Investigation of collision probability of electrons and ions with alkali metal atoms semiannual report, oct. 22, 1964 - may 11, 1965
Electron-cesium atom collision and cesium ion-atom collision cross sections
SCATTERING CROSS SECTION↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Calculation of photoionization cross sections of nitrogen and oxygen atoms and their ions in excited states
Calculation of photoionization cross sections of nitrogen and oxygen atoms and ions in excited states using quantum defect method
Nikolayev, V. M.↗
Energy, angle, and temperature dependencies of the sticking of D atoms on Li surfaces
Detailed experimental and computational information on the response of lithium surfaces to irradiation by slow hydrogenic particles (ions, atoms, molecules) is sparse and mainly speculative. In this work, we present a computational study of the reflection and retention of deuterium (D) atoms at crystalline and amorphous lithium surfaces at 300 and 500 K, where the D atoms have an impact energy in the range of 0.025–5 eV and incident angles of 0° (perpendicular incidence) or 85° (near-grazing incidence). Classical molecular dynamics simulations are performed with the reactive bond-order force field (ReaxFF) potentials. This study provides quantitative information on the deuterium sticking probability and recycling coefficient for lithium surfaces. Further, our results support the ongoing work at the Lithium Tokamak eXperiment-β fusion experiment as well as relevant experiments in the laboratory setting.
74 ATOMIC AND MOLECULAR PHYSICS↗
Quantum simulation of conical intersections using trapped ions
Conical intersections often control the reaction products of photochemical processes and occur when two electronic potential energy surfaces intersect. Theory predicts that the conical intersection will result in a geometric phase for a wavepacket on the ground potential energy surface, and although conical intersections have been observed experimentally, the geometric phase has not been directly observed in a molecular system. Herein we use a trapped atomic ion system to perform a quantum simulation of a conical intersection. The ion’s internal state serves as the electronic state, and the motion of the atomic nuclei is encoded into the motion of the ions. The simulated electronic potential is constructed by applying state-dependent optical forces to the ion. We experimentally observe a clear manifestation of the geometric phase using adiabatic state preparation followed by motional state measurement. Our experiment shows the advantage of combining spin and motion degrees for quantum simulation of chemical reactions.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Limits on the extent of Saturn's hydrogen cloud
The 30-day reports from the Voyager Ultraviolet Spectrometer team characterize the atomic hydrogen observed near Saturn as a torus with a half width of 7 Saturnian radii. The atomic processes occurring in the inner magnetosphere are modelled, including sputtering, ionization, charge exchange, ion-atom interchange, recombination, and transport, and a neutral hydrogen source is added to test the proposal that a hydrogen cloud exists in this region. Plasma observations in the inner magnetosphere are found to be inconsistent with the presence of a dense atomic hydrogen cloud. Thus, it is concluded that the hydrogen cloud must be a torus as originally reported, and that the cloud does not extend inward to the orbits of the inner satellites of Saturn.
Richardson, John D.↗
Analytical ionization cross sections for atomic collisions
General analytical expressions for cross sections for direct ionization in atom-atom collisions are evaluated using the classical impulse approximation. The approach is also applied to ion-atom and molecule-molecule interactions. The overall accuracy of the obtained cross sections in a broad range of energy is better, when compared with existing measurements for many collision systems, than accuracy of other analytical predictions available in literature.
Kunc, J. A.↗
Dynamics Of Ions In A Radio-Frequency Quadrupole Trap
Report describes computer-simulation study of motions of various numbers of ions in Paul trap. Study part of continuing effort to understand motions of trapped charged particles (atoms, ions, molecules, or dust particles). Motions characterized in terms of heating by radio-frequency fields, formation of crystallike structures in cold clouds of trapped particles, and other phenomena important in operation of radio-frequency traps in frequency standards.
