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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Developing low-cost rechargeable batteries: beyond traditional layered oxide cathodes for Li-ion and beyond Li-ion batteries

Here, the rising demand for energy storage systems, driven by the rapid adoption of electric vehicles and the global shift toward renewable energy, necessitates continuous efforts to lower the cost of current lithium-ion batteries (LIBs) and enhance the sustainability of existing battery chemistries. This feature article examines the key challenges associated with Ni- and Co-containing LIB cathodes and compares advancements in cathode development for non-traditional Li-ion and beyond Li-ion chemistries. First, a review of earth-abundant element containing disordered rock-salt cathodes is presented, with a discussion of key strategies such as compositional tuning and carbon coating to improve their electrochemical performance. Hurdles in developing oxide-based cathodes for Na- and K-ion batteries are also highlighted, followed by an in-depth overview of polyanion and Prussian blue cathodes for Na- and K-ion systems. Overall, this article provides a systematic perspective on the design of earth-abundant, low-cost, and sustainable cathode materials for both LIB and beyond LIB technologies.

Lohani, Harshita [Lawrence Berkeley National Labor↗

End-to-End Optimization for Battery Materials and Molecules by Combining Graph Neural Networks and Reinforcement Learning

The National Renewable Energy Laboratory (NREL), together with the Colorado School of Mines (CSM) and Colorado State University (CSU), has developed a machine learning-enhanced approach to the design of new battery materials. Currently, such materials are designed in part via numerous expensive high-fidelity computational simulations that predict the performance of a given composition. Even with computational screening tools, the vast landscape of possible molecular or crystal structures exceeds current and future computational capacity. Improving the efficiency by which new materials can be optimized will therefore disrupt the cost, risk, and time required to bring new energy solutions to the marketplace. Predicting the properties of an organic molecule or periodic crystalline material given its structure has grown increasingly common. These approaches leverage large-scale computational and experimental databases and ML approaches such as graph neural networks. The inverse design problem of finding a material that possesses desired properties is substantially more challenging, since enumerating all valid material structures is not feasible. In this project, we leveraged recent success in reinforcement learning to efficiently navigate this high-dimensional search space. Just as algorithms can find the optimal chess moves from nearly limitless options, we train an approach to evolve a simple starting structure into a complex structure that possess the desired properties. Our solution has been demonstrated by applying it to two related design application tasks for short- and long-term energy storage, respectively: (1) the design of solid-state ion conductors and (2) the design of organic redox-active materials. The project has resulted an open-source software library for material design, documented examples of applying the library to both organic and inorganic material optimization, and peer-reviewed publications detailing the data, computational models, and resulting candidate materials.

25 ENERGY STORAGE↗

Comparing the economic performance of ice storage and batteries for buildings with on-site PV through model predictive control and optimal sizing

Integrating renewable energy and energy storage systems provides a way of operating the electrical grid system more energy efficiently and stably. Thermal storage and batteries are the most common devices for integration. However, it is not clear which integrated storage system performs better in terms of overall economics. Ice storage has low initial and maintenance costs, but there is an efficiency penalty for charging of storage and it can only shift electrical loads associated with building cooling requirements. A battery's round-trip efficiency, on the contrary, is quite consistent and batteries can be used to shift both HVAC and non-HVAC loads. However, batteries have greater initial costs and a shorter life. Finally, this research presents a tool, using model predictive control and optimal sizing, and provides a case study for comparing life-cycle economics of battery and ice storage systems for commercial buildings that have chillers for cooling and an on-site photovoltaic system.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Electric vehicle batteries alone could satisfy short-term grid storage demand by as early as 2030

The energy transition will require a rapid deployment of renewable energy (RE) and electric vehicles (EVs) where other transit modes are unavailable. EV batteries could complement RE generation by providing short-term grid services. However, estimating the market opportunity requires an understanding of many socio-technical parameters and constraints. We quantify the global EV battery capacity available for grid storage using an integrated model incorporating future EV battery deployment, battery degradation, and market participation. We include both in-use and end-of-vehicle-life use phases and find a technical capacity of 32–62 terawatt-hours by 2050. Low participation rates of 12%–43% are needed to provide short-term grid storage demand globally. Participation rates fall below 10% if half of EV batteries at end-of-vehicle-life are used as stationary storage. Short-term grid storage demand could be met as early as 2030 across most regions. Our estimates are generally conservative and offer a lower bound of future opportunities.

