Laser beam directed energy deposition fabrication of MoNbTaTi refractory high entropy alloy via elemental powder processing
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Barrick, Erin Jenna↗
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Directional Solidification and Mechanical Properties of NiAl-NiAlTa Alloys
Directional solidification of eutectic alloys is a promising technique for producing in-situ composite materials exhibiting a balance of properties. Consequently, the microstructure, creep strength and fracture toughness of directionally solidified NiAl-NiAlTa alloys were investigated. Directional solidification was performed by containerless processing techniques to minimize alloy contamination. The eutectic composition was found to be NiAl-15.5 at% Ta and well-aligned microstructures were produced at this composition. A near-eutectic alloy of NiAl-14.5Ta was also investigated. Directional solidification of the near-eutectic composition resulted in microstructures consisting of NiAl dendrites surrounded by aligned eutectic regions. The off-eutectic alloy exhibited promising compressive creep strengths compared to other NiAl-based intermetallics, while preliminary testing indicated that the eutectic alloy was competitive with Ni-base single crystal superalloys. The room temperature toughness of these two-phase alloys was similar to that of polycrystalline NiAl even with the presence of the brittle Laves phase NiAlTa.
Johnson, D. R.↗
Comparison of Iterative and Non-Iterative Strain-Gage Balance Load Calculation Methods
The accuracy of iterative and non-iterative strain-gage balance load calculation methods was compared using data from the calibration of a force balance. Two iterative and one non-iterative method were investigated. In addition, transformations were applied to balance loads in order to process the calibration data in both direct read and force balance format. NASA's regression model optimization tool BALFIT was used to generate optimized regression models of the calibration data for each of the three load calculation methods. This approach made sure that the selected regression models met strict statistical quality requirements. The comparison of the standard deviation of the load residuals showed that the first iterative method may be applied to data in both the direct read and force balance format. The second iterative method, on the other hand, implicitly assumes that the primary gage sensitivities of all balance gages exist. Therefore, the second iterative method only works if the given balance data is processed in force balance format. The calibration data set was also processed using the non-iterative method. Standard deviations of the load residuals for the three load calculation methods were compared. Overall, the standard deviations show very good agreement. The load prediction accuracies of the three methods appear to be compatible as long as regression models used to analyze the calibration data meet strict statistical quality requirements. Recent improvements of the regression model optimization tool BALFIT are also discussed in the paper.
Ulbrich, N.↗
Direct Ionization from Low-Energy Electrons in a Highly-Scaled CMOS Process
Low-energy-electron-induced single-event upsets are observed in a 22 nm fully-depleted silicon-on-insulator process at nominal and higher supply voltages. Electron dose enhancement was also observed.
low-energy electrons↗
Predicting initial trans-membrane pressure across cycles in the ultrafiltration process using random forest
With growing freshwater scarcity, direct potable reuse (DPR) systems that reclaim wastewater for drinking are becoming increasingly important for sustainable water supply. Reliable operation requires minimizing downtime in ultrafiltration (UF) units, where membrane fouling leads to elevated trans-membrane pressure (TMP). This study develops data-driven regression models based on random forest (RF) and autoregressive (AR) approaches to forecast the initial TMP at the start of each UF filtration cycle in a pilot-scale DPR system. The RF model consistently outperforms baseline methods, including historical mean, last observation carried forward, and AR models, across multiple forecast horizons, achieving the lowest root mean square error. To evaluate how different classes of process variables contribute to TMP dynamics over time, we examine the feature importance of independent input variables across multiple forecast horizons. This analysis provides insight into the temporal relevance of operational and sensor-derived features, guiding control and monitoring strategies. Additionally, the impact of hyperparameter tuning on TMP prediction performance is assessed for both direct and recursive RF modelling approaches. The proposed RF framework establishes a robust foundation for predictive monitoring and real-time optimization of UF operations, supporting sustainable and reliable water reuse.
