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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

Experimental Setup for the Laboratory Investigation of Micrometeoroid Ablation Using a Dust Accelerator

A facility has been developed to simulate the ablation of micrometeoroids in laboratory conditions. An electrostatic dust accelerator is used to generate iron particles with velocities of 10-70 kilometers. The particles are then introduced into a chamber pressurized with a target gas, where the pressure is adjustable between 0.01 and 0.5 Torr, and the particle partially or completely ablates over a short distance. An array of biased electrodes above and below the ablation path is used to collect the generated ions/electrons with a spatial resolution of 2.6 centimeters along the ablating particles path, thus allowing the study of the spatiotemporal evolution of the process. For completely ablated particles, the total collected charge directly yields the ionization coefficient of a given dust material-target gas combination. The first results of this facility measured the ionization coefficient of iron atoms with N2, air, CO2, and He target gases for impact velocities greater than 20 kilometers per second, and are reported by Thomas et al. The ablation chamber is also equipped with four optical ports that allow for the detection of the light emitted by the ablating particle. A multichannel photomultiplier tube system is used to observe the ablation process with a spatial and temporal resolution of 0.64 centimeters and 90 nanoseconds. The preliminary results indicate that it is possible to calculate the velocity of the ablating particle from the optical observations, and in conjunction with the spatially resolved charge measurements allow for experimental validation of ablation models in future studies.

Thomas, Evan↗
NASA NTRS1982

Atomization and combustion properties of flashing injectors

Flashing injection involves expanding a fluid through an injector until a supersaturated state is reached, causing a portion of the fluid to flash to a vapor. This investigation considered the flow, atomization and spreading properties of flashing injectors flowing liquids containing dissolved gases (Jet A/air) as well as superheated liquids (Freon 11). The use of a two stage expansion process, separated by an expansion chamber, was found to be beneficial for good atomization properties of flashing injection - particularly for dissolved gas systems. Both locally homogeneous and separated flow models provided good predictions of injector flow properties. Conventional correlations for drop sizes from pressure atomized and airblast injectors were successfully modified, using the separated flow model to prescribe injector exit conditions, to correlate drop size measurements. Additional experimental results are provided for spray angle and combustion properties of sprays from flashing injectors.

Solomon, A. S. P.↗
DOE OSTI2023

Imaging Strain-Localized Single-Photon Emitters in Layered GaSe below the Diffraction Limit

Nanoscale strain control of exciton funneling is an increasingly critical tool for the scalable production of single photon emitters (SPEs) in two-dimensional materials. However, conventional far-field optical microscopies remain constrained in spatial resolution by the diffraction limit and thus can provide only a limited description of nanoscale strain localization of SPEs. Here, we quantify the effects of nanoscale heterogeneous strain on the energy and brightness of GaSe SPEs on nanopillars with correlative cathodoluminescence, photoluminescence, and atomic force microscopy, supported by density functional theory simulations. We report the strain-localized SPEs have a broad range of emission wavelengths from 620 to 900 nm. We reveal substantial strain-controlled SPE wavelength tunability over a ~100 nm spectral range and 2 orders of magnitude enhancement in the SPE brightness at the pillar center due to Type-I exciton funneling. In addition, we show that radiative biexciton cascade processes contribute to observed CL photon superbunching. Also, the GaSe SPEs show excellent stability, where their properties remain unchanged after electron beam exposure. Importantly, we anticipate that this comprehensive study on the nanoscale strain control of two-dimensional SPEs will provide key insights to guide the development of truly deterministic quantum photonics.

2D materials↗
NASA NTRS2018

GMI-IPS: Processing & Visualization Software Used in ATom DC-8 Aircraft Studies

NASA's Atmospheric Tomography Mission (ATom) deployed in each of the four seasons during 2016-2018, the DC-8 aircraft in order to establish global-scale datasets intended to improve the representation of chemically reactive gases in global atmospheric chemistry models (ACMs). The Global Modeling Initiative (GMI) executed simulations for each ATom flight using the GMI Chemistry Transport Model (GMI-CTM) to provide species concentrations of chemical gases along the DC-8 flight transects. To solve the problem of translating the GMI-CTM simulation data to the unique spatial resolutions of each ATom flight, the GMI ICARTT Processing Software (GMI-IPS) was developed.The GMI-IPS is written in Python and provides data processing, flight extraction, and visualization support for aircraft research projects using ICARTT format, which is a standard format for airborne instrument data. Additionally, the GMI-IPS interpolates global gridded model data from Hierarchical Data Format (HDF) to ICARTT compatible flight transects. Software classes for instruments and collections provided by the ATom DC-8 aircraft such as MER10, MMS, etc. are derived from a common base class. Other functionality provided by the GMI-IPS are: deriving missing flight entries along a transect, reading ICARTT entries from file, and providing Python data structures for storing flight and model information, and more.The GMI-IPS is GIT source controlled, has approximately 30,000 lines of code, and supports parallelization across data collections. It delivered GMI-CTM data for more than forty distinct DC-8 aircraft flights that took place under ATom. The output ICARTT files adhere to format standard V1.1, and pass the scan utility provided by NASA LaRC Airborne Science Data for Atmospheric Composition. This presentation will include a software and methods overview, and results from ATom, including assessments using the GMI-CTM showing how well observations from ATom flight transects represent a broader region.

