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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Application of Satellite SAR Imagery in Mapping the Active Layer of Arctic Permafrost

A method of mapping the active layer of Arctic permafrost using a combination of conventional synthetic aperture radar (SAR) backscatter and more sophisticated interferometric SAR (INSAR) techniques is proposed. The proposed research is based on the sensitivity of radar backscatter to the freeze and thaw status of the surface soil, and the sensitivity of INSAR techniques to centimeter- to sub-centimeter-level surface differential deformation. The former capability of SAR is investigated for deriving the timing and duration of the thaw period for surface soil of the active layer over permafrost. The latter is investigated for the feasibility of quantitative measurement of frost heaving and thaw settlement of the active layer during the freezing and thawing processes. The resulting knowledge contributes to remote sensing mapping of the active layer dynamics and Arctic land surface hydrology.

Li, Shu-Sun↗
DOE OSTI2024

Doped semiconductor devices for sub-MeV dark matter detection

Dopant atoms in semiconductors can be ionized with ∼ 10 meV energy depositions, allowing for the design of low-threshold detectors. We propose using doped semiconductor targets to search for sub-MeV dark matter scattering or sub-eV dark matter absorption on electrons. Currently unconstrained cross sections could be tested with a 1 g-day exposure in a doped detector with backgrounds at the level of existing pure semiconductor detectors, but improvements would be needed to probe the freeze-in target. We discuss the corresponding technological requirements and lay out a possible detector design. Published by the American Physical Society 2024

Astronomy & Astrophysics↗
NASA NTRS2001

CO2 Snow on Mars and Early Earth: Experimental Constraints

Greenhouse warming due to carbon dioxide atmospheres may be responsible for maintaining the early Earth's surface temperature above freezing and may even have allowed for liquid water on early Mars. However, the high levels of CO2 required for such warming should have also resulted in the formation of CO2 clouds. These clouds, depending on their particle size, could lead to either warming or cooling. The particle size in turn is determined by the nucleation and growth conditions. Here we present laboratory studies of the nucleation and growth of carbon dioxide on water ice under Martian atmospheric conditions. We find that a critical saturation, S = 1.34, is required for nucleation, corresponding to a contact parameter between solid water and solid carbon dioxide of m = 0.95. We also find that after nucleation occurs, growth of CO2 is very rapid and proceeds without a surface kinetic barrier. Because growth would be expected to continue until the CO2 pressure is lowered to its vapor pressure, we expect particles larger than those being currently suggested for the present and past Martian atmospheres. Using this information in a microphysical model described in a companion paper, we find that CO2 clouds are best described as "snow", having a relatively small number of large particles.

Glandorf, David L.↗
NASA NTRS2013

FRET-Aptamer Assays for Bone Marker Assessment, C-Telopeptide, Creatinine, and Vitamin D

Astronauts lose 1.0 to 1.5% of their bone mass per month on long-duration spaceflights. NASA wishes to monitor the bone loss onboard spacecraft to develop nutritional and exercise countermeasures, and make adjustments during long space missions. On Earth, the same technology could be used to monitor osteoporosis and its therapy. Aptamers bind to targets against which they are developed, much like antibodies. However, aptamers do not require animal hosts or cell culture and are therefore easier, faster, and less expensive to produce. In addition, aptamers sometimes exhibit greater affinity and specificity vs. comparable antibodies. In this work, fluorescent dyes and quenchers were added to the aptamers to enable pushbutton, one-step, bind-and-detect fluorescence resonance energy transfer (FRET) assays or tests that can be freeze-dried, rehydrated with body fluids, and used to quantitate bone loss of vitamin D levels with a handheld fluorometer in the spacecraft environment. This work generated specific, rapid, one-step FRET assays for the bone loss marker C-telopeptide (CTx) when extracted from urine, creatinine from urine, and vitamin D congeners in diluted serum. The assays were quantified in nanograms/mL using a handheld fluorometer connected to a laptop computer to convert the raw fluorescence values into concentrations of each analyte according to linear standard curves. DNA aptamers were selected and amplified for several rounds against a 26- amino acid form of CTx, creatinine, and vitamin D. The commonalities between loop structures were studied, and several common loop structures were converted into aptamer beacons with a fluorophore and quencher on each end. In theory, when the aptamer beacon binds its cognate target (CTx bone peptide, creatinine, or vitamin D), it is forced open and no longer quenched, so it gives off fluorescent light (when excited) in proportion to the amount of target present in a sample. This proportional increase in fluorescence is called a "lights on" FRET response. The vitamin D aptamer beacon gives a "lights off" or inversely proportional fluorescence response to the amount of vitamin D present in diluted serum. These FRET-aptamer assays are rapid (<30 minutes), sensitive (low ng/mL detection limits), and quite easy to carry out (add sample, mix, and detect in the handheld reader). Benefits include the speed of the assays as well as the small amount of space taken up by the handheld reader and cuvette assays. The aptamer DNA sequences represent novel additional features of the existing (patent-pending) FRET-aptamer assay platform.

