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DOE OSTI2024

Institute for Catalysis in Energy Processes (ICEP) (Final Report)

The Institute for Catalysis in Energy Processes (ICEP) was a multi-PI program located at the Northwestern University Center for Catalysis and Surface Science from 2006-2024. Over several renewal cycles and several organizing themes, ICEP addressed fundamental questions in catalysis science. In turn, the scientific questions addressed were directly relevant to the efficient use of the nation’s resources to produce fuels and commodity chemicals, harness alternate energy sources for chemical reactions such as light or electricity, reduce emissions and waste, and minimize the impact of our use of plastics. Selective oxidation, (oxidative) dehydrogenation, deNOx, CO 2 reduction, hydrogen release, polymer decomposition / depolymerization, and many other reactions of intense interest to the US Department of Energy were studied in the center. Major ICEP strengths were in catalyst synthesis, in measurements that elucidated catalyst properties, in reaction mechanisms and kinetics, and in predictive theory and modeling. ICEP researchers were often the inventors or developers of materials and methods that were brought to bear on the Institute’s catalytic systems. Key characterization tools advanced through this project included resonance Raman and related techniques, sum frequency generation, and X-ray standing wave spectroscopy. Center members relied extensively on computational tools such as density functional theory and microkinetic modeling to fully investigate catalyst structures and catalytic mechanisms. ICEP researchers were early developers of atomic layer deposition (ALD) for catalyst synthesis and were early pioneers of metal organic frameworks for catalysis. ICEP innovations are found in areas of intense research such as single-atom catalysts, catalytic deconstruction of plastics, and catalytic MOFs, to name a few. Research areas initiated by ICEP indirectly led to DOE EFRCs, startup companies, and other achievements. Over its 18 years of existence, ICEP involved two different PIs (Stair and Notestein) and 24 senior investigators across several academic disciplines at Northwestern University. There were tight collaborations with Argonne National Laboratory, including specialized equipment and experiments permanently located there. The center supported ~400 person-years of effort by graduate students and postdocs, either directly through DOE support or indirectly by leveraging independent support provided to the trainees, e.g. through the NSF GRFP or internal fellowships. The project resulted in 328 manuscripts and numerous conference presentations.

36 MATERIALS SCIENCE↗

NASA NTRS1982

Photointerpretation of LANDSAT images

Learning objectives include: (1) developing a facility for applying conventional techniques of photointerpretation to small scale (satellite) imager; (2) promoting the ability to locate, identify, and interpret small natural and man made surface features in a LANDSAT image; (3) using supporting imagery, such as aerial and space photography, to conduct specific applications analyses; (4) learning to apply change detection techniques to recognize and explain transient and temporal events in individual or seasonal imagery; (5) producing photointerpretation maps that define major surface units, themes, or classes; (6) classifying or analyzing a scene for specific discipline applications in geology, agriculture, forestry, hyrology, coastal wetlands, and environmental pollution; and (7) evaluating both advantages and shortcomings in relying on the photointerpretive approach (rather than computer based analytical approach) for extracting information from LANDSAT data.

Source record↗

NASA NTRS1994

SN 1991T: Reflections of past glory

We have obtained photometry and spectra of SN 1991T which extend more than 1000 days past maximum light, by far the longest of SN Ia has been followed. Although SN 1991T exhibited nearly photometric behavior in the first 400 days following maximum, by 600 days its decline had slowed, and by 950 days the supernova brightness was consistent with a constant apparent magnitude of m(sub B) = 21.30. Spectra near maximum showed minor variations on the SN Ia theme which grew less conspicuous during the exponential decline. At 270 days the nebular spectrum was composed of Fe and Co lines common to SN Ia. However, by 750 days past maximum light, these lines had shifted in wavelength, and were superposed on a strong blue continuum. The luminosity of SN 1991T at 950 days is more than (9.0 x 10(exp 38)(D/13 Mpc)(2) ergs/s with a rate of decline of less than 0.04 mag per 100 days. We show that this emission is likely to be light that was emitted by SN 1991T near maximum light which has reflected from foreground dust, much like the light echos observed around SN 1987A.