Prestage, John D.↗
Ion-Molecule Chemistry in Titan's Ionosphere
We present a summary of the information available from laboratory studies of ion-molecule reactions that is relevant to the chemistry occuring in Titan's ionopshere. Reaction information from the literature has been collated and we have measured many new reations, including some ion-atom reactions.
planetary atmospheres Titan ion molecule ionospher↗
An experimental and theoretical study of the mean diurnal variation of O/+/, NO/+/, O2/+/, and N2/+/ ions in the mid-latitude F1 layer of the ionosphere
A theoretical model of the diurnal variations in the compositions of the ions O(+), NO(+), O2(+) and N2(+) in the midlatitude F1 layer is presented and compared with measurements made by AE-C. The theoretical model includes the rate coefficients and branching ratios for the dissociative recombination of NO(+), O2(+) and N2(+) with electrons and the ion-atom interchanges of O(+) with N2 and N2(+) with O. Input parameters to the model comprise measurements of ion and electron temperatures, neutral atmosphere composition, the solar EUV flux and the photoelectron spectrum. In general, model calculations are found to agree with satellite measurements, confirming the major ion sources and sinks of the photochemical model, which has an accuracy of + or - 60%.
Torr, D. G.↗
The Deep Space Atomic Clock Mission
The Deep Space Atomic Clock (DSAC) mission will demonstrate the space flight performance of a small, low-mass, high-stability mercury-ion atomic clock with long term stability and accuracy on par with that of the Deep Space Network. The timing stability introduced by DSAC allows for a 1-Way radiometric tracking paradigm for deep space navigation, with benefits including increased tracking via utilization of the DSN's Multiple Spacecraft Per Aperture (MSPA) capability and full ground station-spacecraft view periods, more accurate radio occultation signals, decreased single-frequency measurement noise, and the possibility for fully autonomous on-board navigation. Specific examples of navigation and radio science benefits to deep space missions are highlighted through simulations of Mars orbiter and Europa flyby missions. Additionally, this paper provides an overview of the mercury-ion trap technology behind DSAC, details of and options for the upcoming 2015/2016 space demonstration, and expected on-orbit clock performance.
autonomy↗
Deep Space Atomic Clock Technology Demonstration Mission Results
The Deep Space Atomic Clock (DSAC), a NASA Technology Demonstration Mission, was launched into low-Earth orbit on June 25, 2019 as a hosted payload aboard General Atomics’ Orbital Test Bed (OTB) spacecraft. The DSAC mission has been conducting a two-year demonstration of a mercury ion atomic clock to characterize its space-based performance and to validate its utility for deep space navigation and radio science. Analysis of the collected data using JPL’s GIPSY-OASIS software has shown DSAC’s AD at one-day to be near 310-15; much better than required AD of 210-14. Such low spacecraft clock errors will enable one-way radiometric tracking data with precision equivalent to or better than current-day two way tracking data, allowing a shift to a more efficient and flexible one-way deep space navigation architecture. To verify this, an analog deep space navigation experiment was performed using JPL’s operational navigation software (Monte). The experiment recovered orbit solutions with reduced data sets and geometric variations that are more representative of deep space missions, and showed that orbit determination using DSAC derived data is on par with more traditional two-way datatypes. As a technology demonstrator, DSAC’s development focus has been on maturing the mercury ion trap clock technology rather than achieving the smallest size, weight, and power (SWaP). Over the course of DSAC’s development the project has identified numerous improvements that could be made to significantly reduce SWaP for DSAC’s next version. Indeed, DSAC-2 was recently selected by NASA for further demonstration on the VERITAS mission to Venus. This work will review the DSAC technology, mission, and results from its two-year mission.
