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At least 163 records · Page 9

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NASA NTRS1989

The role of rapid solidification processing in the fabrication of fiber reinforced metal matrix composites

Advanced composite processing techniques for fiber reinforced metal matrix composites require the flexibility to meet several widespread objectives. The development of uniquely desired matrix microstructures and uniformly arrayed fiber spacing with sufficient bonding between fiber and matrix to transmit load between them without degradation to the fiber or matrix are the minimum requirements necessary of any fabrication process. For most applications these criteria can be met by fabricating composite monotapes which are then consolidated into composite panels or more complicated components such as fiber reinforced turbine blades. Regardless of the end component, composite monotapes are the building blocks from which near net shape composite structures can be formed. The most common methods for forming composite monotapes are the powder cloth, foil/fiber, plasma spray, and arc spray processes. These practices, however, employ rapid solidification techniques in processing of the composite matrix phase. Consequently, rapid solidification processes play a vital and yet generally overlooked role in composite fabrication. The future potential of rapid solidification processing is discussed.

Locci, Ivan E.↗

NASA NTRS1988

Enthalpies of a binary alloy during solidification

The purpose of the paper is to present a method of calculating the enthalpy of a dendritic alloy during solidification. The enthalpies of the dendritic solid and interdendritic liquid of alloys of the Pb-Sn system are evaluated, but the method could be applied to other binaries, as well. The enthalpies are consistent with a recent evaluation of the thermodynamics of Pb-Sn alloys and with the redistribution of solute in the same during dendritic solidification. Because of the heat of mixing in Pb-Sn alloys, the interdendritic liquid of hypoeutectic alloys (Pb-rich) of less than 50 wt pct Sn has enthalpies that increase as temperature decreases during solidification.

Poirier, D. R.↗

NASA NTRS1988

Rapid solidification of Nb-base alloys

New Nb-base alloys are of interest for aerospace structural applications at high temperatures, viz, 800 to 1650 C. Fundamental information regarding the effects of rapid solidification in achieving greatly refined microstructures, extended solid solubility, suppression of embrittling equilibrium phases, and formation of new phases is desired in a number of Nb-X alloys. The microstructures and selected properties of Nb-Si and other Nb-base alloys are presented for materials both rapidly quenched from the equilibrium liquidus and rapidly solidified following deep supercooling. Electromagnetic levitation was used to achieve melting and supercooling in a containerless inert gas environment. A variety of solidification conditions were employed including splatting or drop casting of supercooled samples. The morphology and composition of phases formed are discussed in terms of both solidification history and bulk composition.

Gokhale, A. B.↗

NASA NTRS1990

Making Fiber-Reinforced Metal By Rapid Solidification

Report highlights advantages and versatility of rapid-solidification technology in fabrication of fiber-reinforced metal-matrix composites. Discusses present role and future potential of technology. Describes variety of methods for making monotape. Common to all is rapid solidification of liquid metal - "rapid" meaning cooling rates of 10 to 4th power to 10 to 6th power K/s. Also includes tables that compare rapid-solidification methods and provides extensive list of references.

Noebe, Ronald D.↗

NASA NTRS1989

Finite element simulations of thermosolutal convection in vertical solidification of binary alloys

Dendritic vertical solidification of a binary alloy is modeled using the finite element method to assess the effect of thermosolutal convection in macrosegregation. The mathematical model assumes steady-state solidification with a planar, undeformable surface defined by the dendrite tips and the eutectic isotherm. The dendritic region is assumed to advance at a constant solidification velocity v. The stability of the modeled system has been investigated and nonlinear calculations performed that show finger-like convection when the system is unstable. Results for lead-tin alloys show that when the system is unstable, convection is only significant in the uppermost part of the mush and is entirely driven by convection in the bulk fluid.

Heinrich, J. C.↗

NASA NTRS1989

Effects of anisotropic heat conduction on solidification

Two-dimensional solidification influenced by anisotropic heat conduction has been considered. The interfacial energy balance was derived to account for the heat transfer in one direction (x or y) depending on the temperature gradient in both the x and y directions. A parametric study was made to determine the effects of the Stefan number, aspect ratio, initial superheat, and thermal conductivity ratios on the solidification rate. Because of the imposed boundary conditions, the interface became skewed and sometimes was not a straight line between the interface position at the upper and lower adiabatic walls (spatially nonlinear along the height). This skewness depends on the thermal conductivity ratio k(yy)/k(yx). The nonlinearity of the interface is influenced by the solidification rate, aspect ratio, and k(yy/k(yx).

