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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1981

An experimental investigation of gapwise periodicity and unsteady aerodynamic response in an oscillating cascade. Volume 2: Data report. Part 1: Text and mode 1 data

Tests were conducted a linear cascade of airfoils oscillating in pitch to measure the unsteady pressure response on selected blade along the leading edge plane of the cascade, over the chord of the center blade, and on the sidewall in the plane of the leading edge. The tests were conducted for all 96 combinations 2 mean camberline incidence angles 2 pitching amplitudes 3 reduced frequencies and 8 interblade phase angles. The pressure data were reduced to Fourier coefficient form for direct comparison, and were also processed to yield integrated loads and particularly, the aerodynamic damping coefficient. Data obtained during the test program, reproduced from the printout of the data reduction program are complied. A further description of the contents of this report is found in the text that follows.

Carta, F. O.↗
DOE OSTI2024

In situ characterization of two unknown ultrashort laser pulses using four-wave mixing in gas

Accurate characterization of two ultrashort laser pulses is of great interest in many ultrafast pump-probe experiments. We demonstrate a method based on four-wave mixing (FWM) in a gas which could be easily implemented into many existing pump-probe setups with minimal modifications for accurate, in situ characterization of both unknown pulses. This technique is tested on pairs of unknown pulses at wavelengths of 400/800 nm, and 266/400 nm. We measured the spectrogram of the pulse generated through FWM of the two unknown pulses by scanning the delay between two unknown pulses. The retrieval algorithm converges to accurately predict the intensity and the phase profiles of both unknown pulses with a trace error of < 1% and the accuracy is verified using an independent pulse characterization device.

Nambu, Noa (ORCID:0000000197303400)↗
DOE OSTI2026

Storage Field Development Plan: One Earth Energy

This Storage Field Development plan presents the Storage Complex characterization results, construction, monitoring, and operational plans, and costs associated with the proposed One Earth Sequestration Carbon Capture and Storage (OES-CCS) site in McLean County, Illinois, near Gibson City. The proposed storage complex, known as the Mt. Simon Storage Complex, comprises the Cambrian Mt. Simon Sandstone reservoir and the primary seal, the Cambrian Eau Claire Formation. The lowermost Underground Source of Drinking Water (USDW) identified for the site is the Ordovician St. Peter Sandstone. Geologic characterization of the Mt. Simon Storage Complex at the OES-CCS site was performed by the Illinois Storage Corridor CarbonSAFE Phase III project, which also prepared and submitted three UIC Class VI applications to construct three injection wells; the permit applications were submitted and are in the federal EPA review process. A characterization well, OEE #1, was drilled to collect site-specific data. These data were analyzed and used to develop the UIC Class VI applications. The OEE #1 well will be converted to an in-zone monitoring (IZM) well for the injection phase. The proposed buildout for the OES-CCS site includes (1) three injection wells (OES #1, OES #2, and OES #3), (2) two IZM wells, (3) two above confining zone (ACZ) monitoring wells, one of which will be used to monitor the lowermost USDW, (4) capture and compression facilities, and (5) transportation facilities, i.e., pipelines. A pre-operational testing program was proposed in the Class VI permit application and will be employed at the site pending approval. Additional pre-injection (baseline), syn-injection, and post-injection monitoring and site care procedures will be followed by OES to ensure that injection activities are protective of human health and the environment. Injection is scheduled to begin in 2025, distributed across the three injection wells in accordance with the permit operating conditions. One Earth Sequestration intends to inject up to 90 million tonnes of CO 2 over a period of approximately 20 years. Injection will begin at approximately 0.5 million tonnes of CO 2 annually and ramp up to a maximum of 4.5 million tonnes annually. Daily injection rates are expected to range from 1,400 to 1,500 tonnes per day initially and reach a maximum of approximately 4,225 tonnes per day, depending on site geology and injectivity at each injection well location, and CO 2 availability. The costs associated with the OES-CCS project include pre-operational costs (e. g. additional seismic data acquisition and well drilling), capture and transportation facility and equipment costs, predicted field operating expenditures (OpEx), and decommissioning and post-injection site care (PISC) costs. The risks associated with project activities, such as site construction, injection operations, and verification of secure storage were evaluated, and mitigation strategies proposed to alleviate those risks.