25 ENERGY STORAGE↗

Quantifying policy gaps for achieving the net-zero GHG emissions target in the U.S. light-duty vehicle market through electrification

The U.S. light-duty vehicle (LDV) industry, a major greenhouse gas (GHG) emitting sector, is embracing decarbonization. Considering only electrification pathways, this study uses publicly-available tools – MA3T and VISION on vehicle market penetration, fleet accounting and life-cycle analysis to quantify the policy gaps for LDVs to achieve the net-zero GHG emissions target in nine vehicle penetration cases under two electricity mix scenarios, including the U.S. administration's decarbonization strategy – 100% clean electricity by 2035. The MA3T model is a multinomial discrete choice model for market share projection by vehicle technology, and the VISION is a vehicle stocks and GHG emissions projection model by using vehicle and travel characteristics. This study projects the impacts of technology and policy enforcement on shaping the dynamics and decarbonization of the LDV market. Additionally, achieving the expected improvement of battery technology and charging infrastructure is critical but can only reduce the 2050 GHG emissions to 48–54% of the 2020 level under the electricity renewable mix scenario. It is almost impossible to achieve a 100% battery electric vehicle stock by 2050 and the 2050 net-zero target in the LDV industry unless ban of internal combustion engine technology is implemented starting in 2035 and under the 2035 100% clean electricity scenario. These extreme conditions also sacrifice most from the consumer welfare perspective. A greater policy forcing intensity accelerates plug-in electric vehicle penetration, while with declining marginal effect and reduced consumer welfare. Among the investigated policy scenarios, the policy forcing intensity equivalent to a fuel tax of $1–2 per gasoline gallon reduces the most GHG emissions while keeping a positive consumer welfare.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Grid-Constrained Electric Vehicle Fast Charging Sites: Battery-Buffered Options

This case study summarizes recent Joint Office of Energy and Transportation technical assistance work performed by the National Renewable Energy Laboratory which involved helping a state department of transportation analyze the feasibility of a battery energy storage system solution at a grid-constrained EV charging location.

ADVANCED PROPULSION SYSTEMS↗

Storage Futures Study - Distributed Solar and Storage Outlook: Methodology and Scenarios

This presentation discusses the fourth report in NREL’s Storage Futures Study (SFS) publications. The SFS is a multiyear research project that explores the role and impact of energy storage in the evolution and operation of the U.S. power sector. The SFS is designed to examine the potential impact of energy storage technology advancement on the deployment of utility-scale storage and the adoption of distributed storage, and the implications for future power system infrastructure investment and operations. This report describes the expanded capabilities of the Distributed Generation Market Demand (dGen) model to analyze the economics of distributed (behind-the-meter) PV paired with battery storage systems and presents projections of adoption for the contiguous United States out to 2050 under a range of scenarios. These scenarios use technology cost and performance assumptions consistent with the National Renewable Energy Laboratory’s 2020 Standard Scenarios paired with updated battery cost projections and existing policies. Additional scenarios evaluate sensitivities to the value of backup power and DER compensation mechanisms, collectively characterizing the future potential for behind-the-meter storage and identifying key drivers of adoption. Adoption projections of DER and battery storage at high spatial and temporal resolution, as presented in this report, can enable informed planning of technical infrastructure that can help planners capture the benefits and mitigate challenges to support the ongoing trend toward distributed electricity generation.

backup power↗

Technical Evaluation of Battery Electric Bus Potential in Mexico City and León, Mexico

The National Renewable Energy Laboratory (NREL) in partnership with USAID Mexico's Low Emissions Development (MLED) II program explored the technical feasibility of transit bus electrification in Mexico City (CDMX) and León. NREL and USAID engaged CDMX and León transit agencies to understand routes of interest and existing fleet fueling and bus specifications.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Review on Preprocessing Strategies, Deactivation, Thermal Safety, and Future Perspectives in Lithium-Ion Battery Recycling

