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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

The Stratospheric and Mesospheric Sounder (SAMS) experiment

Thermal emission and solar resonance fluorescence from the atmospheric limb are reported. Global measurements are made of radiation from the molecular species. The gas correlation spectroscopy technique based on the use of gas cells to select emission from chosen spectral lines or from particular parts of spectral lines is used. The source function and departure from the thermodynamic equilibrium between 80 and 130 kilometers associated with CO2 emission bands were investigated. The zonal wind velocity component along the line of sight is measured.

Drummond, J. R.↗

A 163 micron laser heterodyne radiometer for OH

A 163 micron (1.836 THz) radiometer developed for airplane and/or balloon platforms is described. The laser local oscillator is a CO2 pumped methanol laser operating at a frequency which is approx. 1 GHz from the J = 3/2 - 1/2 transition of OH. The laser is used directly as a local oscillator or is translated in frequency to closer coincidence with the OH emission, depending on achieved detector IF bandwidth. Frequency translation techniques which are described are diode mixing and a method of single sideband generation using an external Stark modulated gas cell. The photoconductive mixer used is a strained Ge crystal, doped with Ga, originally used as an incoherent detector. The uniaxial strain on the Ga doped Ge crystal shifts the threshold for photoconduction from 100/cm to frequencies as low as 50/cm. These detectors are currently being characterized as mixers in the laboratory. Of particular interest are the effect of local oscillator power and strain on IF, bandwidth detector impedance, and conversion loss. Preliminary results of these tests are described and compared with theorectical expectations.

Pickett, H. M.↗

Radiation hardness of Efratom M-100 rubidium frequency standard

The effects of nuclear radiation on rubidium gas cell frequency standards and components are presented, including the results of recent tests where a continuously operating rubidium frequency standard (Effratom, Model M-100) was subjected to simultaneous neutron/gamma radiation. At the highest neutron fluence 7.5 10 to the 12th power n/sq cm and total dose 11 krad(Si) tested, the unit operated satisfactorily; the total frequency change over the 2 1/2 hour test period due to all causes, including repeated retraction from and insertion into the reactor, was less than 1 x 10 to the -10th power. The effects of combined neutron/gamma radiation on rubidium frequency standard physics package components were also studied, and the results are presented.

English, T. C.↗

Thin metal film and multilayers experiment (A0138-3)

The sources of degradation of in state of the art and newly developed components and testing the usefulness of the concept of storing experiment samples in dry nitrogen under launch and space vacuum conditions during reentry mission phase were investigated. Ultraviolet (UV) and extreme ultraviolet (EUV) experiments suffer degradations during space missions of even 1 month duration. It is suggested that the degradation is due to condensation of outgassing products, followed by solar induced polymerization, however, penetrating charged particles are also known to produce volume effects. Degradation may also start immediately after manufacturing of the component due to oxidation, moisture, or chemical corrosion by atmospheric constituents such as CO2 and SO2. When the filters are used as windows for gas absorption cells or gas filters, or when they define the instrumental bandwidth by themselves. The effects of mechanical degradation by thermal cycling and/or dust may cause a dramatic impact.

Delaboudiniere, J. P.↗

Cell Separations in Microgravity and Development of a Space Bioreactor

A bioreactor optimized for operations in space is now being developed. The current research is focused on determining the optimum cell-bead ratios, medium content and proper maintenance conditions required to keep living cell specimens alive and healthy for the entire flight. The bioreactor development project has recently added a microprocessor/computer to the JSC prototype for control and data analysis. Appropriate new technology is being combined with the current bioreactor designs and tested to determine what specific features must be included in the fabrication of a bioreactor designed to operate for STS demonstration tests. Considerations include: (1) circulation and resupply of culture media; (2) sensors required to monitor temperature, cell growth, mass transport, and oxygen consumption; and (3) inflight control of shear stress on cells, gas transfer in microgravity, diffusion, and intracellular transport. These data and results from the JSC prototype bioreactor test will be used for the design and construction of a small space bioreactor for the Orbiter middeck.

Morrison, D. R.↗

A tandem mirror plasma source for hybrid plume plasma studies

A tandem mirror device to be considered as a hot plasma source for the hybrid plume rocket concept is discussed. The hot plamsa from this device is injected into an exhaust duct, which will interact with an annular hypersonic layer of neutral gas. The device can be used to study the dynamics of the hybrid plume, and to verify the numerical predictions obtained with computer codes. The basic system design is also geared towards low weight and compactness, and high power density at the exhaust. The basic structure of the device consists of four major subsystems: (1) an electric power supply; (2) a low temperature, high density plasma gun, such as a stream gun, an MPD source or gas cell; (3) a power booster in the form of a tandem mirror machine; and (4) an exhaust nozzle arrangement. The configuration of the tandem mirror section is shown.

