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NASA NTRS2013

Application of CO2 Snow Jet Cleaning in Conjunction with Laboratory Based Total Reflection X-Ray Fluorescence

The Genesis mission was the first mission returning solar material to Earth since the Apollo program [1,2]. Unfortunately the return of the space craft on September 8, 2004 resulted in a crash landing, which shattered the samples into small fragments and exposed them to desert soil and other debris. Thus only small fragments of the original collectors are available, each having different degrees of surface contamination. Thorough surface cleaning is required to allow for subsequent analysis of solar wind material embedded within. An initial cleaning procedure was developed in coordination with Johnson Space Center which focused on removing larger sized particulates and a thin film organic contamination acquired during collection in space [3]. However, many of the samples have additional residues and more rigorous and/or innovative cleaning steps might be necessary. These cleaning steps must affect only the surface to avoid leaching and re-distribution of solar wind material from the bulk of the collectors. To aid in development and identification of the most appropriate cleaning procedures each sample has to be thoroughly inspected before and after each cleaning step. Laboratory based total reflection X-ray fluorescence (TXRF) spectrometry lends itself to this task as it is a non-destructive and surface sensitive analytical method permitting analysis of elements from aluminum onward present at and near the surface of a flat substrate [4]. The suitability of TXRF has been demonstrated for several Genesis solar wind samples before and after various cleaning methods including acid treatment, gas cluster ion beam, and CO2 snow jet [5 - 7]. The latter one is non-invasive and did show some promise on one sample [5]. To investigate the feasibility of CO2 snow jet cleaning further, several flown Genesis samples were selected to be characterized before and after CO2 snow application with sample 61052 being discussed below.

Schmeling, M.↗

NASA NTRS2017

Analyzing the Chemical and Spectral Effects of Pulsed Laser Irradiation to Simulate Space Weathering of a Carbonaceous Chondrite

Space weathering processes alter the chemical composition, microstructure, and spectral characteristics of material on the surfaces of airless bodies. The mechanisms driving space weathering include solar wind irradiation and the melting, vaporization and recondensation effects associated with micrometeorite impacts e.g., [1]. While much work has been done to understand space weathering of lunar and ordinary chondritic materials, the effects of these processes on hydrated carbonaceous chondrites is poorly understood. Analysis of space weathering of carbonaceous materials will be critical for understanding the nature of samples returned by upcoming missions targeting primitive, organic-rich bodies (e.g., OSIRIS-REx and Hayabusa 2). Recent experiments have shown the spectral properties of carbonaceous materials and associated minerals are altered by simulated weathering events e.g., [2-5]. However, the resulting type of alteration i.e., reddening vs. bluing of the reflectance spectrum, is not consistent across all experiments [2-5]. In addition, the microstructural and crystal chemical effects of many of these experiments have not been well characterized, making it difficult to attribute spectral changes to specific mineralogical or chemical changes in the samples. Here we report results of a pulsed laser irradiation experiment on a chip of the Murchison CM2 carbonaceous chondrite to simulate micrometeorite impact processing.