Bruno, John G.↗
NASA NTRS2017

Impact Delivery of Reduced Greenhouse Gases on Early MARS

While there is abundant evidence for flowing liquid water on the ancient Martian surface, a widely accepted greenhouse mechanism for explaining this in the presence of a faint young sun has yet to emerge. Gases such as NH3, CO2 alone, SO2, clouds, and CH4, have sustainability issues or limited greenhouse power. Recently, Ramirez et al. proposed that CO2-H2 atmospheres, through collision induced absorptions (CIA), could solve the problem if large amounts are present (1.3-4 bars of CO2, 50-20% H2). However, they had to estimate the strength of the H2- CO2 interaction from the measured strength of the H2- N2 interaction. Recent ab initio calculations show that the strength of CO2-H2 CIA is greater than Ramirez et al. assumed. Wordsworth et al. also calculated the absorption coefficients for CO2-CH4 CIA and show that on early Mars a 0.5 bar CO2 atmosphere with percent levels of H2 or CH4 can raise mean annual temperatures by tens of degrees Kelvin. Freezing temperatures can be reached in atmospheres containing 1-2 bars of CO2 and 2-10% H2 and CH4. The new work demonstrates that less CO2 and reduced gases are needed than Ramirez et al. originally proposed, which improves prospects for their hypothesis. If thick weakly reducing atmospheres are the solution to the faint young sun paradox, then plausible mechanisms must be found to generate and sustain the required concentrations of H2 and CH4. Possible sources of reducing gases include volcanic outgassing, serpentinization, and impact delivery; sinks include photolysis, oxidation, and hydrogen escape. The viability of the reduced greenhouse hypothesis depends, therefore, on the strength of these sources and sinks.

Martian surface↗
DOE OSTI2026

Hybrid Bio-Based Composites: Enabling Cellulose Nanofiber (CNF) Incorporation into Composites via Macroscale Natural Fiber Carriers

Cellulose nanofibers (CNFs) have significant potential in composites as additives to improve mechanical properties, melt rheology, and more. However, agglomeration of CNFs is a key challenge in composite melt processing as obtaining nano-level dispersion of CNFs often requires cost- and energy-intensive processes (e.g., solvent exchange or freeze drying) due to the strong hornification tendencies of CNF. Herein, we avoid these challenges by using a natural fiber carrier method to integrate CNF into thermoplastic composites. Fibers are co-dried to create a hybrid fiber feedstock for compounding in which natural fibers are decorated with dispersed nanofibers. The hybridized fibers result in up to a 24% increase in tensile strength and up to a 35% increase in Young’s modulus compared to composites only containing natural fibers. The lignocellulosic nanofibers are found to outperform their purely cellulosic counterpart, which is theorized to be due to either an increased propensity for fibrillation of the lignocellulosic fibers or the increased hydrophobicity of the fibers due to the presence of lignin. Surface analysis of fiber feedstocks, via streaming potential measurements and dynamic light scattering (DLS), confirmed a significant change in the feedstock hydrophobicity before and after hybridization. While mild additions of CNF (1 wt.% on the macroscale fiber) do not impact the composite melt viscosity, the viscosity is found to increase at higher CNF loadings (5 wt.% on the macroscale fiber), indicating its utility as a rheology modifier. Lastly, use of these materials as novel feedstocks for medium-scale additive manufacturing in high-fidelity part production was demonstrated.

