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At least 1,531 records · Page 85

Fundamental Mechanisms of C-X bond Transformations on Complex Molten Surfaces

Investigations of fundamental and applied catalysis science began in 1989 with surface science studies of single crystal surfaces and moved into work understanding and measuring direct electronic excitations from chemisorption on metals as "hot electrons", to studies of C-H bond activation on metals. Later studies of metal oxide catalysts led to greater understanding C-X bond activation and transformation on complex surfaces including liquids. In addition to an improved fundamental understanding of important industrial reactions, a primary outcome of this work funded by the U.S. taxpayers has been the large number of graduate and undergraduate students and post-docs who have been educated in catalysis science and engineering with support from this program.

03 NATURAL GAS↗

Examining the Ice Nucleating Particles from Southern Great Plains Part II (ExINP-SGP). Field Campaign Report

Knowledge of airborne particulate matter (PM), especially the particles that have supermicron diameters, is key for understanding ice-nucleating particles (INPs). Supported by the Atmospheric Radiation Measurement (ARM) user facility, recent INP measurements at the Southern Great Plains observatory (SGP; 36'' 36' 18→ N, 97° 29' 6'' W) during multiple campaigns, such as SINCE-2014 (DeMott et al. 2015), Examining the Ice-Nucleating Particles from SGP (ExINP-2019; Hiranuma and Vepuri 2020), and Aerosol-Ice Formation Closure Pilot Study (AEROICESTUDY; Knopf et al. 2021a), strongly suggested the contribution of supermicron aerosol particles to observed INP abundance at SGP. However, verification of this hypothesis was hampered since additional offline laboratory analyses require sufficient amounts of collected airborne PM, which was lacking. Therefore, the principal investigators (PIs) conducted a field campaign, named ExINP-SGP II, to collect airborne PM at SGP for complementary laboratory characterization of the particles’ physicochemical properties (including ice nucleation properties). We used a passive particle sampler, which is a 4’ x 4’ x 2” (L x W x D) aluminum pan inside the 12”-high wooden windshield wall at the rooftop deck of the ARM Aerosol Observing System (AOS) trailer to collect dry PM deposits from January to April 2021. Figure 1 shows images of our experimental setup at the site. Additionally, we also collected surface soil near the ARM AOS trailer on 20 November 2020 (Figure 1b) to examine the ground soil dust particles (< 63 µm sieved) for their propensities to initiate immersion freezing compared to collected ambient PM. Surface soil and airborne samples were stored in the chemically inert container separately and kept in a dry, cool place until analyzed.

54 ENVIRONMENTAL SCIENCES↗

What's in a Test Site? Past & Future Lunar Analog Testing at the NNSS

Presentation for the Fall Meeting of Johns Hopkins' Lunar Surface Innovation Consortium (LSIC). Additional details at this link: https://lsic.jhuapl.edu/Events/Agenda/index.php?id=350 Nicholas Downs will be the presenter of these slides. Conference Location: University of Texas El Paso Conference Dates: 11/1/22-11/3/22

