Search NASA⌕ Search

SEARCH · Search NASA

Results for “Mass diffusivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Thermal plasma in outer planet magnetospheres

The plasma environments of the outer planets are a study in contrasts. The magnetosphere of Jupiter is dominated by the prodigious plasma output of Io, with losses due to diffusion driven by mass loading. At Saturn, the small icy satellites are the major sources of plasma for the inner magnetosphere. The low mass loading rates there imply that the densities of the plasma tori are limited by dissociative recombination, rather than diffusive transport. At Uranus, the icy satellites are negligible plasma sources compared to the input from the extended neutral hydrogen cloud and the ionosphere. Convection driven by the solar wind penetrates deep into the inner magnetosphere because of the unique orientation of the rotation axis of Uranus. The expected magnetosphere of Neptune is similar to that of Saturn and Jupiter, with Triton, the ring arcs, and the planet as possible plasma sources. The Voyager 2 encounter with Neptune holds out the hope of a passage through a nonterrestrial auroral region, a unique event in planetary exploration.

Belcher, J. W.↗
NASA NTRS2003

Basic Modeling of the Solar Atmosphere and Spectrum

This grant supported the research and publication of a major 26-page paper in The Astrophysical Journal, by Fontenla, Avrett, & Loeser (2002): 'Energy Balance in the Solar Transition Region. IV. Hydrogen and Helium Mass Flows with Diffusion.' This paper extended our previous modeling of the chromosphere-corona transition region to include cases with particle and mass flows. Inflows and outflows were shown to produce striking changes in the profiles of hydrogen and helium lines. An important conclusion is that line shifts are much less significant than the changes in line intensity and central reversal due to the influence of flows on the excitation and ionization of atoms in the solar atmosphere. This modeling effort at SAO is the only current one being undertaken anywhere to simulate in detail the full range of non-LTE absorption, emission, and scattering processes in the solar atmosphere to account for the entire solar spectrum from radio waves to X-rays. This effort is being continued with internal SAO funding at a relatively slow pace. Further NASA support in the future would yield results of great value for the interpretation of solar observations from NASA spacecraft.

Avrett, Eugene↗
NASA NTRS2001

Diffusivity Measurements Made Instant and Easy

A compact common path interferometer (CPI) system has been developed to measure the diffusivity of liquid pairs. The CPI is an optical technique that can be used to measure changes in the gradient of the refraction index of transparent materials. It uses a shearing interferometer that shares the same optical path from a laser light source to the final imaging plane. The molecular diffusion coefficient of liquids can be determined from the physical relations between changes in the optical path length and liquid phase properties. When the data obtained by using the CPI have been compared with similar results from other techniques, the instrument has been demonstrated to be far superior to other instruments for measuring the diffusivity of miscible liquids while staying very compact and robust (ref. 1). Because of its compactness and ease of use, the CPI has been adopted for use in studies of interface dynamics as well as other diffusion-controlled process applications (ref. 2). This progress will permit experiments in microgravity that can quantitatively answer basic science questions about mass and thermal diffusion and their effect in transport processes. This instrument is a spinoff of a diagnostic development for microgravity fluid physics experiments at the NASA Glenn Research Center that has used optics and electronics existing in the fluid physics laboratory for feasibility studies. Optical diagnostic techniques have become an integral part of many areas of measurement applications in industrial and research laboratories. Many types of interferometers and their phase-shifted versions have been used as instruments for measuring optical wave fronts for lens testing and combustion and fluid flow diagnostics. One of these, the point diffraction interferometer, is considered to be robust (see, for example, ref. 3) because it has a common-path design. The point diffraction interferometer is difficult to align and has a limited measurement range for liquid-phase applications. Interferometry and schlieren techniques have been widely used for many years for gas-flow-visualization. On the other hand, the CPI, which is basically a Wollaston prism Polarizer in combination with an analyser (crystalline quartz retardation plate) is used instead of a point diffraction interferometer unit. The advantage of using the CPI over other optical techniques is that it can make quantitative measurements in liquids with the large index of refraction variations that often occur in interface dynamics studies. This can be simply accomplished by using different prism polarizers for each particular experimental condition.