bio-based↗
DOE OSTI2023

SAM Assessment Report

The System Analysis Module (SAM) is a modern system analysis tool being developed at Argonne National Laboratory (Argonne) for advanced non-LWR safety analysis. A series of assessment cases are modeled using SAM and, when applicable, compared against analytical solutions or engineering judgement. This report documents the assessment of SAM for eleven different categories. Each category contains a series of tests that examine different boundary conditions, system configurations, or modeling options. Although relatively simple, these tests cover the basic equation models, basic component models, and basic system level processes and phenomena that may be utilized during advanced reactor safety analyses.

1-D fluid flow↗
NASA NTRS2018

Freeze Casting of LAGP for 3D Textured Solid-State Structural Electrolytes

In this study, all-solid-state structural lithium-ion batteries, a type of load bearing electrochemical energy storage that provides systems-level weight savings is being pursued for the realization of inherently safe next generation hybrid-electric and all-electric green aerospace propulsion systems. Currently investigated all-solid-state batteries do not meet the requirements for specific power and mechanical stability. To address these issues, freeze casting of lithium aluminum germanium phosphate (LAGP) electrolyte material has been explored for the creation of a textured 3D electrolyte scaffold with large interfacial surface area for high power discharge and hierarchical porosity for accommodation of active material volume changes during electrochemical cycling. We report the effects of freeze casting processing parameters on the microstructural development and mechanical performance of the scaffolds, characterized through scanning electron microscopy and ring-on-ring mechanical testing. Slurry composition and casting parameters such as solids loading, casting speed, tape angle, and temperature gradients have been modified to determine the impact on density, lamellar morphology, and final load-bearing performance.

ceramics↗
NASA NTRS2001

Evidence for the Widespread Presence of Liquid-Phase Particles During the 1999-2000 Arctic Winter

In-situ Multi-Angle Spectrometer Probe (MASP) particle measurements have been analyzed to determine the typical behaviour of sulphate particles during the SOLVE campaign. The analysis has focussed on variations in the total particle concentration measured by MASP, which is a diagnostic that is primarily sensitive to the growth of small particles (those which are initially smaller than 0.2 micrometers in radius). At all levels of the stratosphere, the total MASP concentration varies continuously with temperature. This behaviour is well-reproduced by assuming that the sulphate aerosols are liquid ternary solutions, but cannot be reproduced if the aerosol is assumed to be frozen. This liquid-like behaviour is apparent for all measurements made during SOLVE, both inside and outside the vortex, and even at the coldest temperatures sampled during the campaign. The only anomalous measurements were made during the flight of January 14th, 2001; however, this midlatitude flight is very unlikely to contain SAT particles based on the recent warm temperatures experienced by the air. At the levels with the coldest measured temperatures, at least 90% of the particles grow as liquids. Therefore, the freezing that occurred during the 1999-2000 Arctic winter was selective, causing most of the particles to remain liquid even in the presence of a small number of frozen particles.

Drdla, K↗
NASA NTRS1991

Use of electron microprobe x-ray analysis for determination of low calcium concentrations across leaves deficient in calcium

