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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Thermionic performance of a cesium diminiode with relatively impure 110-tungsten electrodes

Thermionic performance data from a miniature plane cesium diode (diminiode) with 110-tungsten electrodes are presented. The diminiode has a guard-ringed collector and a spacing of 0.23 mm. The data were obtained by using a computerized acquisition system. The diode was tested at increments between 1700 and 1900 K for the emitter, 694 and 1101 K for the collector, and 519 and 650 K for the reservoir. A maximum power density of 4.5 W/sq cm was obtained at an emitter temperature of 1900 K. This relatively low output probably results from high carbon and sodium impurities in the electrode materials.

Smith, A. L.↗

Nitrogen balance for wheat canopies (Triticum aestivum cv. Veery 10) grown under elevated and ambient CO2 concentrations

We examined the hypothesis that elevated CO2 concentration would increase NO3- absorption and assimilation using intact wheat canopies (Triticum aestivum cv. Veery 10). Nitrate consumption, the sum of plant absorption and nitrogen loss, was continuously monitored for 23 d following germination under two CO2 concentrations (360 and 1000 micromol mol-1 CO2) and two root zone NO3- concentrations (100 and 1000 mmol m3 NO3-). The plants were grown at high density (1780 m-2) in a 28 m3 controlled environment chamber using solution culture techniques. Wheat responded to 1000 micromol mol-1 CO2 by increasing carbon allocation to root biomass production. Elevated CO2 also increased root zone NO3- consumption, but most of this increase did not result in higher biomass nitrogen. Rather, nitrogen loss accounted for the greatest part of the difference in NO3- consumption between the elevated and ambient [CO2] treatments. The total amount of NO3(-)-N absorbed by roots or the amount of NO3(-)-N assimilated per unit area did not significantly differ between elevated and ambient [CO2] treatments. Instead, specific leaf organic nitrogen content declined, and NO3- accumulated in canopies growing under 1000 micromol mol-1 CO2. Our results indicated that 1000 micromol mol-1 CO2 diminished NO3- assimilation. If NO3- assimilation were impaired by high [CO2], then this offers an explanation for why organic nitrogen contents are often observed to decline in elevated [CO2] environments.

Non-NASA Center↗

Dry Pressed, High Areal Loading Electrode Architectures Enabled by Holey Graphene

For future electric aviation, advanced battery cell chemistry beyond lithium ion batteries are required to meet mission requirements. High energy density battery concepts such as lithium-sulfur (Li-S) and lithiumoxygen (Li-O2) chemistries are being intensively investigated to realize their extraordinary theoretical promise in terms of energy density. Most fabrication methods of cathodes for these novel battery chemistries followed a conventional approach. In this approach, the active material is mixed with a polymer binder and a conductive carbon in a high-boiling organic solvent to form a slurry, followed by casting onto a current collector and solvent evaporation. The process is usually lengthy and poses environmental hazards due to the use of organic solvents.

Lin Yi↗

NASA research on refractory compounds.

The behavior and properties of the refractory carbides, nitrides, and borides are being investigated by NASA as part of its research aimed at developing superior heat resistant materials for aerospace applications. Studies of the zirconium-carbon-oxygen system show that zirconium oxycarbides of different compositions and lattice parameters can be formed between 1500 C and 1900 C and are stable below 1500 C. More applied studies show that hot working generally improves the microstructure and therefore the strength of TiC and NbC. Sintering studies on UN indicate that very high densities can be achieved. Hot pressing of cermets of HfN and HfC produces good mechanical properties for high temperature bearing applications. Attempts to improve the impact resistance of boride composites by the addition of a nickel or carbon yarn were not overly successful.

