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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,441 records · Page 80

Modeling Savings for ENERGY STAR Smart Home Energy Management Systems

The objective of this study was to develop a repeatable and defensible methodology to analyze the energy savings for Home Energy Management Systems (HEMS) that meets the minimum requirements for certification under ENERGY STAR ® Smart Home Energy Management System (SHEMS) Version 1. Mandatory connected loads include a smart thermostat, two smart lights, and one smart power strip or smart outlet. Control strategies must include feedback to occupants through an in-home display, user programming, occupancy sensor-based controls, and responsiveness to utility signals such as demand response programs. Several occupant behavior patterns were selected to quantify the range of energy savings potential for a HEMS with this basic functionality. A literature review was conducted to establish realistic room-by-room occupancy levels and usage patterns for connected devices. A series of event-driven hourly profiles were created, followed by adjustments based on application of HEMS control strategies to thermostats, interior lighting, and plug load schedules. EnergyPlus modeling was performed using these hourly schedules in three locations (Boston, Houston, and Phoenix) to examine climate dependence of energy savings. Total site energy savings ranged from 4.3 to 27.1 MBtu/year (7%-35%), and utility bill savings ranged from $\$$123 to $\$$670/year (6%-29%). The highest predicted savings was realized by occupants that were not energy conscious prior to HEMS installation, but highly engaged with the HEMS controls once the system was installed. The smart thermostat accounted for most of the savings, followed by the smart power strip. Smart lighting did not save a significant amount of energy in our analysis, based on an assumption that efficient LEDs with no standby power would normally be installed anyway.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Revisiting Multi-Material Composite Structures with Homogenized Composite Properties

Composite structures inherently develop residual stresses during their curing process. Driven predominately by mismatched thermal strains between differing materials or ply orientations, but also affected by curing process phenomena like polymer shrinkage, these residual stresses can lead to failure within composite structures. There are several methods varying in complexity that can be used to model the development of residual stresses, all of which are capable of capturing sufficient detail to understand the residual stress state at the ply level. However, explicitly modeling all plies of a layup in a composite structure can be prohibitively expensive based on the number of plies, structure size, and required element size. The computational cost can be reduced through the homogenization of the composite layup without losing much fidelity of the overall response of the structure. The homogenization process reduces the many plies of a laminate to a single lamina that reduces complexity and increases the mesh size where a single element can span multiple plies. This report focuses on verification and validation efforts for a homogenization process using a suite of finite element simulations rather than an analytic solution derived from classical laminate theory. Initial verification using representative element volumes indicated there was minimal error in the homogenization process; however, this compounded to a small, but acceptable error in strip and split ring experimental composite structures. The error does under predict the residual stress state in the strip and split ring and should be accounted for when simulating composite structures with homogenized properties.

36 MATERIALS SCIENCE↗

Economic Extraction, Recovery and Upgrading of Rare Earth Elements from Coal-Based Resources (Final Report)

The overall objective of this project is to produce a rare earth elements product with greater than 8% rare earth elements from coal-based resources using an economically viable and environmentally benign processing methodology. The objective of the coal processing work will be to acquire appropriate coal feed and produce a viable clean coal product, a concentrated REE feed stream, and a pyrite stream (where available) that can be used to enhance leaching. The objective of the bio-oxidation portion of the project is to utilize bacteria to oxidize sulfide minerals and ferrous ions to ferric ions to accelerate leaching and remove the sulfides to prevent future acid mine drainage and related liabilities. The objective of the solution conditioning work is to remove iron and control leaching solution conditions to facilitate extraction of REEs without significant thorium extraction. The objective of the column leaching work is to engineer/model and simulate heap leaching to demonstrate low-cost extraction of REEs from coal-based resources. The objective of the solvent extraction work is to selectively extract and recover through controlled stripping of REEs that are solubilized through leaching. The objective of the precipitation portion of the project is to recover the REEs from the solvent extraction stripping solutions and dry them to achieve the final product of rare earth elements that is > 8 % REEs. The objective of the technical, economic, and environmental analysis is to determine the overall viability of the processing approach that is demonstrated in this project