An electron microprobe with wavelength-dispersive x-ray spectrometry (WDS) was found to be useful for the determination of Ca concentrations in leaf tissue deficient in Ca. WDS effectively detected Ca concentrations as low as 0.2 mg/g dry wt in the presence of high levels of K and Mg (120 and 50 mg/g dry wt, respectively). Leaf specimens were prepared for analysis by quick-freezing in liquid nitrogen and freeze-drying at -20 degrees C to maintain elemental integrity within the tissue. Because dry material was analyzed, sample preparation was simple and samples could be stored for long periods before analysis. A large beam diameter of 50 gm was used to minimize tissue damage under the beam and analyze mineral concentrations within several cells at one time. Beam penetration was between 50 and 55 microns, approximately one-third of the thickness of the leaf. For analysis of concentrations in interveinal areas, analyses directed into the abaxial epidermis were found most useful. However, because of limited beam penetration, analyses of veinal areas would require use of cross sections [correction of crosssections]. Solid mineral standards were used for instrument standardization. To prevent measurement errors resulting from differences between the matrix of the mineral standards and the analyzed tissue, concentrations in leaves were corrected using gelatin standards prepared and analyzed under the same conditions. WDS was found to be useful for documenting that very low Ca levels occur in specific areas of lettuce leaves exhibiting the Ca deficiency injury termed tipburn.

Non-NASA Center↗
DOE OSTI2025

Freeze-induced crystallization: An overlooked pathway for mineral genesis in natural waters

Natural ice plays salient roles in making the Earth habitable and sustainable. Previously overlooked, its role in chemical processes is now of emerging interest, particularly due to the freeze concentration effect, which can substantially promote chemical reactions during ice formation. We demonstrate here that ice formation can serve as a dynamic and unique pathway for mineral genesis. Freezing solutions containing dissolved manganese and carbonates produced rhodochrosite (Mn II CO 3 ) even under slightly undersaturated conditions. At room temperature, by contrast, this occurred when the solution saturation level was increased by ca. 30,000 times. The cryogenic rhodochrosite formed spherical aggregates of nano-polycrystallites, distinctly different from the cubic monocrystalline particles observed at room temperature. The distinct feature likely resulted from the combined effects of the intensified supersaturation induced by the freeze concentration effect and the low temperatures within liquid-like layers, conditions that make liquid-like layers an exceptional environment for mineral genesis, unlike typical natural water systems. The cryogenic rhodochrosite formation was successfully demonstrated using in situ, real-time X-ray absorption spectroscopy (XAS), enabling direct observation of freeze-induced solid formation. In conclusion, our findings reveal that freeze-induced crystallization may be an active mineralization pathway, potentially influencing elemental cycles within the cryosphere and contributing to minerals with distinguishing properties and reactivities in the environment.

Earth, Atmospheric, and Planetary Sciences↗
DOE OSTI2024

Targeted engineering of camelina and pennycress seeds for ultrahigh accumulation of acetyl-TAG

Acetyl-TAG (3-acetyl-1,2-diacylglycerol), unique triacylglycerols (TAG) possessing an acetate group at the sn -3 position, exhibit valuable properties, such as reduced viscosity and freezing points. Previous attempts to engineer acetyl-TAG production in oilseed crops did not achieve the high levels found in naturally producing Euonymus seeds. Here, we demonstrate the successful generation of camelina and pennycress transgenic lines accumulating nearly pure acetyl-TAG at 93 mol% and 98 mol%, respectively. These ultrahigh acetyl-TAG synthesizing lines were created using gene-edited FATTY ACID ELONGASE1 ( FAE1 ) mutant lines as an improved genetic background to increase levels of acetyl-CoA available for acetyl-TAG synthesis mediated by the expression of EfDAcT, a high-activity diacylglycerol acetyltransferase isolated from Euonymus fortunei . Combining EfDAcT expression with suppression of the competing TAG-synthesizing enzyme DGAT1 further enhanced acetyl-TAG accumulation. These ultrahigh levels of acetyl-TAG exceed those in earlier engineered oilseeds and are equivalent or greater than those in Euonymus seeds. Imaging of lipid localization in transgenic seeds revealed that the low amounts of residual TAG were mostly confined to the embryonic axis. Similar spatial distributions of specific TAG and acetyl-TAG molecular species, as well as their probable diacylglycerol (DAG) precursors, provide additional evidence that acetyl-TAG and TAG are both synthesized from the same tissue-specific DAG pools. Remarkably, this ultrahigh production of acetyl-TAG in transgenic seeds exhibited minimal negative effects on seed properties, highlighting the potential for production of designer oils required for economical biofuel industries.