Rashidnia, Nasser↗
NASA NTRS1992

Solar-wind/magnetospheric dynamos: MHD-scale collective entry of the solar wind energy, momentum and mass into the magnetosphere

A quasi open MHD (Magnetohydrodynamic) scale anomalous transport controlled boundary layer model is proposed, where the MHD collective behavior of magnetofluids (direct dynamo effect, anomalous viscous interaction and anomalous diffusion of the mass and the magnetic field) plays the main role in the conversion of the Solar Wind (SW) kinetic and magnetic energy into electromagnetic energy in the Magnetosphere (MSp). The so called direct and indirect dynamo effects are based on inductive and purely dissipative energy conversion, respectively. The self organization ability of vector fields in turbulent magnetofluids implies an inductive response of the plasma, which leads to the direct dynamo effect. The direct dynamo effect describes the direct formation of localized field aligned currents and the transverse Alfven waves and provides a source for MHD scale anomalous diffusivity and viscosity. The SW/MSp coupling depends on the dynamo efficiency.

Song, Yan↗
NASA NTRS2015

Low-Profile Diffuser

The propellant tanks used in liquid rockets require pressurization gases in order to maintain tank pressure while the tanks are being drained during engine operation. The pressurization gas, which is typically much warmer than the relatively cold propellants in the tank, must be introduced into the empty ullage space at the top of the tank. The purpose of the diffuser is to control the flow of the gas into the tank in order to prevent direct impingement of the gas on the liquid surface and/or the tank walls. If the diffuser did not perform those tasks, the warm gas can create excess heat transfer causing an increase in the amount of pressurization mass required. Typical diffusers are long vertical cylinders that create a large exit area in order to minimize gas velocities. However, long vertical cylinders limit the amount of liquid that can be loaded into the tank in order not to have the liquid surface near the diffuser. A design goal for a pressurization diffuser is to create uniform flow in order to prevent jets that can impact the liquid surface and/or tank walls. The purpose of the task was to create a diffuser design that had a lower vertical profile (in order to be able to raise the liquid surface) while still maintaining uniform flow.

Martin, Michael A.↗
NASA NTRS1954

Summary of Free-flight Performance of a Series of Ram-jet Engines at Mach Numbers from 0.80 to 2.20

Data obtained from the NACA air-launched ram-jet program are summarized with emphasis placed upon the transonic propulsive thrust potential of the engines. Data are presented for boosted and non-boosted engine configurations which incorporate a single-oblique-shock or double-oblique-shock diffuser designed for critical inlet operation at flight Mach numbers of 1.8 and 2.4, respectively. The engines are evaluated in terms of flight Mach number, mass-flow ratio, diffuser pressure recovery, combustion-chamber heat release, propulsive thrust, external drag, and specific impulse. From specific impulse considerations, it appears that for some air-launched missile applications the self-accelerating supersonic ram jet may have a lower gross weight than a rocket-boosted ram jet.

RESEARCH EQUIPMENT, FREE-FLIGHT↗
NASA NTRS1950

Investigation of Perforated Convergent-divergent Diffusers with Initial Boundary Layer

An experimental investigation was made at Mach number 1.90 of the performance of a series of perforated convergent-divergent supersonic diffusers operating with initial boundary layer, which was induced and controlled by lengths of cylindrical inlets affixed to the diffusers. Supercritical mass-flow and peak total-pressure recoveries were decreased slightly by use of the longest inlets (4 inlet diameters in length). Combinations of cylindrical inlets, perforated diffusers, and subsonic diffuser were evaluated as simulated wind tunnels having second throats. Comparisons with noncontracted configurations of similar scale indicated conservatively computed power reductions of 25 percent.