direct potable reuse↗
Experimental Validation and Continuous Testing of an On-Purpose High-Yield Pitch Synthesis Process for Producing Carbon Fiber from US Domestic Coal
This project aims to develop technology that converts domestic United States (US) raw coal to high quality, high value, and marketable carbon fiber. More specifically, the project aims to significantly improve the selectivity and yield of carbon fiber produced per ton of coal over conventional coal pitch-based production by using low-severity direct coal conversion technology to maximize the yield of pitch from coal, suitable for production of carbon fiber. To meet the stated objective of developing a technology platform, capable of producing high quality, high-value and marketable carbon fiber from domestic US coal, the proposed scope of work involves testing of a low-severity direct coal liquefaction (LS-DCL) process approach. The isotropic pitch produced from the LS-DCL process will be thermally treated using conventional processes to convert to a liquid crystal or “mesophase” pitch as a precursor for structural carbon fibers. This mesophase pitch will then be melt-spun into fiber, oxygen stabilized, and carbonized using conventional processes. The resulting carbon fiber will be evaluated for mechanical properties and suitability for structural applications such as automotive parts and spars for wind turbine blades. The overall process is expected to significantly lower the cost of fiber compared to state of the art fibers produced from polyacrylonitrile (PAN) precursors.
01 COAL, LIGNITE, AND PEAT↗
A model to investigate the influence of suspended sediment on the mass transport of a pollutant in open channel flow
An explicit two-dimensional finite difference model, designed to investigate the influence of suspended sediment on the pollutant transport process, is presented. Specific attention is directed toward examining the role of suspended sediment in: (1) the turbulent vertical transport mechanism in a stratified flow, and (2) pollutant uptake due to sorption. Results presented indicate that suspended sediment plays a major role in the pollutant transport process, and subsequently, any meaningful attempt to model the fate of a pollutant in an alluvial channel must account for the presence of a suspended sediment concentration profile. Similarly, the vertical and longitudinal pollutant concentration distributions provided by the model may be utilized to improve upon the predictive capacities of existing water quality models.
Chapman, R. S.↗
Computer-Aided Parallelizer and Optimizer
The Computer-Aided Parallelizer and Optimizer (CAPO) automates the insertion of compiler directives (see figure) to facilitate parallel processing on Shared Memory Parallel (SMP) machines. While CAPO currently is integrated seamlessly into CAPTools (developed at the University of Greenwich, now marketed as ParaWise), CAPO was independently developed at Ames Research Center as one of the components for the Legacy Code Modernization (LCM) project. The current version takes serial FORTRAN programs, performs interprocedural data dependence analysis, and generates OpenMP directives. Due to the widely supported OpenMP standard, the generated OpenMP codes have the potential to run on a wide range of SMP machines. CAPO relies on accurate interprocedural data dependence information currently provided by CAPTools. Compiler directives are generated through identification of parallel loops in the outermost level, construction of parallel regions around parallel loops and optimization of parallel regions, and insertion of directives with automatic identification of private, reduction, induction, and shared variables. Attempts also have been made to identify potential pipeline parallelism (implemented with point-to-point synchronization). Although directives are generated automatically, user interaction with the tool is still important for producing good parallel codes. A comprehensive graphical user interface is included for users to interact with the parallelization process.
Jin, Haoqiang↗
Directional measurement of short ocean waves with stereophotography
Stereophotographs of the sea surface, acquired during the Tower Ocean Wave and Radar Dependence experiment are analyzed to yield directional wave height spectra of short surface waves in the 6-80-cm range. The omnidirectional wave height spectra are found to deviate from the k exp -4 distribution, where k is the wave number. The stereo data processing errors are found to be within + or - 5 percent. The omnidirectional spectra yield 514 deg of freedom for 30-cm-long waves. The directional distribution of short waves is processed with a directional resolution of 30 deg, so as to yield 72 deg of freedom for 30-cm-long waves. The directional distributions show peaks that are aligned with the wind and swell directions. It is found that dynamically relevant measurements can be obtained with stereophotography, after removal of the mean surface associated with long waves.