Gangler, J. J.↗

Quantifying Long-Term Changes in Carbon Stocks and Forest Structure from Amazon Forest Degradation

Despite sustained declines in Amazon deforestation, forest degradation from logging and firecontinues to threaten carbon stocks, habitat, and biodiversity in frontier forests along the Amazon arcof deforestation. Limited data on the magnitude of carbon losses and rates of carbon recoveryfollowing forest degradation have hindered carbon accounting efforts and contributed to incompletenational reporting to reduce emissions from deforestation and forest degradation (REDD+). Wecombined annual time series of Landsat imagery and high-density airborne lidar data to characterizethe variability, magnitude, and persistence of Amazon forest degradation impacts on abovegroundcarbon density (ACD) and canopy structure. On average, degraded forests contained 45.1% of thecarbon stocks in intact forests, and differences persisted even after 15 years of regrowth. Incomparison to logging, understory fires resulted in the largest and longest-lasting differences in ACD.Heterogeneity in burned forest structure varied by fire severity and frequency. Forests with a historyof one, two, and three or more fires retained only 54.4%, 25.2%, and 7.6% of intact ACD,respectively, when measured after a year of regrowth. Unlike the additive impact of successive fires,selective logging before burning did not explain additional variability in modeled ACD loss andrecovery of burned forests. Airborne lidar also provides quantitative measures of habitat structure thatcan aid the estimation of co-benefits of avoided degradation. Notably, forest carbon stocks recoveredfaster than attributes of canopy structure that are critical for biodiversity in tropical forests, includingthe abundance of tall trees. We provide the first comprehensive look-up table of emissions factors forspecific degradation pathways at standard reporting intervals in the Amazon. Estimated carbon lossand recovery trajectories provide an important foundation for assessing the long-term contributionsfrom forest degradation to regional carbon cycling and advance our understanding of the currentstate of frontier forests.

Rappaport, Danielle I.↗

Reflectance measurements for the detection and mapping of soil limitations

During 1971 and 1972 research was conducted on two fallow fields in the proposed Oahe Irrigation Project to investigate the relationship between the tonal variations observed on aerial photographs and the principal soil limitations of the area. A grid sampling procedure was used to collected detailed field data during the 1972 growing season. The field data was compared to imagery collected on May 14, 1971 at 3050 meters altitude. The imagery and field data were initially evaluated by a visual analysis. Correlation and regression analysis revealed a highly significant correlation and regression analysis revealed a highly significant correlation between the digitized color infrared film data and soil properties such as organic matter content, color, depth to carbonates, bulk density and reflectivity. Computer classification of the multiemulsion film data resulted in maps delineating the areas containing claypan and erosion limitations. Reflectance data from the red spectral band provided the best results.

Benson, L. A.↗

Abrupt Changes at the Permian/Triassic Boundary: Tempo of Events from High-Resolution Cyclostratigraphy

The Permian/Triassic (P/Tr) boundary (251.4 +/- 3 Myr) is marked by the most severe mass extinction in the geologic record. Recently, precise absolute dating has bracketed the marine extinctions and associated carbon-isotope anomaly within less than 1 Myr. We improve this resolution through high-resolution stratigraphy across the P/Tr boundary in the 331-m Gartnerkofel-1 core and nearby Reppwand outcrop section (Carnic Alps, Austria) utilizing FFT and wavelet timeseries analyses of cyclic components in down-hole core logs of density and natural gamma-ray intensity, and carbon-isotopic ratios of bulk samples. The wavelet analysis indicates continuity of deposition across the P/Tr boundary interval, and the timeseries analyses show evidence for persistent cycles in the ratio of approximately 40: 10: 4.7: 2.3 meters, correlated with Milankovitch-band orbital cycles of approximately 412: 100: 40: 20 kyr (eccentricity 1 and 2, obliquity, and precession), and giving a consistent average sedimentation rate of approximately 10 cm/1,000 yr. Milankovitch periods in delta C-13 and density in these shallow-water carbonates were most likely the result of climatically induced oscillations of sea level and climate, coupled with changes in ocean circulation and productivity, that affected sedimentation. Fluctuations in gamma radiation reflect varying input of clay minerals and the presence of shaly interbeds. Throughout the P/Tr boundary interval in the core, the 100,000-year eccentricity cycle seems to be dominant. Weaker obliquity and precession cycles are in line with the location of the Austrian section in the latest Permian, close to the Equator in the western bight of the Tethys, where obliquity and precessional effects on seasonal contrast might be subdued. Using the improved resolution provided by cycle analysis in the GK-1 core, we find that the dramatic change in the faunal record that marks the P/Tr boundary takes place over less than 6m, or less than 60,000 years. In the nearby Reppwand outcrop section, the same faunal changes occurs over only 0.8 m or about 8,000 years, close to the limit of time-resolution induced by bioturbation and reworking in these sediments. The sharp negative global carbon-isotope shift took place within less than or equal to 40,000 yr, and the isotope excursions persisted for approximately 480,000 yr into the Early Triassic. The results indicate that the severe marine faunal event that marks the P/Tr boundary was very sudden, perhaps less than the resolution window in the GK-1 core, and suggest a catastrophic cause. The wavelet-analysis approach to high-resolution cyclostratigraphy can be applied to other P/Tr boundary sections, and when combined with precise absolute dating and magnetostratigraphic methods promises a significant increase in resolution in determining the correlation and tempo of the end-Permian extinctions and related events worldwide.