Yang, T. F.↗

Support of validation of SAGE 2 data

An error analysis of differential absorption lidar (DIAL) measurements of stratospheric ozone from a Space Shuttle is discussed. A transmitter system consisting of a KrF excimer laser pumping gas cells of H2 or D2 producing output wavelengths in the near UV is shown to be useful for the measurement of ozone in an altitude range from 15 to 50 km.

Copeland, Gary E.↗

Error analysis of DIAL measurements of ozone by a Shuttle excimer lidar

Attention is given to an error analysis of DIAL measurements of stratospheric ozone from the Space Shuttle. It is shown that a transmitter system consisting of a KrF excimer laser pumping gas cells of H2 or D2 producing output wavelengths in the near UV is useful for the measurement of ozone in a 15-50-km altitude range. It is noted that for increased levels of stratospheric aerosols experienced after violent volcanic eruptions, the relative uncertainties of ozone densities will be large in the region below about 24 km.

Uchino, Osamu↗

Reexamination of data from the asteroid/meteoroid detector

A reexamination of the results of the Pioneer 10 and 11 Asteroid Meteoroid Detector, or Sisyphus, was carried out in the light of a recently derived theory characterizing interplanetary matter and the Zodiacal Light (ZL). Sisyphus measured individual meteoroids from reflected sunlight and ZL between meteoroid events. The results were questioned because meteoroid orbits could not be calculated as intended and the ZL as computed from individual meteoroids did not agree with values determined from the ZL mode and from the other ZL sensor on the spacecraft. It is first shown that, independent of any explanation, the measurements are, with high probability, valid and strongly correlated with the ZL. The model which explains the strange behavior of the Sisyphus instrument also resolves the enigma why the three dust experiments on the Pioneer 10 and 11 spacecraft produced extreme disparate results for the distribution and orbits of meteoric particles and the ZL. The theory based primarily on these measurements requires a population in the inner solar system of cold meteoroid material composed mainly of volatile molecules. These meteoroids in orbits of high eccentricity are called cosmoids. They are impulsively disrupted from solar heating, resulting in order of magnitude increases in optical cross section. The dispersed particles, predominantly micron sized, scatter most of the ZL and supply the polarization. The sublimation time in sunlight for micron sized particles of volatile composition opposes the gravitational flux increase expected in approaching the sun. The other two Pioneer 10/11 dust experiments were: the Imaging Photopolarimeter for the ZL, and the Meteoroid Detection Experiment that measured penetration of 25 micron (Pioneer 10) and 50 micron (Pioneer 11) thick walls of pressurized gas cells.

Soberman, Robert K.↗

Laser studies of the photodissociation dynamics of cometary radicals

In the past year, it was shown that in the 193 nm photolysis of C2H, the C2 radical is produced in a variety of electronic, vibrational, and rotational states. The relative population of the vibrational and rotational states of C2(A 1 Pi u), C2(B 1 Sigma g +), and C2(A 3 Pi u) were determined in a static gas cell and in a pulsed molecular beam. It seems as though the original angular momentum of the C2H molecule appears as part of the angular momentum of the C2 radical. A attempt is being made to discover the mathematical relationship that governs this mapping. New information about the bond dissociation energy of the C2 radical was produces. C2(b 3 Sigma g -) and C2( 1 Delta g) were detected in the photolysis of C2H via time resolved infrared emission spectroscopy. In the former case, vibrational excitation up to v'' = 4 is observed. All of the results suggest that the C2 models in comets need to consider the presence of vibrationally excited C2 radicals in comets. The laser induced fluorescence spectra of the C3 was observed as a product of the 193 nm photolysis of allene and propyne. The populations of the rotational levels are identical in both cases. This result has led us to conclude that an isomerization reaction occurs in the photolysis of propyne which leads to the same C3H2 intermediate that is formed in the photolysis of C3H4. Since the former molecule is one of the most abundant in the interstellar medium it is also likely that its precursor is also present in comets. This would explain why C3 is observed in comets.

