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DOE OSTI2020

Quantitative Prediction of Perovskite Stability Using Accelerated Testing and Machine Learning

PV technologies based on hybrid perovskites offer the potential for reducing solar cell costs, but they are particularly vulnerable to degradation by environmental factors such as moisture, oxygen, and illumination. Commercialization will require not only stable materials and device architectures but also accelerated testing protocols and models that can predict degradation from the accelerated testing data. Here, we report results from in situ photoluminescence (PL) and photoconductivity (PC) measurements during perovskite degradation with simultaneous optical transmittance (Tr) measurements or reflected dark field (DF) imaging. From PL, PC, Tr, and DF, we determine (respectively) the steady-state quasi-Fermi level splitting, the mean effective carrier diffusion length, the extent of conversion of perovskite to higher bandgap degradation products, and the extent of scattering from domains with different orientation or composition, all as a function of time during degradation. Simultaneous measurement of PL-PC-Tr or PL-PC-DF on perovskite absorbers in an environmental chamber over a wide range of humidity, oxygen, temperature, and illumination levels yields a rich data set. We use machine learning to develop a model that accurately predicts (within 10%) the time for the diffusion length to decrease to 85% of its initial value. The model takes the environmental conditions and the first few measurements from the PL-PC-Tr or PL-PC-DF experiment as input. Thus, the model provides a framework to interpret the results of accelerated testing of absorber materials. One of the dominant features in the model of degradation for CH 3 NH 3 PbI 3 is the initial rate at which transmittance increase. For devices with opaque contacts, the pixel-averaged rate of change of the intensity in dark-field images can be used in place of transmittance. Results are also presented on full PV devices with in-situ current-voltage (JV) measurements. Here, the data from simultaneous PL-DF-JV under environmental stresses reveal intimate connection between degradation and shunts and provide a framework to extend accelerated testing to devices. Further, the presentation reveals underlying universal behavior in degradation pathways over a broad range of environmental stresses and perovskite compositions.

14 SOLAR ENERGY↗

NASA NTRS2016

Preferential Heating of Oxygen 5+ Ions by Finite-Amplitude Oblique Alfven Waves

Minor ions in the fast solar wind are known to have higher temperatures and to flow faster than protons in the interplanetary space. In this study we combine previous research on parametric instability theory and 2.5D hybrid simulations to study the onset of preferential heating of Oxygen 5+ ions by large-scale finite-amplitude Alfven waves in the collisionless fast solar wind. We consider initially non-drifting isotropic multi-species plasma, consisting of isothermal massless fluid electrons, kinetic protons and kinetic Oxygen 5+ ions. The external energy source for the plasma heating and energization are oblique monochromatic Alfven-cyclotron waves. The waves have been created by rotating the direction of initial parallel pump, which is a solution of the multi-fluid plasma dispersion relation. We consider propagation angles theta less than or equal to 30 deg. The obliquely propagating Alfven pump waves lead to strong diffusion in the ion phase space, resulting in highly anisotropic heavy ion velocity distribution functions and proton beams. We discuss the application of the model to the problems of preferential heating of minor ions in the solar corona and the fast solar wind.

Maneva, Yana G.↗

NASA NTRS1991

High performance etchant for thinning p(+)-InP and its application to p(+)n InP solar cell fabrication

An etchant, namely (o-H3PO4)u: (HNO3)v: (H2O2)t: (H2O)1-(u+v+t) is developed for thinning, after contacting, the p(+) emitter layer of p(+)n InP structures made by thermal diffusion. Varying u, v, and t, reproducible etch rates of 5 to 110 nm/min are obtained. After thinning the 0.6- to 2.5-micron thick p(+) InP layer down to 60-250 nm, specular surfaces are obtained at up to 80 nm/min etch rate. Due to its intrinsic qualities the resisual P-rich oxide after thinning the emitter layer provides surface passivation of p(+) InP surfaces and can also serve as a first-layer AR coating.