Thompson, M. S.↗

NASA NTRS2007

Decontamination of Genesis Array Materials by UV Ozone Cleaning

Shortly after the NASA Genesis Mission sample return capsule returned to earth on September 8, 2004, the science team discovered that all nine ultra-pure semiconductor materials were contaminated with a thin molecular organic film approximately 0 to 100 angstroms thick. The organic contaminate layer, possibly a silicone, situated on the surface of the materials is speculated to have formed by condensation of organic matter from spacecraft off-gassing at the Lagrange 1 halo orbit during times of solar exposure. While the valuable solar wind atoms are safely secured directly below this organic contamination and/or native oxide layer in approximately the first 1000 angstroms of the ultra-pure material substrate, some analytical techniques that precisely measure solar wind elemental abundances require the removal of this organic contaminate. In 2005, Genesis science team laboratories began to develop various methods for removing the organic thin film without removing the precious material substrate that contained the solar wind atoms. Stephen Sestak and colleagues at Open University first experimented with ultraviolet radiation ozone (UV/O3) cleaning of several non-flight and flown Genesis silicon wafer fragments under a pure flowing oxygen environment. The UV/O3 technique was able to successfully remove organic contamination without etching into the bulk material substrate. At NASA Johnson Space Center Genesis Curation Laboratory, we have installed an UV/O3 cleaning devise in an ambient air environment to further experimentally test the removal of the organic contamination on Genesis wafer materials. Preliminary results from XPS analysis show that the UV/O3 cleaning instrument is a good non-destructive method for removing carbon contamination from flown Genesis array samples. However, spectroscopic ellipsometry results show little change in the thickness of the surface film. All experiments to date have shown UV/O3 cleaning method to be the best non-destructive method for removing organic contamination from the surface of the Genesis materials. The UV/O3 cleaning process can also clean carbon contamination to levels below non-flight standards. This can be seen by comparing sample 60260's carbon 10667 cps with non-flight Si carbon 21675 cps. Therefore, surface carbon contamination should not hinder the analysis of solar wind.

Calaway, Michael J.↗

NASA NTRS2023

Characterizing Space Weathering Features in Grains From Asteroid Ryugu

Airless bodies such as asteroids are characterized by a lack of a protective atmosphere to guard against the effects of micrometeorite bombardment and solar wind irradiation. These processes, cumulatively known as space weathering, alter the microstructural and chemical properties of grains on asteroidal surfaces, signatures of which are recognized as vesiculated textures, amorphous grain rims, and fe-bearing nanoparticles. The accumulation of these features also causes changes in the optical properties of the surface regolith, complicating the interpretation of remote sensing data and the characterization of returned samples.

L. E. Melendez↗

NASA NTRSDate not supplied

The Nature of Space Weathering in Samples From Asteroid (162173) Ryugu Revealed By Coordinated Analysis

Space weathering, driven primarily by micrometeorite bombardment and solar wind ion irradiation, alters the morphology, microstructure, and chemistry of the surface regolith on airless bodies. The accumulation of microstructural and chemical space weathering features, including melt deposits, amorphous rims, and nanophase iron-bearing particles (npFe), are associated with alterations of the spectral properties of the regolith. In particular, space weathering changes the spectral slope and reflectance of surface materials, and causes the attenuation of characteristic absorption bands in the visible to near-infrared wave-lengths, as well as a shift towards longer wavelengths of the Christiansen feature (CF)in thermal infrared spectra. Previous studies of space weathering characteristics have focused on siliceous bodies like the Moon and S-type asteroid Itokawa. However, observations of asteroid Ryugu by the JAXA Hayabusa2 spacecraft and subsequent analyses of returned samples revealed carbonaceous and hydrated materials. These samples provided our first opportunity to constrain the effects of space weathering processes on primitive, C-type asteroids. Analyses of returned samples to understand the space weathering of carbonaceous materials are important for accurately interpreting remote sensing observations of carbonaceous asteroids. In addition, the analysis of Hayabusa2 samples from Ryugu paved the way for the analysis of samples from the asteroid Bennu, re-turned by the NASA OSIRIS-REx mission. As space weathering impacts the microstructure, chemistry, and spectral characteristics of asteroidal surfaces, here we report the results of a coordinated analytical study of the micro-and nano-scale signatures of space weathering in samples returned from Ryugu.