Wang, Rabi↗
On charge exchange and knock-on processes in the exosphere of Io
One direct consequence of magnetospheric interaction of Io is the strong dynamical coupling of its neutral atmosphere with the corotating plasma. The absorption of the thermal ions and the associated neutral injection is an improtant issue not yet explored. As far as nonthermal escape of the neutral atmosphere is concerned, three processes stand out. That is, apart from sputtering, exospheric interactions like atom-ion knock-on collision and charge exchange recombination could be a significant source of the neutral clouds in the Jovian system. Using a current electrodynamic model of Io, both the absorption rate of the corotating thermal plasma and the production rates of new exospheric ions and the fast neutrals are considered. It is found that the source strength of the neutral atoms and molecules with speeds of about 100 km/sec could amount to 10 to the 26th/sec whereas exospheric neutrals emitted at lower speed (of about 10 km/sec) amounts to 4 x 10 to the 25th/sec. The generation of the new ions in connection with the streaming of the magnetospheric plasma around Io could also produce an asymmetric sputtering with a neutral flux of about 10 to the 27th/sec emitted from the region of Io which faces Jupiter. These results may be related to a number of sodium observations.
Ip, W.-H.↗
Testing the Gravitational Redshift With an Inner Solar System Probe: the Veritas Case
The NASA Discovery-class mission VERITAS, selected in June 2021, will be launched towards Venus after 2027. In addition to the science instrumentation that will build global foundational geophysical datasets, VERITAS proposed to conduct a technology demonstration for the Deep Space Atomic Clock (DSAC-2). A first DSAC successfully operated in low-Earth orbit for more than two years, demonstrated the trapped ion atomic clock technology, and established a new level of performance for clocks in space. DSAC-2 would have further improvements in size, power, and performance. It would host a 1× 10 -13 grade USO to produce a frequency output with short-term stability of less than 2× 10 -13 /√ τ (where τ is the averaging time).However, due to funding shortfalls, DSAC-2, had to be canceled. The initially foreseen presence of an atomic clock on board the probe, however, raised the question whether this kind of instrumentation could be useful not only for navigation and time transfer but also for fundamental physics tests. In this work, we consider the DSAC-2 atomic clock and VERITAS mission as a specific example to measure possible discrepancies in the redshift predicted by General Relativity by using an atomic clock onboard an interplanetary spacecraft. In particular we investigate the possibility of measuring possible violations of the Local Lorentz Invariance and Local Position Invariance principles. We perform accurate simulations of the experiment during the VERITAS cruise phase. We consider different parametrizations of the possible violations of the General Relativity, different operational conditions, and several different assumptions on the expected measurement performance. We show that DSAC-2 onboard VERITAS would provide new and improved constraints with respect to the current knowledge. Our analysis shows the scientific value of atomic clocks like DSAC-2 hosted onboard interplanetary spacecraft.
Fabrizio De Marchi↗
Electron-ion coincidence measurements of molecular dynamics with intense X-ray pulses
Molecules can sequentially absorb multiple photons when irradiated by an intense X-ray pulse from a free-electron laser. If the time delay between two photoabsorption events can be determined, this enables pump-probe experiments with a single X-ray pulse, where the absorption of the first photon induces electronic and nuclear dynamics that are probed by the absorption of the second photon. Here we show a realization of such a single-pulse X-ray pump-probe scheme on N 2 molecules, using the X-ray induced dissociation process as an internal clock that is read out via coincident detection of photoelectrons and fragment ions. By coincidence analysis of the kinetic energies of the ionic fragments and photoelectrons, the transition from a bound molecular dication to two isolated atomic ions is observed through the energy shift of the inner-shell electrons. Via ab-initio simulations, we are able to map characteristic features in the kinetic energy release and photoelectron spectrum to specific delay times between photoabsorptions. In contrast to previous studies where nuclear motions were typically revealed by measuring ion kinetics, our work shows that inner-shell photoelectron energies can also be sensitive probes of nuclear dynamics, which adds one more dimension to the study of light-matter interactions with X-ray pulses.