Faur, Maria↗

DOE OSTI2019

Carrier lifetimes of >1 μs in Sn-Pb perovskites enable efficient all-perovskite tandem solar cells

All-perovskite–based polycrystalline thin-film tandem solar cells have the potential to deliver efficiencies of >30%. However, the performance of all-perovskite–based tandem devices has been limited by the lack of high-efficiency, low–band gap tin-lead (Sn-Pb) mixed-perovskite solar cells (PSCs). We found that the addition of guanidinium thiocyanate (GuaSCN) resulted in marked improvements in the structural and optoelectronic properties of Sn-Pb mixed, low–band gap (~1.25 electron volt) perovskite films. The films have defect densities that are lower by a factor of 10, leading to carrier lifetimes of greater than 1 microsecond and diffusion lengths of 2.5 micrometers. These improved properties enable our demonstration of >20% efficient low–band gap PSCs. When combined with wider–band gap PSCs, we achieve 25% efficient four-terminal and 23.1% efficient two-terminal all-perovskite–based polycrystalline thin-film tandem solar cells.

14 SOLAR ENERGY↗

DOE OSTI2018

Optimal design of a model energy conversion device

Fuel cells, batteries, and thermochemical and other energy conversion devices involve the transport of a number of (electro-) chemical species through distinct materials so that they can meet and react at specified multi-material interfaces. Therefore, morphology or arrangement of these different materials can be critical in the performance of an energy conversion device. In this paper, we study a model problem motivated by a solar-driven thermochemical conversion device that splits water into hydrogen and oxygen. We formulate the problem as a system of coupled multi-material reaction-diffusion equations where each species diffuses selectively through a given material and where the reaction occurs at multi-material interfaces. In conclusion, we introduce a phase-field formulation of the optimal design problem and numerically study selected examples.

30 DIRECT ENERGY CONVERSION↗

DOE OSTI2019

Transmission Electron Microscopy Study on Microstructure of Degraded CdTe Mini-Modules

In this paper, we employ transmission electron microscopy coupled with energy-dispersive X-ray spectrometry (EDS) to study the structure and chemistry of cadmium telluride (CdTe) thin-film solar cells with different extents of degradation. The studied regions originate from the same photovoltaic mini-module, which was subjected to one-sun light exposure at a temperature of 100 degrees C for 400 h to induce light and heat degradation. EDS maps reveal a discontinuous CdS layer and particles rich in O and S but Te-depleted within the CdTe absorber layer after the light and heat stress. These features could act as enhanced recombination centers, resulting in decreased photovoltaic conversion efficiency. Additionally, the most degraded CdTe sample shows a strong accumulation of Na precisely localized in the discontinuous part of the CdS layer. The local Na concentration is determined to be ~16 at.%. In addition, appreciable Na accumulation is observed at the soda-lime glass/transparent conductive oxide interface in both degraded CdTe solar cells. The microstructure of the baseline CdTe mini-module with no stress was also investigated to demonstrate that the structure difference was caused by the light- and heat-induced degradation, instead of module fabrication. These results highlight the need to control the distribution of Na in fielded CdTe modules to sustain long-term high-power output.

14 SOLAR ENERGY↗

NASA NTRS1973

ERTS-1 anomalous dark patches

The author has identified the following significant results. Through combined use of imagery from ERTS-1 and NOAA-2 satellites was found that when the sun elevation exceeds 55 degrees, the ERTS-1 imagery is subject to considerable contamination by sunlight even though the actual specular point is nearly 300 nautical miles from nadir. Based on sea surface wave slope information, a wind speed of 10 knots will theoretically provide approximately 0.5 percent incident solar reflectance under observed ERTS multispectral scanner detectors. This reflectance nearly doubles under the influence of a 20 knot wind. The most pronounced effect occurs in areas of calm water where anomalous dark patches are observed. Calm water at distances from the specular point found in ERTS scenes will reflect no solar energy to the multispectral scanner, making these regions stand out as dark areas in all bands in an ocean scene otherwise comprosed by a general diffuse sunlight from rougher ocean surfaces. Anomalous dark patches in the outer parts of the glitter zones may explain the unusual appearance of some scenes.

