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NASA NTRS1993

Venus' impact-crater database: Update to approximately 98 percent of the planet's surface

A total of 912 impact craters between 1.5 and 280 km in diameter have now been identified on about 98% of Venus' surface. This total includes an additional 71 craters (mostly in the southern hemisphere) not in the crater inventory given in Schaber et al. for 89% of the planet. (Extrapolated to 100% of the surface, the inventory should consist of 930 craters greater than 1.5 km in diameter.) The total crater inventory for 98% of the planet is only slightly larger (912 versus 882) than that extrapolated from the inventory of 135 craters when only 15% of the planet had been mapped by Magellan. The remarkably consistent density of about 2.02 impact craters per 10(exp 6) sq km emphasizes the completely random nature of the crater population's distribution. About 400 craters recognized from Magellan mapping have been assigned names.

Schaber, Gerald G.↗

NASA NTRS1964

Lathe converted for grinding aspheric surfaces

A standard overarm tracing lathe converted by the addition of an independently driven diamond grinding wheel is used for grinding aspheric surfaces. The motion of the wheel is controlled by the lathe air tracer following the template which produces the desired aspheric profile.

Larmer, J. W.↗

DOE OSTI2020

Multi-hydrophilic functional network enables porous membranes excellent anti-fouling performance for highly efficient water remediation

Membrane technology is believed as a cost-effective approach for solving the water issues, where as it suffers from serious membrane fouling. Surface grafting and surface coating have been proved to be effective in abating the membrane fouling; however, these processes always need additional procedures and compromise the initial permeance of the membranes. Herein, we developed a kind of highly permeable polyacrylonitrile (PAN) membranes with excellent anti-fouling performance through one-step phase inversion of the PAN casting solution containing water-soluble active additives. During the process, the water-soluble active additives could segregate towards the membrane surface and pore walls; thereby finely tailoring the pore structures of the PAN-based membranes. Moreover, the active additives could react with each other to form crosslinked networks containing multi-hydrophilic functional groups including CH2-O-CH2, -OH or-Si-OH. Consequently, the PAN-based membranes exhibited surprising superhydrophilicity with water contact angle below 10. even after soaking in water for one week and the anti-fouling permeance of the membranes increased significantly with permeance recovery rate above 93%. Interestingly, the modified membranes also demonstrated both high permeances and high separation efficiency, thereby showing strong promise in water environmental remediation including wastewater treatment and oil/water emulsion separation.

Anti-fouling↗

DOE OSTI2015

Theory of fermion condensation as an analog of the liquid-drop theory of atomic nuclei

We discuss problems of theory of systems with a fermion condensate or, in different words, systems with flat bands pinned to the Fermi surface, employing the duality of the momentum distribution n(p) and the density distribution ρ(r). We propose that the Lifshitz topological phase transition associated with the formation of additional pockets of the Fermi surface is the precursor of fermion condensation.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2018

Observed Surface Disturbances Associated with the DPRK’s 3 September 2017 Underground Nuclear Test

Satellite-based Synthetic Aperture Radar (SAR) data of the Punggye-ri nuclear test site, along with pre- and post-test optical commercial satellite imagery and a short official video (which was apparently recorded during the 3 September 2017 test), provide additional insights on the widespread surface disturbances around the peak of Mt. Mantap. These were generated by North Korea’s sixth and by far largest nuclear test (estimated to be roughly a quarter of a megaton; Zerbo, 2017). Although a number of visible landslides that are associated with this test had been previously reported, these additional data reveal more information about the widespread nature of the detected larger-scale movements that have been reported by other researchers, in addition to some smaller scale instances of localized slumping or compression within the top 200 m of the mountain; these took place in an area that was observed to contain stratified volcanic deposits not otherwise described to date. A closer look at two previously described zones of localized slippage, subsidence, or slumping (located within those identified volcanic layer deposits on the western side of Mt. Mantap) revealed useful information about the landscape of the area. Several healthy trees have been knocked down in one zone; in the other, a rock prominence had collapsed, and a 60-m-long crack or crevice appeared to have opened. It remains unclear whether these surface disturbances were associated with what had been allegedly reported by the news media as a “cave-in that was externally observable.” However, given the likely 800 m depth of the test in the lower hard-rock geology, we have been led to conclude that the notable observed localized surface disturbances cannot be interpreted as a “collapse crater” that was a result of a “cave-in” above any nuclear test created cavity and/or associated tunneling. Although the broadscale nature of the SAR and visually detected movements inhibits more precise geolocation of the test within the mountain, the radar imagery did show that the various surface ground movements were generated in opposing directions. The movements were directed away from the center on either side of the mountain; as such, they provided an empirical basis to confirm the previous seismological estimates that the detonation had occurred somewhere under the peak of Mt. Mantap. Moreover, a North Korean-sourced short video that was acquired with a ground-based camera focused directly on the peak shows a large dust cloud rising up from the mountain. In conclusion, this provides additional evidence that is consistent with that conclusion.