The rapid growth in the use of lithium-ion batteries (LIBs) in electric vehicles, consumer electronics, and renewable energy storage has made effective end-of-life management essential. Recycling LIBs is critical not only for resource recovery and environmental protection but also for ensuring safety and economic viability. This review focuses on the preprocessing technologies that precede typical recovery processes, including disassembly, sorting, discharging, electrolyte removal, dismantling, thermal treatment, separation, and flotation. These steps play a foundational role in determining the efficiency, safety, and environmental impact of LIB recycling. LIBs pose substantial fire and explosion risks due to residual charge, flammable electrolytes, and reactive materials. The conditions and successive progression of the exothermic reactions which lead to thermal runaway has been discussed. It also explores secure deactivation techniques such as external circuit discharge, saline immersion, and thermomechanical methods, alongside fire prevention strategies including the use of flame retardants, elimination of oxidants, and reduction of heat generation and accumulation. Challenges and future directions are outlined, highlighting the need for standardized designs, automation, and safer, more sustainable recycling infrastructure. Furthermore, this review is distinguished by its focused analysis of preprocessing and deactivation steps, with particular attention to the thermal safety engineering aspects of LIB recycling.

Battery deactivation↗

Aqueous titanium redox flow batteries—State-of-the-art and future potential

Market-driven deployment of inexpensive (but intermittent) renewable energy sources, such as wind and solar, in the electric power grid necessitates grid-stabilization through energy storage systems Redox flow batteries (RFBs), with their rated power and energy decoupled (resulting in a sub-linear scaling of cost), are an inexpensive solution for the efficient electrochemical storage of large amounts of electrical energy. Titanium-based RFBs, first developed by NASA in the 1970s, are an interesting albeit less examined chemistry and are the focus of the present review. Ti, constituting 0.6% of the Earth’s crust and an ingredient in inexpensive white paints, is amongst the few elements (V and Mn being some others) which exhibit multiple soluble oxidation states in aqueous electrolytes. Further, the very high (approaching 10 M) solubility of Ti in low pH solutions suggests the possibility of developing exceptionally high energy density aqueous Redox Flow Batteries systems. With these advantages in mind, we present the state-of the-art in Ti-RFBs with a focus on Ti/Mn, Ti/Fe and Ti/Ce couples and systems that use Ti as an additive (such as Ti/V/Mn). The inherent advantages of inexpensive Ti actives and relatively high energy density is contrasted with potential side-reactions resulting in reduced energy efficiency. Technological pathways are presented with a view to overcoming critical bottlenecks and a vision is presented for the future development of Ti-RFBs.

25 ENERGY STORAGE↗

Energy Northwest - Horn Rapids Solar and Storage: An Assessment of Battery Technical Performance

Chartered in 1957 as a joint action agency of the state, Energy Northwest (ENW) is a consortium of 27 public utility districts and municipalities across Washington state. ENW takes advantage of economies of scale and shared services to help utilities run their operations more efficiently and at lower cost, to the benefit of more than 1.5 million customers. ENW develops, owns, and operates a diverse mix of electricity generating resources, including hydro, solar, and wind projects – and the Northwest’s only active nuclear energy facility. These projects provide enough reliable, affordable, and environmentally responsible energy to power more than a million homes each year, and that carbon-free electricity is provided at the cost of generation. The agency continually explores new generation projects to meet its members’ needs. In 2017, as part of the second round of funding from the Washington state Clean Energy Fund, the Washington State Department of Commerce granted up to $3 million in matching funds to develop an estimated $6.5 million project that deployed a 4-MW, 20-acre solar generating array of photovoltaic (PV) panels coupled with a 1 MW/5.5 MWh lithium-iron-phosphate battery energy storage system (BESS) in Richland, Washington. The combination of PV and BESS will provide a predictable, renewable generating source and will also serve as a training ground for solar and battery technicians throughout the nation. The City of Richland will purchase the power from the project and utilize the benefits of the energy storage. The project provides Washington state with its first opportunity to integrate a large-scale solar and storage facility into its clean mix of hydro, nuclear, and wind resources. This first-of-its-kind facility combines solar generation with battery storage and technician training. In 2019, Pacific Northwest National Laboratory (PNNL) worked with ENW to assess the integrated PV and BESS in representative use cases that could benefit the City of Richland. Between March and May 2022, extensive testing was conducted, and the results were used to assess the technical performance of the BESS subjected to actual field operations. Both reference performance and use case tests were performed: (A) Reference performance tests assess the general technical capabilities of the BESS, such as energy capacity, round-trip efficiency (RTE), ramp rate, and signal tracking capability. These are the first tests performed (baseline), and they are repeated after use case tests (post cycle). A standardized U.S. Department of Energy (DOE) energy storage performance protocol was used to characterize the BESS, including representative duty cycle profiles, test procedure guidance, and calculation guidance for determining key characteristics. (B) Use case tests examine the performance of the BESS for specific use cases using duty cycles developed by PNNL in collaboration with ENW. Five use cases were selected for testing: 1) demand charge reduction, 2) load shaping, 3) transmission charge reduction, 4) Volt-VAR service, and 5) outage mitigation. The use case duty cycles were developed based on utility and site-specific characteristics in addition to the technical characteristics and physical capabilities of the BESS. Use case tests were performed between the baseline and post cycle tests. This report describes the BESS and its components, presents testing and performance analysis results, and shares key insights and lessons learned from this project. Outcomes of the tests and analyses will help ENW understand the performance of the Horn Rapids BESS in its current state and design appropriate operational strategies for this and other BESSs over the long term.