09 BIOMASS FUELS↗
NASA NTRS1975

LANDSAT-2 launch and flight activation. Launch through orbit 50 and orbit adjust operation

The results of the analysis conducted on the telemetry data from the prelaunch, launch, and flight activation phases of LANDSAT-2 spacecraft are presented according to subsystems and interrelationships that exist between subsystems. Subsystem characteristics are included along with the flight evaluation results. Flight data are compared to baseline data established at the 20 C plateau during thermal vacuum testing of the spacecraft. Evaluation guidelines are derived from the specifications developed from the LANDSAT program objectives: (1) acquisition of multispectral images of the surface of the earth; and (2) use of the LANDSAT-2 receiving, frequency translating, and transmitting equipment as a relay system to gather data from fixed earth-based sensor platforms which are operated by individual investigators. Data are presented on the first 50 orbits of the spacecraft.

Source record↗
NASA NTRS1985

Analysis of remote operating systems for space-based servicing operations, volume 1

A two phase study was conducted to analyze and develop the requirements for remote operating systems as applied to space based operations for the servicing, maintenance, and repair of satellites. Phase one consisted of the development of servicing requirements to establish design criteria for remote operating systems. Phase two defined preferred system concepts and development plans which met the requirements established in phase one. The specific tasks in phase two were to: (1) identify desirable operational and conceptual approaches for selected mission scenarios; (2) examine the potential impact of remote operating systems incorporated into the design of the space station; (3) address remote operating systems design issues, such as mobility, which are effected by the space station configuration; and (4) define the programmatic approaches for technology development, testing, simulation, and flight demonstration.

Source record↗
NASA NTRS1989

Digital 8-DPSK Modem For Trellis-Coded Communication

Digital real-time modem processes octuple differential-phase-shift-keyed trellis-coded modulation. Intended for use in communicating data at rate up to 4.8 kb/s in land-mobile satellite channel (Rician fading) of 5-kHz bandwidth at carrier frequency of 1 to 2 GHz. Modulator and demodulator contain digital signal processors performing modem functions. Design flexible in that functions altered via software. Modem successfully tested and evaluated in both laboratory and field experiments, including recent full-scale satellite experiment. In all cases, modem performed within 1 dB of theory. Other communication systems benefitting from this type of modem include land mobile (without satellites), paging, digitized voice, and frequency-modulation subcarrier data broadcasting.

Jedrey, T. C.↗
NASA NTRS1991

VERDEX: A virtual environment demonstrator for remote driving applications

One of the key areas of the National Advanced Robotics Centre's enabling technologies research program is that of the human system interface, phase 1 of which started in July 1989 and is currently addressing the potential of virtual environments to permit intuitive and natural interactions between a human operator and a remote robotic vehicle. The aim of the first 12 months of this program (to September, 1990) is to develop a virtual human-interface demonstrator for use later as a test bed for human factors experimentation. This presentation will describe the current state of development of the test bed, and will outline some human factors issues and problems for more general discussion. In brief, the virtual telepresence system for remote driving has been designed to take the following form. The human operator will be provided with a helmet-mounted stereo display assembly, facilities for speech recognition and synthesis (using the Marconi Macrospeak system), and a VPL DataGlove Model 2 unit. The vehicle to be used for the purposes of remote driving is a Cybermotion Navmaster K2A system, which will be equipped with a stereo camera and microphone pair, mounted on a motorized high-speed pan-and-tilt head incorporating a closed-loop laser ranging sensor for camera convergence control (currently under contractual development). It will be possible to relay information to and from the vehicle and sensory system via an umbilical or RF link. The aim is to develop an interactive audio-visual display system capable of presenting combined stereo TV pictures and virtual graphics windows, the latter featuring control representations appropriate for vehicle driving and interaction using a graphical 'hand,' slaved to the flex and tracking sensors of the DataGlove and an additional helmet-mounted Polhemus IsoTrack sensor. Developments planned for the virtual environment test bed include transfer of operator control between remote driving and remote manipulation, dexterous end effector integration, virtual force and tactile sensing (also the focus of a current ARRL contract, initially employing a 14-pneumatic bladder glove attachment), and sensor-driven world modeling for total virtual environment generation and operator-assistance in remote scene interrogation.