Schmidt, Brian P.↗

NASA NTRS2013

ISECG Global Exploration Roadmap: A Stepwise Approach to Deep Space Exploration

In 2011, ISECG released the Global Exploration Roadmap (GER), advancing the "Global Exploration Strategy: The Framework for Coordination" by articulating the perspectives of participating agencies on exploration goals and objectives, mission scenarios, and coordination of exploration preparatory activities. The GER featured a stepwise development and demonstration of capabilities ultimately required for human exploration of Mars. In 2013 the GER was updated to reflect the ongoing evolution of agency's exploration policies and plans, informed by individual agency and coordinated analysis activities that are relevant to various elements of the GER framework as well as coordinated stakeholder engagement activities. For this release of version 2 of the GER in the mid 2013 timeframe, a modified mission scenario is presented, more firmly reflecting the importance of a stepwise evolution of critical capabilities provided by multiple partners necessary for executing increasingly complex missions to multiple destinations and leading to human exploration of Mars. This paper will describe the updated mission scenario, the changes since the release of version 1, the mission themes incorporated into the scenario, and risk reduction for Mars missions provided by exploration at various destinations.

Martinez, Roland↗

NASA NTRS2014

NASA Space Launch System Operations Outlook

The National Aeronautics and Space Administration's (NASA) Space Launch System (SLS) Program, managed at the Marshall Space Flight Center (MSFC), is working with the Ground Systems Development and Operations (GSDO) Program, based at the Kennedy Space Center (KSC), to deliver a new safe, affordable, and sustainable capability for human and scientific exploration beyond Earth's orbit (BEO). Larger than the Saturn V Moon rocket, SLS will provide 10 percent more thrust at liftoff in its initial 70 metric ton (t) configuration and 20 percent more in its evolved 130-t configuration. The primary mission of the SLS rocket will be to launch astronauts to deep space destinations in the Orion Multi-Purpose Crew Vehicle (MPCV), also in development and managed by the Johnson Space Center. Several high-priority science missions also may benefit from the increased payload volume and reduced trip times offered by this powerful, versatile rocket. Reducing the life-cycle costs for NASA's space transportation flagship will maximize the exploration and scientific discovery returned from the taxpayer's investment. To that end, decisions made during development of SLS and associated systems will impact the nation's space exploration capabilities for decades. This paper will provide an update to the operations strategy presented at SpaceOps 2012. It will focus on: 1) Preparations to streamline the processing flow and infrastructure needed to produce and launch the world's largest rocket (i.e., through incorporation and modification of proven, heritage systems into the vehicle and ground systems); 2) Implementation of a lean approach to reachback support of hardware manufacturing, green-run testing, and launch site processing and activities; and 3) Partnering between the vehicle design and operations communities on state-ofthe- art predictive operations analysis techniques. An example of innovation is testing the integrated vehicle at the processing facility in parallel, rather than sequentially, saving both time and money. These themes are accomplished under the context of a new cross-program integration model that emphasizes peer-to-peer accountability and collaboration towards a common, shared goal. Utilizing the lessons learned through 50 years of human space flight experience, SLS is assigning the right number of people from appropriate backgrounds, providing them the right tools, and exercising the right processes for the job. The result will be a powerful, versatile, and capable heavy-lift, human-rated asset for the future human and scientific exploration of space.

Hefner, William Keith↗

NASA NTRS2008

Workshop Report on Ares V Solar System Science

The workshop blended three major themes: (1) How can elements of the Constellation program, and specifically, the planned Ares-V heavy-launch vehicle, benefit the planetary community by enabling the launch of large planetary payloads that cannot be launched on existing vehicles, and how can the capabilities of an Ares V allow the planetary community to redesign missions to achieve lower risk, and perhaps lower cost on these missions? (2) What are some of the planetary missions that either can be significantly enhanced or enabled by an Ares-V launch vehicle? What constraints do these mission concepts place on the payload environment of the Ares V? (3) Technology challenges that need to be addressed for launching large planetary payloads. Presentations varied in length from 15-40 minutes. Ample time was provided for discussion.

Langhoff, Stephanie↗

NASA NTRS1995

Proceedings of the Fourth International Mobile Satellite Conference (IMSC 1995)

The theme to the 1995 International Mobile Satellite Conference was 'Mobile Satcom Comes of Age'. The sessions included Modulation, Coding, and Multiple Access; Hybrid Networks - 1; Spacecraft Technology; propagation; Applications and Experiments - 1; Advanced System Concepts and Analysis; Aeronautical Mobile Satellite Communications; Mobile Terminal Antennas; Mobile Terminal Technology; Current and Planned Systems; Direct Broadcast Satellite; The Use of CDMA for LEO and ICO Mobile Satellite Systems; Hybrid Networks - 2; and Applications and Experiments - 2.