Damon, M. R.↗
NASA NTRS1971

An investigation of the normal momentum transfer for gases on tungsten

The near monoenergetic beam of neutral helium and argon atoms impinged on a single crystal tungsten target, with the (100) face exposed to the beam. The target was mounted on a torsion balance. The rotation of this torsion balance was monitored by an optical lever, and this reading was converted to a measurement of the momentum exchange between the beam and the target. The tungsten target was flashed to a temperature in excess of 2000 C before every clean run, and the vacuum levels in the final chamber were typically between 0.5 and 1 ntorr. The momentum exchange for the helium-tungsten surface and the argon-tungsten surface combination was obtained over approximately a decade of incoming energy (for the argon gas) at angles of incidence of 0, 30, and 41 deg on both clean and dirty (gas covered) surfaces. The results exhibited a significant variation in momentum transfer between the data obtained for the clean and dirty surfaces. The values of normal momentum accommodation coefficient for the clean surface were found to be lower than the values previously reported.

Moskal, E. J.↗
NASA NTRS1991

High temperature electronic excitation and ionization rates in gases

The relaxation times for electronic excitation due to electron bombardment of atoms was found to be quite short, so that electron kinetic temperature (T sub e) and the electron excitation temperature (T asterisk) should equilibrate quickly whenever electrons are present. However, once equilibrium has been achieved, further energy to the excited electronic states and to the kinetic energy of free electrons must be fed in by collisions with heavy particles that cause vibrational and electronic state transitions. The rate coefficients for excitation of electronic states produced by heavy particle collision have not been well known. However, a relatively simple semi-classical theory has been developed here which is analytic up to the final integration over a Boltzmann distribution of collision energies; this integral can then be evaluated numerically by quadrature. Once the rate coefficients have been determined, the relaxation of electronic excitation energy can be evaluated and compared with the relaxation rates of vibrational excitation. Then the relative importance of these two factors, electronic excitation and vibrational excitation by heavy particle collision, on the transfer of energy to free electron motion, can be assessed.

Hansen, Frederick↗
DOE OSTI2020

An Ultra-microporous Metal-Organic Framework with Exceptional Xe Capacity

Molecular confinement plays a significant effect on trapped gas and solvent molecules. A fundamental understanding of gas adsorption within the porous confinement provides information necessary to design a material with improved selectivity. In this regard, metal organic frameworks (MOFs) adsorbents are ideal candidate materials to study confinement effects for weakly interacting gas molecules such as noble gases. Among the noble gases, Xenon (Xe) has practical applications in the medical, automotive and aerospace industries. In this communication, we report an ultra-microporous nickel-isonicotinate MOF with exceptional Xe uptake and selectivity compared to all benchmark MOF and porous organic cage materials. The selectivity arises because of the near perfect fit of the atomic Xe inside the porous confinement. Notably, at low partial pressure, the Ni-MOF interacts very strongly with Xe compared to the closely related Krypton gas (Kr) and more polarizable CO2. Further 129Xe NMR suggests a broad isotropic chemical shift due to the reduced motion as a result of confinement.

Confinement effects, atomically precise materials,↗
NASA NTRS1982

Investigation of spray characteristics for flashing injection of fuels containing dissolved air and superheated fuels

The flow, atomization and spreading of flashing injector flowing liquids containing dissolved gases (jet/air) as well as superheated liquids (Freon II) were considered. The use of a two stage expansion process separated by an expansion chamber, ws found to be beneficial for flashing injection particularly for dissolved gas systems. Both locally homogeneous and separated flow models provided good predictions of injector flow properties. Conventional correlations for drop sizes from pressure atomized and airblast injectors were successfully modified, using the separated flow model to prescribe injector exit conditions, to correlate drop size measurements. Additional experimental results are provided for spray angle and combustion properties of sprays from flashing injectors.