L E Melendez↗

NASA NTRS1992

Lunar material resources: An overview

The analysis of returned lunar samples and a comparison of the physical and chemical processes operating on the Moon and on the Earth provide a basis for predicting both the possible types of material resources (especially minerals and rocks) and the physical characteristics of ore deposits potentially available on the Moon. The lack of free water on the Moon eliminates the classes of ore deposits that are most exploitable on Earth; namely, (1) hydrothermal, (2) secondary mobilization and enrichment, (3) precipitation from a body of water, and (4) placer. The types of lunar materials available for exploitation are whole rocks and their contained minerals, regolith, fumarolic and vapor deposits, and nonlunar materials, including solar wind implantations. Early exploitation of lunar material resources will be primarily the use of regolith materials for bulk shielding; the extraction from regolith fines of igneous minerals such as plagioclase feldspars and ilmenite for the production of oxygen, structural metals, and water; and possibly the separation from regolith fines of solar-wind-implanted volatiles. The only element, compound, or mineral, that by itself has been identified as having the economic potential for mining, processing, and return to Earth is helium-3.

Carter, James L.↗

NASA NTRS2023

Space Weathering at the Moon

In this paper we summarize the substantial recent progress in understanding space weathering that has occurred through technical innovations in the laboratory and in space, including employment of ultra-high-resolution imaging of lunar samples, a wave of new remote sensing observations, samples returned from asteroid regolith, and new methods for simulating space weathering to gain insight into its mechanisms. The paper begins with a summary of space weathering processes and their observed effects on lunar samples (Section 2). It then describes new insights gleaned from remote sensing at a broadened range of wavelengths (Section 3.1) and from observations of special lunar environments where space weathering inputs vary, such as the intensity of solar wind at lunar swirls or in permanent shadow in polar regions (Section 3.2). We then outline how laboratory simulations have informed the understanding of space weathering mechanisms and rates (Section 4). Finally, we discuss the integrated observations and simulations and the current state of our knowledge (Section 5) and make suggestions for future investigations (Section 6).

moon↗

NASA NTRS2023

Investigating the Effects of Space Weathering in Ryugu Samples Using Coordinated Microanalyses

Airless planetary surfaces are characterized by a distinct lack of an atmosphere or magnetic field, leading to direct exposure to the effects of hypervelocity micrometeoroid impacts and solar wind ion irradiation [1]. These processes, cumulatively known as space weathering, gradually alter the microstructural and chemical properties of the grains on airless surfaces. Signatures of space weathering include vesiculated textures, amorphous grain rims (upper ~100 nm), solar flare tracks, and Fe-bearing nanoparticles (npFe) [2,3]. The accumulation of these microstructural space weathering characteristics, particularly the presence of npFe, alters the spectral properties of airless regoliths resulting in changes in spectral slope and reflectance of the surfaces, and the attenuation of characteristic absorption bands in the visible to near-infrared (Vis-NIR) wavelengths. These spectral changes complicate our ability to accurately interpret the mineralogy of airless bodies via remote sensing spectroscopy [1,4]. Studies of space weathering have primarily focused on anhydrous silicate minerals, reflecting the main components of the available returned samples from the Moon and S-type asteroid Itokawa [3,5,6]. However, our understanding of space weathering of primitive, organic-rich carbonaceous materials is still a work in progress. The Japan Aerospace Exploration Agency (JAXA)’s Hayabusa2 mission offered the first opportunity to directly investigate carbonaceous asteroids by returning samples from C-type asteroid (162173) Ryugu. Initial studies of Ryugu samples show mineralogical similarities to CI chondrites along with surface modifications consistent with space weathering. These surface modifications are primarily in the form of μm-thick silicate melts, amorphized phyllosilicates, glassy spherules, and burst vesicles [3,7]. Here, we report results from coordinated microanalytical techniques to further our understanding of the mineralogy and space weathering of carbonaceous materials.