01 COAL, LIGNITE, AND PEAT↗

Performance of Lithium-Ion Batteries with 3D Printed Anodes and Compressible Carbon Structures

Carbon scaffolds have been shown to improve the performance of Li metal anodes in Li-ion batteries by acting as conductive hosts for Li metal plating and stripping. The scaffolds provide a more uniform electric field, and their 3D geometry enables smaller diffusion paths for the Li ions. In this project, several different types of carbon lattices were 3D printed, mechanically tested, and analyzed in coin cells. Planar and 3D printed graphite coatings were evaluated as the baseline, since graphite is a common anode material. The results showed that implementing a 3D graphite lattice into a coin cell improved the Li plating and stripping efficiency compared to the planar coating. However, since graphite can intercalate Li ions, other carbon materials were also explored that should act as better hosts for Li plating/stripping. To improve the compressibility of these non-graphite carbon scaffolds, five different carbon ink formulations were 3D printed in lattice configurations. SEM imaging and compression testing showed that both the final dimensions and the compressibility of the carbon lattices depended on the type of carbon precursors used. The two most suitable compositions were found to be those made with graphene oxide-resorcinol formaldehyde and graphene oxide-ammonium hydroxide. In the future, these formulations will be further refined to increase their mechanical strength, and their performance as scaffold hosts for Li metal anodes will be evaluated in coin cells.

25 ENERGY STORAGE↗

Sorbent Based Post-Combustion CO 2 Slipstream Testing

TDA Research, Inc. has developed a low-cost sorbent (alkalized alumina) based technology for post-combustion CO 2 capture. The sorbent runs in an isothermal process for adsorption and regeneration. Neither temperature swing nor pressure swing is needed. TDA designed a system which operated 10 fixed beds to simulate a moving bed process. The flow pattern was optimized to minimize the steam usage for regeneration. An excellent sorbent (Batch 1) was also developed with collaboration with our partner. The sorbent degraded after long term operation. We developed a reprocessing procedure, which can be conducted in situ, to restore the sorbent capture capacity as the fresh sorbent after running for about 1250 hours. The reprocessing extended the sorbent longevity significantly. TDA designed a pilot unit (40’ x 32’ x 11.5’), processing flue gas equivalent to 0.5 MW of power generation. It had 10 beds and each bed could hold 1.75 m 3 of sorbent. We worked with Springs Fabrication, Inc. to complete the construction of the pilot unit. It was then shipped and installed at NCCC. The pilot unit was kept running in 24-hour mode when the flue gas and steam were available. It could run automatically without operator on site. Parametric and long-term (2 months) tests were carried out successfully. The results showed that TDA’s process can achieve 90% capture and 95% CO 2 purity for both coal and NG flue gases. For coal flue gas, the system reached performance target when processing up to 0.62 MW flue gas, 24% higher than the design capacity. Thus, capital cost could be saved on the reactors and sorbent. The strip air flow was designed to be 0.25 of that of the flue gas. The test data showed the strip/flue ratio can be reduced to as little as 0.18, which saves the power consumption for the strip air blower. The pressure drop was found to be lower than what the empirical equation calculated. The sorbent still had 91.7% of original capacity after 3-month test. With the data from the pilot test, we updated the TEA. For a 550-MW e supercritical coal fired power plant with CO 2 capture, the capture cost for TDA’s process is $34.9/tonne CO 2 captured, which meets DOE’s goal of $40/tonne and is 17.1% less than the DOE baseline Case 12. Therefore, TDA’s process has a good potential for commercialization.