J R Rigley↗

NASA NTRS2007

GeoEye(TradeMark) Corporate Overview

This viewgraph presentation gives a corporate overview of GeoEye, the world's largest commercial remote sensing company. The contents include: 1) About GeoEye; 2) GeoEye Mission; 3) The Company; 4) Com,pany Summary; 5) U.S. Government Commitment; 6) GeoEye Constellation; 7) Other Imaging Resources; 8) OrbView-3 & OrbView-2; 9) OrbView-3 System Architecture; 10) OrbView-3; 11) OrbView-2; 12) IKONOS; 13) Largest Image Archive in the World; 14) GeoEye-1; 15) Best-In-Class Development Team; 16) Highest Performance Available in the Commercial Market; and 17) Key Themes

Jones, Dennis↗

NASA NTRS2014

NASA Space Launch System Operations Outlook

The National Aeronautics and Space Administration's (NASA) Space Launch System (SLS) Program, managed at the Marshall Space Flight Center (MSFC), is working with the Ground Systems Development and Operations (GSDO) Program, based at the Kennedy Space Center (KSC), to deliver a new safe, affordable, and sustainable capability for human and scientific exploration beyond Earth's orbit (BEO). Larger than the Saturn V Moon rocket, SLS will provide 10 percent more thrust at liftoff in its initial 70 metric ton (t) configuration and 20 percent more in its evolved 130-t configuration. The primary mission of the SLS rocket will be to launch astronauts to deep space destinations in the Orion Multi- Purpose Crew Vehicle (MPCV), also in development and managed by the Johnson Space Center. Several high-priority science missions also may benefit from the increased payload volume and reduced trip times offered by this powerful, versatile rocket. Reducing the lifecycle costs for NASA's space transportation flagship will maximize the exploration and scientific discovery returned from the taxpayer's investment. To that end, decisions made during development of SLS and associated systems will impact the nation's space exploration capabilities for decades. This paper will provide an update to the operations strategy presented at SpaceOps 2012. It will focus on: 1) Preparations to streamline the processing flow and infrastructure needed to produce and launch the world's largest rocket (i.e., through incorporation and modification of proven, heritage systems into the vehicle and ground systems); 2) Implementation of a lean approach to reach-back support of hardware manufacturing, green-run testing, and launch site processing and activities; and 3) Partnering between the vehicle design and operations communities on state-of-the-art predictive operations analysis techniques. An example of innovation is testing the integrated vehicle at the processing facility in parallel, rather than sequentially, saving both time and money. These themes are accomplished under the context of a new cross-program integration model that emphasizes peer-to-peer accountability and collaboration towards a common, shared goal. Utilizing the lessons learned through 50 years of human space flight experience, SLS is assigning the right number of people from appropriate backgrounds, providing them the right tools, and exercising the right processes for the job. The result will be a powerful, versatile, and capable heavy-lift, human-rated asset for the future human and scientific exploration of space.

Hefner, William Keith↗

NASA NTRS1992

VIEWCACHE: An incremental pointer-base access method for distributed databases. Part 1: The universal index system design document. Part 2: The universal index system low-level design document. Part 3: User's guide. Part 4: Reference manual. Part 5: UIMS test suite

The goal of the Universal Index System (UIS), is to provide an easy-to-use and reliable interface to many different kinds of database systems. The impetus for this system was to simplify database index management for users, thus encouraging the use of indexes. As the idea grew into an actual system design, the concept of increasing database performance by facilitating the use of time-saving techniques at the user level became a theme for the project. This Final Report describes the Design, the Implementation of UIS, and its Language Interfaces. It also includes the User's Guide and the Reference Manual.

Kelley, Steve↗

NASA NTRS2009

Geological Map of the Fredegonde (V-57) Quadrangle, Venus

The area of V-57, the Fredegonde quadrangle (50-75degS, 60-120degE, Fig.1), is located within the eastern portion of Lada Terra within the topographic province of midlands (0-2 km above MPR [1,2]). Midlands form the most abundant portion of the surface of Venus and are characterized by diverse sets of units and structures [3-11]. The area of the Fredegonde quadrangle is in contact with the elevated portion of Lada Terra to the W and with the lowland of Aino Planitia to the NE. The transitions of the mid-lands to the lowlands and highlands are, thus, one of the main themes of the geology within the V-57 quadrangle. The character of the transitions and distribution and sequence of units/structures in the midlands are crucially important in understanding the time and modes of formation of this topographic province. The most prominent features in the map area are linear deformational zones consisting of swarms of grooves and graben and large coronae. The zones characterize the central and NW portions of the map area and represent regionally important, broad (up to 100s km wide) ridges that are 100s m high. Relatively small (100s km across, 100s m deep) equidimensional basins occur between the corona-groove-chains in the west and border the central chain from the east. Here we describe units that make up the surface within the V-57 quadrangle and present a summary of our geological map that shows the areal distribution of the major groups of units.