L E Melendez↗

NASA NTRS1984

Mars exploration in the 1990's

Science objectives for a Mars exploration program in the 1990s, set forth by NASA's Committee on Planetary Exploration, are presented. They include: an intensive study of the Martian surface, the exploration of the structure and general circulation of the atmosphere, the exploration of the nature and dynamics of the planet's interior, the nature of Mars's magnetic field, the character of the upper atmosphere and its interaction with the solar wind, and the establishment of the global chemical and physical characteristics of the Martian surface. Several low cost missions, which have been suggested by the Committee for NASA's CORE program, such as the Mars Geoscience Climatology Observer, the Mars Aeronomy Orbiter, and the Mars Surface Network and Surface Probing missions are also covered. Direct Entry-Direct Return and Out-of-Orbit Entry-Orbital Rendezvous and Docking are two versions of a Mars Rover and Sample Return (MRSR) mission discussed in detail. It is concluded that a MRSR mission will require the combination of full Centaur capability, aerocapture at Mars and earth, and direct return to earth to meet major scientific goals. Further studies should be made in orbit assembly, fuel transfer technology, aeromaneuvering, terminal guidance, rover technology, and robotics.

Albee, A. L.↗

NASA NTRS2017

The Astromaterials X-Ray Computed Tomography Laboratory at Johnson Space Center

The Astromaterials Acquisition and Curation Office at NASA's Johnson Space Center (hereafter JSC curation) is the past, present, and future home of all of NASA's astromaterials sample collections. JSC curation currently houses all or part of nine different sample collections: (1) Apollo samples (1969), (2) Lunar samples (1972), (3) Antarctic meteorites (1976), (4) Cosmic Dust particles (1981), (5) Microparticle Impact Collection (1985), (6) Genesis solar wind atoms (2004); (7) Stardust comet Wild-2 particles (2006), (8) Stardust interstellar particles (2006), and (9) Hayabusa asteroid Itokawa particles (2010). Each sample collection is housed in a dedicated clean room, or suite of clean rooms, that is tailored to the requirements of that sample collection. Our primary goals are to maintain the long-term integrity of the samples and ensure that the samples are distributed for scientific study in a fair, timely, and responsible manner, thus maximizing the return on each sample. Part of the curation process is planning for the future, and we also perform fundamental research in advanced curation initiatives. Advanced Curation is tasked with developing procedures, technology, and data sets necessary for curating new types of sample collections, or getting new results from existing sample collections [2]. We are (and have been) planning for future curation, including cold curation, extended curation of ices and volatiles, curation of samples with special chemical considerations such as perchlorate-rich samples, and curation of organically- and biologically-sensitive samples. As part of these advanced curation efforts we are augmenting our analytical facilities as well. A micro X-Ray computed tomography (micro-XCT) laboratory dedicated to the study of astromaterials will be coming online this spring within the JSC Curation office, and we plan to add additional facilities that will enable nondestructive (or minimally-destructive) analyses of astromaterials in the near future (micro-XRF, confocal imaging Raman Spectroscopy). These facilities will be available to: (1) develop sample handling and storage techniques for future sample return missions; (2) be utilized by PET for future sample return missions; (3) be used for retroactive PET (Positron Emission Tomography)-style analyses of our existing collections; and (4) for periodic assessments of the existing sample collections. Here we describe the new micro-XCT system, as well as some of the ongoing or anticipated applications of the instrument.

Zeigler, R. A.↗

NASA NTRS2017

The Astromaterials X-Ray Computed Tomography Laboratory at Johnson Space Center

Zeigler, R. A.↗

NASA NTRS1974

Radiation damage and structure recorded at high resolution in grains from fine fractions of Luna 16 surface material

Samples returned to earth by Luna 16, were studied with a high voltage electron microscope for ultramicroscopic features. The following amazing features were noted in particles of surface material returned in all the lunar trips: A very high density of tracks of nuclear particles, ultrathin amorphous shells, highly rounded forms, and amazingly good ordering of crystal lattice. These features were used along with calibration experiments in solving the following problems: (1) determining the energy spectrum and chemical abundances of the very heavy nuclei in the solar wind and in the solar cosmic rays; (2) studying the past activity of the sun; (3) obtaining data on lunar dynamic processes affecting dust particles; (4) analyzing composite effects caused by penetration of solar wind into the lunar surface material; and (5) establishing the existence of the ancient lunar atmosphere and magnetic field.