Shemdin, Omar H.↗
The Sudbury Structure (Ontario, Canada) and Vredefort Structure (South Africa): A comparison
Both the Sudbury Structure (SS) and the Witwatersrand Basin surrounding the Vredefort Structure (VS) host some of the most important base and precious metal deposits on earth. In both structures Precambrian igneous, sedimentary and volcanic rocks were affected by the structure forming process, either meteorite impact or endogenic explosion, or as some VS workers propose, by high strain tectonics. Besides these general features there are some geological and geophysical characteristics that are strikingly similar in both structures. There are, however, some obvious differences. Directly related to the structure forming processes are breccias in the footwall rocks of both structures. Pseudotachylite breccias occurring in both structures display great similarities. Chemical and physical characteristics of the pseudotachylites are similar in both structures. Both structures are characterized by overturned collar rocks, not evident everywhere around the SS. The VS is rimmed by an up or overturned collar of sediments and volcanics of the Witwatersrand, Ventersdorp and Transvaal Supergroups. Drilling information proved that the strata of the Witwatersrand Supergroup in the south of the VS are lying horizontally. Shockmetamorphic features such as planar microdeformations in rock forming minerals and shatter cones are present in both structures in the footwall rocks and in the SS also in the breccias of the OF. Both structures have large geophysical anomalies associated with them. In both structures the anomalies were interpreted as being caused by mafic-ultramafic complexes underlying the structures.
Dressler, B. O.↗
Exploring Dust Impacts on Tropical Systems from the NASA HS-3 Field Campaign
One of the overall scientific goals of the NASA Hurricane and Severe Storm Sentinel (HS-3) field campaign is to better understand the role of the Saharan Air Layer (SAL) in tropical storm development. During the 2012 HS-3 deployment, the Cloud Physics Lidar (CPL) observed dust within SAL air in close proximity to a developing Nadine (September 11, 2012). Throughout the mission, the NASA GEOS-5 modeling system supported HS-3 by providing 0.25 degrees resolution 5-day global forecasts of aerosols, which were used to support mission planning. The aerosol module was radiatively interactive within the GEOS-5 model, but aerosols were not directly coupled to cloud and precipitation processes. In this study we revisit the aerosol forecasts with an updated version of the GEOS-5 model. For the duration of Hurricane Nadine, we run multiday climate simulations leading up to each respective Global Hawk flight with and without aerosol direct interaction. For each set of simulations, we compare simulated dust mass fluxes to identify differences in SAL entrainment related to the interaction between dust aerosols and the atmosphere. We find that the direct effects of dust induce a low level anticyclonic circulation that temporarily shields Nadine from the intrusion of dry air, leading to a more intense storm.
hurricanes↗
Finding the Needles in the Haystacks: High-Fidelity Models of the Modern and Archean Solar System for Simulating Exoplanet Observations
We present two state-of-the-art models of the solar system, one corresponding to the present day and one to the Archean Eon 3.5 billion years ago. Each model contains spatial and spectral information for the star, the planets, and the interplanetary dust, extending to 50 au from the Sun and covering the wavelength range 0.3-2.5 micron. In addition, we created a spectral image cube representative of the astronomical backgrounds that will be seen behind deep observations of extrasolar planetary systems, including galaxies and Milky Way stars. These models are intended as inputs to high-fidelity simulations of direct observations of exoplanetary systems using telescopes equipped with high-contrast capability. They will help improve the realism of observation and instrument parameters that are required inputs to statistical observatory yield calculations, as well as guide development of post-processing algorithms for telescopes capable of directly imaging Earth-like planets.
extrasolar planetary systems↗
Near-canopy horizontal concentration heterogeneity of semivolatile oxygenated organic compounds and implications for 2-methyltetrols primary emissions
Semivolatile oxygenated organic compounds (SV-OVOCs) are important atmospheric species, in particular for the production and chemistry of atmospheric particulate matter and related impacts on air quality and climate. In this study, SV-OVOCs were collected in the horizontal plane of the roughness layer over the tropical forest in the central Amazon during the wet season of 2018. A sampler mounted to a copter-type, hovering unmanned aerial vehicle was used. Underlying the collection region, a plateau forest transitioned into a slope forest across several hundred meters. The concentrations of pinonic and pinic acids, which are monoterpene oxidation products, had no statistical difference over the two forests. By comparison, across the study period, differences in the concentration of 2-methyltetrols, which are products of isoprene oxidation, ranged from -70% to +480% over the two forests. The