58 GEOSCIENCES↗

A Lizard-inspired Tube Inspector (LTI) Robot

This final report summarizes the research findings of the current project. This project is a collaboration between New Mexico State University (NMSU) as a lead (Recipient) and Arizona State University (ASU) as a Co-Recipient. Tubular structures are common components of boilers and heat exchangers in power plants. Over time, these components may suffer corrosion, cracks, and stress-corrosion cracks in either the body or the welded connections. A single tube leakage can cause an outage of several weeks. Regular inspection is a key safety factor when ensuring that power plants are maintained in reliable, operational condition. This inspection, however, is challenging, time-consuming, and in many cases impossible due to accessibility issues and safety concerns. Recent developments in robotic-based inspection can offer a great solution. Hard-to-reach places can be inspected without overhauling the unit, saving time and cost. Although several robots have been designed and implemented successfully for inspecting power plant components, in particular tubular structures, their mobility and flexibility are limited. Most of these robots use wheels for mobility which reduces their maneuverability of these robots. Moreover, they usually use magnets to attach to tubes which will not work on tubes with non-ferromagnetic materials. These robots usually carry measurement tools for a particular non-destructive testing (NDT) method such as ultrasound testing (UT) that requires a couplant to perform a point-by-point (scanning) inspection of the tubular structure. In this project, we developed a versatile lizard-inspired tube inspector (LTI) robot with embedded inspection sensing components for tube inspection which removes the need for point-by-point scanning of tube surface for crack and corrosion detection. Inspired by a “lizard”, the novelty of the current project is the integration of couplant-free ultrasound sensing and transmission, advanced data-driven defect detection and imaging, and friction-based mechanical mobility components in a single robot to eliminate a need for smooth surfaces and simple geometry for mobility and scanning. The LTI robot could replace the wheel-based approach with friction-based mobility to significantly increase the flexibility and maneuverability of the robot. The LTI robot can get into a power plant unit, such as a boiler, from a small area allowing it to access a component of interest for inspection (e.g., move on OD, curved and flat surfaces, non-ferromagnetic or ferromagnetic materials, and tubes with rough surfaces and complex geometries). Additionally, an advanced data-driven method using ultrasound data was pioneered to allow the robot to detect defects in the entire area between the robot’s multi-functional mobility system (grippers). Integrating a couplant-free ultrasound sensing in the robot’s grippers as well as using advanced data-driven methods allowed the LTI to detect defects in the entire cross-section of a tube using its grippers when stationary and when mobile.

20 FOSSIL-FUELED POWER PLANTS↗

UNESE Phase 2: Injection and measurement of gaseous tracers at U-12p Tunnel

In June 2018 radioactive ( 37 Ar and 127 Xe) and stable (SF 6 ) tracers were injected into the chimney of the Disko Elm underground nuclear explosion, located in the U-12p tunnel complex. After the injection sampling was performed from locations within the tunnel, a borehole drilled from the surface, and from the surface of the mesa. Additionally, the 127 Xe activity within the chimney was continuously monitored for two months after the injection. While none of the injected radiotracers were detected in the monitoring borehole, elevated levels of 39 Ar (an activation product produced by underground nuclear explosions) were detected and quantified in each sample.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Vind: A Blockchain-Enabled Supply Chain Provenance Framework for Energy Delivery Systems

Enterprise-level energy delivery systems (EDSs) depend on different software or hardware vendors to achieve operational efficiency. Critical components of these systems are typically manufactured and integrated by overseas suppliers, which expands the attack surface to adversaries with additional opportunities to infiltrate into EDSs. Due to this reason, the risk management of the EDS supply chain is crucial to ensure that we are knowledgeable about the vulnerabilities in software and hardware components that comprise any critical part, quantifiable risk metrics to assess the severity and exploitability of the attack, and provide remediation solutions that can influence a prioritized mitigation plan. There is a need to realize cyber supply chain risk management for industrial control systems’ hardware, software, and computing and networking services associated with bulk electric system (BES) operations. This article proposes a blockchain-based cyber supply chain provenance platform (“Vind”) for EDSs to realize data provenance in a cyber supply chain ecosystem.

Bandara, Eranga↗

Optimization of La 2–x Sr x CuO 4 Single Crystal Film Growth via Molecular Beam Epitaxy

Atomic layer-by-layer molecular beam epitaxy (ALL-MBE) combined with ozone is one of the best methods to fabricate single-crystal thin films of complex oxides. Cuprate such as La 2-x Sr x CuO 4 (LSCO) is a representative complex-oxide high-temperature superconductor (HTS) material. Our group utilizes this method to produce high-quality single-crystal HTS films with atomically smooth surfaces and interfaces. In addition, ALL-MBE enables us to engineer multilayer heterostructures with atomic precision. This allows the fabrication of tunnel junctions, various nanostructures, and other HTS devices of interest for superconducting electronics. We have synthesized over three thousand LSCO thin films in the past two decades. These films’ structural and electronic properties have been studied and characterized by various methods. Here, we distill the extensive experience we accumulated into a step-by-step protocol to fabricate atomically perfect LSCO films. The recipe includes substrate preparation, ozone generation and distillation, source calibration, the in situ monitoring of the film synthesis, post-growth annealing, and ex situ characterization. It discloses a reproducible way to fabricate single-crystal LSCO films for basic research and HTS electronic applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Cloud Atlas: Hubble Space Telescope Near-infrared Spectral Library of Brown Dwarfs, Planetary-mass Companions, and Hot Jupiters