Stone, Robert J.↗
NASA NTRS1998

Development of Numerical Extended Hydrodynamics for Transition-Regime Non-Equilibrium Flows Encountered in Semiconductor Manufacturing Processes

Six months of funding was received for the proposed three year research program (funding for the period from March 1, 1997 to August 31, 1997). Although the official starting date for the project was March 1, 1997, no funding for the project was received until July 1997. In the funded research period, considerable progress was made on Phase I of the proposed research program. The initial research efforts concentrated on applying the 10-, 20-, and 35-moment Gaussian-based closures to a series of standard two-dimensional non-reacting single species test flow problems, such as the flat plate, couette, channel, and rearward facing step flows, and to some other two-dimensional flows having geometries similar to those encountered in chemical-vapor deposition (CVD) reactors. Eigensystem analyses for these systems for the case of two spatial dimensions was carried out and efficient formulations of approximate Riemann solvers have been formulated using these eigenstructures. Formulations to include rotational non-equilibrium effects into the moment closure models for the treatment of polyatomic gases were explored, as the original formulations of the closure models were developed strictly for gases composed of monatomic molecules. The development of a software library and computer code for solving relaxing hyperbolic systems in two spatial dimensions of the type arising from the closure models was also initiated. The software makes use of high-resolution upwind finite-volumes schemes, multi-stage point implicit time stepping, and automatic adaptive mesh refinement (AMR) to solve the governing conservation equations for the moment closures. The initial phase of the code development was completed and a numerical investigation of the solutions of the 10-moment closure model for the simple two-dimensional test cases mentioned above was initiated. Predictions of the 10-moment model were compared to available theoretical solutions and the results of direct-simulation Monte Carlo (DSMC) calculations. The first results of this study were presented at a meeting last year.

Groth, Clinton P. T.↗
NASA NTRS2016

Wavefront-Error Performance Characterization for the James Webb Space Telescope (JWST) Integrated Science Instrument Module (ISIM) Science Instruments

The science instruments (SIs) comprising the James Webb Space Telescope (JWST) Integrated Science Instrument Module (ISIM) were tested in three cryogenic-vacuum test campaigns in the NASA Goddard Space Flight Center (GSFC)'s Space Environment Simulator (SES). In this paper, we describe the results of optical wavefront-error performance characterization of the SIs. The wavefront error is determined using image-based wavefront sensing (also known as phase retrieval), and the primary data used by this process are focus sweeps, a series of images recorded by the instrument under test in its as-used configuration, in which the focal plane is systematically changed from one image to the next. High-precision determination of the wavefront error also requires several sources of secondary data, including 1) spectrum, apodization, and wavefront-error characterization of the optical ground-support equipment (OGSE) illumination module, called the OTE Simulator (OSIM), 2) plate scale measurements made using a Pseudo-Nonredundant Mask (PNRM), and 3) pupil geometry predictions as a function of SI and field point, which are complicated because of a tricontagon-shaped outer perimeter and small holes that appear in the exit pupil due to the way that different light sources are injected into the optical path by the OGSE. One set of wavefront-error tests, for the coronagraphic channel of the Near-Infrared Camera (NIRCam) Longwave instruments, was performed using data from transverse translation diversity sweeps instead of focus sweeps, in which a sub-aperture is translated andor rotated across the exit pupil of the system.Several optical-performance requirements that were verified during this ISIM-level testing are levied on the uncertainties of various wavefront-error-related quantities rather than on the wavefront errors themselves. This paper also describes the methodology, based on Monte Carlo simulations of the wavefront-sensing analysis of focus-sweep data, used to establish the uncertainties of the wavefront error maps.

wavefront error↗
NASA NTRS2017

Calibration and Performance Measurements for the NASA Deep Space Network Aperture Enhancement Project (DAEP)

The NASA Deep Space Network (DSN) has recently constructed two new 34-meter antennas at the Canberra Deep Space Communications Complex (CDSCC). These new antennas are part of the larger DAEP project to add six new 34-meter antennas to the DSN, including two in Madrid, three in Canberra and one in Goldstone (California). The DAEP project included development and implementation of several new technologies for the S, X, Ka (26 GHz) and Ka (32 GHz) -band uplink and downlink electronics, as previously reported. The electronics upgrades were driven by several different considerations, including parts obsolescence, cost reduction, improved reliability and maintainability, and capability to meet future performance requirements. The new antennas are required to support TT&C links for all of the NASA deep-space spacecraft, as well as for several international partners. Some of these missions, such as Voyager 1 and 2, have very limited link budgets, which results in demanding requirements for system G/T performance. These antennas are also required to support radio science missions with several spacecraft, which dictate some demanding requirements for spectral purity, amplitude stability and phase stability for both the uplink and downlink electronics. After completion of these upgrades, a comprehensive campaign of tests and measurements took place to characterize the electronics and calibrate the antennas. Radiometric measurement techniques were applied to characterize, calibrate, and optimize the performance of the antenna parameters. These included optical and RF high-resolution holographic and total power radiometry techniques. These techniques, which are described in the article, resulted in the highest antenna aperture efficiency in the DSN, of 66% achieved, at the highest operating frequency of the antenna, which is Ka-Band (32-GHz). The other measurements and results described include antenna noise temperature, photogrammetry and holography alignment of antenna panels, beam-waveguide mirrors, and subreflector, antenna aperture efficiencies and G/T versus frequency, and antenna pointing models. The first antenna (DSS-35) was entered into operations in October, 2014 and the 2nd antenna (DSS-36) in October, 2016. This paper describes the measurement techniques and results of the testing and calibration for both antennas, along with the driving requirements.