01 COAL, LIGNITE, AND PEAT↗

A VXS [VITA41] Trigger Processor for the 12GEV Experimental Programs at Jefferson Lab

The VXS_Trigger_Processor [VTP] was developed and commissioned for CLAS12 in the fall of 2016. This board is a VITA41 switch card and it collects data from a variety of front-end TDC and Flash ADC modules. The VTP has since been used in several experiments at Jefferson Lab serving as the L1 trigger module for a variety of detector types, such as stacked calorimeters, strip calorimeters, time-of-flight, Cerenkov, hodoscopes, drift chambers, and silicon strips. Trigger algorithms implemented include cluster finding (1D, 2D), drift chamber segment and road finding, geometry matching between various detectors, particle counting, and general global trigger bit processing. The VTP is also capable of reading out each front-end crate with up to 40Gbps Ethernet which is an enormous increase compared to the currently used 200MB/s VME bus. Recent progress has been made to show that a firmware and software upgrade can enable existing Jefferson Lab front-end crates to operate in a streaming DAQ mode. In February 2020, tests will be performed on a full calorimeter and matched hodoscope which are components of the CLAS12 Forward Tagger detector system with beam in Hall B. This paper details the hardware performance, triggered, and streaming applications that have been implemented using the VTP for several experiments at Jefferson Lab.

ABBOTT, David↗

Survey of AC-LGADs for future 4D trackers with a proton beam

We will present the first beam test results with centimeter-scale AC-LGAD strip sensors, using the Fermilab Test Beam Facility, and a study of the performance of AC-LGAD sensors as a function of their thickness. Sensors of this type are envisioned for applications that require large-area precision 4D tracking coverage with economical channel counts, including timing layers for the Electron Ion Collider (EIC), and space-based particle experiments. Long strip sensors with sparse readout offer better cost and performance for applications where channel count or electrical power density is a constraint. Thanks to the excellent signal to noise ratio in AC-LGADs, sparse readout can be exploited without significant degradation of spatial or time resolution, which is demonstrated in our studies. A survey of sensor designs is presented, with the aim of optimizing the electrode geometry for spatial resolution and timing performance. We will present our studies of the sensor geometry optimizatio n to maintain the desirable sensor performance characteristics with increasingly larger electrodes.

43 PARTICLE ACCELERATORS↗

Kinetics and Mechanism of Tetravalent Cerium Extraction by Di-2-Ethylhexyl Isobutyramide (DEHiBA)

DEHiBA is a fully-incinerable, CHON extractant with a high selectivity for hexavalent actinides. However, as a recently-developed ligand, much remains unknown about its physical and chemical properties, including its extraction and phase disengagement rates. Here, we present data on the phase transfer kinetics of Ce(IV) extraction and stripping by both DEHiBA and TBP collected using microfluidic devices. Ce(IV) was selected as a surrogate for Pu(IV) and Np(IV) in the initial tests of the microfluidics system prior to testing with the actinides. Pseudo first-order reaction rate constants are determined for both systems, and the corresponding Damköhler numbers (Da) are calculated to establish whether the extraction and stripping processes are kinetically or diffusion controlled. The stoichiometry of the extracted Ce(IV)-DEHiBA complex is determined, and the phase disengagement properties under extraction conditions are assessed using the dimensionless dispersion number. A possible explanation for the favorable extraction of Ce(IV) by DEHiBA, which is known to poorly extract many tetravalent cations, is presented.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The 2023 Gold Run in the Injectors