DIFFUSERS, SUPERSONIC↗
NASA NTRS2006

Pattern Formation in Diffusion Flames Embedded in von Karman Swirling Flows

Pattern formation is observed in nature in many so-called excitable systems that can support wave propagation. It is well-known in the field of combustion that premixed flames can exhibit patterns through differential diffusion mechanism between heat and mass. However, in the case of diffusion flames where fuel and oxidizer are separated initially there have been only a few observations of pattern formation. It is generally perceived that since diffusion flames do not possess an inherent propagation speed they are static and do not form patterns. But in diffusion flames close to their extinction local quenching can occur and produce flame edges which can propagate along stoichiometric surfaces. Recently, we reported experimental observations of rotating spiral flame edges during near-limit combustion of a downward-facing polymethylmethacrylate disk spinning in quiescent air. These spiral flames, though short-lived, exhibited many similarities to patterns commonly found in quiescent excitable media including compound tip meandering motion. Flame disks that grow or shrink with time depending on the rotational speed and in-depth heat loss history of the fuel disk have also been reported. One of the limitations of studying flame patterns with solid fuels is that steady-state conditions cannot be achieved in air at normal atmospheric pressure for experimentally reasonable fuel thickness. As a means to reproduce the flame patterns observed earlier with solid fuels, but under steady-state conditions, we have designed and built a rotating, porous-disk burner through which gaseous fuels can be injected and burned as diffusion flames. The rotating porous disk generates a flow of air toward the disk by a viscous pumping action, generating what is called the von K rm n boundary layer which is of constant thickness over the entire burner disk. In this note we present a map of the various dynamic flame patterns observed during the combustion of methane in air as a function of fuel flow rate and the burner rotational speed.

Nayagam, Vedha↗
NASA NTRS1998

Numerical Modeling of Physical Vapor Transport in Contactless Crystal Growth Geometry

Growth from the vapor under conditions of limited contact with the walls of the growth ampoule is beneficial for the quality of the growing crystal due to reduced stress and contamination which may be caused by interactions with the growth container. The technique may be of a particular interest for studies on crystal growth under microgravity conditions: elimination of some factors affecting the crystal quality may make interpretation of space-conducted processes more conclusive and meaningful. For that reason, and as a part of our continuing studies on 'contactless' growth technique, we have developed a computational model of crystal growth process in such system. The theoretical model was built, and simulations were performed using the commercial computational fluid dynamics code, (CFD) ACE. The code uses an implicit finite volume formulation with a gray discrete ordinate method radiation model which accounts for the diffuse absorption and reflection of radiation throughout the furnace. The three-dimensional model computes the heat transfer through the crystal, quartz, and gas both inside and outside the ampoule, and mass transport from the source to the crystal and the sink. The heat transport mechanisms by conduction, natural convection, and radiation, and mass transport by diffusion and convection are modeled simultaneously and include the heat of the phase transition at the solid-vapor interfaces. As the thermal boundary condition, temperature profile along the walls of the furnace is used. For different thermal profiles and furnace and ampoule dimensions, the crystal growth rate and development of the crystal-vapor and source-vapor interfaces (change of the interface shape and location with time) are obtained. Super/under-saturation in the ampoule is determined and critical factors determining the 'contactless' growth conditions are identified and discussed. The relative importance of the ampoule dimensions and geometry, the furnace dimensions and its temperature, and the properties of the grown material are analyzed. The results of the simulations are compared with related experimental results on growth of CdTe, CdZnTe, ZnTe, PbTe, and PbSnTe crystals by this technique.

Palosz, W.↗
NASA NTRS1989

A model for including thermal conduction in molecular dynamics simulations

A technique is introduced for including thermal conduction in molecular dynamics simulations for solids. A model is developed to allow energy flow between the computational cell and the bulk of the solid when periodic boundary conditions cannot be used. Thermal conduction is achieved by scaling the velocities of atoms in a transitional boundary layer. The scaling factor is obtained from the thermal diffusivity, and the results show good agreement with the solution for a continuous medium at long times. The effects of different temperature and size of the system, and of variations in strength parameter, atomic mass, and thermal diffusivity were investigated. In all cases, no significant change in simulation results has been found.