Rampino, M. R.↗

Woven TPS Enabling Missions Beyond Heritage Carbon Phenolic

WTPS is a new approach to producing TPS architectures that uses precisely engineered 3D weaving techniques to customize material characteristics needed to meet specific missions requirements for protecting space vehicles from the intense heating generated during atmospheric entry. Using WTPS, sustainable, scalable, mission-optimized TPS solutions can be achieved with relatively low life cycle costs compared with the high costs and long development schedules currently associated with material development and certification. WTPS leverages the mature state-of-the-art weaving technology that has evolved from the textile industry to design TPS materials with tailorable performance. Currently, missions anticipated encountering heat fluxes in the range of 1500 4000 Wcm2 and pressures greater than 1.5 atm are limited to using fully dense Carbon Phenolic. However, fully dense carbon phenolic is only mass efficient at higher heat fluxes greater than 4000 Wcm2), and current mission designs suffer this mass inefficiency for lack of an alternative mid-density TPS. WTPS not only bridges this mid-density TPS gap but also offers a replacement for carbon phenolic, which itself requires a significant and costly redevelopment effort to re-establish its capability for use in the high heat flux missions recently prioritized in the NRC Decadal survey, including probe missions to Venus, Saturn and Neptune. This presentation will overview the WTPS concept and present some results from initial testing completed comparing WTPS architectures to heritage carbon phenolic.

ablators↗

Woven TPS Enabling Missions Beyond Heritage Carbon Phenolic

NASAs Office of the Chief Technologist (OCT) Game Changing Division recently funded an effort to advance a Woven TPS (WTPS) concept. WTPS is a new approach to producing TPS architectures that uses precisely engineered 3D weaving techniques to customize material characteristics needed to meet specific missions requirements for protecting space vehicles from the intense heating generated during atmospheric entry. Using WTPS, sustainable, scalable, mission-optimized TPS solutions can be achieved with relatively low life cycle costs compared with the high costs and long development schedules currently associated with material development and certification. WTPS leverages the mature state-of-the-art weaving technology that has evolved from the textile industry to design TPS materials with tailorable performance. Currently, missions anticipated encountering heat fluxes in the range of 1500 4000 Wcm2 and pressures greater than 1.5 atm are limited to using fully dense Carbon Phenolic. However, fully dense carbon phenolic is only mass efficient at higher heat fluxes g(reater than 4000 Wcm2), and current mission designs suffer this mass inefficiency for lack of an alternative mid-density TPS. WTPS not only bridges this mid-density TPS gap but also offers a replacement for carbon phenolic, which itself requires a significant and costly redevelopment effort to re-establish its capability for use in the high heat flux missions recently prioritized in the NRC Decadal survey, including probe missions to Venus, Saturn and Neptune. This presentation will overview the WTPS concept and present some results from initial testing completed comparing WTPS architectures to heritage carbon phenolic.