Durrieu, L.↗

NASA NTRSDate not supplied

Initial Analysis of Volatile Components in the Hayabusa2 Samples

The major objectives of the Hayabusa2-initial-analysis volatile team are (1) to determine the pristine volatile components in the parental materials of the returned Ryugu samples, and (2) to elucidate the origin and chronological history of the asteroid Ryugu, as well as the evolution of the solar system through determination of volatile carrier phases and abundances of volatile components (e.g., presolar grain abundances). Our analytical data will be linked with remote sensing (NIRS3, ONCs, TIR, and LIDAR) data and theoretical modeling [e.g., 1-5]. For example, the erosion rate and the degree of gardening of the surface layer of the asteroid Ryugu can be estimated based on trapped solar wind (SW) and cosmic ray produced (cosmogenic) nuclides, which will be discussed in conjunction with the results based on the remote sensing data [3-5]. Taken together, these will provide characteristics of the surface materials, such as the degree and duration of the alteration by SW/cosmic ray irradiation and micrometeorite bombardments.

volatiles↗

NASA NTRS2026

Adaptive Curation at NASA Johnson Space Center: Preparing for Artemis Samples by Leveraging Proven Practices and Innovative Solution

The proper curation of returned astromaterial samples is essential to ensure that high-quality scientific investigations can be conducted for decades, enabling future generations to address evolving research questions. The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (hereafter JSC Curation) is responsible for curating all of NASA’s extraterrestrial samples. Under the governing document, NASA Procedural Requirement (NPR) 7100.5 “Curation of Extraterrestrial Materials”, JSC Curation is charged with “The curation of all extraterrestrial material under NASA control, including future NASA missions.” The Directive goes on to define Curation as including “...documentation, preservation, preparation, and distribution of samples for research, education, and public outreach.” JSC Curation has a long-standing legacy of curating extraterrestrial materials, including but not limited to Apollo and Luna lunar samples, Genesis solar wind samples, Stardust comet samples, asteroid samples (Hayabusa1, Hayabusa2, and OSIRIS-REx), and Antarctic Meteorite samples from a variety of parent bodies. Building on this foundation, the Artemis program introduces new challenges and opportunities for sample curation, requiring both the application of proven practices and the development of innovative solutions. The Artemis Collection will be curated using established protocols refined through decades of experience with Apollo and subsequent sample collections, including but not limited to the utilization of cleanrooms, custom nitrogen gloveboxes, specialized storage containers and tools; all of which have strict material utilization and prohibition requirements. These practices provide a robust framework for contamination control, documentation, and long-term preservation. However, Artemis samples may present unique scientific and operational requirements, including enhanced contamination control measures (relative to Apollo) driven by evolving science objectives. To meet these needs, JSC Curation is actively developing new technologies and protocols that extend beyond traditional approaches, ensuring that the integrity of samples is maintained under increasingly stringent standards. One critical area of innovation is the development of cold sample curation capabilities. Certain Artemis samples, particularly those from Permanently Shadowed Regions (PSRs) and cold environments, are expected to contain ices and volatile components that require preservation and handling at sub-zero or even cryogenic temperatures. JSC Curation is leveraging best practices from the cold and cryogenic sample industries, as well as other government agencies and academic experts, to design facilities and handling procedures that maintain sample integrity while enabling scientific access. The goal is to develop capabilities to allow researchers to investigate volatiles and other temperature-sensitive materials while minimizing chemical and physical alterations from their returned state. In summary, adaptive curation at JSC combines the reliability of proven methodologies with forward-looking innovations to meet the scientific and operational demands of Artemis. Through enhanced contamination control, advanced cold curation capabilities, and an understanding of known and evolving future science priorities, NASA is preparing to maximize the scientific return from Artemis samples and preserve their value for generations of researchers.