Rochblatt, David J.↗
DOE OSTI2017

High-Pressure, High-Temperature Thermal Hydraulic Test Facility for Nuclear-Renewable Hybrid Energy System Studies; Facility Design Description and Status Report

A high-pressure, high-temperature water flow loop has been designed at Idaho National Laboratory (INL) for deployment in the INL Dynamic Energy Transport and Integration Laboratory (DETAIL) within the Energy Systems Laboratory (ESL) D100 northwest high bay. This loop is the first of three thermally coupled flow loops that will comprise the Advanced Reactor Technology Integral System Test (ARTIST) facility. The ARTIST facility will ultimately include a high temperature helium loop and a liquid salt loop, in addition to the PWR loop. The high-pressure water loop will operate at Pressurized Water Reactor (PWR) conditions. It will support experimental research on nuclear-renewable hybrid energy systems as well as advanced reactor technology topics. Within DETAIL, the water flow loop will also serve as a thermal energy source, emulating a reactor system. The loop will be thermally integrated with co-located energy systems including a thermal energy transport loop, thermal energy storage system, and a 25 kW high-temperature electrolysis system for hydrogen production. DETAIL will include additional energy systems such as an integrated microgrid and renewable energy systems including solar photovoltaics. The electrically heated flow loop will be dynamically controlled to simulate nuclear fuel behavior under normal and off-normal operating conditions. DETAIL will be designed for characterization of complex system dynamics. The various components will be interfaced with Digital Real-Time Simulators for supervisory control and dynamic simulation of complete systems. The design and assembly of the high-pressure water flow loop and supporting systems has been subdivided into two Phases. Phase 1, which will be completed by the end of FY17, includes installation of cable trays and supports, electrical conduit, DI water system, drain lift station and the concrete pad for the chiller located outside of the laboratory. Phase 2 includes the detailed design and final assembly of the flow loop, supporting structures and personnel platforms, the chiller and associated piping. As of September, 2017, the final detailed design of the flow loop is complete. Funding for Phase 2 procurement, assembly, system operability checkout, shakedown testing and initial operation of the flow loop is requested for FY18.

42 ENGINEERING↗
NASA NTRS2001

Solar Cycle Variations and Equatorial Oscillations: Modeling Study

Solar cycle activity effects (SCAE) in the lower and middle atmosphere, reported in several studies, are difficult to explain on the basis of the small changes in solar radiation that accompany the 11-year cycle, It is therefore natural to speculate that dynamical processes may come into play to produce a leverage. Such a leverage may be provided by the Quasi-Biennial Oscillation (QBO) in the zonal circulation of the stratosphere, which has been linked to solar activity variations. Driven primarily by wave mean flow interaction, the QBO period and its amplitude are variable but are also strongly influenced by the seasonal cycle in the solar radiation. This influence extends to low altitudes referred to as "downward control". Relatively small changes in solar radiative forcing can produce small changes in the period and phase of the QBO, but this in turn can produce measurable differences in the wind field. Thus, the QBO may be an amplifier of solar activity variations and a natural conduit of these variations to lower altitudes. To test this hypothesis, we conducted experiments with a 2D (two-dimensional) version of our Numerical Spectral Model that incorporates Hines' Doppler Spread Parameterization for small-scale gravity waves (GW). Solar cycle radiance variations (SCRV) are accounted for by changing the radiative heating rate on a logarithmic scale from 0.1 % at the surface to 1 % at 50 km to 10% at 100 km. With and without SCRV, but with the same GW flux, we then conduct numerical experiments to evaluate the magnitude of the SCAE in the zonal circulation. The numerical results indicate that, under certain conditions, the SCAE is significant and can extend to lower altitudes where the SCRV is inconsequential. At 20-km the differences in the modeled wind velocities are as large as 5 m/s. For a modeled QBO period of 30 months, we find that the seasonal cycle in the solar forcing (through the Semi-annual Oscillation (SAO)) acts as a strong pacemaker to lockup the phase and period of the QBO. The SCAE then shows up primarily as a distinct but relatively weak amplitude modulation. But with the QBO period between 30 and 34 (or less than 30, presumably) months, the seasonal phase lock is weak. Solar flux radiance variations in the seasonal cycle then cause variations in the QBO period and phase that amplify the SCAE to produce relatively large variations in the wind field. These variations also extend to mid latitudes.