RHIC Run 23 used Gold beam from Tandem with an AGS extraction energy of 9.8 GeV. The same basic setup, 8 single bunch transfers from the Booster and a 12-6 merge in the AGS to provide 4 bunches at extraction, had been used before to deliver Tandem Au to RHIC. But in those cases, it was used for low energy runs (3.85 GeV in 2021 and 5.75 GeV in 2020) where extraction was below transition energy (7.9 GeV). Tandem beam was used for this run because the intensity and stability of EBIS Au did not meet the requirements for RHIC. Physics was first declared in RHIC on May 22 nd and on August 1 st the run was cut short by about 2 months due to a major failure in RHIC. Prior to the advent of EBIS as the preinjector in 2012, 9.8 GeV Tandem Au was regularly delivered to RHIC but the setup in the Booster and AGS was quite different: Four Booster transfers of 6 bunches each were merged into 4 bunches using a 24-12-4 merge scheme. The supercycle length was 6.0 sec before June 29 th when it was extended to 6.6 sec to accommodate EBIS commissioning. The Tandem, Booster, and AGS were on user 1 for the 9.8 GeV setup. Some work with EBIS Au 32+ took place on EBIS, Booster, and AGS user 5 using the standard 9.8 GeV injector setup with a 4 to 1 merge in Booster and a 6-3-1 type merge in AGS. The Siemens motor generator was used for the entire run. An intensity limit of 8.0e9 Au 77+ ions in the AGS was in effect during the run to protect the J7 plunging stripping foil and the Copper absorber of the AGS beam dump. This corresponds to a merged bunch intensity limit of 2.0e9 Au 77+ ions for 4 equal intensity bunches. The per bunch intensity limit can be increased to 2.67e9 by reducing the number of BtA transfers from 8 to 6. There was also a Booster Late intensity limit of 16e9 Au ions in effect to protect the BtA stripping foil from damage due to overheating. Lowering the number of transfers also makes this limit less of a constraint. BtA foil 5, which was installed in 2020 and had not been used regularly prior to this run was used all run and showed no obvious signs of deterioration. In May, a Tandem Au 3.85 GeV setup from 2021 was also re-established on AGS user 2. It was used for APEX on May 24 and July 26. Initial work with 3.85 GeV beam was on May 19. Proton beam was also set up during the run and extracted to W dump on July 10. It was used for APEX on July 12. Although the OPPIS source was used the AGS setup was without snakes.

43 PARTICLE ACCELERATORS↗

Beam Scattering Through Foil at NSRL

In this note, we describe the foil structure that is used in the NASA Space Radiation Laboratory (NSRL) transport line just before D6 septum magnet. Foils of different materials and thickness are used through which different ion species at different energies pass. Foil removes the electrons from the incoming ions and make it fully stripped (or partially stripped is also possible). Further, when charged particles pass through a foil, the outgoing particles form a Gaussian like angular distribution. This Gaussian like distribution passes through a set of octupole magnets creates a uniform beam distribution at the NSRL target which is required for various beam experiments. We utilize the Bmad and SRIM packages to calculate the energy loss through the foils for various ion species at different energies and charge states. Finally, we provide a summary of the energy loss calculations through the foils using these two different methods.

43 PARTICLE ACCELERATORS↗

Performance Analysis of Phase 2 Tracker Upgrade Ps Module before and after Irradiation

The Large Hadron Collider will undergo a luminosity upgrade targeting a peak instantaneous luminosity ranging from 5–7.5×1034 cm−2s−1. The ambitious goal of the High Luminosity LHC is to achieve a total of 3000–4000 fb−1 of proton-proton collisions at a center-of-mass energy of 13–14 TeV by 2029. To cope with such challenging environmental conditions, the outer tracker of the CMS experiment will be upgraded using closely spaced silicon sensors (pixels and strips) to provide tracking information at the Level-1 trigger. A PS-Module, composed of both a pixel and a strip sensor, was tested at the Fermilab Test-Beam Facility to evaluate its ability to provide accurate tracking information, Pt discrimination capabilities, and optimal performance at the irradiation levels expected after being exposed to the harsh conditions of the High Luminosity LHC. The results of the test and the comparison of the module performance before and after irradiation will be presented in this poster

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Resonant Slow Extraction Simulation using Bmad

Simulations of slow extraction and transport of charged particle beams from synchrotrons requires careful modeling and experimentation. In this paper, we outline how the Bmad modeling software was adapted and developed to run third-integer resonant extraction simulations of beams at Brookhaven National Laboratory’s Booster synchrotron. Further, we show experimental comparisons of the slowly extracted beams transferred to the NASA Space Radiation Laboratory (NSRL) transport line. In this process, beam passes through a stripping foil element at the extraction point, which, along with stripping remaining electrons from the beam ions, acts as a scatterer to modify the phase space, moving to a more Gaussian-like distribution. This modification to the beam helps generate a uniform beam at the beam line’s target location; which is necessary for the variety of experiments performed at the facility. During this work, beam energy loss and multiple scattering by foil routines were built in conjunction with the Bmad code developers and are now integrated into the software.

