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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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3,258 records · Page 93

Operational Correction for the Temperature Dependence of A Class of Hyperspectral Radiometers

The correction for temperature response of optical radiometers implies access to their working temperature (i.e., either the internal or ambient one with the radiometers in thermal equilibrium). With specific reference to a class of widely used hyperspectral radiometers lacking a thermistor to measure the internal temperature, this work investigated the potential for operational corrections relying on the ambient temperature derived from the radiometer dark digital counts. With the objective to keep within approximately 1% the uncertainty for radiometric corrections in the 400–800-nm spectral range, findings showed the applicability of the method for ambient temperatures higher than approximately 30°C. The alternative use of an ambient temperature proxy, determined from the air temperature incremented by a few degrees Celsius, was shown a valid solution to constrain the uncertainty of radiometric corrections to within 1% over the entire 0°–40°C interval.

Giuseppe Zibordi

CFD Simulation of the Dosing Behavior within the Atomic Layer Deposition Feeding System

The effective operation of atomic layer deposition (ALD) feeding system is the premise of realizing specific ALD processes. In the present work, a detailed computational fluid dynamics (CFD) model of the feeding system has been developed and validated, which accounts for the roles of ALD valves and manifolds. A numerical simulation of the compressible fluid flow and heat/mass transfer within the feeding system was conducted. The dosing amounts and the spatiotemporal distributions of the precursors can be accurately predicted using the CFD model, as validated by experimental results. Different precursors, operating conditions, and structures of the feeding system were simulated and analyzed to examine the operating flexibility of the feeding system. The simulation results can be adopted as the upstream boundary conditions for simulations of the ALD process in the reaction chamber. The substrate-scale simulation indicates that the effect of the feeding system on the film deposition is highly related to the surface kinetics of ALD. The present work can serve as a guide for the development and optimization of different ALD-based processes via proper operation and even the design of the feeding system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Heat Flow and Thermal History of the Moon

An analysis was made of current heat flow data and thermal models of lunar evolution which satisfy the diverse information that has accumulated on internal processes.

Ye A Lyubimova

PV Durability at Scale: Assessing Bifacial and TOPCon Field Performance

Recent field performance results of TOPCon and PERC Bifacial modules are presented based on small-scale deployments at NLR, and a selection of 3rd-party residential data. Bifacial PERC degradation rates are a median of -1 % / yr with bifacial TOPCon modules at a similar rate of -1.1 %/yr over the first couple of years. Comparable PERC Monofacial modules have a degradation rate of -0.5%/yr. Some TOPCon modules exhibited an indoor dark metastability effect which requires recovery by light soaking or UV exposure prior to IV curve measurement. Further monitoring is needed to confirm the long-term stability of TOPCon modules.

14 SOLAR ENERGY

A Survey of Lunar Rock Types and Comparison of the Crusts of Earth and Moon

The principal known types of lunar rocks are briefly reviewed, and their chemical relationships discussed. In the suite of low-KREEP highland rocks, Fe/(Fe + Mg) in the normative mafic minerals increases and the albite content of normative plagioclase decreases as the total amount of normative plagioclase increases, the opposite of the trend predicted by the Bowen reaction principle. Lunar highland samples analyzed are uniformly distributed in this sequence, in which normative plagioclase contents range from ~ 40 percent to ~ 100 percent. The distribution of compositions of rocks from terrestrial layered mafic intrusives is substantially different: here the analyses fall in several discrete clusters (anorthositic rocks, norites, granophyres and ferrogabbros, ultramafics), and the chemical trends noted above are not reproduced. It is suggested that the observed trends in lunar highland rocks could be produced by crystal fractionation in a deep global surface magma system if (1) plagioclase tended to float, upon crystallization, and (2) the magma was kept agitated and well mixed (probably by thermal convection) until crystallization was far advanced and relatively little residual liquid was left. When such a system was finally immobilized, the Fe-, Na-rich residual liquid would produce Fe-rich mafic minerals in the upper levels of the system, but could not much alter the composition of abundant calcic plagioclase. Conversely, the same liquid would produce sodic plagioclase deep in the sequence, but could not much alter the composition of abundant magnesian mafic minerals. After the crustal system solidified, but before extensive cooling had developed a thick, strong lithosphere, mantle convection was able to draw portions of the lunar anorthositic crust down into the mantle in a manner analogous to the present-day behavior of the terrestrial mantle and crust. At depth, the crustal material was heated; KREEP-rich norite was extracted by partial melting and erupted at the surface as a lava, analogous to terrestrial andesite eruptions.