Bayesian atmospheric retrieval tools can place constraints on the properties of brown dwarfs' and hot Jupiters' atmospheres. To fully exploit these methods, high signal-to-noise spectral libraries with well-understood uncertainties are essential. We present a high signal-to-noise spectral library (1.10–1.69 μm) of the thermal emission of 76 brown dwarfs and hot Jupiters. All our spectra have been acquired with the Hubble Space Telescope’s Wide Field Camera 3 instrument and its G141 grism. The near-infrared spectral types of these objects range from L4 to Y1. Eight of our targets have estimated masses below the deuterium-burning limit. We analyze the database to identify peculiar objects and/or multiple systems, concluding that this sample includes two very-low-surface-gravity objects and five intermediate-surface-gravity objects. In addition, spectral indices designed to search for composite-atmosphere brown dwarfs indicate that eight objects in our sample are strong candidates to have such atmospheres. None of these objects are overluminous, so their composite atmospheres are unlikely to be companion-induced artifacts. Five of the eight confirmed candidates have been reported as photometrically variable, suggesting that composite atmospheric indices are useful in identifying brown dwarfs with strongly heterogeneous cloud covers. We compare hot Jupiters and brown dwarfs in a near-infrared color–magnitude diagram. We confirm that the coldest hot Jupiters in our sample have spectra similar to mid-L dwarfs, and the hottest hot Jupiters have spectra similar to those of M-dwarfs. Our sample provides a uniform data set of a broad range of ultracool atmospheres, allowing large-scale comparative studies and providing an HST legacy spectral library.

79 ASTRONOMY AND ASTROPHYSICS↗

Hemispherically symmetric strategies for stratospheric aerosol injection

Stratospheric aerosol injection (SAI) comes with a wide range of possible design choices, such as the location and timing of the injection. Different stratospheric aerosol injection strategies can yield different climate responses; therefore, understanding the range of possible climate outcomes is crucial to making informed future decisions on SAI, along with the consideration of other factors. Yet, to date, there has been no systematic exploration of a broad range of SAI strategies. This limits the ability to determine which effects are robust across different strategies and which depend on specific injection choices. This study systematically explores how the choice of SAI strategy affects climate responses in one climate model. Here, we introduce four hemispherically symmetric injection strategies, all of which are designed to maintain the same global mean surface temperature: an annual injection at the Equator (EQ), an annual injection of equal amounts of SO 2 at 15° N and 15° S (15N+15S), an annual injection of equal amounts of SO 2 at 30° N and 30° S (30N+30S), and a polar injection strategy that injects equal amounts of SO 2 at 60° N and 60° S only during spring in each hemisphere (60N+60S). We compare these four hemispherically symmetric SAI strategies with a more complex injection strategy that injects different quantities of SO 2 at 30° N, 15° N, 15° S, and 30° S in order to maintain not only the global mean surface temperature but also its large-scale horizontal gradients. All five strategies are simulated using version 2 of the Community Earth System Model with the middle atmosphere version of the Whole Atmosphere Community Climate model, version 6, as the atmospheric component, CESM2(WACCM6-MA), with the global warming scenario, Shared Socioeconomic Pathway (SSP)2-4.5. We find that the choice of SAI strategy affects the spatial distribution of aerosol optical depths, injection efficiency, and various surface climate responses. In addition, injecting in the subtropics produces more global cooling per unit injection, with the EQ and the 60N+60S cases requiring, respectively, 59 % and 50 % more injection than the 30N+30S case to meet the same global mean temperature target. Injecting at higher latitudes results in larger Equator-to-pole temperature gradients. While all five strategies restore Arctic September sea ice, the high-latitude injection strategy is more effective due to the SAI-induced cooling occurring preferentially at higher latitudes. These results suggest trade-offs wherein different strategies appear better or worse, depending on which metrics are deemed important.