Woven Thermal protection materials↗

Nanoengineered Thermal Materials Based on Carbon Nanotube Array Composites

State-of-the-art integrated circuits (ICs) for microprocessors routinely dissipate power densities on the order of 50 W/cm2. This large power is due to the localized heating of ICs operating at high frequencies and must be managed for future high-frequency microelectronic applications. As the size of components and devices for ICs and other appliances becomes smaller, it becomes more difficult to provide heat dissipation and transport for such components and devices. A thermal conductor for a macro-sized thermal conductor is generally inadequate for use with a microsized component or device, in part due to scaling problems. A method has been developed for providing for thermal conduction using an array of carbon nanotubes (CNTs). An array of vertically oriented CNTs is grown on a substrate having high thermal conductivity, and interstitial regions between adjacent CNTs in the array are partly or wholly filled with a filler material having a high thermal conductivity so that at least one end of each CNT is exposed. The exposed end of each CNT is pressed against a surface of an object from which heat is to be removed. The CNT-filler-composite adjacent to the substrate provides improved mechanical strength to anchor CNTs in place, and also serves as a heat spreader to improve diffusion of heat flux from the smaller volume (CNTs) to a larger heat sink.

Li, Jun↗

Fabrication of carbon film composites for high-strength structures

Physical and mechanical properties of fiber composite materials consisting of carbon films are described. Application of carbon film structural composites for constructing microwave filters or optical instruments is proposed. Applications in aerospace and architectural structures for high strength and low density properties are discussed.

Preiswerk, P. R.↗

Catalytic crystallization of ices by small silicate smokes at temperatures less than 20K

Samples of methanol and water ices condensed from the vapor onto aluminum substrates at low temperatures (below approximately 80 K) form amorphous ices; annealing at temperatures in excess of 140-155 K is usually required to convert such amorphous samples to crystalline ices. However, we have found that when either methanol or water vapor is deposited on to aluminum substrates that have been coated with a thin (0.1-0.5 mm) layer of amorphous silicate smoke, the ices condense in crystalline form. We believe that crystalline ice forms as the result of energy liberated at the ice/silicate interface perhaps due to weak bonding of the ice at defect sites on the grains and the very high surface to volume ratio and defect density of these smokes. Annealing of amorphous water ice mixed with more volatile components such as methane, carbon monoxide, etc., has been suggested as an efficient way to produce clatherates in the outer solar nebula and thus explain the volatile content of comets and icy satellites of the outer planets. This hypothesis may need to be re-examined if amorphous ice does not form on cold silicate grains.

Moore, M.↗

Engineering Launch Methods for Non-Spherical Hypervelocity Projectiles

The use of carbon-fiber-reinforced polymer (CFRP) in modern satellites has led to a significant amount of space debris, including fragments of CFRP and high-density metals such as steel and copper, produced during catastrophic breakup events. To address this issue, NASA's White Sands Test Facility (WSTF) has been developing the capability to launch "flake-like" and long "needle-like" projectiles. WSTF tested projectiles with different length-to-diameter ratios (L/D), impacting aluminum Whipple shields with thermal blankets on the outer surface, at velocities exceeding 6 km/s. The results of the study suggest that launching and imaging shaped projectiles at high velocities is feasible. Ongoing research is now focused on improving the techniques for launching and imaging shaped projectiles under hypervelocity conditions.