Strong, A. E.↗

NASA NTRS1975

The effect of adiabatic focusing upon charged particle propagation in random magnetic fields

Charged particles propagating along the diverging lines of force of a spatially inhomogeneous guiding field were considered as they are scattered by random fields. Their longitudinal transport is described in terms of the eigenfunctions of a Sturm-Liouville operator incorporating the effect of adiabatic focussing along with that of scattering. The relaxation times and characteristic velocities are graphed and tabulated. The particle density is evaluated as a function of space and time for two different regimes. In the first regime (relatively weak focussing), a diffusive mode of propagation is dominant but coherent modes are also dominant. In the second regime (strong focussing), diffusion does not occur and the propagation is purely coherent. This supercoherent mode corresponds exactly to the so-called scatter-free propagation of kilovolt solar flare electrons. On a larger scale, focussed transport provides an interpretation of many observed characteristics of extragalactic radio sources.

Earl, J. A.↗

NASA NTRS1976

Cosmic-ray transport theory and out-of-the-ecliptic exploration

The reasons for studying cosmic-ray transport theory are summarized and the fundamentally three-dimensional nature of the process is pointed out. It is shown that observations in the solar ecliptic plane cannot unambiguously test transport theories since the solutions to the transport equations depend critically on boundary conditions and variation of parameters such as diffusion tensor out of the ecliptic. Sample calculations (Fokker-Planck coefficient) are shown which illustrate the problem. It is concluded that out-of-the-ecliptic observations are essential to further test transport theory.

Jokipii, J. R.↗

NASA NTRS1976

The scattering of cosmic rays by magnetic bubbles

During large flares, the sun ejects magnetic bubbles which are then convected by the solar wind into the interstellar medium. The bubbles partake of the spherical expansion of the solar wind and grow to spatial scales comparable to the gyroradii of 100- to 1000-GeV cosmic rays. Assuming that most stars leave behind a wake of magnetic bubbles in the interstellar medium and that the rate of bubble production is comparable to the solar rate, 100- to 1000-GeV and possibly higher-energy cosmic rays will be well scattered and have mean free paths consistent with the compound diffusion theory. Particular choices for the scale-length spectrum of bubbles yield mean free paths which depend only weakly on cosmic-ray energy.

Flewelling, R. F.↗

NASA NTRS1978

Diffuse galactic emission

A very large portion of the observed diffuse X-ray intensity below 1 keV is of galactic origin. Observational evidence indicates that the radiation is truly diffuse, is from interstellar gas near 1 million K that is overpressured relative to the nominal interstellar pressure, and is probably from regions close to the solar system.

Kraushaar, W. L.↗

NASA NTRS1980

Comparison of indoor-outdoor thermal performance for the Sunpak evacuated tube liquid collector

Performance data for current Sunpak production collectors is presented. The effects of an improved manifold are seen from the test results. The test results show excellent correlation between the solar simulator derived test results and outdoor test results. Also, because of different incident angle modifiers, the all-day efficiency of this collector with a diffuse reflector is comparable to the performance with the standard shaped specular reflector.

Source record↗

NASA NTRS1979

Tropospheric UV flux calculations and photolysis rates for use with zonally and diurnally averaged models

A computationally fast and efficient method for calculating solar UV fluxes in the troposphere is developed. Calculated fluxes compare favorably with more rigorous multiple scattering results, and qualitatively correct behavior of the direct and diffuse flux components is maintained. In view of the relatively large uncertainties in other aspects of tropospheric photochemical models, the use of approximate UV flux calculations appears warranted. The technique is applied to the calculation of photolysis rates for twelve significant photolytic reactions of nine species.

Matloff, G. L.↗

NASA NTRS1980

Thermal Pollution Mathematical Model: Verification of One-Dimensional Numerical Model at Lake Keowee - Volume 2

A one dimensional model for studying the thermal dynamics of cooling lakes was developed and verified. The model is essentially a set of partial differential equations which are solved by finite difference methods. The model includes the effects of variation of area with depth, surface heating due to solar radiation absorbed at the upper layer, and internal heating due to the transmission of solar radiation to the sub-surface layers. The exchange of mechanical energy between the lake and the atmosphere is included through the coupling of thermal diffusivity and wind speed. The effects of discharge and intake by power plants are also included. The numerical model was calibrated by applying it to Cayuga Lake. The model was then verified through a long term simulation using Lake Keowee data base. The comparison between measured and predicted vertical temperature profiles for the nine years is good. The physical limnology of Lake Keowee is presented through a set of graphical representations of the measured data base.