58 GEOSCIENCES↗

DOE OSTI2021

Ce stabilized Ni–SrO as a catalytic phase transition sorbent for integrated CO 2 capture and CH 4 reforming

Integration of carbon dioxide capture from flue gas with dry reforming of CH 4 represents an attractive approach for CO 2 utilization. The selection of a suitable bifunctional material serving as a catalyst/sorbent is the key. This paper reports Ni decorated and CeO x -stabilized SrO (SrCe 0.5 Ni 0.5 ) as a multi-functional, phase transition catalytic sorbent material. The effect of CeO x on the morphology, structure, decarbonation reactivity, and cycling stability of the catalytic sorbent was determined with TEM-EDX, XRD, in situ XRD, CH 4 -TPR and TGA. Here, cyclic process tests were conducted in a packed bed reactor. The results indicate that large Ni clusters were present on the surface of the SrNi sorbent, and the addition of CeO 2 promoted even distribution of Ni on the surface. Moreover, the Ce–Sr interaction promoted a complex carbonation/decarbonation phase-transition, i.e. SrCO 3 + CeO 2 ↔ Sr 2 CeO 4 + CO 2 as opposed to the conventional, simple carbonation/decarbonation cycles (e.g. SrCO 3 ↔ SrO + CO 2 ). This double replacement crystalline phase transition mechanism not only adjusts the carbonation/calcination thermodynamics to facilitate SrCO 3 decomposition at relatively low temperatures but also inhibits sorbent sintering. As a result, excellent activity and stability were observed with up to 91% CH 4 conversion, >72% CO 2 capture efficiency and ~100% residual O 2 capture efficiency from flue gas by utilizing the CeO 2 ↔ Ce 2 O 3 redox transition. This renders an intensified process with zero coke deposition. Moreover, the SLDRM with SrCe 0.5 Ni 0.5 has the flexibility to produce concentrated CO via CO 2 -splitting while co-producing a syngas with tunable H 2 /CO ratios.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1994

Grain rims on ilmenite in the lunar regolith: Comparison to vapor deposits on regolith silicates

In efforts to understand regolith evolution on airless bodies, increasing attention is now being payed to those processes and events that alter or 'weather' the surfaces of regolith grains. This attention has developed partly out of the ongoing need to optimize models of planetary reflectance spectra and the growing recognition that diverse types of grain coatings and surface alterations occur which can strongly influence mineral reflectance properties. In addition to their implications for optical properties, surface features on regolith grains have provided useful clues to the basic thermal, chemical, and radiation history of regoliths.

Christoffersen, R.↗

NASA NTRS2003

High-Resolution Electrospray Ionization/Ion Mobility Spectrometer for Detection of Abiotic Amino Acids

One of the primary goals of the current NASA thrust in Astrobiology is the detection and identification of organic molecules as part of an in-situ lander platform on the surface of Mars or Europa. The identification of these molecules should help determine whether indigenous organisms exist on the surface of Mars or in an undersea environment on Europa. In addition, a detailed organic chemical inventory of surface and near surface molecules will help elucidate the possibilities of life elsewhere in the Universe. Terrestrial life has, as its backbone, the family of molecules known as the amino acids (AA), and while AA can be found in the terrestrial environments as part of more complex molecules, such as peptides, and proteins, they also exist as individual molecules due to of the hydrolyses of biopolymers. In terrestrial biochemistry, there are 20 principal amino acids which are necessary for life. However, some forms of these molecules can be found in nature synthesized via abiotic process. For example, they are known to exist extraterrestrially as a component of carbonaceous meteorites. The idea that amino acids are readily created by abiotic means has been demonstrated by their positive identification in the Murchison CM2 meteorite, which fell in 1969. This meteorite was analyzed before contamination by terrestrial microbes could result. Three laboratories individually tested parts of the meteorite and concluded that the amino acids present in them were indigenous to the meteorite because, among other reasons, they had equal L- and D- enantiomers. Final identification of the constituents of the Murchison included 33 amino acids which have no known biotic source, 11 amino acids which have limited distribution and 8 (Glycine, Alanine, Valine, Proline, Leucine, Isoleucine, Aspartic Acid, and Glutamic Acid), which readily occur in terrestrial proteins.