Solomon, A. S. P.↗
DOE OSTI2020

Materials Data on GaSe by Materials Project

GaSe is black P-derived structured and crystallizes in the trigonal R3m space group. The structure is two-dimensional and consists of six GaSe sheets oriented in the (0, 0, 1) direction. Ga2+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ga–Se bond lengths are 2.50 Å. Se2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ga2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on GaSe by Materials Project

GaSe is black P-derived structured and crystallizes in the hexagonal P-6m2 space group. The structure is two-dimensional and consists of four GaSe sheets oriented in the (0, 0, 1) direction. Ga2+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ga–Se bond lengths are 2.50 Å. Se2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ga2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on GaSe by Materials Project

GaSe is black P-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is two-dimensional and consists of four GaSe sheets oriented in the (0, 0, 1) direction. Ga2+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ga–Se bond lengths are 2.50 Å. Se2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ga2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on GaSe by Materials Project

GaSe crystallizes in the hexagonal P6_3/mmc space group. The structure is two-dimensional and consists of four GaSe sheets oriented in the (0, 0, 1) direction. Ga2+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ga–Se bond lengths are 2.59 Å. Se2- is bonded in a 3-coordinate geometry to three equivalent Ga2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on GaSe by Materials Project

GaSe is black P-derived structured and crystallizes in the hexagonal P6_3mc space group. The structure is two-dimensional and consists of eight GaSe sheets oriented in the (0, 0, 1) direction. Ga2+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ga–Se bond lengths are 2.49 Å. Se2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ga2+ atoms.

36 MATERIALS SCIENCE↗
NASA NTRS1985

Flow and atomization in flashing injectors

Flashing injection involves expanding a fluid through an injector until a supersaturated state is reached, causing a portion of the fluid to flash to a vapor. This investigation considered the flow, atomization and spreading properties of flashing injectors with flowing liquids containing dissolved gases (Jet A/air) as well as superheated liquids (Freon-11). The use of a two-stage expansion process, separated by an expansion chamber, was found to be beneficial for good atomization properties of flashing injection - particularly for dissolved gas systems. Both locally homogeneous and separated flow models provided good predictions of injector flow properties. Conventional correlations for drop sizes from pressure and airblast injectors were successfully modified, using the separated flow model to prescribe injector exit conditions, and to correlate drop size measurements. Additional experimental results are provided for spray angles of sprays from flashing injectors.

Solomon, A. S. P.↗
NASA NTRS2010

Turbomolecular Pumps for Holding Gases in Open Containers

Proposed special-purpose turbomolecular pumps denoted turbotraps would be designed, along with mating open containers, to prevent the escape of relatively slowly (thermal) moving gas molecules from the containers while allowing atoms moving at much greater speeds to pass through. In the original intended applications, the containers would be electron-attachment cells, and the contained gases would be vapors of alkali metal atoms moving at thermal speeds that would be of the order of a fraction of 300 meters per second. These cells would be parts of apparatuses used to measure fluxes of neutral atoms incident at kinetic energies in the approximate range of 10 eV to 10 keV (corresponding to typical speeds of the order of 40,000 m/s and higher). The incident energetic neutral atoms would pass through the cells, wherein charge-exchange reactions with the alkali metal atoms would convert the neutral atoms to negative ions, which, in turn, could then be analyzed by use of conventional charged-particle optics.

Keller, John W.↗
NASA NTRS1973

Composition of the earth's atmosphere by shock-layer radiometry during the PAET entry probe experiment.

A determination of the composition of the earth's atmosphere obtained from onboard radiometer measurements of the spectra emitted from the bow shock layer of a high-speed entry probe is reported. The N2, O2, CO2, and noble gas concentrations in the earth's atmosphere were determined to good accuracy by this technique. The results demonstrate unequivocally the feasibility of determining the composition of an unknown planetary atmosphere by means of a multichannel radiometer viewing optical emission from the heated atmospheric gases in the region between the bow shock wave and the vehicle surface. The spectral locations in this experiment were preselected to enable the observation of CN violet, N2(+) first negative and atomic oxygen emission at 3870, 3910, and 7775 A, respectively. The atmospheric gases were heated and compressed by the shock wave to a peak temperature of about 6100 K and a corresponding pressure of 0.4 atm. Complete descriptions of the data analysis technique and the onboard radiometer and its calibration are given.

Whiting, E. E.↗
NASA NTRS2017

An Introduction to Atomic Layer Deposition

Atomic Layer Deposition has been instrumental in providing a deposition method for multiple space flight applications. It is well known that ALD is a cost effective nanoadditive-manufacturing technique that allows for the conformal coating of substrates with atomic control in a benign temperature and pressure environment. Through the introduction of paired precursor gases, thin films can be deposited on a myriad of substrates from flat surfaces to those with significant topography. By providing atomic layer control, where single layers of atoms can be deposited, the fabrication of metal transparent films, precise nano-laminates, and coatings of nano-channels, pores and particles is achievable. The feasibility of this technology for NASA line of business applications range from thermal systems, optics, sensors, to environmental protection. An overview of this technology will be presented.

ALD↗