14 SOLAR ENERGY↗

Energy Northwest – Horn Rapids Solar and Storage: A Techno-economic Assessment

In 2017, as part of the second round of funding from the Washington State Clean Energy Fund, the Washington State Department of Commerce granted up to $\$3$ million in matching funds to develop an estimated $6.5 million project that deployed a 4-MW, 20-acre solar generating array of photovoltaic (PV) panels coupled with a 1 MW/4 MWh (nameplate capacity) lithium-iron-phosphate battery energy storage system (BESS) in Richland, Washington. The combination of PV and BESS will provide a predictable, renewable generating source and will also serve as a training ground for solar and battery technicians throughout the nation. This report documents the techno-economic assessment of the integrated system, including the definition of use cases and applications, collection and preparation of data and input parameters, development of modeling and optimization methods, case studies, and analysis results.

14 SOLAR ENERGY↗

The Effect of Clean Energy Generation Targets on the Portfolio of Electric Grid Generation Technologies

A least-cost generation and transmission expansion planning model is used to optimize the U.S. generation portfolio in 2030 under a range of Clean Energy Generation Target (CEGT) policy goals. As reference cases for comparison, the model is used to optimize the generation portfolio for the future electric grid with and without the Investment and Production Tax Credits (ITC and PTC). Next, the model is used to optimize the generation portfolio with a CEGT ranging from 10% to 70%. The results show that due to the ITC and PTC extensions by the 2022 Inflation Reduction Act, there is little additional investment in renewable energy generation assets at low CEGT levels. Significant additional installations of both renewable energy generation and energy storage systems – both batteries and pumped storage hydro – become important at CEGT levels above approximately 30%.

Aldeman, Matthew↗

High-Penetration Microgrids Providing Grid Stability Using Frequency Watt Control

The U.S. grid is rapidly transitioning towards utilizing inverter-based renewable energy resources such as solar, wind, and batteries, reducing the carbon emission footprint. Inverter-based microgrid control architectures remain a critical focus to address power system stability issues in future high penetration markets lacking spinning generation assets. Idaho National Laboratory (INL) is researching an active layered inverter based frequency-Watt control scheme that provides distribution level stability in high-penetration markets where grid inertia is lacking. Hardware in the loop case study was implemented using INL’s Microgrid Testbed to combat scalable frequency deviations ranging from 60 Hz down to 50 Hz initialized by a hydropower model implementing step loads using a 540-kW grid emulator. Our research findings demonstrate the importance of distribution level, inverter-based active frequency-Watt controls utilizing a battery energy storage system (BESS) to provide adequate frequency support at the point of common coupling without major power infrastructure upgrades.