L W Beegle↗

DOE OSTI2017

Surface registration using a multi-beam optical probe and backscatter reflectometer

We introduce a technique for locating the position and orientation of an object surrounding a compound optical probe. The probe allows for simultaneous measurement of 150 points of laser velocimetry, and prior to a dynamic experiment it is important to know the initial position of the surface. Using an optical switch and a Luna OBR rangefinder, we measure the surface distance at hundreds of locations. These measurements are then combined with a dimensional inspection of the object and analysis routines to report the orientation and location of the inner surface relative to the probe. In addition, we present a technique to simultaneously measure the beam paths using a reference hemispherical surface and a number of distance measurements.

47 OTHER INSTRUMENTATION↗

NASA NTRS1996

Visualizing Vector Fields Using Line Integral Convolution and Dye Advection

We present local and global techniques to visualize three-dimensional vector field data. Using the Line Integral Convolution (LIC) method to image the global vector field, our new algorithm allows the user to introduce colored 'dye' into the vector field to highlight local flow features. A fast algorithm is proposed that quickly recomputes the dyed LIC images. In addition, we introduce volume rendering methods that can map the LIC texture on any contour surface and/or translucent region defined by additional scalar quantities, and can follow the advection of colored dye throughout the volume.

Shen, Han-Wei↗

DOE OSTI2015

The influence of silanized nano-SiO{sub 2} on the hydration of cement paste: NMR investigations

It is known that by adding a small amount of nanoparticles to the cement-based materials a strong influence on the workability, strength and durability is obtained. These characteristics of the material are fundamentally determined by the hydration process taking place after mixing the cement grains with water. In the present study the influence introduced by the addition of nano-silica with silanized surfaces on the hydration process was investigated using low-field nuclear magnetic resonance (NMR) relaxometry. The cement samples were prepared using gray cement at a water-to-cement ratio of 0.4 and a 5% addition of nanosilica. The surface of the nanoparticles was modified using a coating of Silane A174. The cement pastes were monitored during their standard curing time of 28 days. It was established that, by using unmodified nanosilica particles, an acceleration of the hydration process takes place as compared with the pure cement paste. On the other side, by adding silanized nanoparticles, the dormancy stage significantly extends and the hydration process is slower. This slowing down process could enhance the mechanical strength of cement based materials as a result of a better compaction of the hydrated samples.

36 MATERIALS SCIENCE↗

DOE OSTI2015

Development of flexible, free-standing, thin films for additive manufacturing and localized energy generation

Film energetics are becoming increasingly popular because a variety of technologies are driving a need for localized energy generation in a stable, safe and flexible form. Aluminum (Al) and molybdenum trioxide (MoO{sub 3}) composites were mixed into a silicon binder and extruded using a blade casting technique to form flexible free-standing films ideal for localized energy generation. Since this material can be extruded onto a surface it is well suited to additive manufacturing applications. This study examines the influence of 0-35% by mass potassium perchlorate (KClO{sub 4}) additive on the combustion behavior of these energetic films. Without KClO{sub 4} the film exhibits thermal instabilities that produce unsteady energy propagation upon reaction. All films were cast at a thickness of 1 mm with constant volume percent solids to ensure consistent rheological properties. The films were ignited and flame propagation was measured. The results show that as the mass percent KClO{sub 4} increased, the flame speed increased and peaked at 0.43 cm/s and 30 wt% KClO{sub 4}. Thermochemical equilibrium simulations show that the heat of combustion increases with increasing KClO{sub 4} concentration up to a maximum at 20 wt% when the heat of combustion plateaus, indicating that the increased chemical energy liberated by the additional KClO{sub 4} promotes stable energy propagation. Differential scanning calorimeter and thermogravimetric analysis show that the silicone binder participates as a fuel and reacts with KClO{sub 4} adding energy to the reaction and promoting propagation.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Experimental Investigation of Sweeping Jet Film Cooling in a Transonic Turbine Cascade