43 PARTICLE ACCELERATORS↗

Jump-Start U.S. Manufacturing of High-Performance Permanent Magnets

Gas atomized feedstock powders for Nd-Fe-B based magnets are more robust and cost effective than the strip-cast sheet currently used as feedstock for milling by the magnet industry. However, gas atomized powder’s crystallinity and grain boundary phases are less ideal than the strip cast flake. We proposed to optimize the atomization process as well as the powder chemistry to address this issue and to eliminate heavy rare earth elements from these magnet alloys. Our goal is to help GKN-Hoeganaes, a US metal powder company, who used to make Nd-Fe-B magnets, to bring back US manufacturing of these high energy density permanent magnets.

36 MATERIALS SCIENCE↗

T-1075: Large Area Fast Timing Beam Time of Flight (LAFTBToF) for ProtoDUNE

Large-area Picosecond Photodetectors (LAPPDs), developed at Argonne National Laboratory (ANL), present an opportunity to provide identification of charged particles in the 2-10 GeV/c range. Traditional methods using ionization or Cherenkov detectors require large amounts of material or pathlength for the particle to traverse in order to get a clean measurement, and are ill suited for particle beam identification in fixed-target experiments. The 6x6 cm 2 LAPPD uses mm-thick borosilicate glass micro-channel plates with a resistive surface coating added via atomic layer deposition. An electrical connection schematic of the LAPPD is shown in Figure 1. Electrons emitted by the photocathode are accelerated through the MCPs, which have µm-sized capillaries, and an avalanche of electrons is created as the electrons collide against the walls of the capillaries of the MCPs. The resulting electron avalanche is collected on anode strip lines and the signal may be read out on both ends of the stipline. The resistive coating of the thin MCPs and the short path length of the electrons to the readout results in fast rise times, gains of greater than 10 6 and typical timing resolutions of 50 ps. Differential timing on the ends of the strip lines can provide mm-level position measurements. The material of the bare LAPPD presents less than 0.05 of an interaction length and approximately 0.12 of a radiation length for a charged particle of I GeV/c. In our application, two large-area photodetectors separated by 5-10 meters can be used in a time-of-flight (ToF) measurement for 3σ separation of2-7 GeV/c charged pions, kaons and protons with minimal impact on the particle's trajectory and momentum.

43 PARTICLE ACCELERATORS↗

MaPSA Quality Control and AI-Enhanced Grading For the CMS Phase-II Tracker Upgrade

The Compact Muon Solenoid (CMS) experiment will undergo changes as part of the Large Hadron Collider upgrade. The CMS tracker will be upgraded to cope with the new radiation environment and to provide tracking at the first level trigger. This upgrade features a new type of silicon module called PS Module, which combines a Pixel sensor and a Strip sensor in the same module. The pixel portion of the PS module has a sensor bump bonded to 16 Macro Pixel ASICs (MPA) to form a Macro Pixel Sub Assembly (MaPSA). At Fermilab, MaPSAs are tested for quality control before being assembled with the strip sensors, readout and service electronics to form a PS Module. All of this test data is stored in a centralized database, and is used to grade the final module to determine if it will be installed in the detector. The Phase II Outer Tracker Analyzer of Test Outputs (POTATO) is the software that processes this data and determines the module grades. Using recent technologies, an AI agent is being im plemented into POTATO in order to allow users to more efficiently sort through the large amounts of analysis data and ensure that only the user specified data is being considered. This poster will display the process of testing a MaPSA, how that test data is relevant to module assembly and grading, and how the POTATO grading tool is being improved with the use of an embedded AI agent.

Gzamouranis, Olivia [Purdue U.]↗

In Situ Li Seed Formation Enables Uniform Plating in Anode-Free Solid-State Batteries