74 ATOMIC AND MOLECULAR PHYSICS↗
Fluid and hybrid simulations of the ionization instabilities in Hall thruster
Low-frequency axial oscillations in the range of 5–50 kHz stand out as a pervasive feature observed in many types of Hall thrusters. While it is widely recognized that the ionization effects play the central role in this mode, as manifested via the large-scale oscillations of neutral and plasma density, the exact mechanism(s) of the instabilities remain unclear. To gain further insight into the physics of the breathing mode and evaluate the role of kinetic effects, a one-dimensional time-dependent full nonlinear low-frequency model describing neutral atoms, ions, and electrons is developed in full fluid formulation and compared to the hybrid model in which the ions and neutrals are kinetic. Both models are quasi-neutral and share the same electron fluid equations that include the electron diffusion, mobility across the magnetic field, and the electron energy evolution. The ionization models are also similar in both approaches. Further, the predictions of fluid and hybrid simulations are compared for different test cases. Two main regimes are identified in both models: one with pure low-frequency behavior and the other one, where the low-frequency oscillations coexist with high-frequency oscillations in the range of 100–200 kHz, with the characteristic time scale of the ion channel fly-by time, 100–200 kHz. The other test case demonstrates the effect of a finite temperature of injected neutral atoms, which has a substantial suppression effect on the oscillation amplitude.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Recent Advances in Nonclassical Crystallization: Fundamentals, Applications, and Challenges
We report crystals are ubiquitous and play an important role in our daily life. Recent studies on properties and formation of crystals have proven the attachment of particle ranging from ion pairs to well-crystallized nanocrystal is one of the most important ways for crystallization. Compared with the monomer-by-monomer (i.e., atoms, ions, or molecules) addition described in longstanding classical theories, so-called nonclassical crystallization pathways are more complex as the non-specific interaction of variation in system free energy and reaction kinetics. In view of the detailed insights into nonclassical crystallization pathways has broadened the scope of research across various disciplines such as geological events, biomineralization mechanisms, environmental remediation, and the development of functional materials, this paper reviews the current state of the art in nonclassical nucleation (the prenucleation clusters pathway, aggregation pathway, etc.) and growth pathways (oriented attachment and random attachment) based on several spotlights. In addition, the observed specific phenomena on crystallization in the last 10 years as well as recent advancements and achievements made on the synthesis of mesocrystals are also elucidated. With implications and perspectives of nonclassical crystallization researches proposed in this paper, this review aims to summarize research advancement regarding crystallizing systems. Emphasis will be placed on novel insights into nonclassical crystallization of materials, which are expected to provide completely new perspectives on the underlying crystallization mechanisms.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Extended linear ion trap frequency standard apparatus
A linear ion trap for frequency standard applications is provided with a plurality of trapping rods equally spaced and applied quadruple rf voltages for radial confinement of atomic ions and biased level pins at each end for axial confinement of the ions. The trapping rods are divided into two linear ion trap regions by a gap in each rod in a common radial plane to provide dc discontinuity, thus dc isolating one region from the other. A first region for ion-loading and preparation fluorescence is biased with a dc voltage to transport ions into a second region for resonance frequency comparison with a local oscillator derived frequency while the second region is held at zero voltage. The dc bias voltage of the regions is reversed for transporting the ions back into the first region for fluorescence measurement. The dual mode cycle is repeated continuously for comparison and feedback control of the local oscillator derived frequency. Only the second region requires magnetic shielding for the resonance function which is sensitive to any ambient magnetic fields.
Prestage, John D.↗
New ion trap for atomic frequency standard applications
A novel linear ion trap that permits storage of a large number of ions with reduced susceptibility to the second-order Doppler effect caused by the radio frequency (RF) confining fields has been designed and built. This new trap should store about 20 times the number of ions a conventional RF trap stores with no corresponding increase in second-order Doppler shift from the confining field. In addition, the sensitivity of this shift to trapping parameters, i.e., RF voltage, RF frequency, and trap size, is greatly reduced.
Prestage, J. D.↗