Wu, Yue↗
NASA NTRS1972

A direct numerical method for predicting concentration profiles in a turbulent boundary layer over a flat plate

A numerical solution of the turbulent mass transport equation utilizing the concept of eddy diffusivity is presented as an efficient method of investigating turbulent mass transport in boundary layer type flows. A FORTRAN computer program is used to study the two-dimensional diffusion of ammonia, from a line source on the surface, into a turbulent boundary layer over a flat plate. The results of the numerical solution are compared with experimental data to verify the results of the solution. Several other solutions to diffusion problems are presented to illustrate the versatility of the computer program and to provide some insight into the problem of mass diffusion as a whole.

Dow, J. W.↗
NASA NTRS1994

Candle Flames in Microgravity: USML-1 Results - 1 Year Later

We report on the sustained behavior of a candle flame in microgravity determined in the glovebox facility aboard the First United States Microgravity Labomtofy. In a quiescent, microgmvjfy environment, diffusive transport becomes the dominant mode of heat and mass transfer; whether the diffusive transport rate is fast enough to sustain low-gravity candle flames in air was unknown to this series of about 70 tests. After an initial transient in which soot is observed, the microgravity candle flame in air becomes and remains hemispherical and blue (apparently soot-Ne) with a large flame standoff distance. Near flame extinction, spontaneous flame oscillations are regularly observed; these are explained as a flashback of flame through a premixed combustible gas followed by a retreat owed to flame quenching. The frequency of oscillations can be related to diffusive transport rates, and not to residual buoyant convective flow. The fact that the flame tip is the last point of the flame to survive suggests that it is the location of maximum fuel reactivity; this is unlike normal gravity, where the location of maximum fuel reactivity is the flame base. The flame color, size, and shape behaved in a quasi-steady manner; the finite size of the glovebox, combined with the restricted passages of the candlebox, inhibited the observation of true steady-state burning. Nonetheless, through calculations, and inference from the series of shuttle tests, if is concluded that a candle can burn indefinitely in a large enough ambient of air in microgravity. After igniting one candle, a second candle in close pximity could not be lit. This may be due to wax coating the wick and/or local oxygen depletion around the second, unlit candle. Post-mission testing suggests that simultaneous ignition may overcome these behaviors and enable both candles to be ignited.

Ross, H. D.↗
NASA NTRS2024

The Peregrine Ion Trap Mass Spectrometer (PITMS) Investigation Development and Pre-Flight Planning

The Peregrine Ion Trap Mass Spectrometer (PITMS) is a mass spectrometer instrument that operated during the Astrobotic Peregrine Mission-1 as part of the NASA Commercial Lunar Payload Services (CLPS) initiative. This paper describes the instrument and investigation design, development, and planning conducted by the PITMS team consisting of a successful partnership between NASA Goddard Space Flight Center (GSFC), The Open University (OU), NASA, and ESA. PITMS was designed to measure the abundance and temporal variability of volatile species in the near-surface lunar exosphere from a landed platform on the lunar surface. The PITMS instrument consisted of an ESA-provided Exospheric Mass Spectrometer (EMS; including sensor, electronics, controller, power supply boards) and a GSFC wrapper that provided structural elements, thermal control, and a deployable dust cover. PITMS was designed to operate as a passive sampler, where ambient gases would enter PITMS through an aperture, diffuse around the mass analyzer cavity, become ionized by electron impact and trapped in a radiofrequency field, then sequentially released to a detector to build a mass spectrum. PITMS was capable of measuring species with a massto-charge ratio (m/z) from 10 to 150 Da, with a mass resolution of approximately 0.5 amu. The PITMS science investigation was planned to be operated by GSFC with an international team of scientists. Though the mission did not achieve its lunar landing, information about the PITMS instrument and planning is provided to be able to understand and effectively use data that will be forthcoming from the investigation.