Anode-free solid-state batteries (AFSSBs) are a promising route toward achieving high energy density. In these cells, the anode contains no pre-stored lithium (Li). Instead, all Li inventory originates from the cathode and is freshly deposited onto a bare current collector during charging. However, achieving uniform and defect-free Li plating on this bare current collector remains a major challenging, often resulting in low Li plating/stripping efficiency and rapid capacity decay. Here, for the first time, operando neutron imaging is employed to visualize Li plating/stripping behavior in an anode-free full cell with LiNi 0.82 Mn 0.07 Co 0.11 O 2 (NMC) as the cathode. Operando measurements reveal that complete stripping of Li leaves isolated Li residues on the current collector, which degrades interfacial contact between the current collector and solid-state electrolyte. To mitigate this interfacial issue and promote more uniform Li deposition, we implement a discharge cutoff voltage strategy that intentionally retains a thin residual Li layer after stripping. This thin Li layer, serving as an in situ–formed seed layer, not only enables more homogeneous subsequent Li plating but also improves interfacial contact. As a result, the anode-free cell with a controlled discharge voltage of 3.5 V exhibits excellent long-term cycling stability, maintaining a discharge capacity of 116 mAh g -1 with a retention rate of 83.4% and an average Coulombic efficiency of approximately 99.9% after 430 cycles at 0.25 C. In contrast, the cell with a conventional discharge cutoff voltage of 2.8 V exhibits rapid capacity decay, retaining only 59.7 mAh g -1 after 50 cycles with a capacity retention of 40.7%. This work offers a practical strategy to unlock the long-term viability of anode-free solid-state batteries.

25 ENERGY STORAGE↗

Direct Mercury Detection in Landfill Leachate Using a Novel AuNP-Biopolymer Carbon Screen-Printed Electrode Sensor

A novel Au nanoparticle (AuNP)-biopolymer coated carbon screen-printed electrode (SPE) sensor was developed through the co-electrodeposition of Au and chitosan for mercury (Hg) ion detection. This new sensor showed successful Hg2+ detection in landfill leachate using square wave anodic stripping voltammetry (SWASV) with an optimized condition: a deposition potential of −0.6 V, deposition time of 200 s, amplitude of 25 mV, frequency of 60 Hz, and square wave step voltage of 4 mV. A noticeable peak was observed at +0.58 V associated with the stripping current of the Hg ion. The sensor exhibited a good sensitivity of ~0.09 μA/μg (~0.02 μA/nM) and a linear response over the concentration range of 10 to 100 ppb (50–500 nM). The limit of detection (LOD) was 1.69 ppb, which is significantly lower than the safety limit defined by the United States Environmental Protection Agency (USEPA). The sensor had an excellent selective response to Hg2+ in landfill leachate against other interfering cations (e.g., Zn2+, Pb2+, Cd2+, and Cu2+). Fifteen successive measurements with a stable peak current and a lower relative standard deviation (RSD = 5.1%) were recorded continuously using the AuNP-biopolymer-coated carbon SPE sensor, which showed excellent stability, sensitivity and reproducibility and consistent performance in detecting the Hg2+ ion. It also exhibited a good reliability and performance in measuring heavy metals in landfill leachate.

Hwang, Jae-Hoon (ORCID:0000000220100864)↗

VARIABILITY IN ACTIVE GALACTIC NUCLEI FROM PROPAGATING TURBULENT RELATIVISTIC JETS

We use the Athena hydrodynamics code to model propagating two-dimensional relativistic jets as approximations to the growth of radio-loud active galactic nuclei for various input jet velocities and jet-to-ambient matter density ratios. Using results from these simulations we estimate the changing synchrotron emission by summing the fluxes from a vertical strip of zones behind the reconfinement shock, which is nearly stationary, and from which a substantial portion of the flux variability should arise. We explore a wide range of timescales by considering two light curves from each simulation; one uses a relativistic turbulence code with bulk velocities taken from our simulations as input, while the other uses the bulk velocity data to compute fluctuations caused by variations in the Doppler boosting due to changes in the direction and the speed of the flow through all zones in the strip. We then calculate power spectral densities (PSDs) from the light curves for both turbulent and bulk velocity origins for variability. The range of the power-law slopes of the PSDs for the turbulence induced variations is −1.8 to −2.3, while for the bulk velocity produced variations this range is −2.1 to −2.9; these are in agreement with most observations. When superimposed, these power spectra span a very large range in frequency (about five decades), with the turbulent fluctuations yielding most of the shorter timescale variations and the bulk flow changes dominating the longer periods.

79 ASTRONOMY AND ASTROPHYSICS↗