Engineering↗

Segmentation of Lightweight Ablator Micro-Tomography Using Deep Learning

Ablative thermal protection systems (TPS) are essential for high speed entry of planetary atmospheres, such as those of Earth and Mars. Upon entry the kinetic energy of the spacecraft is converted into thermal energy, leading to high heat fluxes at the wall of the craft. Because of this extreme heating, a robust ablative TPS material must be selected. A common material selection today is phenolic-impregnated carbon ablator (PICA), which is a low-density carbon material known for producing dust that is not suitable to a cleanroom environment. To mitigate dust created by a PICA heatshield, a silicone-based spray called NuSil is applied to the surface of the TPS, creating PICA-NuSil (PICA-N). PICA-N has been observed to have a different material response from regular PICA during high enthalpy flow testing, producing surface temperatures up to 200K less than those seen for PICA [1]. To better understand this phenomenon, it is critical that robust methods of PICA-N material characterization are developed. The purpose of this project is to investigate Object Research Systems’ (ORS) Dragonfly deep learning tools as a means of accurately segmenting and characterizing PICA-N. Systematic testing of this software has shown that Dragonfly deep learning tools have strong potential for accurate segmentation/ characterization of PICA-N and other TPS materials.

Micro-tomography↗

Low-Isp derated ion thruster operation

The performance and lifetime expectations of 30 cm xenon ion thruster technology at low values of specific impulse were evaluated, with emphasis on 1000-2500 s operation. Power levels of up to 2.0 kW, appropriate for auxiliary and orbit maneuvering propulsion, were processed at thrust-to-power ratios up to 57 mN/kW. These tests were conducted using a derated 30 cm ion thruster with high-perveance design two-grid ion optics with xenon propellent. Lifetime projections were made based on a simple analysis of critical component erosion rates, and it was found that a strong correlation exists with the ratio of the specific impulse-to-input power. Under all operating conditions for which the projected thruster lifetime is less than 10,000 hrs, the life-limiting component of this technology is erosion of the accelerator grid due to charge-exchange ions. The use of alternative grid materials such as carbon is estimated to increase useful thruster lifetimes by as much as an order of magnitude and may enable long-life high thrust-density, sub-2500 s Isp operation. The performance and life of the derated thruster appears similar to that of the Russian SPT-100 thruster in the 1.0-2.0 kW, 1600-2000 s operational envelope.

Patterson, Michael J.↗

Low-Isp derated ion thruster operation

The performance and lifetime expectations of 30 cm xenon ion thruster technology at low values of specific impulse were evaluated, with emphasis on 1000-2500 s operation. Power levels of up to 2.0 kW, appropriate for auxiliary and orbit maneuvering propulsion, were processed at thrust-to-power ratios up to 57 mN/kW. These tests were conducted using a derated 30 cm ion thruster with high-perveance design two-grid ion optics with xenon propellant. Lifetime projections were made based on a simple analysis of critical component erosion rates, and it was found that a strong correlation exists with the ratio of the specific impulse-to-input power. Under all operating conditions for which the projected thruster lifetime is less than 10,000 hrs, the life-limiting component of this technology is erosion of the accelerator grid due to charge-exchange ions. The use of alternative grid materials such as carbon is estimated to increase useful thruster lifetimes by as much as an order of magnitude and may enable long-life high thrust-density, sub-2500 s Isp operation. The performance and life of the derated thruster appears similar to that of the Russian SPT-100 thruster in the 1.0-2.0 kW, 1600-2000 s operational envelope.

Patterson, Michael J.↗

Launch Vehicle Performance with Solid Particle Feed Systems for Atomic Propellants

An analysis of launch vehicle Gross Liftoff Weight (GLOW) using high energy density atomic propellants with solid particle feed systems was conducted. The analyses covered several propellant combinations, including atoms of aluminum (Al), boron (B). carbon (C), and hydrogen (H) stored in a solid cryogenic particle, with a cryogenic liquid as the carrier fluid. Several different weight percents (wt%) for the liquid carrier were investigated and the gross lift off weight (GLOW) of the vehicles using the solid particle feed systems were compared with a conventional 02/H2 propellant vehicle. The potential benefits and effects of feed systems using solid particles in a liquid cryogenic fluid are discussed.

Palaszewski, Bryan↗