Barbara Cohen↗
NASA NTRS1980

A physical model of Titan's clouds

A physical model of the formation and growth of aerosols in the atmosphere of Titan has been constructed in light of the observed correlation between variations in Titan's albedo and the sunspot cycle. The model was developed to fit spectral observations of deep methane bands, pressures, temperature distributions, and cloud structure, and is based on a one-dimensional physical-chemical model developed to simulate the earth's stratospheric aerosol layer. Sensitivity tests reveal the model parameters to be relatively insensitive to particle shape but sensitive to particle density, with high particle densities requiring larger aerosol mass production rates to produce compatible clouds. Solution of the aerosol continuity equations for particles of sizes 13 A to about 3 microns indicates the importance of a warm upper atmosphere and a high-altitude mass injection layer, and the production of aerosols at very low aerosol optical depths. Limits are obtained for the chemical production of aerosol mass and the eddy diffusion coefficient, and it is found that an increase in mass input causes a decrease in mean particle size.

Toon, O. B.↗
NASA NTRS1981

Ring current impoundment of the Io plasma torus

A newly discovered feature in the Io plasma formation that may be described as a ramp separating a high-density plasma ledge on its Jupiterward side from the lower-density radially distended Io plasma disc on its anti-Jupiterward side is observed to coincide with a marked inward decrease in the ring current population. The spatial congruency of the counter-directed maximal gradients in both plasma bodies reveals a profound coupling between them. The existence of the ramp requires a local order-of-magnitude reduction in the diffusion coefficient that governs radial mass transport. It is demonstrated that the diminished diffusive efficiency there is caused by strong pressure gradient inhibition of the interchange instability that underlies mass transport. The Io plasma torus, which is defined as the region of strong ultraviolet emissions, is identified as the plasma ledge. The plasma density in the ledge is high and, incidentally therefore, able to emit strongly because it is impounded against rapid, centrifugal expulsion by the inwardly directed pressure of the ring current at its inner edge.

Siscoe, G. L.↗
DOE OSTI2026

A multiscale packed-bed reactor model for sustainable ethylene production via chemical looping oxidative coupling of methane

The rising global warming concerns and shale gas discovery have prompted research in the direction of greenhouse gas (GHG), such as methane, reduction and conversion. Oxidative coupling of methane (OCM) offers a pathway to low carbon-intense valorization of methane while producing ethylene, a chemical regarded as central to the petrochemical industry. Even after decades of OCM discovery, researchers keep understanding the process and underlying chemical reactions in a pursuit to achieve industrial viability for OCM. Here, in general, OCM suffers from low C 2 selectivity, yield and reactor temperature runaways due to highly exothermic nature of its reactions. Computational Fluid Dynamics (CFD) tools help analyze spatial gradients within the reactor to deeply understand the diffusion of species, mass and heat transfer phenomena. Furthermore, challenges associated with scaling up such as hot spot formation and parametric sensitivity can be addressed without having to expend on costly experiments. The current paper presents a multiscale packed-bed reactor CFD model coupled with a chemical kinetic model for the chemical looping OCM. The CFD model includes two scales i.e., macroscale for catalyst bed and microscale for individual pellets. Moreover, a chemical kinetic model based on 10 gas-phase reactions is integrated with the CFD model. An additional surface reaction for the formation of gas-phase oxygen from catalyst surface is added to account for the absence of feed oxygen. The model is calibrated against experimental results. The calibrated model captures trends in CH 4 conversion, C 2 selectivity and C 2 yield within a ± 4.35 % range across a temperature range of 700-900 °C. Moreover, model fidelity is evaluated by varying key computational parameters such as mesh resolution and time step size. The model is also verified by varying the inlet methane concentration and the gas hourly space velocity (GHSV) and comparing the results with literature. A sensitivity analysis and scale-up of the current model is undergoing.

Chemical looping↗