John A Wood

Disorder-induced spin-cluster magnetism in a doped kagome spin liquid candidate

The search for new quantum spin liquid materials relies on systems with strong frustration such as spins on an ideal kagome lattice. However, lattice imperfections can have substantial effects which are as yet not well understood. In recent work, the two-dimensional kagome system YCu 3 ⁢(OH) 6 ⁢[(Cl 𝑥 ⁢Br (1−𝑥) ) 3−𝑦 ⁢(OH) 𝑦 ] has emerged as a leading candidate hosting a Dirac spin liquid which appears to survive at least for 𝑥 < 0.4, associated with alternating-bond-hexagon (ABH) disorder. Here in magnetic samples with 𝑥 = 0.58, 𝑦 = 0.1 we report unusual in-plane ferromagnetic canting (FM) of the in-plane antiferromagnet (AFM), with an unusually wide regime of short-ranged order, and propose theoretical models to explain this behavior. First, we show that Kitaev-type exchanges naturally arise on the kagome lattice to second order in the known Dzyaloshinskii-Moriya exchanges, and that these interactions can produce the unusual in-plane FM canting from antichiral AFM. Second, we propose a phenomenological model of weakly FM-canted spin clusters to describe the short-ranged regime and analyze quantum fluctuations in an ABH toy model to show how ABH disorder can stabilize this regime. Here, the combination of experimental observation and theory suggests that kagome-Kitaev interactions and ABH disorder are necessary for describing the magnetic fluctuations in this family of materials, with potential implications for the proposed proximate spin liquid phase.

Seth, Arnab [Georgia Institute of Technology, Atla

Battery performance of the SKYNET 4A spacecraft during the first six years of on station operation

The SKYNET 4A spacecraft is a three-axis stabilized geostationary earth-orbiting military communications satellite which was launched on 1 Jan. 1990 aboard a Titan 3 launch vehicle. The power subsystem is a twin bus, twin battery semi-regulated system and is equipped with one 28-cell, 35 Ampere-hour battery per bus. The cells were manufactured by Gates Aerospace Batteries of Gainesville, FL, and the batteries were built, tested and integrated by British Aerospace Space Systems Ltd. This paper presents a brief survey of the first six years of on-station operation and the operational battery management strategy that has been adopted. Thermal management constraints have led to an unconventional battery operational regime. However, no sign of degradation is evident and the observed spacecraft battery performance remains nominal.

Johnson, P. J.

Chemomechanics in alloy phase stability

We describe a first-principles statistical mechanics method to calculate the free energies of crystalline alloys that depend on temperature, composition, and strain. The approach relies on an extension of the alloy cluster expansion to include an explicit dependence on homogeneous strain in addition to site occupation variables that track the degree of chemical ordering. The method is applied to the Si-Ge binary alloy and is used to calculate free energies that describe phase stability under arbitrary epitaxial constraints. We find that while the incoherent phase diagram (in which coexisting phases are not affected by coherency constraints) hosts a miscibility gap, coherent phase equilibrium predicts ordering and negative enthalpies of mixing. Instead of chemical instability, the chemomechanical free energy exhibits instabilities along directions that couple the composition of the alloy with a volumetric strain order parameter. Furthermore, this has fundamental implications for phase field models of spinodal decomposition as it indicates the importance of gradient energy coefficients that couple gradients in composition with gradients in strain.

Materials Science

Composite Lithium Metal Structure to Mitigate Pulverization and Enable Long‐Life Batteries

In lithium metal batteries, non‐uniform stripping of lithium results in pit formation, which promotes subsequent non‐uniform, dendritic deposition. This viscous cycle leads to pulverization of lithium which promotes cell shorting or capacity degradation, symptoms further exaggerated by high electrode areal loading and lean electrolytes. Here, to address this challenge, a composite lithium metal anode is engineered that contains uniformly distributed, nanometer‐sized carbon particles. This composite lithium is shown to strip more uniformly since the growth of non‐uniform pits is intercepted by the carbon particles. This mechanism is corroborated by a continuum electrochemical model. Subsequent lithium deposition on carbon particles is also found to be more uniform than on the surface with irregular pits. Notably, the pulverization rate of composite lithium is 26 times slower than that of commercial lithium. Moreover, in a Li‐S battery with sulfurized polyacrylonitrile cathode, the use of the composite anode extends the cycle life by three times when the areal capacity is 8 mAh cm −2 . The approach of using an engineered lithium composite structure to address challenges during both stripping and plating can inform future designs of lithium metal anodes for high areal capacity operations.

high areal capacity

Symposium on Thermal Radiation of Solids

The Symposium was intended to provide for presentation and discussion of significant developments in the theory of thermal radiation of solids and in our understanding of the important effects of surfaces and interfaces and of surface imperfections on this radiation, of the effects of the space environment on radiation properties, and of the application of this information to the thermal designer's problems. Presentation of data as such-for example, absorptances and emittances of various types of coatings-was not considered a primary purpose of the Symposium; nevertheless, as the reader will observe, an appreciable amount of significant data of this type is contained in some of the papers. Developments in measurement techniques were also not considered basic to the main theme, especially since it was the theme of the preceding Symposium. However, because the subject remains of continuing concern, one session was devoted to it. These Proceedings contain all the papers presented orally at the Symposium together with the discussions that followed them, and, in addition, nine papers that were accepted for publication only. Each paper was reviewed by the session chairman and by the editor, and any apparent technical discrepancies were called to the attention of the author for clarification. As a further aid to the reader, the editor has tried to achieve some degree of uniformity in organization and format of the papers—at least to the extent permitted by the subject matter, and he has also striven for clarity and readability of the text. In this task he has had not only the cooperation of the authors but also extensive help from the Langley Technical Editing Section, the Langley Library (where most of the cited references were checked), and the NASA Headquarters Technical Publications Branch.

Solids