54 ENVIRONMENTAL SCIENCES↗

A strainmeter array as the fulcrum of novel observatory sites along the Alto Tiberina Near Fault Observatory

Fault slip is a complex natural phenomenon involving multiple spatiotemporal scales from seconds to days to weeks. To understand the physical and chemical processes responsible for the full fault slip spectrum, a multidisciplinary approach is highly recommended. The Near Fault Observatories (NFOs) aim at providing high-precision and spatiotemporally dense multidisciplinary near-fault data, enabling the generation of new original observations and innovative scientific products. The Alto Tiberina Near Fault Observatory is a permanent monitoring infrastructure established around the Alto Tiberina fault (ATF), a 60 km long low-angle normal fault (mean dip 20°), located along a sector of the Northern Apennines (central Italy) undergoing an extension at a rate of about 3 mm yr –1 . The presence of repeating earthquakes on the ATF and a steep gradient in crustal velocities measured across the ATF by GNSS stations suggest large and deep (5–12 km) portions of the ATF undergoing aseismic creep. Both laboratory and theoretical studies indicate that any given patch of a fault can creep, nucleate slow earthquakes, and host large earthquakes, as also documented in nature for certain ruptures (e.g., Iquique in 2014, Tōhoku in 2011, and Parkfield in 2004). Nonetheless, how a fault patch switches from one mode of slip to another, as well as the interaction between creep, slow slip, and regular earthquakes, is still poorly documented by near-field observation. With the strainmeter array along the Alto Tiberina fault system (STAR) project, we build a series of six geophysical observatory sites consisting of 80–160 m deep vertical boreholes instrumented with strainmeters and seismometers as well as meteorological and GNSS antennas and additional seismometers at the surface. By covering the portions of the ATF that exhibits repeated earthquakes at shallow depth (above 4 km) with these new observatory sites, we aim to collect unique open-access data to answer fundamental questions about the relationship between creep, slow slip, dynamic earthquake rupture, and tectonic faulting.

58 GEOSCIENCES↗

Large-eddy simulation of an atmospheric bore and associated gravity wave effects on wind farm performance in the southern Great Plains

Gravity waves are a common occurrence in the atmosphere, with a variety of generation mechanisms. Their impact on wind farms has only recently gained attention, with most studies focused on wind farm-induced gravity waves. In this study, the interaction between a wind farm and gravity waves generated by an atmospheric bore event is assessed using multiscale large-eddy simulations. The atmospheric bore is created by a thunderstorm downdraft from a nocturnal mesoscale convective system (MCS). The associated gravity waves impact the wind resource and power production at a nearby wind farm during the American Wake Experiment (AWAKEN) in the US southern Great Plains. A two-domain nested setup (Δx=300 and 20 m) is used in the Weather Research and Forecasting (WRF) model, forced with data from the High-Resolution Rapid Refresh model, to capture both the formation of the bore and its interaction with individual wind turbines. The MCS is resolved on the large outer domain, where the structure of the bore and the associated gravity waves are found to be especially sensitive to parameterized microphysics processes. On the finer inner domain, gravity wave interactions with individual wind turbines are resolved; wake dynamics are captured using a generalized actuator disk parameterization in WRF. The gravity waves are found to have a strong effect on the atmosphere above the wind farm; however, the effect of the waves is more nuanced closer to the surface where there is additional turbulence, both ambient and wake-generated. Notably, the gravity waves modulate the mesoscale environment by weakening and dissipating the preexisting low-level jet, which reduces hub-height wind speed and hence the simulated power output, which is confirmed by the observed supervisory control and data acquisition (SCADA) power data. Additionally, the gravity waves induce local wind direction variations correlated with fluctuations in pressure, which lead to fluctuations in the simulated power output as various turbines within the farm are subjected to waking from nearby turbines.

17 WIND ENERGY↗

Cold-air aerodynamic study in a two-dimensional cascade of a turbine stator blade with suction-surface film cooling

The effect on aerodynamic performance of a single row of spanwise-spaced coolant holes located at four positions chordwise along the suction surface was investigated. In addition, multiple-row data were obtained. The data are presented in terms of primary efficiency, coolant-to-primary-flow percentage, and coolant pressure ratio. Primary efficiencies of multirow blade configurations compare satisfactorily with that calculated from the single-row efficiency increments. At any given coolant flow percentage, the efficiency was about the same for all row locations. For a given coolant pressure, the efficiency varied by as much as 1 percent, depending on the row location.