Jackson, William M.↗

An overview of the halogen occultation experiment (HALOE)

The HALOE experiment will fly on the Upper Atmosphere Research Satellite (UARS) in the last quarter of 1991. The experiment uses the solar occultation limb sounding approach, in combination with gas filter and broadband radiometry to provide measurements of temperature profiles and key gases in the ClO(y), NO(y), and HO(y) chemical families of the middle atmosphere. The instrument has been characterized in great detail to determine gains, spectral response, noise, crosstalk, field-of-view, and thermal drift characteristics. A final end-to-end test using a gas cell to simulate the atmosphere demonstrated measurement repeatability to about 1 percent and agreement between measured and calculated signals to within about 1 percent to 3 percent. This latter agreement provides confidence in knowledge of both the hardware as well as the software.

Russell, James M., III↗

Frequency standards from industry over the next 25 years

Present and possible future performance for many of the existing and new commercial frequency standards is presented here. Recent progress in the gas cell atomic standards with regards to size and cost is significant and considerable improvement is expected. Cesium beam standards will benefit in stability and accuracy from optical pumping. Cooled hydrogen masers will offer extremely good stability. Advances in trapped ion and cesium fountain technologies make them good high performance candidates for the future. The quartz oscillator field is more mature and consequently performance improvements for the future are going to be less spectacular. Oscillators stabilized to GPS will have many applications. Recent performance of cooled microwave dielectric resonator oscillators is very good and they offer the promise of serving as flywheel oscillators for advanced performance atomic standards.

Cutler, Leonard S.↗

Measurement of precipitation induced FUV emission and Geocoronal Lyman Alpha from the IMI mission

This final report describes the activities of the Lockheed Martin Palo Alto Research Laboratory in studying the measurement of ion and electron precipitation induced Far Ultra-Violet (FUV) emissions and Geocoronal Lyman Alpha for the NASA Inner Magnetospheric Imager (IMI) mission. this study examined promising techniques that may allow combining several FUV instruments that would separately measure proton aurora, electron aurora, and geocoronal Lyman alpha into a single instrument operated on a spinning spacecraft. The study consisted of two parts. First, the geocoronal Lyman alpha, proton aurora, and electron aurora emissions were modeled to determine instrument requirements. Second, several promising techniques were investigated to determine if they were suitable for use in an IMI-type mission. Among the techniques investigated were the Hydrogen gas cell for eliminating cold geocoronal Lyman alpha emissions, and a coded aperture spectrometer with sufficient resolution to separate Doppler shifted Lyman alpha components.

Mende, Stephen B.↗

Interchange for Joint Research Entitled: Measurement of Stable Nitrogen and Sulfur Isotopes

Viking measurements of the Martian atmosphere indicate a value of N-15/N-14 which is markedly greater than that found in Earth's atmosphere. These isotopic measurements provide a powerful diagnostic tool which may be used to derive valuable information regarding the past history of Mars and they have been used to place important constraints on the evolution of Mars' atmosphere. Initial partial pressures of nitrogen, outgassing rates, and integrated deposition of nitrogen into minerals have been calculated from this important atmospheric data (McElroy et al., 1976 and 1977; Fox and Dalgarno, 1983). The greater precision obtained in laser spectrometer isotopic measurements compared to the Viking data will greatly improve these calculated values. It has also been proposed that the N-15/N-14 value in Mars' atmosphere has increased monotonically over time (McElroy et al., 1977; Fox and Dalgarno, 1983; Wallis, 1989) owing to preferential escape of atmospheric 14N to space. Nitrogen isotopic ratios might be used to identify relatively ancient crustal rocks (R. Mancinelli, personal communication), and perhaps determine relative aces of surface samples. As a first step in successfully measuring nitrogen isotopes optically we have demonstrated the measurement of 15NI14N to a precision of 0.1% (See Figures 1-4) using a tunable diode laser and an available gas (N-,O) with spectral lines in the 2188 cm-1 region. The sample and reference gas cells contained gases of identical isotopic composition so that the 15NI14N absorption ratio determined from the sample cell, when divided by the 15NI14N absorption ratio determined from the reference cell, should yield an ideal value of unity. The average measured value of this "ratio of ratios" was 0.9983 with a standard deviation (20 values) of 0.0010. This corresponds to a precision of 0.1% (1 per mil) for nitrogen isotopes, a value sufficiently precise to provide important isotopic data of interest to exobiologists. The precision presently attainable in gases is sufficient to permit the instrument to be used in the measurement of isotopic ratios of interest to exobiologists as well as geologists and planetary scientists.