Mayr, H. G.↗
DOE OSTI2016

Response to External Peer Review Team Report for Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada National Security Site, Nye County, Nevada, Revision 1

The Underground Test Area (UGTA) Corrective Action Unit (CAU) 97, Yucca Flat/Climax Mine (YF/CM), in the northeast part of the Nevada National Security Site (NNSS) requires environmental corrective action activities to assess contamination resulting from underground nuclear testing. These activities are necessary to comply with the UGTA corrective action strategy defined in Appendix VI, Revision No. 4, of the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended). The Phase I Flow and Transport Model Document for Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada National Security Site, Nye County, Nevada (N-I, 2013a) was developed and subjected to an external peer review as required by the corrective action investigation (CAI) stage of the UGTA strategy. The YF/CM Peer Review Committee (PRC) raised a number of questions and provided recommendations for supplemental analyses (in the External Peer Review Team Report for Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada National Security Site, Nye County, Nevada [N-I, 2015]). The purpose of this document is to provide responses to the PRC recommendations addressing the uncertainties identified by the PRC so that sufficient confidence in the contaminant boundary forecasts is established to advance to the Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) stage and initiate model evaluations. The PRC summarized their concerns and recommendations, and presented discussions of each of these uncertainties in their report (N-I, 2015). The U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) responses are summarized in Table ES-1.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1977

Development of low cost, high reliability sealing techniques for hybrid microcircuit packages, phase 2

Adhesives were evaluated to determine if they qualify for application to hybrid microcircuit packages. The effort consisted of the following: (1) seal gold-plated Kovar packages with selective adhesives and determine seal integrity after exposure to temperature humidity environments; (2) seal both gold-plated Kovar and ceramic packages with the four best adhesives identified in (1) and determine seal integrity after exposure to MIL-STD-883A test environments; and (3) subject the best adhesive identified in (2) to a 60 C/98% RH environment and determine susceptibility to moisture permeation. Test results are provided.

Perkins, K. L.↗
DOE OSTI2019

Effects of Co{sub 3}O{sub 4} Addition on Friction and Dry Sliding Wear Characteristics of 8 mol% Yttria-Stabilized Cubic Zirconia

The aim of the present study was to investigate the influence of Co{sub 3}O{sub 4} additive on the microstructure, wear, and tribological properties of 8 mol% yttria-stabilized cubic zirconia (8YSZ) using a pin-on-disk tribometer, surface profilometer, hardness tester, and a scanning electron microscopy system. Specimens were produced by doping 1-15 wt.% Co{sub 3}O{sub 4} in 8YSZ using a colloidal process, sintering at 1500 °C for 1 h, and subsequent annealing at 1500 °C for 10 and 50 h. Microstructural analysis showed that Co{sub 3}O{sub 4} dissolved partially in 8YSZ, with the undissolved Co{sub 3}O{sub 4} precipitating as a secondary phase at the grain boundaries. Further, the addition of Co{sub 3}O{sub 4} enhanced the grain size. Wear tests were carried out using an Al{sub 2}O{sub 3} ball as the counterface against ceramic disk under dry sliding friction conditions at room temperature (24 °C). The wear volume of 8YSZ decreased from 0.30 to 0.11 mm{sup 3} as a result of the addition of 15 wt.% Co{sub 3}O{sub 4}. Additionally, friction coefficient of the 8YSZ significantly reduced from 0.55 to 0.17 at the beginning stage of the sliding after the addition of 15 wt.% Co{sub 3}O{sub 4}. This was because Co{sub 3}O{sub 4} creates a thin lubricating layer on the friction surface. In addition, the undoped and Co{sub 3}O{sub 4}-doped 8YSZ specimens exhibited abrasive wear under the dry sliding friction conditions, owing to the formation and propagation of microcracks, which resulted in the removal of material from the surface. The specific wear rate of 8YSZ decreased with increasing the Co{sub 3}O{sub 4} content. Thus, the addition of Co{sub 3}O{sub 4} to 8YSZ improves its wear resistance and surface topography.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Pretreatments for the continuous production of pyrolytic sugar from lignocellulosic biomass