09 BIOMASS FUELS↗
NASA NTRS1978

Controlled freezing of biological samples

Apparatus consists of thermocouple connected to semiconductor reference junction. Junction is connected to amplifier that boosts signal by 1,000. High-level signal is displayed on recorder and fed into second amplifier where it is compared with signal from potentiometer of programmed dc reference in bag-temperature programer. Difference in signals indicates output voltage. Remaining circuitry provides zero-phase, time-proportion control of heaters such that heater power is directly proportional to error signal.

Cygnarowicz, T. A.↗
NASA NTRS2016

Water Phase Change Heat Exchanger System Level Analysis for Low Lunar Orbit

In low Lunar orbit (LLO) the thermal environment is cyclic - extremely cold in the eclipse and as warm as room temperature near the subsolar point. Phase change material heat exchangers (PCHXs) are the best option for long term missions in these environments. The Orion spacecraft will use a n-pentadecane wax PCHX for its envisioned mission to LLO. Using water as a PCM material is attractive because its higher heat of fusion and greater density result in a lighter, more compact PCHX. To assess the use of a water PCHX for a human spacecraft in a circular LLO, a system level analysis was performed for the Orion spacecraft. Three cases were evaluated: 1) A one-to-one replacement of the wax PCHX on the internal thermal control loop with a water PCHX (including the appropriate control modifications), 2) reducing the radiator return setpoint temperature below Orion's value to enhance PCHX freezing, and 3) placing the water PCM on the external loop. The model showed that the water PCHX could not be used as a drop-in replacement for the wax PCHX. It did not freeze fully during the eclipse owing to its low freezing point. To obtain equivalent performance, 40% more radiator area than the Orion baseline was required. The study shows that, although water PCHXs are attractive at a component level, system level effects mean that they are not the best choice for LLO.

Navarro, Moses↗
NASA NTRSDate not supplied

A Daily Surface Melt Product From Passive Microwave Swath Observations for Arctic Sea Ice Studies

Most passive microwave sea ice data products are produced with daily gridded brightness temperatures. However, a single polar-orbiting passive microwave instrument makes many measurements per day where swaths overlap in the polar regions. These level 1 swath brightness temperature observations can be used to derive information on sub-daily sea ice processes. One such process is the rapid transition of snow and ice between freezing and melting due to diurnal freeze-thaw cycling or brief warming events in the pre-melt season. Here, a new method utilizing the sub-daily variability in swath-to-swath observations is used to produce daily, binary maps of the melting status on Arctic Sea ice using Level 1C brightness temperatures from the Special Sensor Microwave Imager and Sounder (SSM/I-SSMIS) data record. The resulting data set will enable investigations of the frequency, inter-annual variability, and spatial extent of brief surface melting events occurring in the winter and shoulder seasons outside of the traditional summer melt season.

Angela C. Bliss↗
DOE OSTI2019

Simulating a Mesoscale Convective System Using WRF with a New Spectral Bin Microphysics: Part 1: Hail vs Graupel

A modified Fast Spectral Bin Microphysics scheme (FSBM-2) embedded into the Weather Research and Forecasting Model (WRF) is used to simulate a mesoscale deep convective system observed during the Midlatitude Continental Convective Clouds Experiment (MC3E). FSBM-2 uses modified source codes as compared to the current FSBM (FSBM-1). In contrast to FSBM-1, FSBM-2 can simulate hail of several cm in diameter and includes additional processes such as spontaneous breakup of raindrops and aerosol regeneration by drop evaporation. It is shown that allowing large hail particles of diameters exceeding about 1 cm substantially increases the agreement between the simulated and observed squall-line structures both in the convective and stratiform regions. In contrast, if graupel particles are used to represent high-density hydrometeors in convective areas, the ratio of convective-to-stratiform areas diverges from the ratio seen in observations and maximum radar reflectivities are substantially underestimated. Analysis of snow size distributions in the stratiform area shows an important link between the ice crystals formed by homogeneous freezing in the convective area to ice particle number concentration in the stratiform region. Simulated raindrop size distributions in the stratiform area below the melting level from FSBM-2 show a good agreement with observations. The regeneration of CCN by droplet evaporation and detrainment of these CCN to the stratiform region increases the concentration of CCN there up to 8-9 km altitude; the additional CCN penetrate clouds and produce new droplets, leading to some convection intensification. Key words: Mesoscale convective systems (MCS), squall lines, spectral bin microphysics, large hail, in-cloud nucleation, size distributions of hydrometeors in MCS.