14 SOLAR ENERGY↗

Enhancing Power Resilience for Remote Communities: A Comprehensive Renewable Energy Solution for Itbayat Island

The island of Itbayat, Philippines, faces significant challenges in maintaining a reliable and resilient power supply due to its current reliance on a vulnerable power distribution system managed by a local electric cooperative. The existing infrastructure, which includes diesel generators and a radial network configuration with some above-ground lines, is highly susceptible to frequent typhoons and adverse weather conditions. These factors, combined with inadequate staffing and high operational costs, result in frequent power outages that disrupt daily life and hinder economic development. This white paper proposes a comprehensive solution to enhance the resilience and reliability of Itbayat's power system by integrating renewable energy sources, specifically solar photovoltaic (PV) systems, battery storage, and a microgrid controller. The proposed solution aims to reduce dependency on diesel fuel, optimize energy use, and provide a sustainable and robust power supply for the island. Key components of the solution include: 1. Solar PV Installation: Deploying solar PV panels to harness abundant solar energy, reducing reliance on diesel fuel. 2. Battery Storage Systems: Installing battery storage to store excess solar energy and ensure a continuous power supply during low solar generation periods. 3. Microgrid Controller: Implementing a microgrid controller to manage and optimize the integration of solar PV, battery storage, and existing diesel generators. The proposed solution addresses several critical issues, including system vulnerability, generator dependency, and operational inefficiencies. By adopting this innovative approach, Itbayat Island can achieve a more resilient, efficient, and sustainable energy infrastructure, ensuring a stable power supply for its residents and enhancing overall energy security.

14 SOLAR ENERGY↗

EVSE Cybersecurity and Resilience

Consequence-driven Cybersecurity Analysis for Extreme Fast Charging Electric Vehicle Infrastructure Electric vehicle (EV) development and associated charging infrastructure are expected to advance rapidly. Thirty percent of all global vehicle sales may be EVs and hybrid EVs by 2025, and they will rely on increasingly sophisticated strategies for grid integration. Next-generation EV charging infrastructure is expected to include interconnected renewable resources, such as photovoltaic (PV) arrays and battery storage systems, along with grid-edge devices. Although distributed energy resources (DERs) are useful in several ways, such as peak shaving at high demand times and backup supply for added resilience, the integration of vehicle charging and DERs could create more avenues for cyberattack. Physical and/or remote access to EV charging station components, including charge ports, power electronics, controllers, and local generation (e.g., PV and energy storage) could be paths to cause power fluctuations, leading to altered operations at the charging station, escalated privileges to administrative systems, exfiltration of financial information (including personally identifiable information), and reduced grid stability. One compromised EV supply equipment component can open the door to a variety of exploitable vulnerabilities. Cloud computing and mobile application control have the potential to expand the threat surface to non-repudiation and firmware integrity challenges. Vendor clouds have access to hundreds of chargers, and if compromised, can scale the attack surface exponentially. The high power and voltage levels of xFC infrastructure (e.g., 400 kW at 1000- V DC) increase the hazards and ability to impact the grid and vehicles more than lower-power charging systems. Legacy communications systems and protocols could also put EV infrastructure at risk of cyberattacks requiring a robust patch management process. Communications networks link EVs and chargers to several stakeholders - including charging station operators, grid operators, vendors/manufacturers, and aggregators - who have both physical and network access to share information for control, monitoring, and analytics. Information in these networks that is vulnerable to compromise includes the state of charge, charging duration, payment information, electricity price, and load control. Analyzing and prioritizing these interconnections risks could help address cybersecurity related to data leakage and manipulation.

charging↗

High Penetration Microgrids Providing Grid Stability Using Frequency-Watt Control Presentation

The U.S. grid is rapidly transitioning towards utilizing inverter-based renewable energy resources such as solar, wind, and batteries, reducing the carbon emission footprint.Inverter-based microgrid control architectures remain a critical focus to address power system stability issues in future high penetration markets lacking spinning generation assets. Idaho National Laboratory (INL) is researching an active layered inverter based frequency-Watt control scheme that provides distribution level stability in high-penetration markets where grid inertia is lacking. Hardware in the loop case study was implemented using INL’s Microgrid Testbed to combat scalable frequency deviations ranging from 60 Hz down to 50 Hz initialized by a hydropower model implementing step loads using a 540-kW grid emulator. Our research findings demonstrate the importance of distribution level, inverter-based active frequency-Watt controls utilizing a battery energy storage system (BESS) to provide adequate frequency support at the point of common coupling without major power infrastructure upgrades.

13 HYDRO ENERGY↗