Ivanov, M. A.↗

NASA NTRS2010

How Cold are the Floors of Lunar Polar Shadowed Craters?

Almost five decades ago Watson, et al, [1] speculated that molecules of volatile species might accumulate within the cryogenic environments of permanently shadowed polar craters. The subject was largely a scientific curiosity until recently. In the mid-1980's, people began to seriously discuss the feasibility of long-term or permanent human settlement of the Moon. Given that the Moon was known be missing the compounds need to support life and that importing volatiles from Earth is prohibitively expensive, lunar colonists were pictured as processing the putative polar volatiles. A bistatic radar experiment performed with the Clementine spacecraft was interpreted to suggest the presence of large quantities of ice at some polar locations. [2] The neutron spectrometer aboard the Lunar Prospector spacecraft reported high concentrations of hydrogen in the polar regolith, [3] and some interpretations of the data set pointed to very high concentrations in permanently shadowed craters. The reformulation of civilian space policy in 2004, known as the Vision for Space Exploration, emphasized lunar exploration with eye toward development of economic returns from cislunar space and long-tern human presence on the Moon. The theme of finding lunar resources was an impetus for the inclusion of the Diviner Lunar Radiometer Experiment on the Lunar Reconnaissance Orbiter. Preliminary results from Diviner report an unexpectedly low temperature down to 35K in the depths of some craters. [4]

Mendell, Wendell W.↗

DOE OSTI2024

Hydropower Black Start: A Guidebook for Retrofitting Grid Dependent Hydropower

Not all United States (US) hydropower plants were designed to provide black start, but they are increasingly needed to uphold resilience in the evolving electric grid. This guidance is designed to help understand the minimal retrofits required for grid dependent hydropower (GDH) plants behind the point of interconnection (POI). For distribution connected hydropower plants or those with dedicated cranking paths, such upgrades can be sufficient for the plant to provide black start. For others, more coordination with the transmission system operator will be needed. This guidebook answers a number of questions relevant to retrofitting hydropower plants with black start capabilities. For example, the guidebook answers: • How flexible do the wicket gate controls need to be? • Who needs to do hydro governor model validation, why, and how? • How robust and flexible do the excitation and AVR controls need to be? • What protection settings need to be adjusted? • What relay(s) will need to be bypassed or overridden and at what risk? • What is the electrical energy demand of the station load or auxiliary power systems? • What should the strategy to energize transformer(s) along cranking path to address inrush currents be? • How should the critical load restoration be sequenced? In addition to outlining the specifications that hydropower plants need to meet for each component to be able to perform black start, this guidebook provides a set of case studies for specific upgrades needed at actual plants. Between the case studies of plants that have already performed black start retrofits and the examples of how this guidebook can be applied to scope future retrofits, five key themes have been identified for retrofit needs. 1. Protection needs “black start” mode: hydropower plants that are not designed with black start capabilities will have protections that prevent them from interconnecting to a “dead bus.” These protections will need to be overridden in every retrofit case and a separate black start mode should be established so that operators can safely switch between black start and grid connected modes, minimizing the risk to the plant. 2. Wicket gates need modern controls: digital governors accelerate the parameter tuning process and gate position sensors improve controllability, so plants with mechanical governors should be upgraded. Furthermore, a black start and islanding mode should be established for controls to maximize plant performance. 3. Robust excitation support: the DC system or excitation generator needs to be reliable enough to form and sustain the rotor electromagnetic field. These systems are typically undersized in plants that were not designed for black start, so they will need to be upgraded. 4. Turbine-governor model validation and operator training: validation of a standard hydro governor model is needed to characterize the dynamic response (i.e., inertial and primary frequency response) of the GDH. This is required for control development and old hydropower plants often have outdated or incorrect models. Operator training is also typically required to ensure the hardware retrofits are utilized correctly during the black start process. 5. Transformer and cranking path energization: any upgradation and control adjustment in front of the POI will depend upon the existing interconnection. Coordination with the transmission or distribution operator may be required.