Becker, Joseph F.↗

Wavelength-Agile Optical Sensor for Exhaust Plume and Cryogenic Fluid Interrogation

Two optical sensors developed in UW-Madison labs were evaluated for their potential to characterize rocket engine exhaust plumes and liquid oxygen (LOX) fluid properties. The plume sensor is based on wavelength-agile absorption spectroscopy A device called a chirped white pulse emitter (CWPE) is used to generate the wavelength agile light, scanning, for example, 1340 - 1560 nm every microsecond. Properties of the gases in the rocket plume (for example temperature and water mole fraction) can be monitored using these wavelength scans. We have performed preliminary tests in static gas cells, a laboratory GOX/GH2 thrust chamber, and a solid-fuel hybrid thrust chamber, and these initial tests demonstrate the potential of the CWPE for monitoring rocket plumes. The LOX sensor uses an alternative to wavelength agile sensing: two independent, fixed-wavelength lasers are combined into a single fiber. One laser is absorbed by LOX and the other not: by monitoring the differential transmission the LOX concentration in cryogenic feed lines can be inferred. The sensor was successful in interrogating static LOX pools in laboratory tests. Even in ice- and bubble-laden cryogenic fluids, LOX concentrations were measured to better than 1% with a 3 microsec time constant.

Sanders, Scott T.↗

Performance characteristics of narrow linewidth fiber laser pumped mid-IR difference frequency mixing light source for methane detection

A high-power, narrow-linewidth Yb fiber laser with a fiber Bragg grating (FBG) pumped difference frequency generation (DFG) in a periodically poled lithium niobate (PPLN) crystal was investigated in detail. A mid-IR power of approximately 2.3 microW at 3.3 micrometers with a slope efficiency of 0.85 mW/W2 was achieved. A Doppler-broadened absorption spectrum of CH4 at 3038.497 cm-1 (3.2911 micrometers) was obtained with a 0.1-m long-gas cell at a pressure of 133 Pa. The linewidth of the DFG source was evaluated to be less than 96 MHz from the observed spectral linewidth. Real-time monitoring of CH4 (approximately 1.78 ppm) in ambient air in a multipass cell which has an optical path length of 10 m was also demonstrated.

Non-NASA Center↗

Optical remote measurement of toxic gases

Enactment of the Clean Air Act Amendments (CAAA) of 1990 has resulted in increased ambient air monitoring needs for industry, some of which may be met efficiently using open-path optical remote sensing techniques. These techniques include Fourier transform spectroscopy, differential optical absorption spectroscopy, laser long-path absorption, differential absorption lidar, and gas cell correlation spectroscopy. With this regulatory impetus, it is an opportune time to consider applying these technologies to the remote and/or path-averaged measurement and monitoring of toxic gases covered by the CAAA. This article reviews the optical remote sensing technology and literature for that application.

Review↗

Checking Contamination during Storage of Carbonaceous Chondrites for Micro FTIR Measurements

We examined organic contamination by Fourier transform infrared micro spectroscopic (micro FTIR) measurements of carbonaceous chondrite samples. Carbonaceous chondrites, Tagish Lake (C2), Murchison (CM2) and Moss (CO3), and some mineral powder samples pressed on aluminum plates were measured by micro FTIR before and after storage in several containers with silicone rubber mat. During storage, samples did not touch directly anything except the holding aluminum plates. The carbonaceous chondrites containing hydrous minerals (Tagish Lake and Murchison) pressed on aluminum plates and measured by transmission-reflection micro FTIR measurements were found to be contaminated during storage after only one day, as revealed by an increase of approximately 2965 /cm and approximately 1260 /cm peaks. The Moss meteorite which contains no hydrous minerals, did not show an increase of these peaks, indicating no organic contamination. This difference is probably related to the differing mineralogy and physical properties (including porosity and permeability) of these chondrites. Hydrous minerals such as antigorite, muscovite, montmorillonite and silica gel showed organic contamination by the same infrared measurements, while anhydrous materials such as SiO2 and KBr showed no contamination. These results indicate importance of surface OH groups for the organic contamination. Organic contamination was found on silica gel samples pressed on aluminum plates when they were stored within containers including silicone rubber, silicone grease or adhesive tape. Long path gas cell FTIR measurements for silicone rubber indicated methylsiloxane oligomers were released from the silicone rubber. In-situ heating infrared measurements on the contaminated antigorite and Tagish Lake showed decrease of the 1262 /cm (Si-CH3) and 2963 /cm (CH3) peaks from room temperature to 200-300 C indicating desorption of volatile contaminants. These results indicate that careful preparation and storage are essential for FTIR measurements on precious astromaterial samples such as meteorites, IDPs and samples returned from comets, asteroids and Mars. Every possible contamination source should be evaluated before anything is done to these samples.

Zolensky, Michael E.↗