Brown, D. B.↗

Synthetic sea water - An improved stress corrosion test medium for aluminum alloys

A major problem in evaluating the stress corrosion cracking resistance of aluminum alloys by alternate immersion in 3.5 percent salt (NaCl) water is excessive pitting corrosion. Several methods were examined to eliminate this problem and to find an improved accelerated test medium. These included the addition of chromate inhibitors, surface treatment of specimens, and immersion in synthetic sea water. The results indicate that alternate immersion in synthetic sea water is a very promising stress corrosion test medium. Neither chromate inhibitors nor surface treatment (anodize and alodine) of the aluminum specimens improved the performance of alternate immersion in 3.5 percent salt water sufficiently to be classified as an effective stress corrosion test method.

Humphries, T. S.↗

Development and application of ride-quality criteria

Ride quality vibration criteria applicable to the design and evaluation of air and surface transportation systems are described. Consideration is given to the magnitude of vehicle vibration experienced by the passenger, the frequency of vibration, the direction of vibration measurements are presented for a variety of air and surface transportation systems. In addition, simulator data on seat dynamics and passenger response are presented. Results suggest the relative merits of various physical descriptors and measurement locations for characterizing the vibration in terms suitable for the design and/or evaluation of transportation systems.

Stephens, D. G.↗

Detailed transonic flow field measurements about a supercritical airfoil section

The transonic flow field about a Whitcomb-type supercritical airfoil profile was measured in detail. In addition to the usual surface pressure distributions and wake surveys, schlieren photographs were taken and velocity vector profiles were determined in the upper surface boundary layer and in the near wake. Spanwise variations in the measured pressures were also determined. The data are analyzed with the aid of an inviscid transonic finite-difference computer program as well as with boundary layer modeling and calculation schemes.

Hurley, F. X.↗

Development and application of ride-quality criteria

A program for the development of ride-quality vibration criteria applicable to the design and evaluation of air and surface transportation systems is described. Consideration is given to the magnitude of vehicle vibration experienced by the passenger, the frequency of vibration, the direction of vibration, and the influence of seat dynamics on passenger response. Comparative vibration measurements are presented for a variety of air and surface transportation systems. In addition, simulator data on seat dynamics and passenger response are presented. Results suggest the relative merits of various physical descriptors and measurement locations for characterizing the vibration in terms suitable for the design and/or evaluation of transportation systems.

Stephens, D. G.↗

Effect of empennage interference on single-engine afterbody/nozzle drag

An investigation has been conducted in the Langley 16-foot transonic tunnel to determine the effects of empennage surfaces on single-engine afterbody and nozzle drag at Mach numbers up to 1.20. Empennage interference drag was obtained by using experimental values of afterbody/nozzle drag and theoretical values of empennage drag. Three methods for minimizing adverse empennage interference effects were investigated. Results show that empennage interference effects were always detrimental but could be reduced by proper location of tail surfaces. Afterbody contouring and addition of 'contour' bumps were generally ineffective in reducing aft-end drag for Mach numbers less than 0.95.

Berrier, B. L.↗

On the habitability of Mars: An approach to planetary ecosynthesis

The possibility of utilizing Mars as a habitat for terrestrial life, including man, is examined. Available data, assumptions, and speculations on the climate, physical state, and chemical inventory of Mars are reviewed and compared with the known requirements and environmental limits of terrestrial life. No fundamental, insuperable limitation of the ability of Mars to support a terrestrial ecology is identified. The lack of an oxygen-containing atmosphere would prevent the unaided habitation of Mars by man. The present strong ultraviolet surface irradiation is an additional major barrier. The creation of an adequate oxygen and ozone-containing atmosphere on Mars may be feasible through the use of photosynthetic organisms. The time needed to generate such an atmosphere, however, might be several millions of years. This period might be drastically reduced by the synthesis of novel, Mars-adapted, oxygen producing photosynthetic strains by techniques of genetic engineering, and modifying the present Martian climate by melting of the Martian polar caps and concomitant advective and greenhouse heating effects.

Averner, M. M.↗