Shpund, Kobby↗
DOE OSTI2021

Comparing Satellite- and Ground-Based Observations of Cloud Occurrence Over High Southern Latitudes

The 2B-CLDCLASS-LIDAR R05 (2BCL5) and the raDAR/liDAR (DARDAR) satellite retrievals of cloud occurrence are compared as a function of altitude and latitude. The largest disparities are observed at low altitudes over high southern latitudes. These data sets are cross referenced to ground-based measurements from the Atmospheric Radiation Measurement (ARM) West Antarctic Radiation Experiment (AWARE) campaign at McMurdo Station, Antarctica. Compared with AWARE observations, both 2BCL5 and DARDAR underestimate cloud occurrence below 1.5 km, with 2BCL5 and DARDAR distinguishing roughly one third of cloud occurrences observed by AWARE at 0.5 km. While DARDAR identifies greater cloud occurrences than 2BCL5 below 1.5 km, cloud occurrence values for the two data sets have similar differences relative to ground-based measurements. Therefore, the DARDAR retrievals of greater cloud occurrence at low altitudes are likely due to a larger quantity of false positives associated with radar ground clutter or attenuated lidar retrievals. DARDAR cloud occurrences match better with AWARE than 2BCL5 above 5 km. However, the likely underestimation of ground-based measurements at higher altitudes suggests DARDAR may underestimate high level cloud occurrence. Finally, both data sets indicate the presence of liquid containing clouds at temperatures within the homogeneous freezing regime, despite the fact that the ECMWF-AUX data set implemented in their processing clearly indicates temperatures below -38°C. Finally, using AWARE radiosonde (ECMWF-AUX) temperature data, we find that 2BCL5 detects 13.3% (13.8%) of mixed phase clouds below -38°C, while DARDAR detects 5.7% (6.6%) of mixed phase and 1.1% (1.3%) of liquid phase clouds below -38°C.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2011

Space Shuttle Propulsion Finishing Strong

Numerous lessons have been documented from the Space Shuttle Propulsion elements. Major events include loss of the SRB's on STS-4 and shutdown of an SSME during ascent on STS- 51F. On STS-112 only half the pyrotechnics fired to release the vehicle from the launch pad, a testament for redundancy. STS-91 exhibited freezing of a main combustion chamber pressure measurement and on STS-93 nozzle tube ruptures necessitated a low liquid level oxygen cut off of the main engines. A number of on pad aborts were experienced during the early program resulting in delays. And the two accidents, STS-51L and STS-107, had unique heritage in history from early Program decisions and vehicle configuration. Following STS-51L significant resources were invested in developing fundamental physical understanding of solid rocket motor environments and material system behavior. Human rating of solid rocket motors was truly achieved. And following STS-107, the risk of ascent debris was better characterized and controlled. Situational awareness during all mission phases improved, and the management team instituted effective risk assessment practices. These major events and lessons for the future are discussed. The last 22 flights of the Space Shuttle, following the Columbia accident, were characterized by remarkable improvement in safety and reliability. Numerous problems were solved in addition to reduction of the ascent debris hazard. The propulsion system elements evolved to high reliability and heavy lift capability. The Shuttle system, though not a operable as envisioned in the 1970's, successfully assembled the International Space Station (ISS) and provided significant logistics and down mass for ISS operations. By the end of the Program, the remarkable Space Shuttle Propulsion system achieved very high performance, was largely reusable, exhibited high reliability, and is a heavy lift earth to orbit propulsion system. The story of this amazing system is discussed in detail in the paper.

Owen, James W.↗