Fast pyrolysis of lignocellulosic biomass yields little sugar or anhydrosugars compared to pyrolysis of pure polysaccharides because naturally abundant alkali and alkaline earth metals (AAEM) in biomass catalyze the fragmentation of pyranose and furanose rings. Sugar yields can be increased dramatically by pretreating the biomass with sulfuric acid prior to pyrolysis, which passivates the catalytic activity of the metals by converting them into thermally stable salts. However, depolymerization of lignin in biomass also depends on the catalytic activity of AAEM. Thus, passivating AAEM has the unintended consequence of slowing the rate of depolymerization and volatilization of lignin, resulting in a transient melt phase that agglomerates and can foul pyrolysis reactors. Here, to overcome this problem, various non-alkali metal sulfates were tested as replacements for sulfuric acid. Iron in the form of ferrous sulfate proved the most effective in depolymerizing lignin without fragmenting pyranose rings. Conventional nitrogen-blown pyrolysis of ferrous sulfate pretreated corn stover achieved WHSV of 4 h –1 compared to only 0.6 h –1 for acid pretreated corn stover. Autothermal (air-blown) pyrolysis of ferrous sulfate pretreated corn stover showed even more dramatic improvement, increasing WHSV from 1 h –1 to 10 h –1 compared to acid pretreated corn stover under autothermal operation. Fermentable sugar yields from the pyrolysis of corn stover increased from 0.9 wt% to 11.8 wt% on a biomass basis, a 13-fold increase as a result of the ferrous sulfate pretreatment. These advantages combine to increase volumetric sugar productivity from 62 g L –1 h –1 for conventional pyrolysis of untreated corn stover to 2041 g L –1 h –1 for autothermal pyrolysis of ferrous sulfate treated corn stover.

09 BIOMASS FUELS↗
DOE OSTI2017

A power compensated differential scanning calorimeter for protein stability characterization

This study presented a power compensated MEMS differential scanning calorimeter (DSC) for protein stability characterization. In this microfabricated sensor, PDMS (Polydimethylsiloxane) and polyimide were used to construct the adiabatic chamber (1 μL) and temperature sensitive vanadium oxide was used as the thermistor material. A power compensation system was implemented to maintain the sample and reference at the same temperature. The resolution study and step response characterization indicated the high sensitivity (6 V/W) and low noise level (60 μk) of the device. The test with IgG1 antibody (mAb1) samples showed clear phase transitions and the data was confirmed to be reasonable by comparing it with the results of commercial DSC’s test. Finally, this device used ~1uL sample amount and could complete the scanning process in 4 min, significantly increasing the throughput of the bimolecular thermodynamics study like drug formulation process.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Wet-Etching of Acoustically Spalled GaAs for Substrate Reuse

Acoustic spalling is a promising technique for substrate reuse in the fabrication of gallium arsenide (GaAs) photovoltaic cells. However, the acoustic spalling process can leave the substrate with areas of rough surface morphology that can interfere with subsequent cell growth and processing. In this work, we investigate the use of wet etchants to smooth the surface of acoustically spalled GaAs substrates. We evaluated six different etchants. Of those tested, an 8:1:1 mixture of sulfuric acid, hydrogen peroxide, and water at 30 degrees C and a moderate stirring rate showed the greatest roughness reduction per mass loss while producing the desired morphology. This etchant was then applied to an acoustically spalled 2-inch GaAs wafer. A single-junction GaAs cell was then grown via metalorganic vapor-phase epitaxy on this substrate, an acoustic spalled substrate without a smoothing etch, and an epi-ready substrate. Use of the 8:1:1 H2SO4:H2O2:H2O etchant produced cells an average efficiency of 12.8% as compared to that of 2.0% grown on the unetched acoustically spalled substrate and 16.3% grown on the epi-ready substrate. The results of this work demonstrate that wet etching is a viable method for smoothing the surface of spalled GaAs substrates, paving the way for substrate reuse via acoustic spalling at efficiencies that approach growth on epi-ready substrates.

etching↗