Andrea D Harrington↗

NASA NTRS1977

What's new on the moon. II

Apollo missions and returned lunar samples have provided new information about the moon, the earth, the sun, and the universe. Analyses show that all the planets were formed by the rapid accumulation of small bodies into larger ones about 4.6 billion years ago. The existence of simple molecules formed by reactions between the soil particles and atoms of carbon, oxygen, and nitrogen that have come from the sun, suggests that the basic ingredients for life are common in the universe. The ratio of hydrogen to helium in the solar wind reaching the moon is found to be 20 to 1, whereas the earth-based measurements show this ratio to be 10 to 1. Although the moon does not have any magnetic field at the present, the analyses revealed the existence of such a field three billion years ago. The understanding of the reasons for the disappearance of this field is vital for understanding planetary magnetic fields. The determination of the chemical composition of the whole moon, the explanation of the moon's observed asymmetry, and the understanding of the nature of moon's interior will have to be achieved by future, possibly unmanned, missions.

French, B. M.↗

NASA NTRSDate not supplied

Coarsening Up: Expanding the Particle Size Distributions of Lunar Simulants to Encompass A Comprehensive Range of Regolith Granularity

Due to a paucity of lunar regolith samples, simulated granular materials (simulants) have been developed and deployed for a variety of engineering and research purposes in an attempt to meet the requirements for lunar exploration. Broadly speaking, these manufactured materials aim to replicate the compositional (i.e., mineralogy and chemistry) and physical (e.g., particle size distribution, particle shape) profiles of lunar soil samples collected during the Apollo missions. While creating a “near-perfect” lunar simulant is prohibitive due to the unique formative processes (i.e., meteorite impacts, solar wind implantation) and conditions (anhydrous, reducing environment and exposure to radiation on the surface over billions of years) encountered on the moon, certain granular properties of the regolith can be recreated with a high level of fidelity by leveraging contemporary technologies. A fundamental physical property and descriptor, grain size can be correlated between samples and replicated through processing; however, a holistic understanding of the particle size distribution of lunar regolith must be considered when creating analog materials. This study produces particle size distributions for Apollo 16 returned samples, incorporating the sieved out >1 cm coarse-grained fraction, in order to provide a more comprehensive characterization of surficial lunar regolith grain sizes for the development of highlands-type granular analog testing materials.

R. N. Kovtun↗

NASA NTRS2023

Investigating the Role of Incident Ion Flux in Solar Wind Space Weathering of Carbon-Rich Asteroidal Regolith Via H+ and He+ Irradiation of the Murchison Meteorite

We present results from a set of low and high flux 1 keV/amu H + and He + irradiation experiments performed on slabs of the Murchison CM2 carbonaceous chondrite. The low flux conditions for H + and He + irradiation were ~1-1.5 orders of magnitude lower than the high flux conditions, and each experiment was irradiated to a total fluence between ~3 × 10 16 to ~6 × 10 16 ions/cm 2 . Irradiation-induced changes in the surface chemistry and optical properties of the Murchison samples were evaluated using in situ X-ray photoelectron spectroscopy (XPS) and visible and near-infrared spectroscopy (VNIR). We characterized the microstructure and composition of ion damaged rims in focused ion beam (FIB) cross-sections extracted from olivine and matrix material in each irradiated Murchison slab using transmission electron microscopy (TEM). XPS results suggest that both low flux and high flux H + and He + irradiation cause minor sputtering of surface carbon as well as a reduction in the valence state of iron, from Fe 3+ to Fe 2+ . Slope bluing is observed in VNIR spectra of the irradiated samples which may reflect carbonization and dehydrogenation of organic species and contrasts with reddening trends associated with npFe 0 formation. Although we do not observe a strong flux-dependence on the crystallinity of ion-damaged olivine, TEM analyses reveal a variety of microstructures in all olivine FIB-sections, suggesting that crystallographic orientation affects amorphization efficiency. Analyses of matrix FIB-sections indicate that phyllosilicate alteration is mainly driven by He+ irradiation, where the higher incident flux leads to greater amorphization and the formation of more distinct ion-damaged layers, similar to smooth layers in returned Ryugu particles. TEM results also provide some evidence that higher ion flux leads to greater vesiculation, with He + irradiation being more efficient at vesiculation than H + irradiation, and that higher ion flux may promote the segregation of Mg and Si into laterally extensive lenses and layers in olivine samples. We discuss the implications of these findings for constraining the role that ion flux plays in the development of space weathering characteristics in silicate phases present in carbonaceous asteroidal regoliths. These results will be important for understanding the complexity of this process and how it operates on carbon-rich airless bodies like asteroids Bennu and Ryugu.