Abstract The sweeping jet (SJ) film cooling hole has shown promising cooling performance compared to the standard shaped hole in low-speed conditions. The present work demonstrates the first attempt of SJ film cooling at an engine relevant Mach number. An experimental investigation was conducted to study the SJ film cooling on a nozzle guide vane suction surface. A well-established additive manufacturing technique commonly known as stereolithography (SLA) was utilized to design a transonic, engine representative vane geometry in which a row of SJ holes was used on the vane suction surface. Experiments were performed in a linear transonic cascade at an exit Mach number of 0.8 and blowing ratios of BR = 0.25–2.23. The measurement of heat transfer was conducted with the transient IR method, and the convective heat transfer coefficient (HTC) and adiabatic film cooling effectiveness were estimated using a dual linear regression technique (DLRT). Aerodynamic loss measurements were also performed with a total pressure Kiel probe at 0.25Cax downstream of the exit plane of the vane cascade. Experiments were also conducted for a baseline-shaped hole (777-hole) for a direct comparison. Results showed that the SJ hole has a wider coolant spreading in the lateral direction near the hole exit due to its sweeping motion that improves the overall cooling performance particularly at high blowing ratios (BR > 1). Aerodynamic loss measurement suggested that the SJ hole has a comparable total pressure loss to the 777-shaped hole.

Engineering↗

NASA NTRS1933

The Aerodynamic Characteristics of Airfoils as Affected by Surface Roughness

The effect on airfoil characteristics of surface roughness of varying degrees and types at different locations on an airfoil was investigated at high values of the Reynolds number in a variable density wind tunnel. Tests were made on a number of National Advisory Committee for Aeronautics (NACA) 0012 airfoil models on which the nature of the surface was varied from a rough to a very smooth finish. The effect on the airfoil characteristics of varying the location of a rough area in the region of the leading edge was also investigated. Airfoils with surfaces simulating lap joints were also tested. Measurable adverse effects were found to be caused by small irregularities in airfoil surfaces which might ordinarily be overlooked. The flow is sensitive to small irregularities of approximately 0.0002c in depth near the leading edge. The tests made on the surfaces simulating lap joints indicated that such surfaces cause small adverse effects. Additional data from earlier tests of another symmetrical airfoil are also included to indicate the variation of the maximum lift coefficient with the Reynolds number for an airfoil with a polished surface and with a very rough one.

HOCKER RAY W↗

NASA NTRS1995

CO2 (dry ice) cleaning system

Tomco Equipment Company has participated in the dry ice (solid carbon dioxide, CO2) cleaning industry for over ten years as a pioneer in the manufacturer of high density, dry ice cleaning pellet production equipment. For over four years Tomco high density pelletizers have been available to the dry ice cleaning industry. Approximately one year ago Tomco introduced the DI-250, a new dry ice blast unit making Tomco a single source supplier for sublimable media, particle blast, cleaning systems. This new blast unit is an all pneumatic, single discharge hose device. It meters the insertion of 1/8 inch diameter (or smaller), high density, dry ice pellets into a high pressure, propellant gas stream. The dry ice and propellant streams are controlled and mixed from the blast cabinet. From there the mixture is transported to the nozzle where the pellets are accelerated to an appropriate blasting velocity. When directed to impact upon a target area, these dry ice pellets have sufficient energy to effectively remove most surface coatings through dry, abrasive contact. The meta-stable, dry ice pellets used for CO2 cleaning, while labeled 'high density,' are less dense than alternate, abrasive, particle blast media. In addition, after contacting the target surface, they return to their equilibrium condition: a superheated gas state. Most currently used grit blasting media are silicon dioxide based, which possess a sharp tetrahedral molecular structure. Silicon dioxide crystal structures will always produce smaller sharp-edged replicas of the original crystal upon fracture. Larger, softer dry ice pellets do not share the same sharp-edged crystalline structures as their non-sublimable counterparts when broken. In fact, upon contact with the target surface, dry ice pellets will plastically deform and break apart. As such, dry ice cleaning is less harmful to sensitive substrates, workers and the environment than chemical or abrasive cleaning systems. Dry ice cleaning system components include: a dry ice pellet supply, a non-reactive propellant gas source, a pellet and propellant metering device, and a media transport and acceleration hose and nozzle arrangement. Dry ice cleaning system operating parameters include: choice of propellant gas, its pressure and temperature, dry ice mass flow rate, dry ice pellet size and shape, and acceleration nozzle configuration. These parameters may be modified to fit different applications. The growth of the dry ice cleaning industry will depend upon timely data acquisition of the effects that independent changes in these parameters have on cleaning rates, with respect to different surface coating and substrate combinations. With this data, optimization of cleaning rates for particular applications will be possible. The analysis of the applicable range of modulation of these parameters, within system component mechanical constraints, has just begun.