Weaver, J. A.↗

NASA NTRS1990

Dual purpose pyrometer for temperature and solidification velocity measurement

A dual purpose pyrometer is described that allows both accurate radiance temperature measurement and fast temporal response. The system uses two silicon photodiodes with separate optical paths derived from a common spot on the sample. The optical bandwidths and response times of each detection circuit are tailored to the function of each radiometer. The radiance temperature of electromagnetically levitated metallic samples is measured over a narrow optical bandwidth with a high-gain silicon detector. The velocity of solidification of undercooled melts can be deduced from the rise time of the second silicon detector which samples a broad optical bandwidth and has a fast response time. Results from experiments on the undercooling and solidification behavior of electromagnetically levitated pure nickel show that the solidification velocity approaches 17 m/s at high undercooling.

Hofmeister, W. H.↗

NASA NTRS1990

Directional solidification of superalloys

This invention relates to the directional solidification of superalloys, in particular nickel-based superalloys, by imposition of a predetermined temperature profile in the solidification front and, depending on the desired results, a predetermined rate of advance of said solidification front, whereas castings of markedly superior fatigue resistance are produced.

Schmidt, Deborah Diane↗

NASA NTRS1991

Influence of a magnetic field during directional solidification of MAR-M 246 + Hf superalloy

An area that has been almost totally overlooked in the optimization of properties in directionally solidified superalloys is the control of microstructural features through the application of a magnetic field during solidification. The influence of a magnetic field on the microstructural features of a nickel-base superalloys is investigated. Studies were performed on the dendritic MAR-M 246+Hf alloy, which was solidified under both a 5 K gauss magnetic field and under no-applied-field conditions. The possible influences of the magnetic field on the solidification process were observed by studying variations in microstructural features including volume fraction, surface area, number, and shape of the carbide particles. Stereological factors analyzed also included primary and secondary dendrite arm spacing and the volume fraction of the interdendritic eutectic constituent. Microprobe analysis was performed to determine the chemistry of the carbides, dendrites, and interdendritic constituents, and how it varied between field and no-field solidification samples. Experiments involving periodic application and removal of the magnetic field were also performed in order to permit a comparison with structural variations observed in a MAR-M 246+Hf alloy solidified during KC-135 high-g, low-g maneuvers.

Andrews, J. Barry↗

NASA NTRS1991

Modelling directional solidification

The long range goal of this program is to develop an improved understanding of phenomena of importance to directional solidification and to enable explanation and prediction of differences in behavior between solidification on Earth and in space. Current emphasis is on determining the influence of perturbations on directional solidification.

Wilcox, William R.↗

NASA NTRS1991

Numerical modeling of solidification and convection in a viscous pure binary eutectic system

The solidification and convection of the pure binary eutectic silicate system diopside-anorthite (Di-An) is numerically modeled. A mass-weighted enthalpy of fusion is used to account for the second solid phase (An) which crystallizes at the solidus temperature. Variable under-relaxation is used to aid convergence of the momentum equations in the implementation of the SIMPLER algorithm used to solve the two-dimensional continuum conservation equations. Numerical experiments of the solidification of Di80 melt show that a large temperature drop occurs across the solid and mush regions which decreases convective vigor in the liquid. Interesting compositional segregation patterns are produced during the solidification of Di80.

Oldenburg, Curtis M.↗

NASA NTRS1992

Cooling and solidification of liquid-metal drops in a gaseous atmosphere

The free fall of a liquid-metal drop, heat transfer from the drop to its environment, and solidification of the drop are described for both gaseous and vacuum atmospheres. A simple model, in which the drop is assumed to fall rectilinearly, with behavior like that of a rigid particle, is developed to describe cooling behavior. Recalescence of supercooled drops is assumed to occur instantaneously when a specified temperature is passed. The effects of solidification and experimental parameters on drop cooling are calculated and discussed. Major results include temperature as a function of time, and of drag, time to complete solidification, and drag as a function of the fraction of the drop solidified.

