ni(110), where experiments by Pleth Nielsen el al.indicate that at low Au coverage (less than 0. 5 ML), Au atoms replace Ni atoms in the surface layer forming a surface alloy while the Ni atoms form islands on the surface. In this paper, we present results of a theoretical modeling of this phenomenon using the recently developed Bozzolo-Ferrante-Smith method for alloys. We provide results of an extensive analysis of the growth process that strongly support the conclusions drawn from the experiment: at very low coverages, there is a tendency for dimer formation on the overlayer, which later exchange positions with Ni atoms in the surface layer, thus accounting for the large number of substituted dimers. Ni island formation as well as other alternative short-range-order patterns are discussed.

Bozzolo, Guillermo↗
NASA NTRS1987

The measurement of boundary layers on a compressor blade in cascade. III - Pressure surface boundary layers and the near wake

A one-component laser Doppler velocimeter (LDV) has been used to measure the two-dimensional periodic flow field about a double circular arc, compressor blade in cascade. Eleven boundary layer profiles were taken on both the pressure and suction surfaces of the blade, and two profiles were taken in the near wake. In this part of the study, the detailed LDV studies are described. The measurements indicate that the onset of transition occurs near 60 percent chord. The lack of a logarithmic region in the data measured at 97.9 percent chord indicates that transition is not complete. The thin laminar boundary layers near the leading edge led to some measurement problems, characterized by large turbulence intensities, in using the LDV.

Deutsch, Steven↗
NASA NTRS1987

The measurement of boundary layers on a compressor blade in cascade. II - Suction surface boundary layers

A one-component laser Doppler velocimeter (LDV) has been used to measure the two-dimensional, periodic flow field about a double circular arc, compressor blade in cascade. Eleven boundary layer profiles were taken on both the pressure and suction surfaces of the blade, and two were taken in the near wake. In this part of the study, the LDV system is described and the suction surface flow field is documented. The suction surface profiles appear to separate both at the leading edge and again somewhat beyond midchord; the leading edge separation apparently reattaches by 2.6 percent chord.

Deutsch, Steven↗
NASA NTRS1998

Convective Instability of a Gravity Modulated Fluid Layer with Surface Tension Variation

Gravity modulation of an unbounded fluid layer with surface tension variations along its free surface is investigated. In parameter space of (wavenumber, Marangoni number) modulation has a destabilizing effect on the unmodulated neutral stability curve for large Prandtl number, Pr, and small modulation frequency, Omega, while a stabilizing effect is observed for small Pr and large Omega. As Omega yields infinity, the modulated neutral stability curves approach the unmodulated neutral stability curve. At certain values of Pr and L2 multiple minima are observed and the neutral stability curves become highly distorted. Closed regions of subharmonic instability are also observed. Alternating regions of synchronous and subharmonic instability separated by very thin stable regions are observed in (1/Omega,g(sub 1)) space for the singly diffusive cases. Quasiperiodic behavior in addition to the synchronous and subharmonic responses, are observed for the case of a double diffusive fluid layer. Minimum acceleration amplitudes were observed to closely correspond with a subharmonic response, Lambda(sub im) = Omega/2 .

Skarda, J. Raymond Lee↗
DOE OSTI2023

Resolving the Heat Generated from ZrO 2 Atomic Layer Deposition Surface Reactions

Abstract In situ pyroelectric calorimetry and spectroscopic ellipsometry were used to investigate surface reactions in atomic layer deposition (ALD) of zirconium oxide (ZrO 2 ). Calibrated and time‐resolved in situ ALD calorimetry provides new insights into the thermodynamics and kinetics of saturating surface reactions for tetrakis(dimethylamino)zirconium(IV) (TDMAZr) and water. The net ALD reaction heat ranged from 0.197 mJ cm −2 at 76 °C to 0.155 mJ cm −2 at 158 °C, corresponding to an average of 4.0 eV/Zr at all temperatures. A temperature dependence for reaction kinetics was not resolved over the range investigated. The temperature dependence of net reaction heat and distribution among metalorganic and oxygen source exposure is attributed to factors including growth rate, equilibrium surface hydroxylation, and the extent of the reaction. ZrO 2 ‐forming surface reactions were investigated computationally using DFT methods to better understand the influence of surface hydration on reaction thermodynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Surface Reconstruction in Hydrated Amphiphilic Block Copolymer Thin Films Probed by Fluid Cell Atomic Force Microscopy

In many thin film materials, nuanced interplays of interfacial energies control the surface morphology and rearrangement. This work evaluates polymer−solvent interactions and solvent-driven surface reconstructions via ex situ and in situ fluid cell Atomic Force Microscopy (fc-AFM) analysis of amphiphilic block copolymer (BCP) thin films upon exposure to deionized (DI) water. We examine the differences in surface morphology, whole-film swelling, and force response in thin films of polystyrene-block-poly(ethylene oxide) (PS-b-PEO) and polystyrene- block-poly[(allyl glycidyl ether)-co-(ethylene oxide)] (PS-b- P[AGE-co-EO]) processed into standing-up cylinder morphologies perpendicular to a silicon substrate (⊥C). Using Amplitude Modulation AFM (AM-AFM) and Amplitude-Phase Distance (APD) force spectroscopy, this work probes the mechanoresponsive nature of the dynamic surface layers of these films, unveiling surface layer stratification and surface chain rearrangement via minimal tip−sample stimulation. To help rationalize the observed reconfigurations, the energetic driving forces were estimated using the harmonic mean approximations of interfacial energies. Given the nonionizable nature of the minority P(AGE-co-EO) block and the energetic driving forces for chain mobility, this work shows how the elimination of unfavorable PS−water interfaces drives chain rearrangement and coverage of the PS surface by chains of the hydrophilic block. This work highlights considerations for increasing the heterogeneity and complexity of BCP thin films via random blocks and how those changes to local interfacial energies may drive larger scale film morphology reconstructions, with broader implications for tuning interface hydrophilicity.

Copolymers↗