meteorites↗

NASA NTRS2020

The Old, Unique C1 Chondrite Flensburg – Insight Into the First Processes of Aqueous Alteration, Brecciation, and the Diversity of Water-Bearing Parent Bodies and Lithologies

On September 12, 2019 at 12:49:48 (UT) a bolide was observed by hundreds of eye-witnesses from the Netherlands, Germany, Belgium, Denmark and the UK. One day later a small meteorite stone was found by accident in Flensburg. The presence of short-lived cosmogenic radionuclides with half-lives as short as 16 days proves the recent exposure of the found object to cosmic rays in space linking it clearly to the bolide event. An exceptionally short exposure time of ∼5000 years was determined. The 24.5 g stone has a fresh black fusion crust, a low density of <2 g/cm(exp 3), and a magnetic susceptibility of logχ = 4.35 (χ in 10−9 m(exp 3)/kg). The rock consists of relict chondrules and clusters of sulfide and magnetite grains set in a fine-grained matrix. The most abundant phases are phyllosilicates. Carbonates (∼3.9 vol.%) occur as calcites, dolomites, and a Na-rich phase. The relict chondrules (often surrounded by sulfide laths) are free of anhydrous silicates and contain abundant serpentine. Lithic clasts are also surrounded by similar sulfide laths partly intergrown with carbonates. Mn-53-Cr-53 ages of carbonates in Flensburg indicate that brecciation and contemporaneous formation of the pyrrhotite-carbonate intergrowths by hydrothermal activities occurred no later than 4564.6 ± 1.0 Ma (using the angrite D'Orbigny as the Mn-Cr age anchor). This corresponds to 2.6 ± 1.0 or 3.4 ± 1.0 Ma after formation of CAIs, depending on the exact absolute age of CAIs. This is the oldest dated evidence for brecciation and carbonate formation, which likely occurred during parent body growth and incipient heating due to decay of Al-26. In the three oxygen isotope diagram, Flensburg plots at the 16O-rich end of the CM chondrite field and in the transition field to CV-CK-CR chondrites. The mass-dependent Te isotopic composition of Flensburg is slightly different from mean CM chondrites and is most similar to those of the ungrouped C2 chondrite Tagish Lake. On the other hand, Ti-50 and Cr-54 isotope anomalies indicate that Flensburg is similar to CM chondrites, as do the ∼10 wt.% H2O of the bulk material. Yet, the bulk Zn, Cu, and Pb concentrations are about 30% lower than those of mean CM chondrites. The He, Ne, and Ar isotopes of Flensburg show no solar wind contribution; its trapped noble gas signature is similar to that of CMs with a slightly lower concentration of Ne(sub tr)-20. Based on the bulk H, C, and N elemental abundances and isotopic compositions, Flensburg is unique among chondrites, because it has the lightest bulk H and N isotopic compositions of any type 1 or 2 chondrite investigated so far. Moreover, the number of soluble organic compounds in Flensburg is even lower than that of the brecciated CI chondrite Orgueil. The extraordinary significance of Flensburg is evident from the observation that it represents the oldest chondrite sample in which the contemporaneous episodes of aqueous alteration and brecciation have been preserved. The characterization of a large variety of carbonaceous chondrites with different alteration histories is important for interpreting returned samples from the OSIRIS-REx and Hayabusa 2 missions.

C1 chondrite↗