13 HYDRO ENERGY↗

NASA NTRS2011

Impact of Aerosols on Convective Clouds and Precipitation

Aerosols are a critical factor in the atmospheric hydrological cycle and radiation budget. As a major reason for clouds to form and a significant attenuator of solar radiation, aerosols affect climate in several ways. Current research suggests that aerosol effects on clouds could further extend to precipitation, both through the formation of cloud particles and by exerting persistent radiative forcing on the climate system that disturbs dynamics. However, the various mechanisms behind these effects, in particular the ones connected to precipitation, are not yet well understood. The atmospheric and climate communities have long been working to gain a better grasp of these critical effects and hence to reduce the significant uncertainties in climate prediction resulting from such a lack of adequate knowledge. The central theme of this paper is to review past efforts and summarize our current understanding of the effect of aerosols on precipitation processes from theoretical analysis of microphysics, observational evidence, and a range of numerical model simulations. In addition, the discrepancy between results simulated by models, as well as that between simulations and observations will be presented. Specifically, this paper will address the following topics: (1) fundamental theories of aerosol effects on microphysics and precipitation processes, (2) observational evidence of the effect of aerosols on precipitation processes, (3) signatures of the aerosol impact on precipitation from large-scale analyses, (4) results from cloud-resolving model simulations, and (5) results from large-scale numerical model simulations. Finally, several future research directions on aerosol - precipitation interactions are suggested.

Tao, Wei-Kuo↗

NASA NTRS1995

Oxidants and oxidation in the Earth's atmosphere

The 1994 BOC Priestley Conference was held at Bucknell University in Lewisburg, Pennsylvania, from June 24 through June 27, 1994. This conference, managed by the American Chemical Society (ACS), was a joint celebration with the Royal Society of Chemistry (RSC) commemorating Joseph Priestley's arrival in the U.S. and his discovery of oxygen. The basic theme of the conference was 'Oxidants and Oxidation in the Earth's Atmosphere,' with a keynote lecture on the history of ozone. A distinguished group of U.S. and international atmospheric chemists addressed the issues dominating current research and policy agendas. Topics crucial to the atmospheric chemistry of global change and local and regional air pollution were discussed. The program for the conference included four technical sessions on the following topics: (1) Oxidative Fate of Atmospheric Pollutants; (2) Photochemical Smog and Ozone; (3) Stratospheric Ozone; and (4) Global Tropospheric Ozone.

Source record↗

NASA NTRS2020

The Integration of Life Sciences in Space: Astrobiology and Space Biology Virtual Workshops Report

A series of virtual workshops was held during June 2020 to seek ways to integrate the efforts of the astrobiology and space biology research communities under a broad umbrella of space life sciences. The overall goal was to help inspire creativity that will guide us towards new synergistic ideas complementing these existing disciplines that are of such importance to NASA. Workshop participants aspired to: (1) Exploit synergies across the biological sciences at NASA, (2) Foster research, enabling technology, and mission concepts that support commonalities in space biology, astrobiology, synthetic biology, planetary protection, and relevant human health, performance, and habitation concerns, (3) Envision the development of an “Arc of Biology in Space” to encompass this multi-faceted joint research community. The focused objective of the workshop series was to explore and demonstrate how the integration of astrobiology and space biology could be achieved, identify strengths and weaknesses in the current state of the art, and recognize where our greatest challenges lay. Specifically, we seek to: (1) Establish a scientific framework for an integrated life sciences effort, (2) Pioneer discovery by creating unique opportunities in the fundamental biological sciences, (3) Explore novel combinations of existing technologies across the relevant disciplines, (4) Invent new technologies and applications in space life sciences, and (5) Creatively increase access to spaceflight, emerging and novel technologies, Earth analogs, and simulated natural and spaceflight environments. The community aims for a broad arc of biological competence in the context of space and planetary science, spaceflight, and habitation. We will present dominant themes and innovative ideas that resulted from this interchange of relevant communities.

astrobiology↗

NASA NTRSDate not supplied

The Integration of Life Sciences in Space: Astrobiology and Space Biology Virtual Workshops Report

astrobiology↗

NASA NTRS1991

Technology for the Future: In-Space Technology Experiments Program, part 2

The purpose of the Office of Aeronautics and Space Technology (OAST) In-Space Technology Experiments Program In-STEP 1988 Workshop was to identify and prioritize technologies that are critical for future national space programs and require validation in the space environment, and review current NASA (In-Reach) and industry/ university (Out-Reach) experiments. A prioritized list of the critical technology needs was developed for the following eight disciplines: structures; environmental effects; power systems and thermal management; fluid management and propulsion systems; automation and robotics; sensors and information systems; in-space systems; and humans in space. This is part two of two parts and contains the critical technology presentations for the eight theme elements and a summary listing of critical space technology needs for each theme.

Breckenridge, Roger A.↗