Mccoy, J. K.↗

NASA NTRS1991

Solidification processing superalloys in an electric field

The phase morphology of a given superalloy's microstructure is established during solidification. Solidification-processing in an applied electric field is a technique currently undergoing experimental characterization at NASA-Marshall. The method is predicated on the simplest model of a metallic solid, in which ions are arranged in basic space lattices that are permeated by an 'electron gas' whose valence electrons are free to move in the solid. When in a superheated liquid state, the metal is seen as a dense 'cold plasma' of electrons and ions. The application of an electric field during solidification establishes a steady, continuous current flow; the direction of propagation of the plasma waves coincides with the direction of the electric field. Such an alignment introduces an ordered arrangement of the electric vectors and introduces an additional degree of order in an already highly ordered alloy.

Ahmed, Shaffiq↗

NASA NTRS1992

Boundary-conforming mapping applied to computations of highly deformed solidification interfaces

A new boundary-conforming mapping is developed for the calculation of highly deformed cellular solidification interfaces in a model of directional solidification of a binary alloy. The mapping is derived through a variational formulation that is designed so that the grid penetrates the grooves between cells along the interface without causing a loss of ellipticity of the mapping equations. A finite element/Newton method is presented for simultaneous solution of the free boundary problem described by the solutal model of directional solidification and the mapping equations. Results are compared to previous calculations and demonstrate the importance of accurate representation of the interface shape for understanding the solution structure.

Tsiveriotis, K.↗

NASA NTRS1992

Modelling Directional Solidification

The long range goal of this program has been to develop an improved understanding of phenomena of importance to directional solidification, in order to enable explanation and prediction of differences in behavior between solidification on Earth and in space. Current emphasis is on determining the influence of perturbations on directional solidification.

Wilcox, William R.↗

NASA NTRS1992

Microstructural development during directional solidification of peritectic alloys

Despite the widespread commercial use of peritectic alloys (e.g., steels, brass, bronze, intermetallic compounds, Co based superalloys and A3B type superconductors), the characterization of the microstructural development during directional solidification of peritectics has historically lagged behind similar efforts directed towards other types of binary invariant reactions such as eutectic or monotectic. A wide variety of possible microstructures has been shown to form in peritectics depending upon the imposed temperature gradient, G, the solidification velocity, V, as well as the presence or absence of convection in the melt. This has important technological implications since many commercially important alloys exhibit peritectics and processing methods such as casting and welding often involve widely changing conditions. It has been the aim of this project to examine, in a systematic fashion, both experimentally and theoretically, the influence of gravitationally driven convection on segregation and microstructural development during solidification in peritectic systems under terrestrial conditions. The scientific results of the project will be used to establish ground based data in support of a meaningful microgravity flight experiment.

Lograsso, Thomas A.↗

NASA NTRS1993

Study on solidification of immisible alloys (M-10)

Alloying of immiscible alloys under microgravity is of interest in metallurgical processes. Several experiments investigating the alloying of immiscible alloys, such as Al-In, Al-Bi, Zn-Bi, and Zn-Pb, were done in space. Homogeneous distribution of small L2 particles in the matrix, such as an emulsion structure, was expected in the space-solidifed alloys. However, the alloys demonstrated an extremely segregated structure. To date insufficient information was obtained to explain these unexpected results. Our experiment was proposed to clarify the solidification manner of immiscible alloys and to obtain fundamental information concerning structural control of the alloys. In space, density differences between the two liquids separated in immiscible regions can be neglected, so that no sedimentation of L(sub 2) phase will take place. When the growth of the alloys is interrupted and this status is frozen by an adequate rapid cooling procedure, it will provide much information concerning decomposing homogeneous liquid and the interaction between the monotectic growth front morphology and the distribution of L(sub 2) phase. It is anticipated that the results will be useful for elucidating the monotectic solidification manner and it will be instructive to explain the segregated structures obtained in the past space experiments.

Kamio, Akihiko↗

NASA NTRS1993

The influence of a microgravity environment on the dendritic morphology during directional solidification of hypoeutectic Al-Si alloys

NASA grant NAGW-2540 provided the opportunity to evaluate and extend ongoing studies of directionally solidified Al-Si alloys. Microstructural development was further characterized in terms of solidification processing parameters; novel relationships between processing and development of dendrite trunk diameters and tertiary dendrite arm spacings were found. This has resulted in three publications (one in print, one in press, and one in review). Microstructural development under conditions of controlled acceleration during directional solidification has been investigated; this has culminated in a Master's degree and will be submitted for publication. The above work not only contributes to our understanding of solidification phenomena but also defines the processing parameters for a successful microgravity experiment while providing a data base to which mu g samples can be unequivocally compared and evaluated.

Grugel, Richard N.↗