Lee, S. S.↗

NASA NTRS1981

Recent developments in space-borne zodiacal light photometry

The zodiacal light experiment to be flown aboard the International Solar Polar Mission in 1985 is presented. Overall objectives of the Zodiacal Light/Background Starlight Experiment include the study of the brightness, polarization, and color of the diffuse sky brightness and the determination of the spatial distributions and physical properties of the interplanetary dust as a function of spacecraft position in and out of the ecliptic. To meet these objectives, a multicolor sky-scanning photopolarimeter will be carried on the NASA spacecraft which will provide optimized stray light suppression and a capability for changing the viewing cone angle based on the use of a stepping device. Brightness and polarization measurements will be made for 11 center wavelengths in the UV and visible with 5.6 deg circular and 1.0 sq deg rectangular fields of view.

Schwehm, G. H.↗

NASA NTRS1981

The atmosphere and ionosphere of Jupiter

The thermal structure of the upper atmosphere of Jupiter, the composition of the atmosphere and the strength of mechanical mixing, and sources and sinks of ionization in the Jupiter ionosphere are described from Voyager UV spectrometer, radio, IR, and imaging data. A topside ionospheric temperature of 1300 K was observed, along with an energy equilibrium between the plasma and neutral gas in the upper atmosphere. A composite thermal structure is provided, noting a close similarity to earth conditions at upper levels, and enhanced thermal behavior has been detected between the times of solar minimum and maximum activity. Ammonia photochemistry is examined, and measured concentrations of H2, CH4, C2H6, and C2H2 as a function of height are outlined. Eddy diffusion coefficient calculations are carried out, yielding a highest Ly-alpha intensity of 100 million sq cm/sec. The increased exospheric temperature between 1973 and 1980 is stressed to have no known satisfactory explanation.

Atreya, S. K.↗

NASA NTRS1983

On the penetration of the solar wind into the cometary ionosphere

Questions of interaction between the cometary ionosphere and the solar wind are considered, taking into account present steady-state models of the global flow pattern. The stability of the ionopause and the feasibility of its penetration by the solar wind magnetic field and plasma are found to be central factors in connection with a consideration of the flow patterns. An investigation is conducted regarding a magnetic field penetration of the ionopause. It is concluded that a 'magnetic barrier' is expected to form ahead of the cometary ionopause. The stability of the ionopause is studied in some detail, taking into consideration a four-component fluid (neutrals, ions, protons, and electrons). The present study leads to the conclusion that any deep penetration of the solar wind magnetic field into the cometary ionosphere should be due to the Kelvin-Helmholtz instability of the ionopause, rather than due to the continuous diffusion process recently proposed by Marochnik (1982).

Ershkovich, A. I.↗

NASA NTRS1985

Application of closed-form solutions to a mesh point field in silicon solar cells

A computer simulation method is discussed that provides for equivalent simulation accuracy, but that exhibits significantly lower CPU running time per bias point compared to other techniques. This new method is applied to a mesh point field as is customary in numerical integration (NI) techniques. The assumption of a linear approximation for the dependent variable, which is typically used in the finite difference and finite element NI methods, is not required. Instead, the set of device transport equations is applied to, and the closed-form solutions obtained for, each mesh point. The mesh point field is generated so that the coefficients in the set of transport equations exhibit small changes between adjacent mesh points. Application of this method to high-efficiency silicon solar cells is described; and the method by which Auger recombination, ambipolar considerations, built-in and induced electric fields, bandgap narrowing, carrier confinement, and carrier diffusivities are treated. Bandgap narrowing has been investigated using Fermi-Dirac statistics, and these results show that bandgap narrowing is more pronounced and that it is temperature-dependent in contrast to the results based on Boltzmann statistics.

Lamorte, M. F.↗