Barnett, Donald M.↗

DOE OSTI2019

Fundamental Surface Science of PFCs for Improved Plasma Performance in NSTX-U

This research applies to improving the plasma performance in the National Spherical Torus Experiment-Upgrade (NSTX-U). NSTX-U will extend the high performance plasmas produced and controlled in NSTX by doubling the heating power and extending the pulse duration by a factor of five. Both of these will substantially raise the thermal stress on plasma facing components (PFCs). Liquid metal-based PFCs, in particular lithium, have been used to improve the plasma performance of many tokamaks, but the predictive understanding needed for confident application of liquid metals and coatings in NSTX-U and future machines is in its infancy. Our work is aimed at applying surface analysis techniques to relevant materials and coatings in a controlled laboratory environment to understand the fundamental surface science and measure key properties that will guide the operations and optimize plasma facing materials at the higher temperatures expected in NSTX-U. Current plans for NSTX-U are to begin operations with carbon PFCs and gradually transition to refractory metal PFCs and liquid metal PFCs toward the end of the first 5 years. Accordingly, our research emphasizes the surface science of lithium on PFC substrates comprised of carbon, molybdenum, and stainless steel. Conditioning of these substrates with boron and the influence of impurities, such as water vapor, present in the tokamak environment will be investigated. These studies make quantitative measurements with low energy ion scattering (LEIS) and high-resolution X-ray photoelectron spectroscopy (HR-XPS) to characterize lithium and complex mixed-material deposits on metal single crystals, e.g. molybdenum, and practical alloys. We utilize ultrathin films of these deposits to be able to follow the surface chemistry and determine stoichiometry. The temperature dependence of surface properties and reactivity is a key parameter. Temperature programmed desorption (TPD) mass spectrometry is utilized to measure deuterium uptake and retention by these materials, and vibrational spectroscopy provides crucial information needed on surface species and chemical compounds. Additional measurements probe diffusion of oxygen into bulk lithium and explore lithium diffusion and wetting on molybdenum and stainless steel. The outcomes of these studies contributes to an improved understanding of plasma surface interactions and specific information needed for NSTX-U operations and the future development of lithium-conditioned plasma-facing components in high-heat flux long-pulse scenarios.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1993

Preliminary Studies Leading Toward the Development of a LIDAR Bathymetry Mapping Instrument

The National Aeronautics and Space Administration (NASA) at Goddard Space Flight Center (GSFC) has developed a laser ranging device (LIDAR) which provides accurate and timely data of earth features. NASA/GSFC recently modified the sensor to include a scanning capability to produce LIDAR swaths. They have also integrated a Global Positioning System (GPS) and an Inertial Navigation System (INS) to accurately determine the absolute aircraft location and aircraft attitude (pitch, yaw, and roll), respectively. The sensor has been flown in research mode by NASA for many years. The LIDAR has been used in different configurations or modes to acquire such data as altimetry (topography), bathymetry (water depth), laser-induced fluorosensing (tracer dye movements, oil spills and oil thickness, chlorophyll and plant stress identification), forestry, and wetland discrimination studies. NASA and HARC are developing a commercial version of the instrument for topographic mapping applications. The next phase of the commercialization project will be to investigate other applications such as wetlands mapping and coastal bathymetry. In this paper we report on preliminary laboratory measurements to determine the feasibility of making accurate depth measurements in relatively shallow water (approximately 2 to 6 feet deep) using a LIDAR system. The LIDAR bathymetry measurements are relatively simple in theory. The water depth is determined by measuring the time interval between the water surface reflection and the bottom surface reflection signals. Depth is then calculated by dividing by the index of refraction of water. However, the measurements are somewhat complicated due to the convolution of the water surface return signal with the bottom surface return signal. Therefore in addition to the laboratory experiments, computer simulations of the data were made to show these convolution effects in the return pulse waveform due to: (1) water depth, and (2) changes in bottom surface reflectivity.

Hill, John M.↗

DOE OSTI2021

Origins of electronic bands in the antiferromagnetic topological insulator MnBi 2 Te 4

Despite the rapid progress in understanding the first intrinsic magnetic topological insulator MnBi 2 Te 4 , its electronic structure remains a topic under debates. In this work, we perform a thorough spectroscopic investigation into the electronic structure of MnBi 2 Te 4 via laser-based angle-resolved photoemission spectroscopy. Through quantitative analysis, we estimate an upper bound of 3 meV for the gap size of the topological surface state. Furthermore, our circular dichroism measurements reveal band chiralities for both the topological surface state and quasi-2D bands, which can be well reproduced in a band hybridization model. A numerical simulation of energy-momentum dispersions based on a four-band model with an additional step potential near the surface provides a promising explanation for the origin of the quasi-2D bands. Our study represents a solid step forward in reconciling the existing controversies in the electronic structure of MnBi 2 Te 4 , and provides an important framework to understand the electronic structures of other relevant topological materials MnBi 2n Te 3n+1 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