chemical lifetime of 2-methyltetrols in the atmosphere is sufficiently long that heterogeneity in the isoprene emission rate from the two forests followed by atmospheric oxidation does not explain the concentration heterogeneity of 2-methyltetrols. Standing waves and local meteorology also cannot account for the heterogeneity. Of the possibilities considered, the most plausible explanation is the direct emission from the forest of 2-methyltetrols produced through biological processes within the plants. Under this explanation, the rate of direct SV-OVOC emissions should be modulated by forest type and related environmental stressors. Direct emissions of SV-OVOCs should be more broadly considered for constraining and improving models of atmospheric composition, transport, and chemistry over tropical forests.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Nonprompt direct-photon production in Au + Au collisions at $\sqrt{s_{NN}}$ = 200 GeV
The measurement of the direct-photon spectrum from Au + Au collisions at $\sqrt{s_{NN}}$ = 200 GeV is presented by the PHENIX Collaboration using the external-photon-conversion technique for 0%–93% central collisions in a transverse-momentum (𝑝 𝑇 ) range of 0.8–10 GeV/𝑐. An excess of direct photons, above prompt-photon production from hard-scattering processes, is observed for 𝑝 𝑇 < 6 GeV/𝑐. Nonprompt direct photons are measured by subtracting the prompt component, which is estimated as 𝑁 coll -scaled direct photons from 𝑝 + 𝑝 collisions at 200 GeV, from the direct-photon spectrum. Results are obtained for 0.8 < 𝑝 𝑇 < 6.0 GeV/𝑐 and suggest that the spectrum has an increasing inverse slope from ≈0.2 to 0.4 GeV/𝑐 with increasing 𝑝 𝑇 , which indicates a possible sensitivity of the measurement to photons from earlier stages of the evolution of the collision. In addition, like the direct-photon production, the 𝑝 𝑇 -integrated nonprompt direct-photon yields also follow a power-law scaling behavior as a function of collision-system size. Finally, the exponent, 𝛼, for the nonprompt component is found to be consistent with 1.1 with no apparent 𝑝 𝑇 dependence.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Laser-driven hydrothermal processing
Systems for processing a material by submerging the material in a fluid and directing laser pulses at the fluid and the material for processing the material. An embodiment removes the surface of concrete, brick, or rock or minerals in a relatively gentle, energy-efficient, and controlled manner that also confines the material that is removed.
36 MATERIALS SCIENCE↗
Laser-driven hydrothermal processing
Systems for processing a material by submerging the material in a fluid and directing laser pulses at the fluid and the material for processing the material. An embodiment removes the surface of concrete, brick, or rock or minerals in a relatively gentle, energy-efficient, and controlled manner that also confines the material that is removed.
Mariella, Jr., Raymond P.↗
Laser-driven hydrothermal processing
Systems for processing a material by submerging the material in a fluid and directing laser pulses at the fluid and the material for processing the material. An embodiment removes the surface of concrete, brick, or rock or minerals in a relatively gentle, energy-efficient, and controlled manner that also confines the material that is removed.
Mariella, Jr., Raymond P.↗
Discontinuous Aligned Carbon Fiber Intermediates for Automotive and Related Applications
This work focused on preferentially aligning discontinuous carbon fibers in wet-laid or air-laid processes. It is well known that aligned fibers provides higher directional strength and stiffness. Discontinuous fibers further allow higher degree of draw and formability as the gaps in the fibers allow for higher material movement. The current processes are limited in their ability to align carbon fibers during processing. The aligned fibers have several benefits - (a) in applications where chopped fibers can replace continuous fibers for targeted strength and stiffness metrics, but at a substantially reduced cost; (b) they can tolerate deeper draws than continuous fiber composites in thermo-stamping and compression molding processes; (c) they can be tailored for pultrusion and unidirectional applications. Although pultrusion is primarily a process that adopts continuous fibers, stitch bonded entangled discontinuous fibers can provide unique intermediates. This is analogous to natural coir fibers which get aligned and entangled to produce ropes/rods for example, (d) they can be processed in cross-ply and multi-directional formats, like composite laminates. In this work Neenah Paper partnered with IACMI, UT and ORNL to evaluate structure-process-property relationships with Zoltek carbon fiber. A few process parameters such as machine speed, weight basis, fiber length, effect of fiber sizing, direction of mat lay-up etc. were investigated. The produced mats were converted to thermoplastic composite laminates using polyamide 6 (PA6, nylon) resin. The specific objective of this project is to produce a wet-laid nonwoven carbon fiber mat with a high degree of unidirectional fiber alignment, using discontinuous carbon fibers. The report provides details about the processing, characterization, and lower-upper bound properties.
36 MATERIALS SCIENCE↗